专利快速检索-快速检索全球专利，免费商用专利数据库-IPRDB

1. 发明授权

US5728884A Process for the work-up of complex amine hydrofluroides 失效
标题翻译：复杂胺氢氟酸的处理方法
公开(公告)号：US5728884A
公开(公告)日：1998-03-17
申请号：US574221
申请日：1995-12-18
申请人： Ulrich Hahn , Raimund Franz , Gunter Siegemund
发明人： Ulrich Hahn , Raimund Franz , Gunter Siegemund
IPC分类号： C07B39/00 , C07C17/087 , C07C17/38 , C07C209/86 , C07C211/03 , C07C211/07 , C07C209/84
CPC分类号： C07C17/38 , C07B39/00 , C07C17/087 , C07C209/86
摘要： The invention relates to a process for the work-up of a liquid complex hydrofluoride of a tertiary amine of the formula (I) �R.sup.1 R.sup.2 R.sup.3 N.multidot.n HF!, where the radicals R.sup.1, R.sup.2 and R.sup.3 are C.sub.1 -C.sub.8 -alkyl groups which together have at least 7 carbon atoms and n is an integer or fractional number where 1.5
摘要翻译：本发明涉及一种用于处理式（I）[R1R2R3NxnHF]的叔胺的液体复合氢氟酸的方法，其中基团R 1，R 2和R 3是C 1 -C 8烷基，它们共同具有至少7个碳原子，n是整数或分数，其中1.5

2. 发明授权

US5969199A Process for the addition of HF to halogenated alkenes 失效
标题翻译：向卤代烯烃中加入HF的方法
公开(公告)号：US5969199A
公开(公告)日：1999-10-19
申请号：US93534
申请日：1998-06-08
申请人： Raimund Franz , Gunter Siegemund
发明人： Raimund Franz , Gunter Siegemund
IPC分类号： C07C17/20 , C07B61/00 , C07C17/087 , C07C19/08
CPC分类号： C07C17/087
摘要： The invention relates to a process for the addition of HF to halogenated alkenes by reacting these with at least one hydrofluoride of the formula [B.cndot.n HF], in which B is an organic nitrogen base and n is an integer or fraction .ltoreq.4, it being intended that the reaction of perfluoroiso-butene CF.sub.2 =C(CF.sub.3).sub.2 is excluded.
摘要翻译：本发明涉及通过使这些与至少一种式[Bn HF]的氢氟酸反应，其中B是有机氮碱并且n是整数或分数的方法，将HF加成到卤代烯烃中的方法，意图是排除全氟异丁烯CF 2 = C（CF 3）2的反应。

3. 发明授权

US5847245A Process for the addition of HF to halogenated alkenes 失效
标题翻译：向卤代烯烃中加入HF的方法
公开(公告)号：US5847245A
公开(公告)日：1998-12-08
申请号：US723462
申请日：1996-10-09
申请人： Raimund Franz , Gunter Siegemund
发明人： Raimund Franz , Gunter Siegemund
IPC分类号： C07C17/20 , C07B61/00 , C07C17/087 , C07C19/08
CPC分类号： C07C17/087
摘要： The invention relates to a process for the addition of HF to halogenated alkenes by reacting these with at least one hydrofluoride of the formula �B.n HF!, in which B is an organic nitrogen base and n is an integer or fraction .ltoreq.4, it being intended that the reaction of perfluoroisobutene CF.sub.2 .dbd.C(CF.sub.3).sub.2 is excluded.
摘要翻译：本发明涉及通过使这些与至少一种式[Bn HF]的氢氟酸反应，其中B是有机氮碱并且n是整数或分数的方法将HF加成到卤代烯烃中的方法，意图是排除全氟异丁烯CF 2 = C（CF 3）2的反应。

4. 发明授权

US5684193A Process for the preparation of perfluoropropionyl fluoride 失效
标题翻译：制备全氟丙酰氟的方法
公开(公告)号：US5684193A
公开(公告)日：1997-11-04
申请号：US745816
申请日：1996-11-12
申请人： Gunter Siegemund , Raimund Franz
发明人： Gunter Siegemund , Raimund Franz
IPC分类号： B01J31/02 , C07B61/00 , C07C51/58 , C07C53/50
CPC分类号： C07C51/58
摘要： The invention relates to a process for the preparation of perfluoropropionyl fluoride (II) by the isomerization of hexafluoropropene oxide (I): ##STR1## wherein the reaction medium used is a liquid complex ammonium hydrofluoride.
摘要翻译：本发明涉及通过六氟丙烯氧化物（I）的异构化制备全氟丙酰氟（II）的方法：其中所用的反应介质是液体复合氢氟酸铵。

5. 发明授权

US5399795A Process for the preparation of 2-H-heptafluoropropane 失效
标题翻译：制备2-H-七氟丙烷的方法
公开(公告)号：US5399795A
公开(公告)日：1995-03-21
申请号：US273945
申请日：1994-07-12
申请人： Raimund Franz , Gunter Siegemund
发明人： Raimund Franz , Gunter Siegemund
IPC分类号： B01J31/08 , C07B61/00 , C07C17/087 , C07C19/08 , C07C17/08
CPC分类号： C07C17/087
摘要： The invention relates to a process for the preparation of 2-H-heptafluoropropane, wherein hexafluoropropene is reacted with hydrogen fluoride in the presence of a weakly basic ion exchanger whose reactive centers comprise tertiary amino groups.
摘要翻译：本发明涉及一种制备2-H-七氟丙烷的方法，其中六氟丙烯在反应中心包含叔氨基的弱碱性离子交换剂存在下与氟化氢反应。

6. 发明授权

US5912392A Process for the preparation of 2H-heptafluoropropane 失效
标题翻译：制备2H-七氟丙烷的方法
公开(公告)号：US5912392A
公开(公告)日：1999-06-15
申请号：US842119
申请日：1997-04-28
申请人： Helmut Vollmueller , Raimund Franz , Guenter Siegemund
发明人： Helmut Vollmueller , Raimund Franz , Guenter Siegemund
IPC分类号： B01J31/02 , C07B61/00 , C07C17/087 , C07C19/08 , C07C17/08
CPC分类号： C07C17/087
摘要： Process for the preparation of 2H-heptafluoropropane from hexafluoropropene and hydrogen fluoride in an apparatus equipped with bubble columns fitted with flow resistances, in which a liquid hydrofluoride of an organic base circulates.
摘要翻译：在具有装配有流动阻力的气泡塔的装置中，六氟丙烯和氟化氢制备2H-七氟丙烷的方法，其中有机碱的液体氢氟酸循环。

7. 发明授权

US4260561A Process for the preparation of carbonyl difluorides 失效
标题翻译：羰基二氟化物的制备方法
公开(公告)号：US4260561A
公开(公告)日：1981-04-07
申请号：US43736
申请日：1979-05-30
申请人： Raimund Franz
发明人： Raimund Franz
IPC分类号： C01B31/28 , C01B31/00 , C07C51/58 , C07C51/04
CPC分类号： C01B31/00 , C07C51/58
摘要： Carbonyl difluorides of the formulaF--(CO).sub.n --F,in which n is 1 (difluorophosgene) or 2 (oxalyl fluoride), are prepared by fluorination of the corresponding carbonyl dichlorides (phosgene, oxalyl chloride) with HF in the presence of CH.sub.3 CN and optionally also of a tertiary amine which binds HCl.
摘要翻译：通过在CH 3 CN存在下用HF氟化相应的羰基二氯（光气，草酰氯）制备其中n为1（二氟光气）或2（草酰氟）的式F-（CO）nF的羰基二氟化物，也可任选地结合HCl的叔胺。

8. 发明授权

US4847372A Process for the single-stage preparation of glycosyl fluorides 失效
标题翻译：单阶段制备糖基氟化物的方法
公开(公告)号：US4847372A
公开(公告)日：1989-07-11
申请号：US45752
申请日：1987-04-28
申请人： Raimund Franz , Hans M. Deger , Merten Schlingmann
发明人： Raimund Franz , Hans M. Deger , Merten Schlingmann
IPC分类号： C07H1/00 , C07H5/02 , C07H13/04
CPC分类号： C07H13/04 , C07H5/02
摘要： A process for the single-stage preparation of glycosyl fluorides by dissolving saccharides in liquid hydrogen fluoride and evaporating the hydrogen fluoride, wherein the resulting glycosyl fluoride is isolated in such a way that, when the evaporation of the hydrogen fluoride is started at a relatively high temperature, in general at -20.degree. to +20.degree. C., the evaporation is effected at a high evaporation rate or, when a low evaporation rate is used at the start of the evaporation, a sufficiently low temperature is set, in general -80.degree. C. to -30.degree. C.
摘要翻译：通过将糖溶解在液体氟化氢中并蒸发氟化氢来单级制备糖基氟化物的方法，其中所得的糖基氟化物以这样的方式被分离，使得当氟化氢的蒸发以相对较高的速度开始时温度通常在-20℃至+ 20℃，蒸发是以高蒸发速率进行的，或者当在蒸发开始时使用低蒸发速率时，设定足够低的温度， 80℃〜-30℃

9. 发明授权

US4766207A Process for the preparation of water-soluble polysaccharides, the saccharides thus obtainable, and their use 失效
标题翻译：制备水溶性多糖，所得糖类及其用途的方法
公开(公告)号：US4766207A
公开(公告)日：1988-08-23
申请号：US748934
申请日：1985-06-26
申请人： Hans-Matthias Deger , Rudiger Erckel , Raimund Franz , Wolfram Fritsche-Lang , Gert-Wolfhard von Rymon Lipinski , Merten Schlingmann
发明人： Hans-Matthias Deger , Rudiger Erckel , Raimund Franz , Wolfram Fritsche-Lang , Gert-Wolfhard von Rymon Lipinski , Merten Schlingmann
IPC分类号： A23G3/34 , A23L1/308 , C08B37/00 , A21D13/08 , A23G3/00 , A23L1/30
CPC分类号： C08B37/0009 , A23G3/346 , A23L33/24 , A23G2200/06
摘要： Polysaccharides built up from anhydroglucose are obtained when glucose or carbohydrates containing glucose as the monomer structural unit are condensed with polyhydric alcohols in hydrogen fluoride. The products may be used as water binding agents and water retaining agents, especially for dietetic foodstuffs.
摘要翻译：当葡萄糖或葡萄糖作为单体结构单元的碳水化合物与氟化氢中的多元醇缩合时，可获得由脱水葡萄糖构成的多糖。该产品可用作水结合剂和保水剂，特别是用于饮食食品。

10. 发明授权

US4556432A Process for hydrolyzing cellulose-containing material with gaseous hydrogen fluoride 失效
标题翻译：用氟化氢气水解含纤维素材料的方法
公开(公告)号：US4556432A
公开(公告)日：1985-12-03
申请号：US710533
申请日：1985-03-12
申请人： Rudiger Erckel , Raimund Franz , Rolf Woernle , Theodor Riehm
发明人： Rudiger Erckel , Raimund Franz , Rolf Woernle , Theodor Riehm
IPC分类号： C13K1/02
CPC分类号： C13K1/02
摘要： The continuous process for hydrolyzing cellulose-containing material (substrate) is carried out by sorption of gaseous HF in a sorption reaction (1) and subsequent desorption in n steps, which are carried out in n reactors which are separated from one another in a gas-tight manner. The substrate is introduced via a gas-tight valve into the sorption reactor (1), passes through this and then reaches consecutively, through gas-tight valves, a hold-up reactor (2) and the first (3c), second (3b), . . . nth desporption reactor, from which it is then removed. The desorption is carried out in each case by the action of one of the n inert gas streams on the substrate at different temperatures, the particular inert gas stream being enriched with the HF being liberated during desorption. The gas streams, which are enriched to different extents with HF, are allowed to act on the substrate in the sorption reactor (1) in such a manner that the gas streams of low HF concentration act on a substrate having a zero or low concentration of HF and thereafter the gas streams of higher HF concentration act on substrate having higher HF concentration. The total gas stream (8a) produced from the individual gas streams leaves, after completion of sorption, the sorption reactor (1) largely freed of HF and is either conveyed to the desorption steps after dividing up into individual gas streams or it initially passes through the last desorption step (3a) and is thereafter divided up and passed to the other desorption steps in order, after passing through the latter, to be returned to the sorption reactor (1).
摘要翻译：用于水解含纤维素的材料（底物）的连续方法是通过在吸附反应（1）中吸附气态HF并随后在n个步骤中脱附进行的，其在n个反应器中进行，这些反应器在气体中彼此分离轻松的方式将衬底通过气密阀引入吸附反应器（1）中，通过该吸附反应器（1），然后连续地通过气密阀，保持反应器（2）和第一（3c），第二（3b）），。。。第n个分离反应器，然后从中除去。在每种情况下，通过在不同温度下的衬底上的n个惰性气体流中的一个的作用进行解吸，在解吸期间富集HF的特定惰性气体流被释放。允许用HF富集到不同程度的气流以这样的方式作用在吸附反应器（1）中的衬底上，使得低HF浓度的气流作用在具有零或低浓度的 HF，此后较高HF浓度的气流作用于具有较高HF浓度的底物上。由各个气流产生的总气流（8a）在吸附完成之后离开吸附反应器（1），大部分不含HF，并且在分成单独的气流之后被输送到解吸步骤，或者最初通过最后解吸步骤（3a），然后分级并依次通过另一个解吸步骤，然后通过该脱附步骤返回到吸附反应器（1）。

你已经成功收藏专利！

检索式保存成功!

IPRDB

热门服务

关于我们

友情链接

联系方式