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1. 发明授权

US5532329A Copolymers and mixtures which are self-curable with atmospheric humidity 失效
标题翻译：在大气湿度下可自行固化的共聚物和混合物
公开(公告)号：US5532329A
公开(公告)日：1996-07-02
申请号：US365316
申请日：1994-12-28
申请人： Ulrich Filges , Oral Aydin , Gerhard Auchter , Juergen Barwich , Hermann Anders , Werner Langer , Klaus Vorspohl
发明人： Ulrich Filges , Oral Aydin , Gerhard Auchter , Juergen Barwich , Hermann Anders , Werner Langer , Klaus Vorspohl
IPC分类号： C08L33/00 , C08F2/38 , C08F8/00 , C08F8/30 , C08F8/46 , C08F218/04 , C08F220/12 , C08F220/18 , C08G18/30 , C08G18/32 , C08G18/62 , C08G18/72 , C08K5/54 , C08L33/04 , C08L33/06 , C08L75/00 , C08L75/04 , C09D175/00 , C09J175/00 , C09K3/10 , C08F230/08 , C08F220/08 , C08F220/10 , C08F220/52 , C08F226/02
CPC分类号： C08F8/00 , C08F2/38 , C08F218/04 , C08F220/12 , C08F220/18 , C08F8/30 , C08F8/46 , C08G18/307 , C08G18/3256 , C08G18/6229 , C08G18/6245 , C08G18/728 , C08K5/5406
摘要： Copolymers which are self-curable with atmospheric humidity and are based on acrylic, methacrylic and/or vinyl esters which have been prepared using silicon-containing regulators, and mixtures of such polymers with crosslinkers, are suitable as adhesive, sealing and coating compositions which are self-curable with atmospheric humidity.
摘要翻译：在大气湿度下可自行固化并基于使用含硅调节剂制备的丙烯酸，甲基丙烯酸和/或乙烯基酯的共聚物，以及这些聚合物与交联剂的混合物，可适用作粘合剂，密封和涂料组合物可固化与大气湿度。

2. 发明授权

US5298554A Polymers of olefinically unsaturated monomers and solutions of these polymers 失效
标题翻译：烯属不饱和单体的聚合物和这些聚合物的溶液
公开(公告)号：US5298554A
公开(公告)日：1994-03-29
申请号：US721836
申请日：1991-06-26
申请人： Gerd Rehmer , Juergen Barwich , Gerhard Auchter
发明人： Gerd Rehmer , Juergen Barwich , Gerhard Auchter
IPC分类号： C08F2/00 , C08F2/04 , C08F2/06 , C08F220/10 , C08F220/18 , C08L33/04 , C08L33/08 , C09J133/04 , C09J133/08 , C08F20/02 , C08F20/56 , C08F20/68
CPC分类号： C08F2/06
摘要： Abstract of the Disclosure: Polymers of olefinically unsaturated monomers and solutions of these polymers are obtainable by a process in which the olefinically unsaturated monomers are polymerized in the presence of a free radical initiator in solution under polymerization conditions which are otherwise predetermined, in such a way that the solvent and/or a liquid part of one or more reactants of the polymerization batch are initially taken and heated to the polymerization temperature, and some or the total amount of the monomers to be polymerized is fed continuously to the agitated initially taken part of the polymerization batch via one or more feeds, with maintenance or initiation of the polymerization, in such a way that the outlet orifice of the one or more feeds is located below the surface of the initially taken liquid part of the polymerization batch.
摘要翻译：摘要：烯属不饱和单体的聚合物和这些聚合物的溶液可通过其中烯属不饱和单体在自由基引发剂存在下在溶液中在聚合条件下进行聚合的方法获得，这些聚合条件以其它方式预先确定首先将聚合批料的一种或多种反应物的溶剂和/或液体部分取出并加热至聚合温度，并将待聚合的单体的一些或总量连续供给到搅拌的初始取出的部分通过一个或多个进料的聚合批料，维持或开始聚合，使得一种或多种进料的出口孔位于聚合批料的初始取出的液体部分的表面下方。

3. 发明授权

US5532321A Copolymers and blends which are self-curable under the action of atmospheric humidity 失效
标题翻译：在大气湿度作用下可自行固化的共聚物和共混物
公开(公告)号：US5532321A
公开(公告)日：1996-07-02
申请号：US238901
申请日：1994-05-06
申请人： Juergen Barwich , Heinz Plaumann , Eckehardt Wistuba
发明人： Juergen Barwich , Heinz Plaumann , Eckehardt Wistuba
IPC分类号： C08L31/02 , C08F218/04 , C08F220/12 , C08L31/04 , C08L33/04 , C08L33/06 , C08L43/00 , C08L43/04 , C09D133/04 , C09D133/06 , C09D137/00 , C09D143/04 , C09J131/00 , C09J131/02 , C09J133/04 , C09J133/06 , C09J137/00 , C09J143/04 , C09K3/10 , C08F222/06
CPC分类号： C09J143/04 , C08F218/04 , C08F220/12 , C09D143/04
摘要： Essentially isocyanate-free, ketimine- and aldimine-free, one-component sealing, adhesive or coating materials which are self-curable under the action of atmospheric humidity containing a copolymer A composed of50-99.8% by weight of a C.sub.1 -C.sub.16 -alkyl (meth)acrylate or vinyl ester of carboxylic acids of 1 to 20 carbon atoms a),0.1-20% by weight of an unsaturated carboxylic anhydride b),0.1-10% by weight of an Si-containing compound c) capable of undergoing hydrolysis and0-40% by weight of a further, copolymerizable unsaturated compound d)or containing a mixture of copolymers comprising5-95% by weight, based on the mixture, of a copolymer B), composed of50-99.9% by weight of a C.sub.1 -C.sub.16 -alkyl (meth)acrylate or vinyl ester of carboxylic acids of 1 to 20 carbon atoms a),0-20% by weight of an unsaturated carboxylic anhydride b)0.1-10% by weight of an Si-containing compound c) capable of undergoing hydrolysis and0-40% by weight of a further, copolymerizable unsaturated compound d)and5-95% by weight, based on the mixture, of a copolymer C) composed of50-99.9% by weight of a C.sub.1 -C.sub.16 -alkyl (meth)acrylate or vinyl ester of carboxylic acids of 1 to 20 carbon atoms a),0.1-20% by weight of an unsaturated carboxylic anhydride b),0-10% by weight of an Si-containing compound c) capable of undergoing hydrolysis and0-40% by weight of a further, copolymerizable unsaturated compound d),the K value of one of the copolymers B) or C) being from 12 to 40 and that of the other copolymer being from 30 to 70 and the K values of the two copolymers differing by at least 5K value units, where the K value is measured according to DIN 53,726.
摘要翻译：基本上无异氰酸酯，不含酮亚胺和不含亚胺基的单组分密封，粘合剂或涂层材料，其在大气湿度的作用下可自行固化，包含由50-99.8重量％的C1-C16- （甲基）丙烯酸烷基酯或1-20个碳原子的羧酸乙烯基酯a），0.1-20重量％的不饱和羧酸酐b），0.1-10重量％的含Si化合物c）进行水解和0-40重量％的另外的可共聚不饱和化合物d）或含有基于混合物的基于混合物的5-95重量％的共聚物B）的共混物的混合物，共聚物B）由50-99.9％碳原子数1〜20的（甲基）丙烯酸C 1 -C 16烷基酯或碳酸乙烯酯的重量a），0〜20重量％的不饱和羧酸酐b）0.1-10重量％的Si- 含有能够进行水解的化合物c）和0-40重量％的另外的可共聚不饱和化合物d）和5- 95重量％的基于混合物的由50-99.9重量％的（甲基）丙烯酸C 1 -C 16烷基酯或1至20个碳原子的羧酸乙烯基酯组成的共聚物C）a），0.1 -20重量％的不饱和羧酸酐b），0-10重量％的能够进行水解的含Si化合物c）和0-40重量％的另外的可共聚不饱和化合物d），K 共聚物B）或C）之一的值为12〜40，另一种共聚物的值为30〜70，两种共聚物的K值相差至少5K值，其中K值根据根据DIN 53,726。

4. 发明授权

US5223645A Unsaturated phenone derivatives and their use as contact adhesives 失效
标题翻译：不饱和的苯醌衍生物及其作为联系人粘合剂的用途
公开(公告)号：US5223645A
公开(公告)日：1993-06-29
申请号：US764205
申请日：1991-09-23
申请人： Juergen Barwich , Gerd Rehmer , Kaspar Bott
发明人： Juergen Barwich , Gerd Rehmer , Kaspar Bott
IPC分类号： C07C231/06 , C07C235/20 , C07C235/78 , C07C235/84 , C08F20/60 , C08F220/60 , C08F246/00 , C09J7/02 , C09J133/24
CPC分类号： C08F220/60 , C07C235/20 , C07C235/78 , C07C235/84 , C08F246/00 , C09J133/24 , C09J7/0217
摘要： Unsaturated phenone derivatives of the general formula I ##STR1##whereR.sup.1 is C.sub.1 -C.sub.4 -alkyl, cyclopropyl, cyclopentyl, cyclohexyl, indanonyl, tetralonyl, phenyl or phenyl in which some or all of the hydrogen atoms have been replaced by a C.sub.1 -C.sub.4 -alkyl, C.sub.1 -C.sub.4 -alkoxy or C.sub.1 -C.sub.4 -thioalkyl group, or together with R.sup.2 or R.sup.6 forms an ethylene or propylene bridge,R.sup.2 to R.sup.6 are each hydrogen, C.sub.1 -C.sub.4 -alkyl, C.sub.1 -C.sub.4 -alkoxy or C.sub.1 -C.sub.4 -thioalkyl, and R.sup.3, R.sup.4 and R.sup.5 may each additionally be hydroxyl, R.sup.2 or R.sup.6 may additionally together with R.sup.1 form an ethylene or propylene bridge and one or more, but not more than three, of the radicals R.sup.2 to R.sup.6 are a group of the general formula II ##STR2## whereK is C.sub.1 -C.sub.10 -alkylene which may contain 1 or 2 oxygen or sulfur atoms,Y is straight-chain or branched C.sub.1 -C.sub.10 -alkylene or is C.sub.1 -C.sub.10 -alkylene which is substituted by carboxyl, a carboxylate anion, an alkyl C.sub.1 -C.sub.4 -carboxylate group or hydroxyl, X is --NH-- or --(N-Alkyl)-- of 1 to 4 carbon atoms andZ is hydrogen or C.sub.1 -C.sub.4 -alkyl.
摘要翻译：其中R 1是C 1 -C 4 - 烷基，环丙基，环戊基，环己基，茚满基，四氢萘基，苯基或苯基，其中一些或全部氢原子被C1- 或者与R 2或R 6一起形成乙烯或丙烯桥，R 2至R 6各自为氢，C 1 -C 4烷基，C 1 -C 4 - 烷氧基或C 1 -C 4 - 烷氧基或C 1 -C 4 - -C 4 - 硫代烷基和R 3，R 4和R 5可各自另外为羟基，R 2或R 6可以另外与R 1一起形成乙烯或丙烯桥，并且一个或多个但不多于三个基团R 2至R 6为其中K是可以含有1或2个氧或硫原子的C 1 -C 10 - 亚烷基，Y是直链或支链C 1 -C 10 - 亚烷基或是C 1 -C 10亚烷基被羧基，羧酸根阴离子，C1-C4羧酸烷基酯基或羟基取代的-C10-亚烷基，X是1〜4个碳原子的-NH-或 - （N-烷基），Z是氢或C 1 -C 4 - 烷基。

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