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    • 4. 发明授权
    • Herbicidal tetrahydropyran-2,4-diones
    • 除草四氢吡喃-2,4-二酮
    • US5389602A
    • 1995-02-14
    • US76687
    • 1993-06-15
    • Juergen KastDieter KolassaNorbert MeyerBruno WuerzerKarl-Otto WestphalenWilhelm RademacherJohann Jung
    • Juergen KastDieter KolassaNorbert MeyerBruno WuerzerKarl-Otto WestphalenWilhelm RademacherJohann Jung
    • A01N43/16A01N43/36A01N43/50A01N43/56A01N43/78A01N43/80C07D405/04C07D407/04C07D409/04C07D413/04C07D413/14C07D417/04A01N43/74
    • C07D405/04A01N43/16A01N43/36A01N43/50A01N43/56A01N43/78A01N43/80C07D407/04C07D409/04C07D413/04C07D413/14C07D417/04
    • Tetrahydropyran-2,4-diones of the formula ##STR1## where R.sup.1 is hydrogen; C.sub.1 -C.sub.6 -alkyl; C.sub.2 -C.sub.6 -alkenyl; C.sub.2 -C.sub.6 -alkynyl; substituted or unsubstituted phenyl; C.sub.1 -C.sub.6 -alkylsulfonyl; substituted or unsubstituted benzenesulfonyl; C.sub.3 -C.sub.6 -alkenylcarbonyl; or substituted or unsubstituted benzoyl;R.sup.2 is C.sub.1 -C.sub.6 -alkyl; C.sub.2 -C.sub.6 -alkenyl; C.sub.2 -C.sub.6 -alkynyl; C.sub.1 -C.sub.6 -haloalkyl; or C.sub.3 -C.sub.6 -cycloalkyl;A, B and D are each .dbd.CH-- or .dbd.N--;E is oxygen, sulfur or --NR.sup.7 --.R.sup.7 is hydrogen; C.sub.1 -C.sub.6 -alkyl; C.sub.2 -C.sub.6 -alkenyl; C.sub.2 -C.sub.6 -alkanoyl; substituted or unsubstituted benzoyl; benzyl; or substituted or unsubstituted phenyl;X is halogen; C.sub.1 -C.sub.6 -alkyl; substituted or unsubstituted C.sub.3 -C.sub.6 -cycloalkyl; C.sub.2 -C.sub.6 -alkenyl; C.sub.2 -C.sub.6 -alkynyl; C.sub.1 -C.sub.6 -alkoxy; C.sub.2 -C.sub.6 -alkenyloxy; C.sub.1 -C.sub.6 -alkylthio; C.sub.1 -C.sub.6 -alkoxycarbonyl; C.sub.2 -C.sub.6 -alkanoyloxy; substituted or unsubstituted benzyloxy; substituted or unsubstituted NR.sup.5 R.sup.6 ; formyl; C.sub.2 -C.sub.6 -alkanoyl or its imine, oxime or Schiff's base; or substituted or unsubstituted phenyl;n is 0, 1 or 2;R.sup.3, R.sup.4, R.sup.5 and R.sup.6 are each hydrogen, C.sub.1 -C.sub.6 -alkyl, phenyl, C.sub.2 -C.sub.6 -alkanoyl, benzoyl and/or benzyl;Z is oxygen or --NOR.sup.8 ; andR.sup.8 is substituted or unsubstituted C.sub.1 -C.sub.6 -alkyl; C.sub.2 -C.sub.6 -alkenyl; C.sub.2 -C.sub.6 -alkynyl; C.sub.2 -C.sub.6 -haloalkynyl; or substituted or unsubstituted thenyl;their environmentally compatible salts, and agents containing them.
    • 其中R 1是氢的式(VI)的四氢吡喃-2,4-二酮: C 1 -C 6 - 烷基; C 2 -C 6 - 烯基; C2-C6-炔基; 取代或未取代的苯基; C 1 -C 6烷基磺酰基; 取代或未取代的苯磺酰基; C 3 -C 6 - 烯基羰基; 或取代或未取代的苯甲酰基; R2是C1-C6-烷基; C 2 -C 6 - 烯基; C2-C6-炔基; C 1 -C 6 - 卤代烷基; 或C 3 -C 6 - 环烷基; A,B和D各自为= CH-或= N-; E是氧,硫或-NR7-。 R7是氢; C 1 -C 6 - 烷基; C 2 -C 6 - 烯基; C 2 -C 6烷酰基; 取代或未取代的苯甲酰基; 苄基; 或取代或未取代的苯基; X是卤素; C 1 -C 6 - 烷基; 取代或未取代的C 3 -C 6 - 环烷基; C 2 -C 6 - 烯基; C2-C6-炔基; C1-C6-烷氧基; C 2 -C 6 - 烯氧基; C1-C6-烷硫基; C1-C6烷氧基羰基; C2-C6-烷酰氧基; 取代或未取代的苄氧基; 取代或未取代的NR5R6; 甲酰基 C2-C6-烷酰基或其亚胺,肟或席夫碱; 或取代或未取代的苯基; n为0,1或2; R 3,R 4,R 5和R 6各自为氢,C 1 -C 6 - 烷基,苯基,C 2 -C 6 - 烷酰基,苯甲酰基和/或苄基; Z是氧或-NOR8; 且R 8为取代或未取代的C 1 -C 6 - 烷基; C 2 -C 6 - 烯基; C2-C6-炔基; C 2 -C 6 - 卤代炔基; 或取代或未取代的噻吩基; 它们与环境相容的盐和含有它们的试剂。
    • 5. 发明授权
    • Cyclohexenone derivatives and their use as herbicides
    • 环己烯酮衍生物及其作为除草剂的用途
    • US5034047A
    • 1991-07-23
    • US572357
    • 1990-08-24
    • Dieter KolassaJuergen KastThomas KuekenhoehnerNorbert MeyerKarl-Otto WestphalenBruno Wuerzer
    • Dieter KolassaJuergen KastThomas KuekenhoehnerNorbert MeyerKarl-Otto WestphalenBruno Wuerzer
    • A01N43/10A01N43/14A01N43/50A01N43/74A01N43/80A01N43/82C07D261/04C07D261/08C07D271/06C07D271/10C07D333/22C07D413/04
    • C07D271/06A01N43/10A01N43/14A01N43/50A01N43/74A01N43/80A01N43/82C07D261/04C07D261/08C07D271/10C07D333/22C07D413/04
    • Cyclohexenone derivatives of the general formula I ##STR1## where the substituents have the following meanings: R.sup.1 : substituted or unsubstituted C.sub.1 -C.sub.6 -alkyl, C.sub.3 -C.sub.6 -alkenyl or C.sub.3 -C.sub.6 -alkynyl, phenyl, benzyl or thenyl;R.sup.2 : substituted or unsubstituted C.sub.1 -C.sub.6 -alkenyl, C.sub.3 -C.sub.6 -alkenyl, C.sub.3 -C.sub.6 -alkynyl or phenyl;R.sup.3 : hydrogen, C.sub.1 -C.sub.6 -alkyl, C.sub.1 -C.sub.10 -alkylcarbonyl, C.sub.1 -C.sub.6 -alkylsulfonyl, C.sub.1 -C.sub.4 -trialkylsilyl, C.sub.1 -C.sub.4 -dialkylphosphonyl, C.sub.1 -C.sub.4 -dialkylthiophosphonyl, C.sub.3 -C.sub.6 -alkenyl, C.sub.3 -C.sub.6 -alkenylcarbonyl, C.sub.3 -C.sub.6 -alkynyl or substituted or unsubstituted benzoyl- or phenylsulfonyl;R.sup.4 : hydrogen, cyano, halogen, C.sub.1 -C.sub.6 -alkyl or C.sub.1 -C.sub.6 -alkoxycarbonyl;A: a substituted or unsubstituted C.sub.1 -C.sub.4 -alkylene chain in which a methylene group may be replaced by an oxygen or sulfur atom;m: 0 or 1;B: a 5-membered mono- or diunsaturated heterocycle containing up to 2 nitrogen atoms and/or up to one oxygen or sulfur atom; substituted or unsubstituted C.sub.1 -C.sub.6 -alkyl, C.sub.2 -C.sub.6 -alkenyl or C.sub.2 -C.sub.6 -alkynyl; C.sub.1 -C.sub.4 -alkoxy, C.sub.1 -C.sub.4 -alkylthio, C.sub.3 -C.sub.6 -alkenyloxy or C.sub.3 -C.sub.6 -alkynyloxy;n: 1, 2 or 3;Y: not denoting hydrogen when m is O, B is isoxazol-5-yl and X is 3-(C.sub.3 -C.sub.6 -cycloalkyl),and environmentally acceptable salts thereof, processes for their manufacture, and their use as herbicidal agents.
    • 通式I的环己烯酮衍生物,其中取代基具有以下含义:R 1:取代或未取代的C 1 -C 6 - 烷基,C 3 -C 6 - 烯基或C 3 -C 6 - 炔基,苯基,苄基或异丁基; R2:取代或未取代的C1-C6-烯基,C3-C6-烯基,C3-C6-炔基或苯基; R3:氢,C1-C6-烷基,C1-C10-烷基羰基,C1-C6-烷基磺酰基,C1-C4-三烷基甲硅烷基,C1-C4-二烷基膦酰基,C1-C4-二烷基硫代膦酰基,C3-C6-烯基,C3-C6- 烯基羰基,C 3 -C 6炔基或取代或未取代的苯甲酰基或苯基磺酰基; R4:氢,氰基,卤素,C1-C6-烷基或C1-C6-烷氧基羰基; A:取代或未取代的亚甲基可被氧或硫原子代替的C 1 -C 4 - 亚烷基链; m:0或1; B:含有至多2个氮原子和/或至多一个氧或硫原子的5元单或二不饱和杂环; 取代或未取代的C 1 -C 6 - 烷基,C 2 -C 6 - 烯基或C 2 -C 6 - 炔基; C 1 -C 4 - 烷氧基,C 1 -C 4 - 烷硫基,C 3 -C 6 - 烯氧基或C 3 -C 6 - 炔氧基; n:1,2或3; Y:当m为O时不表示氢,B为异唑-5-基,X为3-(C 3 -C 6环烷基),其环保可接受的盐,其制备方法及其作为除草剂的用途。
    • 8. 发明授权
    • Cyclohexenone derivatives
    • 环己烯酮衍生物
    • US5201935A
    • 1993-04-13
    • US934304
    • 1992-08-26
    • Dieter KolassaJuergen KasiThomas KuekenhoehnerNorbert MeyerKarl-Otto WestphalenBruno Wuerzer
    • Dieter KolassaJuergen KasiThomas KuekenhoehnerNorbert MeyerKarl-Otto WestphalenBruno Wuerzer
    • A01N43/10A01N43/14A01N43/50A01N43/74A01N43/80A01N43/82C07D261/04C07D261/08C07D271/06C07D271/10C07D333/22C07D413/04
    • C07D271/06A01N43/10A01N43/14A01N43/50A01N43/74A01N43/80A01N43/82C07D261/04C07D261/08C07D271/10C07D333/22C07D413/04
    • Cyclohexenone derivatives of the general formula I ##STR1## where the substituents have the following meanings: R.sup.1 substituted or unsubstituted C.sub.1 -C.sub.6 -alkyl, C.sub.3 -C.sub.6 -alkenyl or C.sub.3 -C.sub.6 -alkynyl, phenyl, benzyl or thenyl;R.sup.2 substituted or unsubstituted C.sub.1 -C.sub.6 -alkyl, C.sub.3 -C.sub.6 -alkenyl, C.sub.3 -C.sub.6 -alkynyl or phenyl;R.sup.3 hydrogen, C.sub.1 -C.sub.6 -alkyl, C.sub.1 -C.sub.10 -alkylcarbonyl, C.sub.1 -C.sub.6 -alkylsulfonyl, C.sub.1 -C.sub.4 -trialkylsilyl, C.sub.1 -C.sub.4 -dialkylphosphonyl, C.sub.1 -C.sub.4 -dialkylthiophosphonyl, C.sub.3 -C.sub.6 -alkenyl, C.sub.3 -C.sub.6 -alkenylcarbonyl, C.sub.3 -C.sub.6 -alkynyl orsubstituted or unsubstituted benzoyl- or phenylsulfonyl;R.sup.4 hydrogen, cyano, halogen, C.sub.1 -C.sub.6 -alkyl or C.sub.1 -C.sub.6 -alkoxycarbonyl;A a substituted or unsubstituted C.sub.1 -C.sub.4 -alkylene chain in which a methylene group may be replaced by an oxygen or sulfur atom;m 0 or 1;B a 5-membered mono- or diunsaturated heterocycle containing up to 2 nitrogen atoms and/or up to one oxygen or sulfur atom;substituted or unsubstituted C.sub.1 -C.sub.6 -alkyl, C.sub.2 -C.sub.6 -alkenyl or C.sub.2 -C.sub.6 -alkynyl;C.sub.1 -C.sub.4 -alkoxy, C.sub.1 -C.sub.4 -alkylthio, C.sub.3 -C.sub.6 -alkenyloxy or C.sub.3 -C.sub.6 -alkynyloxy;n 1, 2 or 3;Y not denoting hydrogen when m is 0, B is isoxazol-5-yl and X is 3-(C.sub.3 -C.sub.6 -cycloalkyl),and environmentally acceptable salts thereof, processes for their manufacture, and their use as herbicidal agents.
    • 通式I的环己烯酮衍生物,其中取代基具有以下含义:R 1取代或未取代的C 1 -C 6 - 烷基,C 3 -C 6 - 烯基或C 3 -C 6 - 炔基,苯基,苄基或异丁基; R2取代或未取代的C1-C6-烷基,C3-C6-烯基,C3-C6-炔基或苯基; R3,C1-C6-烷基,C1-C10-烷基羰基,C1-C6-烷基磺酰基,C1-C4-三烷基甲硅烷基,C1-C4-二烷基膦酰基,C1-C4-二烷基硫代膦酰基,C3-C6-烯基,C3-C6-烯基羰基 ,C 3 -C 6炔基或取代或未取代的苯甲酰基或苯基磺酰基; R 4氢,氰基,卤素,C 1 -C 6 - 烷基或C 1 -C 6 - 烷氧基羰基; 取代或未取代的C1-C4亚烷基链,其中亚甲基可被氧或硫原子代替; m 0或1; B是含有至多2个氮原子和/或至多一个氧原子或硫原子的5元单或二不饱和杂环; 取代或未取代的C 1 -C 6 - 烷基,C 2 -C 6 - 烯基或C 2 -C 6 - 炔基; C 1 -C 4 - 烷氧基,C 1 -C 4 - 烷硫基,C 3 -C 6 - 烯氧基或C 3 -C 6 - 炔氧基; n 1,2或3; 当m为0时,Y不表示氢,B为异唑-5-基,X为3-(C 3 -C 6 - 环烷基)及其环境可接受的盐,其制备方法及其作为除草剂的用途。