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    • 1. 发明授权
    • Castable fluorocarbon composite propellants
    • 可燃氟橡胶复合材料
    • US3629020A
    • 1971-12-21
    • US3629020D
    • 1964-10-09
    • US NAVY
    • KAUFMAN MARTIN HO'DROBINAK JOHN D
    • C06B45/10C06D5/06
    • C06B45/10
    • 1. A propellant composition comprising A FLUOROCARBON BINDER; A METAL FUEL; AND AN INORGANIC OXIDIZER; SAID BINDER COMPRISING A FLUOROCARBON MONOMER SELECTED FROM THE GROUP CONSISTING OF 1H, 1H, 9H-Hexadecafluoro-1nonanomethacylate, 1H, 1H, 7H-Dodecafluoro-1-heptanoacrylate, 1H, 1H, 5H-Octafluoro-1-pentanoacrylate, and mixtures thereof; a plasticizer selected from the group consisting of triethylene glycol dinitrate, pentaerythritol trinitrate, trimethylol ethane trinitrate, diethylene glycol dinitrate, butanediol dinitrate, a copolymer of vinylidene fluoride and perfluoropropylene, bis(2fluoro-2,2-dinitroethyl)formal and mixtures thereof; a crosslinking agent selected from the group consisting of triallylcyanurate and divinyl benzene; and a free radical catalyst selected from the group consisting of azo-bisisobutyronitrile, benzoyl peroxide, dichlorobenzoyl peroxide, and methylethylketone peroxide; SAID FUEL BEING A MEMBER SELECTED FROM THE GROUP CONSISTING OF ALUMINUM, BERYLLIUM, AND ZIRCONIUM; AND SAID OXIDIZER SELECTED FROM A GROUP CONSISTING OF AMMONIUM PERCHLORATE, SODIUM PERCHLORATE, POTASSIUM PERCHLORATE, SODIUM NITRATE, POTASSIUM NITRATE AND BARIUM NITRATE.
    • 2. 发明授权
    • Wet process for compounding polymer-solids compositions
    • 用于混合聚合物 - 固体组合物的湿法
    • US3872192A
    • 1975-03-18
    • US6951270
    • 1970-08-07
    • US NAVY
    • KAUFMAN MARTIN HROY EDWARD M
    • C06B21/00C08J3/00C08J3/21C06B21/02
    • C08J3/005C06B21/0075C08J3/212
    • A wet process for compounding polymers which comprises forming a paste consisting of solid ingredients such as oxidizers and metal powder, a rubber polymer and low boiling hydrocarbon; extruding said paste through a plastic or metal tube provided with a multiperforated nozzle and a plastic plunger whereby strands are formed; and dropping said strands through a current of warm air or warm inert gas whereby said strands are dry to the touch as they fall to the bottom of said cylinder. This process provides compositions which are homogeneous and the solid ingredients are retained within the polymer-solid composition.
    • 一种用于复合聚合物的湿法,其包括形成由固体成分如氧化剂和金属粉末,橡胶聚合物和低沸点烃组成的糊料; 通过设置有多孔喷嘴和塑料柱塞的塑料或金属管挤压所述糊料,从而形成股线; 并且通过暖空气或暖惰性气体的流动将所述股线滴落,由此当它们落到所述气缸的底部时,所述股线接触干燥。 该方法提供均匀的组合物,并且固体成分保留在聚合物 - 固体组合物内。
    • 3. 发明授权
    • Hybrid propellant system
    • 混合动力系统
    • US3640070A
    • 1972-02-08
    • US3640070D
    • 1964-10-28
    • US NAVY
    • KAUFMAN MARTIN HO'DROBINAK JOHN DDAKE JAMES O JR
    • C06B45/10C06D5/10
    • C06B45/10C06D5/10Y10S149/118
    • 1. The method for creating propulsive thrust by burning a solid phase with a liquid phase injectant and exhausting the products from a rocket nozzle; said solid phase comprising from 17 to 22 percent by weight of a fluorocarbon binder selected from the group consisting of 1H, 1H, 9H-Hexadecafluoro-1nonanomethacrylate, 1H, 1H, 7H-Dodecafluoro-1-heptanoacrylate, 1H, 1H, 5H-Octafluoro-1-pentanoacrylate and mixtures thereof; a plasticizer selected from the group consisting of triethylene glycol dinitrate, pentaerythritol trinitrate, trimethylol ethane trinitrate, butanediol dinitrate, a copolymer of vinylidene fluoride and perfluoropropylene, bis(2-fluoro-2,2dinitroethyl)formal and mixtures thereof; and a free radical catalyst selected from the group consisting of azobisisobutyronitrile, benzoyl peroxide, dichlorobenzoyl peroxide, and methylethylketone peroxide; from 10-22 percent by weight of a metal fuel being a member selected from the group consisting of aluminum, beryllium, zirconium, thorium, uranium, boron, and mixtures thereof; and from 43 to 55 percent by weight of an oxidizer comprising a member selected from the group consisting of ammonium perchlorate, sodium perchlorate, potassium perchlorate, sodium nitrate, potassium nitrate, and barium nitrate; SAID LIQUID PHASE INJECTANT COMPRISING FROM 4 TO 12 PERCENT BY WEIGHT OF A MEMBER SELECTED FROM THE GROUP CONSISTING OF HYDRAZINE, MONOMETHYLHYDRAZINE, UNSYMMETRICAL DIMETHYLHYDRAZINE, PERCHLOROFLUORIDE, TETRAFLUOROHYDRAZINE, HYDROGEN PEROXIDE, NITRIC ACID, TETRANITROMETHANE, TRI(DIFLUOROAMINE)FLUOROETHANE, AND MIXTURES THEREOF.
    • 1.通过用液相注射剂燃烧固相并从火箭喷嘴排出产物来产生推进推力的方法; 所述固相包含17至22重量%的选自1H,1H,9H-十六氟-1-壬酸甲酯的氟碳粘合剂,1H,1H,7H-十一氟-1-庚烯丙烯酸酯,1H,1H,5H - 十氟-1-戊烯丙酸酯及其混合物; 选自三甘醇二硝酸酯,季戊四醇三硝酸酯,三羟甲基乙烷三硝酸酯,丁二醇二硝酸酯,偏二氟乙烯与全氟丙烯的共聚物,双(2-氟-2,2-二硝基乙基)甲醛及其混合物的增塑剂; 和选自偶氮 - 双异丁腈,过氧化苯甲酰,过氧化二苯甲酰和过氧化甲乙酮的自由基催化剂; 10-22重量%的金属燃料是选自铝,铍,锆,钍,铀,硼及其混合物的成员; 和43至55重量%的氧化剂,其包含选自高氯酸铵,高氯酸钠,高氯酸钾,硝酸钠,硝酸钾和硝酸钡的成员; 上述液相注入物包括从4至12%(重量)SELECTED选自肼,甲肼,偏二甲基肼,PERCHLOROFLUORIDE,四氟肼,过氧化氢,硝酸,四硝基甲烷,三(二氟代胺)氟乙烷,以及它们的混合物组成的部件构成。