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    • 1. 发明授权
    • Treatment of textile materials
    • 纺织材料的处理
    • US3632391A
    • 1972-01-04
    • US80537969
    • 1969-03-07
    • US AGRICULTURE
    • WHITFIELD ROBERT EPITTMAN ALLEN GWASLEY WILLIAM L
    • D06M13/184D06M13/192D06M13/325D06M15/21D06M15/227D06M15/267D06M15/273D06M15/285D06M15/39D06M15/507D06M15/53D06M15/564D06M15/59D06M15/61D06M15/643D06M23/00B44D1/44
    • D06M23/00D06M13/184D06M13/192D06M13/325D06M15/21D06M15/227D06M15/267D06M15/273D06M15/285D06M15/39D06M15/507D06M15/53D06M15/564D06M15/59D06M15/61D06M15/6436Y10T428/2938Y10T442/2033Y10T442/2279Y10T442/2352Y10T442/2385Y10T442/2393Y10T442/2549Y10T442/259Y10T442/2762
    • Fibrous materials (e.g., wool, cotton, viscose, etc.) carrying a deposit of a preformed polymer containing functional groups, which is cross-linked in situ through reaction with a fixative containing functional groups complementary to those on the polymer. Typically, the functional groups on the polymer are carbonyl halide, haloformate, isocyanate, anhydride, or carbamyl halide groups. In such case, the functional groups on the fixative may be amino or hydroxyl groups. Alternatively, the polymer may contain amino or hydroxyl groups, in which case the fixative would contain carbonyl halide, haloformate, isocyanate, anhydride, or carbamyl groups. Various types of polymers may be employed including addition polymers and copolymers, and condensation polymers such as polyesters, polyamides, and polyethers. The novel products are made by processes which utilize a phase boundary limited reaction. One embodiment thereof is to form the complementary agents (the preformed polymer and fixative) into separate solutions in mutually immiscible solvents, these solutions then being applied serially to the fibrous material. Alternatively, a solution of one of the agents in a volatile solvent is applied to the substrate, which is then dried to remove solvent, and the complementary agent is then applied in fluid form, e.g., as a vapor or dissolved in a solvent which is not necessarily immiscible with the first solvent.
    • 纤维材料(例如,羊毛,棉花,粘胶等),其携带预先形成的含有官能团的聚合物的沉积物,其通过与包含与聚合物上的官能团互补的官能团的固定剂反应而原位交联。 通常,聚合物上的官能团是羰基卤,卤代甲酸酯,异氰酸酯,酸酐或氨基甲酰卤基团。 在这种情况下,固定剂上的官能团可以是氨基或羟基。 或者,聚合物可以含有氨基或羟基,在这种情况下,固定剂将含有羰基卤,卤代甲酸酯,异氰酸酯,酸酐或氨基甲酰基。 可以使用各种类型的聚合物,包括加成聚合物和共聚物,以及缩聚物如聚酯,聚酰胺和聚醚。 新产品由利用相界限反应的方法制成。 其一个实施方案是将互补剂(预先形成的聚合物和固定剂)在相互不混溶的溶剂中形成分离的溶液,然后将这些溶液顺序施加到纤维材料上。 或者,将一种试剂在挥发性溶剂中的溶液施加到基材上,然后将其干燥以除去溶剂,然后以流体形式例如以蒸气或溶解在溶剂中的方式施用互补剂,溶剂是 不一定与第一溶剂不混溶。