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    • 2. 发明授权
    • Process for producing amorphous alloy material
    • 生产非晶合金材料的方法
    • US5296059A
    • 1994-03-22
    • US943703
    • 1992-09-11
    • Tsuyoshi MasumotoAkihisa InoueJunichi NagahoraKazuhiko Kita
    • Tsuyoshi MasumotoAkihisa InoueJunichi NagahoraKazuhiko Kita
    • C22C45/00B22F3/00C22C1/00C22C45/08C22F1/00C22F1/04C22F1/06C22F1/18
    • C22F1/186B22F3/006C22C1/00C22F1/00C22F1/04C22F1/06C22F1/18C21D2201/03
    • A process for producing an amorphous alloy material characterized by imparting ductility to an amorphous alloy having a supercooled liquid region by giving a prescribed amount of strain at a prescribed strain rate to the alloy in the glass transition temperature region of the alloy. The amorphous alloy may be in the form of spherical or irregular-shaped powders or thin ribbons or in the form of primary consolidated shapes thereof or an amorphous alloy casting. The amount of strain and strain rate are preferably 50% or greater and 2.times.10.sup.-2 /sec or higher, respectively, and the worked amorphous alloy material is preferably allowed to cool in a furnace or spontaneously. Suitable examples of the amorphous alloy to be employed include Al-TM-Ln, Mg-TM-Ln, Zr-TM-Al and Hf-TM-Al alloys, wherein TM is a transition metal element and Ln is a rare earth metal element. The thus obtained amorphous alloy is greatly improved in the prevention of embrittlement in hot working peculiar to the alloy.
    • 一种非晶态合金材料的制造方法,其特征在于,在合金的玻璃化转变温度区域中,通过以规定的应变速率向合金赋予规定量的应变率,赋予具有过冷液体区域的非晶质合金的延展性。 非晶合金可以是球形或不规则形状的粉末或薄带的形式,或者是其主要固结形状或非晶态合金铸件的形式。 应变量和应变速率分别优选为50%以上且2×10 -2 /秒以上,加工后的非晶态合金材料优选在炉内自发冷却。 所使用的非晶合金的合适实例包括Al-TM-Ln,Mg-TM-Ln,Zr-TM-Al和Hf-TM-Al合金,其中TM是过渡金属元素,Ln是稀土金属元素 。 由此获得的非晶态合金在防止合金特有的热加工中脆化方面大大提高。
    • 5. 发明授权
    • Highly hard thin film and method for production thereof
    • 高硬度薄膜及其制造方法
    • US5648174A
    • 1997-07-15
    • US420606
    • 1995-04-12
    • Hiroshi YamagataAkihisa InoueTsuyoshi MasumotoJunichi Nagahora
    • Hiroshi YamagataAkihisa InoueTsuyoshi MasumotoJunichi Nagahora
    • C23C14/00C23C14/06C23C14/14C23C14/58
    • C23C14/5806C23C14/0042C23C14/06C23C14/0688C23C14/14C23C14/58C23C14/584Y10T428/24942Y10T428/25Y10T428/31678
    • A hard thin film having fine crystalline ceramic particles dispersed in a metallic matrix phase is disclosed. The production of the film is effected by first depositing a substantially amorphous film on a substrate and then heat-treating the deposited film. Deposition of the film on the substrate is carried out by using a source of evaporation having a composition represented by the general formula: Al.sub.a M.sub.b, wherein M stands for at least one element selected from the group consisting of Ti, Ta, V, Cr, Zr, Nb, Mo, Hf, W, Mn, Fe, Co, Ni, and Cu and "a" and "b" respectively stand for atomic % in the ranges of 60.ltoreq.a.ltoreq.98.5 and 1.5.ltoreq.b.ltoreq.40, providing a+b=100. Deposition is effected by a physical vapor deposition process in an atmosphere of an inert gas containing a reaction gas while controlling the feed rate of the reaction gas into a chamber in such a manner that the partial pressure of the react/on gas is kept constant or varied continuously or stepwise. By this method, there can be obtained a hard composite film having fine ceramic particles dispersed in a metallic matrix phase or a dense, hard, and composite film having a composition and structure obliquely varied from a substantially crystalline metallic phase to a crystalline ceramic phase in the direction of thickness of the film.
    • 公开了一种具有分散在金属基体相中的细晶体陶瓷颗粒的硬质薄膜。 通过首先在基板上沉积基本上非晶的膜然后对沉积的膜进行热处理来实现膜的制备。 通过使用具有由通式AlaMb表示的组成的蒸发源进行膜的沉积,其中M表示选自Ti,Ta,V,Cr,Zr中的至少一种元素 ,Nb,Mo,Hf,W,Mn,Fe,Co,Ni和Cu,“a”和“b”分别表示60≤a≤98.5的范围内的原子% b = 40,提供+ b = 100。 通过在包含反应气体的惰性气体的气氛中的物理气相沉积工艺进行沉积,同时将反应气体的进料速率控制在室内,使得反应/导入气体的分压保持恒定,或 连续或逐步变化。 通过该方法,可以获得具有分散在金属基体相中的细微陶瓷颗粒的硬质复合膜或致密的,硬的和复合的膜,其具有从基本上结晶的金属相到结晶陶瓷相倾斜变化的组成和结构 膜的厚度方向。
    • 7. 发明授权
    • Magnetic material
    • 磁性材料
    • US5397490A
    • 1995-03-14
    • US96275
    • 1993-07-26
    • Tsuyoshi MasumotoAkihisa InoueJunichi Nagahora
    • Tsuyoshi MasumotoAkihisa InoueJunichi Nagahora
    • C22C1/00C22C1/02C22C21/00C22C45/08H01F1/00H01F1/14H01F1/147H01F1/153
    • B82Y25/00H01F1/147H01F1/153
    • A magnetic material consisting essentially of A1 and 10 to 50 at. % of at least one capable of alloying with A1 to form quasicrystals (for example, 5 to 25 at. % of at least one member selected between Cu and Pd and 5 to 35 at. % of Mn) and up to 25 at. % of at least one element having a smaller atomic radius than those of the above elements (for example, B). The magnetic material is produced by adding, to a mixture consisting of A1 and at least one element capable of alloying with A1 to form quasicrystals and including at least one transition metal, at least one element having a smaller atomic radius than those of A1 and the above elements to dissolve the element having a smaller atomic radius in a solid solution form in a quasicrystalline phase. The thus obtained magnetic crystal is useful in various applications, such as magnetic recording heads, and a process for producing the same.
    • 基本上由A1和10至50at组成的磁性材料。 至少一种能够与Al合金化以形成准晶体的至少一种(例如,在Cu和Pd之间选择的至少一种成分和5至35原子%的Mn的5至25at。%)和至多25at。 至少一种元素的原子半径小于上述元素(例如B)的原子半径的百分比。 磁性材料是通过向由Al组成的混合物和能够与Al合金化的至少一种元素混合形成准晶体并包括至少一种过渡金属,至少一种具有比A1的原子半径小的元素和 上述元素以固溶体形式在准晶相中溶解具有较小原子半径的元素。 由此获得的磁晶体可用于各种应用中,例如磁记录头,及其制造方法。