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    • 5. 发明授权
    • Sacrificial film-forming composition, patterning process, sacrificial film and removal method
    • 牺牲成膜组合物,图案化工艺,牺牲膜和去除方法
    • US07485690B2
    • 2009-02-03
    • US11148380
    • 2005-06-09
    • Yoshitaka HamadaTsutomu OgiharaMotoaki IwabuchiTakeshi AsanoTakafumi UedaDirk Pfeiffer
    • Yoshitaka HamadaTsutomu OgiharaMotoaki IwabuchiTakeshi AsanoTakafumi UedaDirk Pfeiffer
    • C08G77/08
    • G03F7/094G03F7/0752H01L21/31116H01L21/31144H01L21/76808
    • A sacrificial film-forming composition is provided comprising (A) a silicone resin which is a co-hydrolytic condensate of hydrolyzable silanes having formulae (1) and (2): X—Y—SiZ3  (1) RnSiZ4-n  (2) wherein Z is a hydrolyzable group, X is a crosslinkable organofunctional group such as an unsubstituted hydroxyl group or a substituted or unsubstituted epoxy, acyloxy or acryloxy group, Y is a single bond or a divalent hydrocarbon group, R is hydrogen or a monovalent hydrocarbon group, and n is an integer of 0 to 3, the silicone resin being capable of crosslinking reaction by the crosslinkable organofunctional group in formula (1), (B) a crosslinking agent, (C) an acid generator, and (D) an organic solvent. The composition has improved storage stability, filling properties, adhesion and coating uniformity sufficient to form a sacrificial film which is effectively dissolvable in a stripping solution.
    • 提供牺牲性成膜组合物,其包含(A)作为具有式(1)和(2)的可水解硅烷的共水解缩合物的硅氧烷树脂:<?在线配方说明=“在线配方” end =“lead”?> XY-SiZ3(1)<?in-line-formula description =“In-line Formulas”end =“tail”?> <?in-line-formula description =“In-line formula end =“lead”?> RnSiZ4-n(2)<?in-line-formula description =“In-line Formulas”end =“tail”?>其中Z是可水解基团,X是可交联的有机官能团,例如 未取代的羟基或取代或未取代的环氧基,酰氧基或丙烯酰氧基,Y为单键或二价烃基,R为氢或一价烃基,n为0〜3的整数,有机硅树脂为 能够通过式(1)中的交联性有机官能团交联反应,(B)交联剂,(C)酸产生剂和(D)有机溶剂进行交联反应。 该组合物具有提高的储存稳定性,填充性能,粘附性和涂层均匀性,足以形成有效地溶解在剥离溶液中的牺牲膜。
    • 9. 发明授权
    • Sacrificial film-forming composition, patterning process, sacrificial film and removal method
    • 牺牲成膜组合物,图案化工艺,牺牲膜和去除方法
    • US07385021B2
    • 2008-06-10
    • US11148161
    • 2005-06-09
    • Yoshitaka HamadaTsutomu OgiharaMotoaki IwabuchiTakeshi AsanoTakafumi Ueda
    • Yoshitaka HamadaTsutomu OgiharaMotoaki IwabuchiTakeshi AsanoTakafumi Ueda
    • C08G77/08
    • G03F7/0752C08K5/0025C08L83/06G03F7/091G03F7/11C08L2666/28
    • A sacrificial film-forming composition is provided comprising (A) an organofunctional silicone resin which is a co-hydrolytic condensate of hydrolyzable silanes having formula (1) and formula (2) and/or (3): X—Y—SiZ3   (1) RnSiZ4-n   (2) P—SiZ3   (3) wherein Z is a hydrolyzable group, X is a crosslinkable organofunctional group, Y is a single bond or a divalent hydrocarbon group, R is hydrogen or a monovalent hydrocarbon group, n is an integer of 0-3, and P is a substituent group which readily decomposes and volatilizes upon thermal decomposition, (B) a crosslinking agent, (C) an acid generator, (D) an extender or porogen, and (E) an organic solvent. The composition has improved storage stability, filling properties, adhesion and coating uniformity sufficient to form a sacrificial film which is effectively dissolvable in a stripping solution.
    • 提供了牺牲成膜组合物,其包含(A)有机官能有机硅树脂,其为具有式(1)和式(2)和/或(3)的可水解硅烷的共水解缩合物:<β直列式 描述=“在线公式”end =“lead”?> XY-SiZ 3(1)<?in-line-formula description =“In-line Formulas”end =“tail”? > <?in-line-formula description =“In-line Formulas”end =“lead”?> R SiZ 4-n(2) line-formula description =“In-line Formulas”end =“tail”?> <?in-line-formula description =“In-line Formulas”end =“lead”?> P-SiZ <3 >(3)<?in-line-formula description =“In-line Formulas”end =“tail”?>其中Z是可水解基团,X是可交联的有机官能团,Y是单键或二价烃基 ,R为氢或一价烃基,n为0-3的整数,P为在热分解时容易分解挥发的取代基,(B)交联剂,(C)aci (D)增量剂或致孔剂,和(E)有机溶剂。 该组合物具有提高的储存稳定性,填充性能,粘附性和涂层均匀性,足以形成有效地溶解在剥离溶液中的牺牲膜。