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    • 1. 发明授权
    • Method for melt-molding water-soluble vinyl alcohol polymers
    • 熔融成型水溶性乙烯醇聚合物的方法
    • US5190712A
    • 1993-03-02
    • US753165
    • 1991-08-30
    • Tsukasa OishiToru SekiTakuya Honda
    • Tsukasa OishiToru SekiTakuya Honda
    • C08F8/12C08J5/00
    • C08J5/00B29C47/00C08F8/12C08F2800/10C08J2329/04F04C2210/26
    • A method for melt-molding a water-soluble vinyl alcohol polymer which includes melt-molding a water-soluble oxyalkylene group-containing vinyl alcohol copolymer under substantially anhydrous conditions and substantially without use of plasticizer, the copolymer having a vinyl alcohol unit (A), a vinyl ester unit (B) and an oxyalkylene ether unit (C) of the formulas: ##STR1## wherein R.sup.1 is an alkyl group; R.sup.2 and R.sup.3 each is a hydrogen atom or an alkyl group; R.sup.4 is a hydrogen atom, an alkyl group, a phenyl group or a substituted phenyl group; n is equal to 1 through 50; in proportions of a mol %, b mol % and c mol %, respectively, where0.1.ltoreq.c.ltoreq.20,50.ltoreq.100a/(a+b).ltoreq.100,and the oxyalkylene moiety (CHR.sup.2 --CHR.sup.3 --O--).sub.n of unit (C) accounts for 3 to 40 percent by weight of the total resin, and having a melt index of not less than 5 g/10 min. under a load of 2160 at a temperature of 210.degree. C.
    • 一种熔融模塑水溶性乙烯醇聚合物的方法,该方法包括在基本上无水条件下基本上不使用增塑剂熔融模塑含水溶性含氧化烯基的乙烯醇共聚物,所述共聚物具有乙烯醇单元(A) ,乙烯基酯单元(B)和下式的氧化烯醚单元(C):(A)其中R 1是烷基;(B)其中R 1是烷基; R2和R3各自为氢原子或烷基; R4是氢原子,烷基,苯基或取代的苯基; n等于1到50; 分别为摩尔%,b摩尔%和c摩尔%,其中0.1≤i≤20,50≤(a + b)≤100,氧化烯部分(CHR2 单元(C)的-CHR 3 -O-)n占总树脂的3〜40重量%,熔体指数不小于5g / 10分钟。 在2160℃的负荷下,在210℃的温度下
    • 8. 发明授权
    • Multi-layered laminate comprising hydrolyzed EVOH and use thereof
    • 包含水解EVOH的多层层压材料及其用途
    • US5849376A
    • 1998-12-15
    • US699465
    • 1996-08-19
    • Tsukasa OishiMasahiko Toyozumi
    • Tsukasa OishiMasahiko Toyozumi
    • B32B27/32B32B5/14B32B9/04B32B27/30
    • B32B27/32Y10T428/1328Y10T428/31913Y10T428/31935
    • A laminate having an excellent gas barrier property and an improved organic solvent resistance and suitable for use in containers for chemicals and volatile materials such as organic solvents and fuels. The laminate comprises: (A) a layer comprising (A1) a hydrolyzed ethylene-vinyl acetate copolymer having an ethylene content of 10 to 70% by mole and a degree of hydrolysis of at least 85% by mole, (B) a layer of a resin composition comprising (B1) a polyolefin resin and (B2) 0.5 to 40% by weight, based on said polyolefin (B1), of a hydrolyzed ethylene-vinyl acetate copolymer having an ethylene content of 10 to 70% by mole and a degree of hydrolysis of at least 85% by mole, (C) an outer layer of a polyolefin resin disposed on the outer side of said layer (A), and optionally an outer layer of said polyolefin resin (C) disposed on the other side and at least one adhesive layer disposed between adjacent two layers, wherein the ratio of the apparent melt viscosity of said polyolefin (B1) to that of said hydrolyzed copolymer (B2) at a rate of shear of 100 cm.sup.-1 and at 230.degree. C. is from 0.1 to 50.
    • 具有优异的阻气性和改善的耐有机溶剂性并且适用于化学品和挥发性物质如有机溶剂和燃料的容器中的层压体。 层压体包括:(A)包含(A1)乙烯含量为10〜70摩尔%,水解度为85摩尔%以上的水解乙烯 - 乙酸乙烯酯共聚物的层(A),(B) 一种树脂组合物,其包含(B1)聚烯烃树脂和(B2)基于所述聚烯烃(B1)0.5至40重量%的乙烯含量为10至70摩尔%的水解乙烯 - 乙酸乙烯酯共聚物和 水解度至少为85摩尔%,(C)设置在所述层(A)的外侧的聚烯烃树脂的外层,以及任选设置在另一侧的所述聚烯烃树脂(C)的外层 以及设置在相邻两层之间的至少一个粘合剂层,其中所述聚烯烃(B1)与所述水解共聚物(B2)的表观熔体粘度在100cm -1的剪切速率和230℃下的比例 为0.1〜50。