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    • 6. 发明授权
    • Thermal transfer sheet
    • 热转印片
    • US06946424B2
    • 2005-09-20
    • US10368476
    • 2003-02-20
    • Munenori IeshigeNaohiro ObonaiKenichi HirotaTakenori Omata
    • Munenori IeshigeNaohiro ObonaiKenichi HirotaTakenori Omata
    • B41M5/392B41M5/42B41M7/00B41M5/40
    • B41M5/42B41M5/345B41M5/44B41M7/0027B41M2205/02B41M2205/26B41M2205/36B41M2205/40
    • The present invention is first directed to a thermal transfer sheet which is not high in cost for obtaining a substrate, does not involve a problem of blocking or the like at the time of winding after coating of a backside layer onto the substrate, can eliminate the need to provide a release layer on the protective layer region, and further can enhance glossiness of a print with a protective layer. The thermal transfer sheet comprises a substrate, a dye layer of at least one color and a thermally transferable protective layer provided in a face serial manner on one side of the substrate, a protective layer provided on a part of one side of the substrate, an easy-adhesion layer provided on the whole surface of the protective layer and the substrate, the dye layer being provided on the easy-adhesion layer in its region where the protective layer is not located on the underside of the easy-adhesion layer. The second invention is directed to a thermal transfer sheet which can cope with increased printing speed in the thermal transfer, can meet demands for the provision of thermally transferred images having high density and high quality, can prevent the occurrence of abnormal transfer, cockles, etc., and can improve sensitivity in transfer at the time of printing. The thermal transfer sheet according to the second invention comprises a substrate, a heat-resistant slip layer provided on one side of the substrate, and an adhesive layer and a dye layer provided in that order on the other side of the substrate, the adhesive layer comprising a polyvinylpyrrolidone resin. By virtue of this construction, the sensitivity in transfer can be significantly improved at the time of thermal transfer, and a high-density thermally transferred image can be provided without applying high energy.
    • 本发明首先涉及用于获得基板的成本不高的热转印片,在将背面层涂覆到基板上之后不卷绕卷绕时的问题,可以消除 需要在保护层区域上提供剥离层,并且还可以增强具有保护层的印刷物的光泽度。 热转印片材包括基材,至少一种颜色的染料层和在基材的一侧上以面串联方式设置的可热转印保护层,设置在基材的一侧的一部分上的保护层, 易保护层设置在保护层和基板的整个表面上,染色层设置在容易粘附层上的保护层不位于易粘合层下侧的区域中。 第二发明涉及能够应对在热转印中提高的印刷速度的热转印片,可以满足提供具有高密度和高质量的热转印图像的需求,可以防止异常转印,起泡等的发生 ,并且可以提高印刷时的转印灵敏度。 根据第二发明的热转印片包括基板,设置在基板的一侧上的耐热滑动层,以及在基板的另一侧上依次设置的粘合层和染料层,粘合层 包括聚乙烯吡咯烷酮树脂。 由于这种结构,在热转印时可以显着提高转印的灵敏度,并且可以在不施加高能量的情况下提供高密度的热转印图像。
    • 8. 发明授权
    • Thermal transfer recording material
    • 热转印记录材料
    • US06692879B2
    • 2004-02-17
    • US10258217
    • 2002-10-21
    • Shino SuzukiMasahiro YukiTakenori OmataMunenori IeshigeHidemasa Kaida
    • Shino SuzukiMasahiro YukiTakenori OmataMunenori IeshigeHidemasa Kaida
    • G03C810
    • B41M5/3858B41M5/385B41M5/5236B41M5/529B41M7/0027B41M2205/02B41M2205/32Y10S430/142Y10S430/165Y10T428/31663Y10T428/31971
    • There is provided a thermal transfer image-receiving sheet which has dyeability high enough to realize high-speed printing and low-energy printing, permits a protective layer to be thermally transferred onto an image formed on the thermal transfer image-receiving sheet, is free from heat fusing to a thermal transfer sheet at the time of image formation on the thermal transfer image-receiving sheet, and has satisfactory separability from the thermal transfer sheet. The thermal transfer image-receiving sheet comprises: a substrate sheet; and a receptive layer provided on at least one side of the substrate sheet, said receptive layer comprising at least a combination of a cellulose ester resin (A) having a degree of acetylation of 10 to 30% with a cellulose ester resin (B) having a degree of acetylation of less than 6%, the total degree of acetylation of the cellulose ester resin (A) and the cellulose ester resin (B) being 8 to 14%, the content of hydroxyl groups in the cellulose ester resin (A) and the content of hydroxyl groups in the cellulose ester resin (B) each being not more than 6% by weight, the remaining hydroxyl groups having been esterified with an organic acid excluding acetic acid. By virtue of the above construction, the thermal transfer image-receiving sheet can realize printing of an image thereon with high dyeability at a high speed, has excellent separability from a thermal transfer sheet, is free from smudge and blurring derived from plasticizers, and permits a protective layer to be adhered onto the receptive layer.
    • 提供了一种热转印图像接收片材,其具有足够高的染色性以实现高速印刷和低能量印刷,允许保护层热转印到形成在热转印图像接收片材上的图像上,是免费的 在热转印图像接收片材上形成图像时从热熔融到热转印片材,并且与热转印片材具有令人满意的分离性。 热转印图像接收片包括:基片; 以及设置在所述基材片的至少一侧的接收层,所述接受层至少包含具有10〜30%乙酰化度的纤维素酯树脂(A)与纤维素酯树脂(B)的组合,所述纤维素酯树脂 乙酰化度小于6%,纤维素酯树脂(A)和纤维素酯树脂(B)的总乙酰化度为8〜14%,纤维素酯树脂(A)中的羟基含量为 纤维素酯树脂(B)中的羟基含量不超过6重量%,剩余的羟基已被除乙酸以外的有机酸酯化。 通过上述结构,热转印图像接收纸可以高速染色,可以实现高染色性的印刷,与热转印片具有优异的分离性,不会因增塑剂而产生污迹和模糊,并且允许 要粘附到接收层上的保护层。
    • 9. 发明申请
    • Thermal transfer sheet
    • 热转印片
    • US20090022913A1
    • 2009-01-22
    • US11659163
    • 2005-07-28
    • Tomoko ArakiMunenori Ieshige
    • Tomoko ArakiMunenori Ieshige
    • B41M5/395B41M5/40B41M5/382B41J31/00
    • B41M5/395
    • The present invention is directed to the provision of a thermal transfer sheet that can realize a high maximum transfer density in printing, does not cause blocking during storage in a roll form, can suppress, in a roll form, the transfer of a dye onto a backside layer, which faces the dye layer, does not cause an abnormal transfer in which, in printing on an object, the dye is transferred together with a dye layer onto the object, can further reduce the density in a highlight part in printing, and can form printed matter which is excellent in reproduction of gradation from highlight to shadow without any trouble. The thermal transfer sheet comprises a base material, a heat resistant slip layer provided on one side of the base material, and a dye layer provided on the other side of the base material, wherein the dye layer comprises a binder resin having a loss modulus at 60° C. of not less than 107 Pa, a loss modulus at 100° C. of not less than 106 Pa and a loss modulus at 150° C. in the range of 104 Pa to 105 Pa.
    • 本发明涉及提供能够在印刷中实现高的最大转印密度的热转印片,不会在以卷形式存储期间引起粘连,可以以卷形式抑制将染料转移到 面向染料层的背面层不会引起异常转印,其中在将目标物上印刷染料与染料层一起转印到物体上时,能够进一步降低印刷中的高亮部分的密度, 可以形成从高亮到阴影的渐变再现性优异的印刷品,没有任何麻烦。 热转印片材包括基材,设置在基材的一侧的耐热滑动层和设置在基材另一侧的染料层,其中染料层包含具有损耗模量的粘合剂树脂 60℃,不低于107Pa,在100℃下的损耗模量不低于106Pa,在150℃下的损耗模量在104Pa至105Pa的范围内。
    • 10. 发明授权
    • Thermal transfer sheet
    • 热转印片
    • US06498123B2
    • 2002-12-24
    • US09802677
    • 2001-03-09
    • Taro SuzukiDaisuke FukuiMunenori Ieshige
    • Taro SuzukiDaisuke FukuiMunenori Ieshige
    • B41M540
    • B41M5/443B41M5/44
    • The present invention is to provide a thermal transfer sheet provided with a backface layer having high heat resistance and slipping characteristics by using a one-solution type coating solution adopting an environmentally acceptable general solvent without performing heat treatment such as aging. The thermal transfer sheet provided with the backface layer according to the present invention comprises a transfer ink layer which is melted or sublimated by heating on one surface of a substrate and the backface layer on the other surface of the substrate film, wherein the backface layer comprises a binder which comprises a polyamideimide resin and a polyamideimide silicone resin each having a grass transition temperatures of 200° C. or more based on differential thermal analysis at a specified mixing ratio, a polevalent metal salt of alkyl phosphate and filler at a specified mixing ratio. The thermal transfer sheet prevents the fusion of the film caused by the heat of a thermal head, has high lubricity and stands against high energy, thereby preventing refuses from adhering to the thermal head, enabling high speed printing and also the thermal transfer sheet has high printing stability and running stability.
    • 本发明提供一种具有耐热性和滑动特性的背面层的热转印片,其通过使用采用环境可接受的一般溶剂的单溶液型涂布溶液而不进行诸如老化的热处理。 设置有根据本发明的背面层的热转印片包括通过在衬底的一个表面上加热并在衬底膜的另一个表面上的背面层熔化或升华的转印油墨层,其中背面层包含 包含聚酰胺酰亚胺树脂和聚酰胺酰亚胺硅氧烷树脂的粘结剂,其特征在于,根据特定混合比例的差热分析法,以特定的混合比例,烷基磷酸酯和填料的极性金属盐,具有200℃以上的草地转变温度 。 热转印片防止由热敏头的热量引起的膜的熔合,具有高的润滑性并且抵抗高能量,从而防止拒绝粘附到热敏头上,从而能够进行高速印刷,并且热转印片材具有高的 印刷稳定性和运行稳定性。