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    • 1. 发明授权
    • Chemical-mechanical polishing techniques and methods of end point
detection in chemical-mechanical polishing processes
    • 化学机械抛光技术和化学机械抛光工艺终点检测方法
    • US5439551A
    • 1995-08-08
    • US205312
    • 1994-03-02
    • Scott MeikleTrung T. Doan
    • Scott MeikleTrung T. Doan
    • B24B37/04H01L21/304
    • B24B37/013B24B37/042B24B49/003
    • A semiconductor processing method of detecting polishing end point in a chemical-mechanical polishing planarization process includes the following steps: a) chemical-mechanical polishing an outer surface of a semiconductor substrate using a chemical-mechanical polishing pad; b) during such chemical-mechanical polishing, measuring sound waves emanating from the chemical-mechanical polishing action of the substrate against the pad; c) detecting a change in the sound waves as the surface being chemical-mechanical polished becomes substantially planar; and d) ceasing chemical-mechanical polishing upon detection of the change. Alternately instead of ceasing chemical-mechanical polishing, a mechanical polishing process operational parameter could be changed upon detection of the change and then continuing mechanical polishing with the changed operational parameter. In another aspect of the invention, first and second layers to be polished are provided on a semiconductor wafer. The second layer is in situ measured during polishing to determine its substantial complete removal from the substrate by chemical-mechanical polishing. Such in situ measuring of the second layer during polishing might be conducted by a number of different manners, such as by acoustically, chemically, optically or others. Also claimed is a polishing apparatus for acoustically monitoring polishing action.
    • 在化学机械抛光平面化处理中检测抛光终点的半导体处理方法包括以下步骤:a)使用化学机械抛光垫对半导体衬底的外表面进行化学机械抛光; b)在这种化学机械抛光期间,测量从衬底的化学机械抛光作用发出的声波对衬垫; c)当化学机械抛光的表面变得基本平坦时,检测声波的变化; 和d)在检测到变化后停止化学机械抛光。 或者替代停止化学机械抛光,可以在检测到变化后改变机械抛光工艺操作参数,然后用改变的操作参数继续机械抛光。 在本发明的另一方面,将待抛光的第一和第二层设置在半导体晶片上。 在抛光过程中原位测量第二层,以确定其通过化学机械抛光从基材中大量完全除去。 在抛光期间原位测量第二层可以通过多种不同的方式进行,例如通过声学,化学,光学或其它方式进行。 还要求的是用于声学监测抛光动作的抛光装置。
    • 2. 发明授权
    • Chemical-mechanical polishing processes of planarizing insulating layers
    • 平面化绝缘层的化学机械抛光工艺
    • US5395801A
    • 1995-03-07
    • US130117
    • 1993-09-29
    • Trung T. DoanScott Meikle
    • Trung T. DoanScott Meikle
    • B24B1/00H01L21/304H01L21/3105H01L21/768H01L21/302H01L21/463
    • H01L21/31053H01L21/76819
    • A semiconductor processing method of providing and planarizing an insulating layer on a semiconductor wafer includes the following sequential steps: a) providing a conformal layer of insulating material to a first thickness over a semiconductor wafer having non-planar topography; b) providing a CMP polishing protective layer over the conformal layer to a second thickness, the protective layer being of different composition than the conformal layer; and c) chemical-mechanical polishing the protective layer and conformal layer in a single CMP step using a single CMP slurry and under conditions which in combination with the slurry remove the conformal layer material at a faster rate than the protective layer material, the protective layer upon outward exposure of conformal layer material in high topographical areas restricting material removal from low topographical areas during such chemical-mechanical polishing. Alternately, the protective layer and conformal layer are CMPed in at least two steps using first and second respective CMP slurries. The first CMP step and slurry remove outermost portions of the protective layer in a manner which is substantially selective to the underlying conformal layer to outwardly expose conformal layer material in high topographical areas. The second CMP step and slurry remove the conformal layer material at a faster rate than the protective layer material. The protective layer upon outward exposure of conformal layer material in high topographical areas restricts material removal from low topographical areas during such second CMP step.
    • 在半导体晶片上提供和平坦化绝缘层的半导体处理方法包括以下顺序步骤:a)在具有非平面形貌的半导体晶片上提供具有第一厚度的绝缘材料的共形层; b)在所述共形层上提供CMP抛光保护层至第二厚度,所述保护层具有不同于所述共形层的组成; 和c)在单个CMP步骤中使用单个CMP浆料在保护层和共形层上进行化学机械抛光,在与浆料组合的情况下,以比保护层材料更快的速率去除保形层材料,保护层 在保护层材料在高地形区域中向外暴露时,限制在这种化学机械抛光期间从低地形区域移除材料。 或者,使用第一和第二各自的CMP浆料,至少两个步骤将保护层和共形层CMP化。 第一CMP步骤和浆料以对下面的共形层基本上选择性的方式去除保护层的最外部分,以在高地形区域中向外暴露共形层材料。 第二CMP步骤和浆料以比保护层材料更快的速率除去保形层材料。 保护层在保形层材料向外暴露于高地形区域时,限制了在这样的第二CMP步骤期间从低地形区域的材料去除。
    • 4. 发明授权
    • Container capacitor structure and method of formation thereof
    • 集装箱电容器结构及其形成方法
    • US08124491B2
    • 2012-02-28
    • US12547197
    • 2009-08-25
    • D. Mark DurcanTrung T. DoanRoger R. LeeFernando Gonzalez
    • D. Mark DurcanTrung T. DoanRoger R. LeeFernando Gonzalez
    • H01L21/8242
    • H01L28/91H01L27/10811H01L27/10817H01L27/10852H01L27/10888H01L28/65Y10S257/905
    • Disclosed is a container capacitor structure and method of constructing it. An etch mask and etch are used to expose portions of an exterior surface of electrode (“bottom electrodes”) of the container capacitor structure. The etch provides a recess between proximal pairs of container capacitor structures, which recess is available for forming additional capacitance. Accordingly, a capacitor dielectric and a top electrode are formed on and adjacent to, respectively, both an interior surface and portions of the exterior surface of the first electrode. Advantageously, surface area common to both the first electrode and second electrodes is increased over using only the interior surface, which provides additional capacitance without a decrease in spacing for clearing portions of the capacitor dielectric and the second electrode away from a contact hole location. Furthermore, such clearing of the capacitor dielectric and the second electrode portions may be done at an upper location of a substrate assembly in contrast to clearing at a bottom location of a contact via.
    • 公开了一种容器电容器结构及其构造方法。 蚀刻掩模和蚀刻用于暴露容器电容器结构的电极(“底部电极”)的外部表面的部分。 蚀刻在容器电容器结构的近端对之间提供凹槽,该凹槽可用于形成额外的电容。 因此,电容器电介质和顶电极分别形成在第一电极的外表面的内表面和部分上并相邻。 有利地,仅使用内表面增加了第一电极和第二电极两者共同的表面积,这提供了额外的电容,而不会减小用于清除电容器电介质部分和第二电极远离接触孔位置的间隔。 此外,与在接触通孔的底部位置处的清除相反,电容器电介质和第二电极部分的这种清除可以在衬底组件的上部位置进行。
    • 9. 发明授权
    • Selective provision of a diblock copolymer material
    • 选择性提供二嵌段共聚物材料
    • US07625694B2
    • 2009-12-01
    • US10840535
    • 2004-05-06
    • Eugene P. MarshDaryl C. NewTrung T. Doan
    • Eugene P. MarshDaryl C. NewTrung T. Doan
    • B05D1/36G03F1/00
    • H01L21/0274G03F7/039H01L21/312
    • Disclosed herein are techniques for using diblock copolymer (DBCP) films as etch masks to form small dots or holes in integrated circuit layers. In an embodiment, the DBCP film is deposited on the circuit layer to be etched. Then the DCBP film is confined to define an area of interest in the DCBP film in which hexagonal domains will eventually be formed. Such confinement can constitute masking and exposing the DCBP film using photolithographic techniques. Such masking preferably incorporates knowledge of the domain spacing and/or grain size of the to-be-formed domains in the area of interest to ensure that a predictable number and/or orientation of the domains will result in the area of interest, although this is not strictly necessary in all useful embodiments. Domains are then formed in the area of interest in the DBCP film which comprises a hexagonal array of cylindrical domains in a matrix. The film is then treated (e.g., with osmium or ozone) to render either the domains or the matrix susceptible to removal, while the other component is then used as a mask to etch either dots or holes in the underlying circuit layer.
    • 本文公开了使用二嵌段共聚物(DBCP)膜作为蚀刻掩模在集成电路层中形成小点或孔的技术。 在一个实施例中,DBCP膜沉积在待蚀刻的电路层上。 然后将DCBP膜限制在DCBP膜中限定最终将形成六方结构域的感兴趣区域。 这种约束可以使用光刻技术构成掩蔽和暴露DCBP膜。 这种掩蔽优选地结合了感兴趣区域中待形成区域的结构域间隔和/或晶粒尺寸的知识,以确保域的可预测数量和/或取向将导致感兴趣的区域,尽管这 在所有有用的实施例中并不是绝对必要的。 然后在DBCP膜中的感兴趣区域中形成畴,其包括在矩阵中的圆柱形域的六边形阵列。 然后将膜处理(例如,用锇或臭氧)以使得区域或基质易于除去,而另一种组分然后用作掩模来蚀刻底层电路层中的任何点或孔。
    • 10. 发明申请
    • CO-SPUTTER DEPOSITION OF METAL-DOPED CHALCOGENIDES
    • 金属聚合物的共溅射沉积
    • US20090098717A1
    • 2009-04-16
    • US12249744
    • 2008-10-10
    • Jiutao LiAllen McTeerGregory HerdtTrung T. Doan
    • Jiutao LiAllen McTeerGregory HerdtTrung T. Doan
    • H01L31/20
    • C23C14/548C23C14/0623C23C14/3464H01L45/085H01L45/1233H01L45/142H01L45/143H01L45/1625
    • The present invention is related to methods and apparatus that allow a chalcogenide glass such as germanium selenide (GexSe1-x) to be doped with a metal such as silver, copper, or zinc without utilizing an ultraviolet (UV) photodoping step to dope the chalcogenide glass with the metal. The chalcogenide glass doped with the metal can be used to store data in a memory device. Advantageously, the systems and methods co-sputter the metal and the chalcogenide glass and allow for relatively precise and efficient control of a constituent ratio between the doping metal and the chalcogenide glass. Further advantageously, the systems and methods enable the doping of the chalcogenide glass with a relatively high degree of uniformity over the depth of the formed layer of chalcogenide glass and the metal. Also, the systems and methods allow a metal concentration to be varied in a controlled manner along the thin film depth.
    • 本发明涉及允许诸如硒化锗(GexSe1-x)的硫族化物玻璃掺杂金属如银,铜或锌的方法和装置,而不用紫外线(UV)光二极化步骤来掺杂硫族化物 玻璃与金属。 掺杂有金属的硫族化物玻璃可用于将数据存储在存储器件中。 有利的是,系统和方法共同溅射金属和硫族化物玻璃,并允许相对精确和有效地控制掺杂金属和硫族化物玻璃之间的组成比。 进一步有利的是,这些系统和方法能够在硫族化物玻璃和金属的形成层的深度上以相对高的均匀度掺杂硫族化物玻璃。 而且,这些系统和方法允许以薄膜深度的受控方式改变金属浓度。