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    • 3. 发明授权
    • Method for removing sodium salts from polyphosphazene polymer solutions
    • 从聚磷腈聚合物溶液中除去钠盐的方法
    • US4477656A
    • 1984-10-16
    • US572271
    • 1984-01-20
    • Trent F. LongoVispi R. SagarMark L. Stayer
    • Trent F. LongoVispi R. SagarMark L. Stayer
    • C08G79/02C08G79/04
    • C08G79/025
    • An improved method for removing sodium salts from mixtures of such salts and polyaryloxyphosphazene or polyalkoxyphosphazene or polyalkoxyaryloxyphosphazene polymer solutions is provided. The method involves first treating the mixture with an acid to neutralize any excess alkoxide or aryloxide. Then, water is added to the mixture to extract the sodium salts therefrom resulting in an at least partial separation of the mixture into a polyphosphazene polymer solution phase and a brine phase comprising water and the sodium salts. Following addition of the water to the mixture, a sulfated fatty acid ester of a natural non-petroleum based oil is added to the mixture to effect a more complete separation of the mixture into the polyphosphazene polymer solution phase and the brine phase. The polyphosphazene polymer solution phase is then separated from the brine phase.
    • 提供了一种用于从这些盐与聚芳基磷腈或聚烷氧基磷腈或聚烷氧基氧基磷腈聚合物溶液的混合物中除去钠盐的改进方法。 该方法首先用酸处理混合物以中和任何过量的醇盐或芳氧化物。 然后,将水加入到混合物中以从其中提取钠盐,从而将混合物至少部分分离成聚磷腈聚合物溶液相和包含水和钠盐的盐水相。 在向混合物中加入水之后,向混合物中加入天然非石油基油的硫酸化脂肪酸酯,以使混合物更完全分离成聚磷腈聚合物溶液相和盐水相。 然后将聚磷腈聚合物溶液相与盐水相分离。