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1. 发明授权

US08142931B2 Nonaqueous electrolyte secondary battery and method of manufacturing negative electrode thereof 失效
标题翻译：非水电解质二次电池及其负极的制造方法
公开(公告)号：US08142931B2
公开(公告)日：2012-03-27
申请号：US12088323
申请日：2007-10-11
申请人： Toshitada Sato , Daisuke Suetsugu , Katsumi Kashiwagi , Kazuyoshi Honda
发明人： Toshitada Sato , Daisuke Suetsugu , Katsumi Kashiwagi , Kazuyoshi Honda
IPC分类号： H01M4/13 , H01M4/58
CPC分类号： H01M4/139 , H01M4/0471 , H01M4/134 , H01M4/1395 , H01M4/505 , H01M4/525 , H01M4/582 , H01M4/5825 , H01M10/0525 , H01M2004/021 , H01M2004/025 , H01M2004/027 , Y02T10/7011
摘要： A method of manufacturing a negative electrode for a nonaqueous electrolyte secondary battery includes the following three steps of: A) fabricating the negative electrode by depositing a negative electrode active material on a current collector; B) heat-treating the negative electrode; and C) imparting lithium to the negative electrode active material after the B step.
摘要翻译：一种制造非水电解质二次电池用负极的方法包括以下三个步骤：A）通过在集电体上沉积负极活性物质来制造负极; B）对负极进行热处理; 和C）在B步骤之后将锂赋予负极活性材料。

2. 发明授权

US08486549B2 Lithium ion secondary battery 失效
标题翻译：锂离子二次电池
公开(公告)号：US08486549B2
公开(公告)日：2013-07-16
申请号：US12600391
申请日：2008-07-18
申请人： Kazuyoshi Honda , Toshitada Sato , Daisuke Suetsugu , Katsumi Kashiwagi , Kunihiko Bessho
发明人： Kazuyoshi Honda , Toshitada Sato , Daisuke Suetsugu , Katsumi Kashiwagi , Kunihiko Bessho
IPC分类号： H01M6/10 , H01M4/58
CPC分类号： H01M10/0525 , H01M4/0421 , H01M4/131 , H01M4/134 , H01M4/1391 , H01M4/1395 , H01M4/386 , H01M4/387 , H01M4/485 , H01M10/446
摘要： A lithium ion secondary battery including: a positive electrode current collector; a positive electrode active material layer that is provided in contact with the positive electrode current collector; a separator layer that is provided on a side of the positive electrode active material layer on which the positive electrode current collector is not provided; a negative electrode active material layer that is provided on a side of the separator layer on which the positive electrode active material layer is not provided, that primarily contains silicon or tin, and that includes a opposing portion opposing the positive electrode active material layer and a non-opposing portion not opposing the positive electrode active material layer, the opposing portion and the non-opposing portion containing lithium produced by a thin film-forming method; and a negative electrode current collector that is provided on a side of the negative electrode active material layer on which the separator layer is not provided. Thereby, deformation of the negative electrode and deterioration in cycle characteristics accompanied by such deformation can be prevented.
摘要翻译： 1.一种锂离子二次电池，包括：正极集电体; 设置为与正极集电体接触的正极活性物质层; 设置在不设置正极集电体的正极活性物质层的一侧的隔离层; 设置在不设置正极活性物质层的隔板层的一侧的负极活性物质层，其主要含有硅或锡，并且包括与正极活性物质层相对的相对部分和不与正极活性物质层相对的非相对部分，相对部分和非相对部分含有通过薄膜形成方法生产的锂; 以及负极集电体，其设置在不设置隔板层的负极活性物质层的一侧。由此，可以防止负极的变形和伴随这种变形的循环特性的劣化。

3. 发明申请

US20100167112A1 LITHIUM ION SECONDARY BATTERY 失效
标题翻译：锂离子二次电池
公开(公告)号：US20100167112A1
公开(公告)日：2010-07-01
申请号：US12600391
申请日：2008-07-18
申请人： Kazuyoshi Honda , Toshitada Sato , Daisuke Suetsugu , Katsumi Kashiwagi , Kunihiko Bessho
发明人： Kazuyoshi Honda , Toshitada Sato , Daisuke Suetsugu , Katsumi Kashiwagi , Kunihiko Bessho
IPC分类号： H01M6/10 , H01M4/58
CPC分类号： H01M10/0525 , H01M4/0421 , H01M4/131 , H01M4/134 , H01M4/1391 , H01M4/1395 , H01M4/386 , H01M4/387 , H01M4/485 , H01M10/446
摘要： A lithium ion secondary battery including: a positive electrode current collector; a positive electrode active material layer that is provided in contact with the positive electrode current collector; a separator layer that is provided on a side of the positive electrode active material layer on which the positive electrode current collector is not provided; a negative electrode active material layer that is provided on a side of the separator layer on which the positive electrode active material layer is not provided, that primarily contains silicon or tin, and that includes a opposing portion opposing the positive electrode active material layer and a non-opposing portion not opposing the positive electrode active material layer, the opposing portion and the non-opposing portion containing lithium produced by a thin film-forming method; and a negative electrode current collector that is provided on a side of the negative electrode active material layer on which the separator layer is not provided. Thereby, deformation of the negative electrode and deterioration in cycle characteristics accompanied by such deformation can be prevented.
摘要翻译： 1.一种锂离子二次电池，包括：正极集电体; 设置为与正极集电体接触的正极活性物质层; 设置在不设置正极集电体的正极活性物质层的一侧的隔离层; 设置在不设置正极活性物质层的隔板层的一侧的负极活性物质层，其主要含有硅或锡，并且包括与正极活性物质层相对的相对部分和不与正极活性物质层相对的非相对部分，相对部分和非相对部分含有通过薄膜形成方法生产的锂; 以及负极集电体，其设置在不设置隔板层的负极活性物质层的一侧。由此，可以防止负极的变形和伴随这种变形的循环特性的劣化。

4. 发明申请

US20100151322A1 NONAQUEOUS ELECTROLYTE SECONDARY BATTERY AND METHOD OF MANUFACTURING NEGATIVE ELECTRODE THEREOF 失效
标题翻译：非电解电解质二次电池及其制造负极的方法
公开(公告)号：US20100151322A1
公开(公告)日：2010-06-17
申请号：US12088323
申请日：2007-10-11
申请人： Toshitada Sato , Daisuke Suetsugu , Katsumi Kashiwagi , Kazuyoshi Honda
发明人： Toshitada Sato , Daisuke Suetsugu , Katsumi Kashiwagi , Kazuyoshi Honda
IPC分类号： H01M10/052 , H01M4/26 , H01M4/48
CPC分类号： H01M4/139 , H01M4/0471 , H01M4/134 , H01M4/1395 , H01M4/505 , H01M4/525 , H01M4/582 , H01M4/5825 , H01M10/0525 , H01M2004/021 , H01M2004/025 , H01M2004/027 , Y02T10/7011
摘要： Disclosed is a method for producing a negative electrode for nonaqueous electrolyte batteries, which comprises the following three steps: (A) a step for forming a negative electrode by depositing a negative electrode active material on a collector; (B) a step for subjecting the negative electrode to a heat treatment; and (C) a step for providing the negative electrode active material with lithium after the step (B).
摘要翻译：公开了一种非水电解质电池用负极的制造方法，其特征在于，包括以下三个步骤：（A）通过在集电体上沉积负极活性物质形成负极的工序; （B）负极进行热处理的工序; 和（C）在步骤（B）之后提供负极活性物质的步骤。

5. 发明申请

US20100129711A1 NEGATIVE ELECTRODE FOR NON-AQUEOUS ELECTROLYTE SECONDARY BATTERY, METHOD FOR PRODUCING THE SAME, AND NON-AQUEOUS ELECTROLYTE SECONDARY BATTERY 失效
标题翻译：用于非水电解质二次电池的负极，其制造方法和非水电解质二次电池
公开(公告)号：US20100129711A1
公开(公告)日：2010-05-27
申请号：US12303854
申请日：2007-08-22
申请人： Katsumi Kashiwagi , Kazuyoshi Honda , Masaki Hasegawa , Masaya Ugaji , Yasutaka Kogetsu , Shuji Ito
发明人： Katsumi Kashiwagi , Kazuyoshi Honda , Masaki Hasegawa , Masaya Ugaji , Yasutaka Kogetsu , Shuji Ito
IPC分类号： H01M4/02 , H01M4/04 , B05D5/12
CPC分类号： H01M4/13 , H01M4/386 , H01M4/40 , H01M4/70 , H01M10/0525 , H01M2004/025 , H01M2004/027
摘要： This invention provides a negative electrode and a non-aqueous electrolyte secondary battery including the negative electrode. The negative electrode includes a Li-absorbing element as a negative electrode active material, is free from deformation, separation of the negative electrode active material layer from the negative electrode current collector, and deposition of lithium on the negative electrode current collector, and is excellent in cycle characteristic, large-current discharge characteristic, and low-temperature discharge characteristic.The negative electrode of this invention includes: a current collector having depressions and protrusions on a surface in the thickness direction thereof; and a negative electrode active material layer that includes a plurality of columns containing a negative electrode active material that absorbs and releases lithium ions, the columns being grown outwardly from the surface of the current collector. The negative electrode of this invention is characterized in that the columns are grown at an inclination angle relative to the direction perpendicular to the surface of the current collector, and that the inclination angle of the columns changes reversibly depending on absorption and release of lithium ions by the negative electrode active material.
摘要翻译：本发明提供一种负极和含有负极的非水电解质二次电池。负极包括作为负极活性物质的Li吸收元件，没有变形，负极活性物质层与负极集电体分离，并且在负极集电体上沉积锂，并且优异循环特性，大电流放电特性和低温放电特性。本发明的负极包括：在其厚度方向的表面上具有凹陷和突起的集电器; 以及包含吸收和释放锂离子的负极活性物质的多个列的负极活性物质层，所述列从集电体的表面向外生长。本发明的负极的特征在于，柱相对于与集电体的表面垂直的方向以倾斜角度生长，并且柱的倾斜角随着锂离子的吸收和释放而可逆地变化负极活性物质。

6. 发明授权

US08389156B2 Negative electrode for non-aqueous electrolyte secondary battery, method for producing the same, and non-aqueous electrolyte secondary battery 失效
标题翻译：非水电解质二次电池用负极及其制造方法以及非水电解质二次电池
公开(公告)号：US08389156B2
公开(公告)日：2013-03-05
申请号：US12303854
申请日：2007-08-22
申请人： Katsumi Kashiwagi , Kazuyoshi Honda , Masaki Hasegawa , Masaya Ugaji , Yasutaka Kogetsu , Shuji Ito
发明人： Katsumi Kashiwagi , Kazuyoshi Honda , Masaki Hasegawa , Masaya Ugaji , Yasutaka Kogetsu , Shuji Ito
IPC分类号： H01M4/02
CPC分类号： H01M4/13 , H01M4/386 , H01M4/40 , H01M4/70 , H01M10/0525 , H01M2004/025 , H01M2004/027
摘要： This invention provides a negative electrode and a non-aqueous electrolyte secondary battery including the negative electrode. The negative electrode includes a Li-absorbing element as a negative electrode active material, is free from deformation, separation of the negative electrode active material layer from the negative electrode current collector, and deposition of lithium on the negative electrode current collector, and is excellent in cycle characteristic, large-current discharge characteristic, and low-temperature discharge characteristic.The negative electrode of this invention includes: a current collector having depressions and protrusions on a surface in the thickness direction thereof; and a negative electrode active material layer that includes a plurality of columns containing a negative electrode active material that absorbs and releases lithium ions, the columns being grown outwardly from the surface of the current collector. The negative electrode of this invention is characterized in that the columns are grown at an inclination angle relative to the direction perpendicular to the surface of the current collector, and that the inclination angle of the columns changes reversibly depending on absorption and release of lithium ions by the negative electrode active material.
摘要翻译：本发明提供一种负极和含有负极的非水电解质二次电池。负极包括作为负极活性物质的Li吸收元件，没有变形，负极活性物质层与负极集电体分离，并且在负极集电体上沉积锂，并且优异循环特性，大电流放电特性和低温放电特性。本发明的负极包括：在其厚度方向的表面上具有凹陷和突起的集电器; 以及包含吸收和释放锂离子的负极活性物质的多个列的负极活性物质层，所述列从集电体的表面向外生长。本发明的负极的特征在于，柱相对于与集电体的表面垂直的方向以倾斜角度生长，并且柱的倾斜角随着锂离子的吸收和释放而可逆地变化负极活性物质。

7. 发明授权

US08715848B2 Lithium ion secondary battery with insulating member having a broken hollow portion and method for producing the same 失效
标题翻译：具有中空部分断裂的绝缘部件的锂离子二次电池及其制造方法
公开(公告)号：US08715848B2
公开(公告)日：2014-05-06
申请号：US13254111
申请日：2011-01-12
申请人： Kunihiko Mineya , Katsumi Kashiwagi
发明人： Kunihiko Mineya , Katsumi Kashiwagi
IPC分类号： H01M2/14 , H01M10/0587 , H01M10/04
CPC分类号： H01M10/0431 , H01M2/08 , H01M10/0409 , H01M10/0525 , H01M10/0587 , Y10T29/49108
摘要： An electrode assembly (30) is formed by combining a positive electrode plate (14), a separator (15), and a negative electrode plate (18), and the electrode assembly (30) was wound. An insulating member (21) having a hollow portion (22) is placed on the positive electrode plate (14), the negative electrode plate (18), or the separator (15) before the end of the winding step so that the insulating member (21) is incorporated inside the outermost of the electrode assembly (30) and into a corner portion (31) of the electrode assembly (30) in the winding direction. After a winding end portion (32) of the electrode assembly (30) is fixed, the hollow portion (22) is broken. Thereby, a space (20) resulting from the hollow portion (22) is formed inside the outermost of the electrode assembly (30).
摘要翻译：通过组合正电极板（14），隔板（15）和负极板（18）形成电极组件（30），并缠绕电极组件（30）。具有中空部分（22）的绝缘构件（21）被放置在正极板（14），负极板（18）或隔板（15）之前，在卷绕步骤结束之前，绝缘构件（21）在电极组件（30）的最外侧并入电极组件（30）的沿着卷绕方向的角部（31）内。在电极组件（30）的卷绕端部（32）固定之后，中空部分（22）被破坏。由此，在电极组件（30）的最外侧形成由中空部（22）形成的空间（20）。

8. 发明申请

US20120208084A1 NEGATIVE ELECTRODE FOR LITHIUM ION SECONDARY BATTERIES, AND LITHIUM ION SECONDARY BATTERY 审中-公开
标题翻译：用于锂离子二次电池和锂离子二次电池的负极
公开(公告)号：US20120208084A1
公开(公告)日：2012-08-16
申请号：US13502068
申请日：2011-04-26
申请人： Tatsuki Hiraoka , Taisuke Yamamoto , Katsumi Kashiwagi , Masaya Ugaji
发明人： Tatsuki Hiraoka , Taisuke Yamamoto , Katsumi Kashiwagi , Masaya Ugaji
IPC分类号： H01M4/70 , H01M4/66 , H01M4/64
CPC分类号： H01M4/70 , H01M4/134 , H01M4/386 , H01M4/387 , H01M4/622 , H01M10/052
摘要： A negative electrode for lithium ion secondary batteries, including: a negative electrode current collector having a plurality of protrusions formed on a surface thereof; and a plurality of granular bodies, the granular bodies being supported on the protrusions, respectively, and including an alloy-formable active material capable of absorbing and releasing lithium ions, wherein: the granular bodies have a resin layer on their respective surfaces; and the resin layer includes a first resin component which is at least one selected from polyimides and polyacrylic acid, and a second resin component which is composed of a copolymer including vinylidene fluoride units and hexafluoropropylene units. A lithium ion secondary battery including the above negative electrode.
摘要翻译： 1.一种锂离子二次电池用负极，其特征在于，具备：在其表面形成有多个突起的负极集电体; 以及多个粒状体，所述粒状体分别被支撑在所述突起上，并且包括能够吸收和释放锂离子的合金可形成的活性物质，其中：所述粒状体在其各自表面上具有树脂层; 树脂层包括选自聚酰亚胺和聚丙烯酸中的至少一种的第一树脂成分和由包含偏二氟乙烯单元和六氟丙烯单元的共聚物构成的第二树脂成分。包括上述负极的锂离子二次电池。

9. 发明申请

US20110318621A1 LITHIUM ION SECONDARY BATTERY AND METHOD FOR PRODUCING THE SAME 失效
标题翻译：锂离子二次电池及其制造方法
公开(公告)号：US20110318621A1
公开(公告)日：2011-12-29
申请号：US13254111
申请日：2011-01-12
申请人： Kunihiko Mineya , Katsumi Kashiwagi
发明人： Kunihiko Mineya , Katsumi Kashiwagi
IPC分类号： H01M10/0587 , H01M10/36
CPC分类号： H01M10/0431 , H01M2/08 , H01M10/0409 , H01M10/0525 , H01M10/0587 , Y10T29/49108
摘要： An electrode assembly (30) is formed by combining a positive electrode plate (14), a separator (15), and a negative electrode plate (18), and the electrode assembly (30) was wound. An insulating member (21) having a hollow portion (22) is placed on the positive electrode plate (14), the negative electrode plate (18), or the separator (15) before the end of the winding step so that the insulating member (21) is incorporated inside the outermost of the electrode assembly (30) and into a corner portion (31) of the electrode assembly (30) in the winding direction. After a winding end portion (32) of the electrode assembly (30) is fixed, the hollow portion (22) is broken. Thereby, a space (20) resulting from the hollow portion (22) is formed inside the outermost of the electrode assembly (30).
摘要翻译：通过组合正电极板（14），隔板（15）和负极板（18）形成电极组件（30），并缠绕电极组件（30）。具有中空部分（22）的绝缘构件（21）被放置在正极板（14），负极板（18）或隔板（15）之前，在卷绕步骤结束之前，绝缘构件（21）在电极组件（30）的最外侧并入电极组件（30）的沿着卷绕方向的角部（31）内。在电极组件（30）的卷绕端部（32）固定之后，中空部分（22）被破坏。由此，在电极组件（30）的最外侧形成由中空部（22）形成的空间（20）。

10. 发明申请

US20120070740A1 NEGATIVE ELECTRODE FOR LITHIUM ION SECONDARY BATTERY AND LITHIUM ION SECONDARY BATTERY 审中-公开
标题翻译：用于锂离子二次电池和锂离子二次电池的负极
公开(公告)号：US20120070740A1
公开(公告)日：2012-03-22
申请号：US13322002
申请日：2011-03-16
申请人： Katsumi Kashiwagi , Hideharu Takezawa , Masaya Ugaji
发明人： Katsumi Kashiwagi , Hideharu Takezawa , Masaya Ugaji
IPC分类号： H01M4/134
CPC分类号： H01M4/131 , H01M4/0421 , H01M4/134 , H01M4/386 , H01M4/485 , H01M4/70
摘要： Disclosed is a negative electrode for a lithium ion secondary battery, the negative electrode including a negative electrode current collector with protrusions formed on a surface thereon, and columnar bodies being carried on the protrusions and comprising an alloy active material capable of absorbing and releasing lithium ions. The columnar bodies each have a multilayer structure in which a plurality of unit layers comprising the alloy active material are stacked sequentially on the surface of the protrusion, and the average layer thickness of the unit layer in a region within 20% of the thickness of the columnar body extending from the surface of the protrusion is smaller than that in a region within 80% of the thickness of the columnar body extending from the top of the columnar body.
摘要翻译：公开了一种用于锂离子二次电池的负极，该负极包括在其表面上形成有突起的负极集电体，并且在该突起上承载有柱状体，并且包括能够吸收和释放锂离子的合金活性材料。柱状体各自具有多层结构，其中包括合金活性物质的多个单位层依次层叠在突起的表面上，单位层的平均层厚度在厚度的20％以内的区域中从突起的表面延伸的柱状体比从柱状体的顶部延伸的柱状体的厚度的80％以内的区域小。

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