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    • 2. 发明授权
    • Hexafluoropropylene oxide compounds and a method of making same
    • 六氟环氧丙烷化合物及其制备方法
    • US5414119A
    • 1995-05-09
    • US203250
    • 1994-03-01
    • Yasuo TarumiNoriyuki KoikeToshio Takago
    • Yasuo TarumiNoriyuki KoikeToshio Takago
    • C07C59/60C07C51/58
    • C07C59/60
    • Hexafluoropropylene oxide (HFPO) compounds, including polymers, expressed by the general chemical formula (1) below: ##STR1## wherein R.sup.1 is a single bond, an alkylene group of 1 to 10 carbon atoms, or said alkylene group in which a part of, or all of, the hydrogen atoms are substituted by fluorine atoms, Rf is a fluorine atom, a perfluoroalkyl group of 1 to 10 carbon atoms, or a perfluoroalkyl ether group, and n is 0 or an integer of at least 1. A manufacturing method for the HFPO compounds which is characterized by the reaction between hexafluoropropylene oxide and a vinyl group containing compound, expressed by the general chemical formula (2) below: ##STR2## wherein R.sup.1 and Rf are same as above. The compounds have utility as important intermediate raw materials for the production of novel functional silicone compounds having HFPO polymer units.
    • 由下列通式(1)表示的六氟环氧丙烷(HFPO)化合物,包括聚合物:其中R 1为单键,1至10个碳原子的亚烷基或所述亚烷基,其中 一部分或全部氢原子被氟原子取代,Rf为氟原子,1-10个碳原子的全氟烷基或全氟烷基醚基,n为0或至少为1的整数 以下通式(2)表示的特征在于六氟环氧丙烷与含乙烯基的化合物反应的HFPO化合物的制造方法:其中R1和Rf与上述相同。 该化合物可用作生产具有HFPO​​聚合物单元的新型功能硅氧烷化合物的重要中间体原料。