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1. 发明授权

US08221559B2 Metal surface treatment liquid for cation electrodeposition coating 有权
标题翻译：用于阳离子电沉积涂层的金属表面处理液
公开(公告)号：US08221559B2
公开(公告)日：2012-07-17
申请号：US12077464
申请日：2008-03-19
申请人： Toshio Inbe , Hiroshi Kameda , Thomas Kolberg
发明人： Toshio Inbe , Hiroshi Kameda , Thomas Kolberg
IPC分类号： C23C10/02 , C25D13/12
CPC分类号： C23C22/34 , C23C2222/20 , C25D3/56 , C25D13/20
摘要： A surface treatment with a zirconium ion that enables sufficient throwing power and superior anti-corrosion properties to be exhibited when thus surface treated metal base material is subjected to cation electrodeposition coating is provided. A metal surface treatment liquid thereof for cation electrodeposition coating includes zirconium ions, copper ions, and other metal ions, and having a pH of 1.5 to 6.5, in which: the other metal ions are at least one selected from the group consisting of tin ions, indium ions, aluminum ions, niobium ions, tantalum ions, yttrium ions and cerium ions; the concentration of zirconium ions is 10 to 10,000 ppm; the concentration ratio of the copper ions to the zirconium ions is 0.005 to 1 on a mass basis; and the concentration ratio of the other metal ions to the copper ions is 0.1 to 1,000 on a mass basis.
摘要翻译：提供了一种用这种表面处理的金属基材进行阳离子电沉积涂覆时能够发挥足够的抛光力和优异的抗腐蚀性能的锆离子的表面处理。用于阳离子电沉积涂层的金属表面处理液包括锆离子，铜离子和其它金属离子，并且具有1.5至6.5的pH，其中：其它金属离子是选自锡离子铟离子，铝离子，铌离子，钽离子，钇离子和铈离子; 锆离子的浓度为10〜10000ppm; 基于质量计，铜离子与锆离子的浓度比为0.005〜1; 并且其他金属离子与铜离子的浓度比以质量计为0.1〜1,000。

2. 发明申请

US20100243465A1 METHOD OF PRODUCING SURFACE-TREATED METAL MATERIAL AND METHOD OF PRODUCING COATED METAL ITEM 有权
标题翻译：生产表面处理金属材料的方法及其制造方法
公开(公告)号：US20100243465A1
公开(公告)日：2010-09-30
申请号：US12679048
申请日：2008-09-26
申请人： Toshio Inbe , Hiroshi Kameda , Thomas Kolberg
发明人： Toshio Inbe , Hiroshi Kameda , Thomas Kolberg
IPC分类号： C23C22/80 , B05D3/10
CPC分类号： C23C22/361 , C09D5/4488 , C23C22/34 , C23C22/83 , C23C2222/20 , C25D13/04
摘要： A method of producing a surface-treated metal material, comprising: surface treating a metal material using a treatment liquid (1), which comprises from 10 to 10,000 ppm of tin ions and has a pH of 1.0 or greater, and subjecting the metal material that has undergone surface treatment with the treatment liquid (1) to an additional chemical conversion treatment using a treatment liquid (2), which comprises zirconium ions and/or titanium ions.
摘要翻译：一种表面处理金属材料的制造方法，其特征在于，包括：使用处理液（1）对金属材料进行表面处理，所述处理液包含10〜10000ppm的锡离子，pH为1.0以上，并对所述金属材料已经用处理液（1）进行表面处理，使用包含锆离子和/或钛离子的处理液（2）进行附加的化学转化处理。

3. 发明申请

US20080230395A1 Metal surface treatment liquid for cation electrodeposition coating 有权
标题翻译：用于阳离子电沉积涂层的金属表面处理液
公开(公告)号：US20080230395A1
公开(公告)日：2008-09-25
申请号：US12077464
申请日：2008-03-19
申请人： Toshio Inbe , Hiroshi Kameda , Thomas Kolberg
发明人： Toshio Inbe , Hiroshi Kameda , Thomas Kolberg
IPC分类号： C25D5/00
CPC分类号： C23C22/34 , C23C2222/20 , C25D3/56 , C25D13/20
摘要： A surface treatment with a zirconium ion that enables sufficient throwing power and superior anti-corrosion properties to be exhibited when thus surface treated metal base material is subjected to cation electrodeposition coating is provided. A metal surface treatment liquid thereof for cation electrodeposition coating includes zirconium ions, copper ions, and other metal ions, and having a pH of 1.5 to 6.5, in which: the other metal ions are at least one selected from the group consisting of tin ions, indium ions, aluminum ions, niobium ions, tantalum ions, yttrium ions and cerium ions; the concentration of zirconium ions is 10 to 10,000 ppm; the concentration ratio of the copper ions to the zirconium ions is 0.005 to 1 on a mass basis; and the concentration ratio of the other metal ions to the copper ions is 0.1 to 1,000 on a mass basis.
摘要翻译：提供了一种用这种表面处理的金属基材进行阳离子电沉积涂覆时能够发挥足够的抛光力和优异的抗腐蚀性能的锆离子的表面处理。用于阳离子电沉积涂层的金属表面处理液包括锆离子，铜离子和其它金属离子，并且具有1.5至6.5的pH，其中：其它金属离子是选自锡离子铟离子，铝离子，铌离子，钽离子，钇离子和铈离子; 锆离子的浓度为10〜10000ppm; 基于质量计，铜离子与锆离子的浓度比为0.005〜1; 并且其他金属离子与铜离子的浓度比以质量计为0.1〜1,000。

4. 发明授权

US08784629B2 Method of producing surface-treated metal material and method of producing coated metal item 有权
标题翻译：表面处理金属材料的制造方法及其制造方法
公开(公告)号：US08784629B2
公开(公告)日：2014-07-22
申请号：US12679048
申请日：2008-09-26
申请人： Toshio Inbe , Hiroshi Kameda , Thomas Kolberg
发明人： Toshio Inbe , Hiroshi Kameda , Thomas Kolberg
IPC分类号： C25D13/04 , C23C10/02 , C23C22/80
CPC分类号： C23C22/361 , C09D5/4488 , C23C22/34 , C23C22/83 , C23C2222/20 , C25D13/04
摘要： A method of producing a surface-treated metal material, comprising: surface treating a metal material using a treatment liquid (1), which comprises from 10 to 10,000 ppm of tin ions and has a pH of 1.0 or greater, and subjecting the metal material that has undergone surface treatment with the treatment liquid (1) to an additional chemical conversion treatment using a treatment liquid (2), which comprises zirconium ions and/or titanium ions.
摘要翻译：一种表面处理金属材料的制造方法，其特征在于，包括：使用处理液（1）对金属材料进行表面处理，所述处理液包含10〜10000ppm的锡离子，pH为1.0以上，并对金属材料已经用处理液（1）进行表面处理，使用包含锆离子和/或钛离子的处理液（2）进行附加的化学转化处理。

5. 发明申请

US20080230394A1 Metal surface treatment liquid for cation electrodeposition coating 审中-公开
标题翻译：用于阳离子电沉积涂层的金属表面处理液
公开(公告)号：US20080230394A1
公开(公告)日：2008-09-25
申请号：US12077429
申请日：2008-03-19
申请人： Toshio Inbe , Hiroshi Kameda , Thomas Kolberg
发明人： Toshio Inbe , Hiroshi Kameda , Thomas Kolberg
IPC分类号： C25D3/56
CPC分类号： C23C22/34 , C23C2222/20 , C25D3/56 , C25D3/60 , C25D13/04 , C25D13/20
摘要： A surface treatment with a zirconium ion that enables sufficient throwing power, and superior anti-corrosion properties to be exhibited when thus surface treated metal base material is subjected to cation electrodeposition coating is provided. A metal surface treatment liquid for cation electrodeposition coating includes zirconium ions and tin ions, and has a pH of 1.5 to 6.5, in which: the concentration of zirconium ions is in the range of 10 to 10,000 ppm; and the content of the tin ions to the zirconium ions is 0.005 to 1 on a mass basis. Furthermore, a polyamine compound, copper ions, fluorine ions, and a chelate compound may also be included.
摘要翻译：提供了一种具有能够实现足够的投掷力的锆离子的表面处理，并且当这样表面处理的金属基材进行阳离子电沉积涂覆时，可以发挥优异的抗腐蚀性能。用于阳离子电沉积涂层的金属表面处理液包括锆离子和锡离子，并且具有1.5至6.5的pH，其中：锆离子的浓度在10至10,000ppm的范围内; 并且锡离子与锆离子的含量以质量计为0.005〜1。此外，还可以包括多胺化合物，铜离子，氟离子和螯合化合物。

6. 发明申请

US20090218228A1 Composition for Metal Surface Treatment, Metal Surface Treatment Method And Metal Material 有权
标题翻译：金属表面处理，金属表面处理方法和金属材料的组成
公开(公告)号：US20090218228A1
公开(公告)日：2009-09-03
申请号：US12224628
申请日：2007-02-28
申请人： Toshio Inbe , Thomas Kolberg
发明人： Toshio Inbe , Thomas Kolberg
IPC分类号： B32B15/00 , C11D3/04 , B05D3/10 , C25D5/00 , C23G1/02
CPC分类号： C23C22/48 , C08G59/50 , C08G77/26 , C08K3/10 , C09D163/00 , C09D175/04 , C23C22/50 , C23C22/56 , C23C22/83 , Y10T428/12729 , Y10T428/12736 , Y10T428/12792 , Y10T428/12951
摘要： An easily handleable composition for metal surface treatment is provided which achieves foundation surface concealment, coating adhesion and corrosion resistance equal to or higher than those obtained by the conventional metal surface treatment compositions. This composition for metal surface treatment places no burden on the environment. A method for treating the surface of a metal material in which such a composition for metal surface treatment is used, and a metal material treated by such a metal surface treatment method, are also provided. Specifically disclosed is a metal surface treatment composition used for a treatment of a metal surface, which composition contains a zirconium compound and/or titanium compound substantially not containing fluorine, and an inorganic acid and/or a salt thereof. This metal surface treatment composition has a pH of not less than 1.5 but not more than 6.5.
摘要翻译：提供了用于金属表面处理的易于处理的组合物，其实现了与通过常规金属表面处理组合物获得的那些相同或更高的基础表面隐蔽性，涂层粘附性和耐腐蚀性。这种金属表面处理用组合物不会对环境造成负担。还提供了一种用于处理金属表面处理用金属材料的表面的方法以及通过这种金属表面处理方法处理的金属材料。具体公开了用于处理金属表面的金属表面处理组合物，该组合物含有基本上不含氟的锆化合物和/或钛化合物，以及无机酸和/或其盐。该金属表面处理组合物的pH值不低于1.5但不大于6.5。

7. 发明授权

US08262809B2 Composition for metal surface treatment, metal surface treatment method and metal material 有权
标题翻译：金属表面处理用组合物，金属表面处理方法和金属材料
公开(公告)号：US08262809B2
公开(公告)日：2012-09-11
申请号：US12224628
申请日：2007-02-28
申请人： Toshio Inbe , Thomas Kolberg
发明人： Toshio Inbe , Thomas Kolberg
IPC分类号： C22C22/48 , C25D9/00
CPC分类号： C23C22/48 , C08G59/50 , C08G77/26 , C08K3/10 , C09D163/00 , C09D175/04 , C23C22/50 , C23C22/56 , C23C22/83 , Y10T428/12729 , Y10T428/12736 , Y10T428/12792 , Y10T428/12951
摘要： An easily handleable composition for metal surface treatment is provided which achieves foundation surface concealment, coating adhesion and corrosion resistance equal to or higher than those obtained by the conventional metal surface treatment compositions. This composition for metal surface treatment places no burden on the environment. A method for treating the surface of a metal material in which such a composition for metal surface treatment is used, and a metal material treated by such a metal surface treatment method, are also provided. Specifically disclosed is a metal surface treatment composition used for a treatment of a metal surface, which composition contains a zirconium compound and/or titanium compound substantially not containing fluorine, and an inorganic acid and/or a salt thereof. This metal surface treatment composition has a pH of not less than 1.5 but not more than 6.5.
摘要翻译：提供了用于金属表面处理的易于处理的组合物，其实现了与通过常规金属表面处理组合物获得的那些相同或更高的基础表面隐蔽性，涂层粘附性和耐腐蚀性。这种金属表面处理用组合物不会对环境造成负担。还提供了一种用于处理金属表面处理用金属材料的表面的方法以及通过这种金属表面处理方法处理的金属材料。具体公开了用于处理金属表面的金属表面处理组合物，该组合物含有基本上不含氟的锆化合物和/或钛化合物，以及无机酸和/或其盐。该金属表面处理组合物的pH值不低于1.5但不大于6.5。

8. 发明授权

US08916006B2 Method of treating surface of metal base metallic material treated by the surface treatment method and method of coating the metallic material 有权
标题翻译：通过表面处理方法处理的金属基体金属材料的表面处理方法和涂覆金属材料的方法
公开(公告)号：US08916006B2
公开(公告)日：2014-12-23
申请号：US12440265
申请日：2007-09-07
申请人： Toshio Inbe , Kazuhiro Makino , Hiroshi Kameda , Masanobu Futsuhara
发明人： Toshio Inbe , Kazuhiro Makino , Hiroshi Kameda , Masanobu Futsuhara
IPC分类号： C23C22/34
CPC分类号： C25D5/34 , C23C22/05 , C23C22/34 , C23C22/73 , C23C22/82 , C23C22/83 , C23C28/00 , C23C2222/20 , C25D9/08 , C25D13/20 , Y10T428/24628
摘要： A metal surface treatment method for a metal base material in order to improve the uniformity of a cathodic electrodeposition coating film, the method including: a surface treatment step for forming a chemical conversion film on a metal base material by contacting the metal base material with a metal surface treatment composition including zirconium and/or titanium ions and an adhesive imparting agent characterized in being at least one selected from the group consisting of (A) silicon-containing compound, (B) adhesive imparting metal ion, and (C) adhesive imparting resin; and a heating/drying step to heat and dry the metal base material, on which the chemical conversion film is formed, at 60° C. to 190° C. for at least 30 seconds.
摘要翻译：为了提高阴极电沉积涂膜的均匀性，金属基材的金属表面处理方法，该方法包括：表面处理步骤，用于通过使金属基材与金属基材接触而在金属基材上形成化学转化膜金属表面处理组合物，包括锆和/或钛离子，以及粘合剂赋予剂，其特征在于：选自（A）含硅化合物，（B）赋予金属的金属离子和（C）赋予粘合剂的组中的至少一种树脂; 以及加热干燥步骤，将形成有化学转化膜的金属基材在60℃〜190℃下加热干燥至少30秒钟。

9. 发明授权

US09028667B2 Composition for metal surface treatment, metal surface treatment method, and metal material 有权
标题翻译：金属表面处理用组合物，金属表面处理方法和金属材料
公开(公告)号：US09028667B2
公开(公告)日：2015-05-12
申请号：US13613544
申请日：2012-09-13
申请人： Toshio Inbe , Thomas Kolberg
发明人： Toshio Inbe , Thomas Kolberg
IPC分类号： C23C22/48 , C25D3/02 , C25D11/00 , C09D183/08 , C23C22/34 , C23C22/83 , C25D13/20 , C23C22/02 , C23C22/00
CPC分类号： C25D11/00 , C09D183/08 , C23C22/02 , C23C22/34 , C23C22/361 , C23C22/48 , C23C22/82 , C23C22/83 , C25D3/02 , C25D13/20 , Y02T50/67 , Y10T428/12472 , Y10T428/273 , Y10T428/31529
摘要： A metal material is contacted with a treatment solution containing zirconium and/or titanium compound, and a polyamine compound having a number average molecular weight from 150 to 500,000 and containing from 0.1 mmol to 17 mmol of primary and/or secondary amino group per 1 g of solid content and at least one siloxane unit. Concentration of zirconium and/or titanium compound in the metal surface treatment composition is from 10 ppm to 10,000 ppm with respect to the metal element, and mass ratio of the zirconium and/or titanium element is from 0.1 to 100 with respect to the polyamine compound. The metal material is washed with water after contacted by the treatment solution.
摘要翻译：将金属材料与含有锆和/或钛化合物的处理溶液和数均分子量为150至500,000的多胺化合物接触，并且每1g含有0.1mmol至17mmol的伯和/或仲氨基的固体含量和至少一种硅氧烷单元。金属表面处理组合物中锆和/或钛化合物的浓度相对于金属元素为10ppm〜10000ppm，相对于多胺化合物，锆和/或钛元素的质量比为0.1〜100 。金属材料在用处理溶液接触后用水洗涤。

10. 发明授权

US08828151B2 Composition for metal surface treatment, metal surface treatment method and metal material 有权
标题翻译：金属表面处理用组合物，金属表面处理方法和金属材料
公开(公告)号：US08828151B2
公开(公告)日：2014-09-09
申请号：US13479570
申请日：2012-05-24
申请人： Toshio Inbe , Thomas Kolberg
发明人： Toshio Inbe , Thomas Kolberg
IPC分类号： C23C22/48 , C25D9/00
CPC分类号： C23C22/48 , C08G59/50 , C08G77/26 , C08K3/10 , C09D163/00 , C09D175/04 , C23C22/50 , C23C22/56 , C23C22/83 , Y10T428/12729 , Y10T428/12736 , Y10T428/12792 , Y10T428/12951
摘要： Disclosed is an easily handleable composition for metal surface treatment which enables to achieve foundation surface concealment, coating adhesion and corrosion resistance equal to or higher than those obtained by the conventional metal surface treatment compositions. This composition for metal surface treatment places no burden on the environment. Also disclosed are a method for treating the surface of a metal material wherein such a composition for metal surface treatment is used, and a metal material treated by such a metal surface treatment method. Specifically disclosed is a metal surface treatment composition used for a treatment of a metal surface, which composition contains a zirconium compound and/or titanium compound substantially not containing fluorine, and an inorganic acid and/or a salt thereof. This metal surface treatment composition has a pH of not less than 1.5 but not more than 6.5.
摘要翻译：公开了用于金属表面处理的易于处理的组合物，其能够实现等于或高于通过常规金属表面处理组合物获得的基础表面隐蔽性，涂层粘附性和耐腐蚀性。这种金属表面处理用组合物不会对环境造成负担。还公开了一种处理金属材料的表面的方法，其中使用了这种用于金属表面处理的组合物，以及通过这种金属表面处理方法处理的金属材料。具体公开了用于处理金属表面的金属表面处理组合物，该组合物含有基本上不含氟的锆化合物和/或钛化合物，以及无机酸和/或其盐。该金属表面处理组合物的pH值不低于1.5但不大于6.5。

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