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    • 1. 发明申请
    • Separator for Battery and Alkaline Battery
    • 电池和碱性电池分离器
    • US20080274409A1
    • 2008-11-06
    • US11570135
    • 2005-06-13
    • Toshimitsu HaradaHisashi NagiHiroyuki KawaiSeiji WadaEiji Tano
    • Toshimitsu HaradaHisashi NagiHiroyuki KawaiSeiji WadaEiji Tano
    • H01M2/14
    • H01M2/1666D21H13/16D21H17/37D21H17/56H01M2/1686H01M6/08Y10T428/2913
    • A separator for alkaline batteries which is obtained by bonding 5.0 to 45.0 g/m2 of a highly hygroscopic macromolecular compound of the crosslinking type having carboxyl group to a wetlaid nonwoven fabric comprising an alkali-resistant fiber, followed by crosslinking the macromolecular compound, wherein a silicate compound is added to the highly hygroscopic macromolecular compound of the crosslinking type in an amount of 1.0×10−4 to 10 mg/cm2 per unit area of the separator. By adding the silicate compound, absorption of the electrolyte is increased, the electrolyte can be held for a long time, the electric resistance of the separator itself can be kept small, growth of dendrite can be suppressed, short circuit due to the formed dendrite can be prevented, the volume of the negative electrode material can be increased by suppressing the thickness of the separator after absorbing the electrolyte, impact of dropping can be endured, and oxidative degradation in the alkaline dry cells can be suppressed. An alkaline primary battery can be constructed using the separator.
    • 通过将具有羧基的具有羧基的交联型高吸湿性高分子化合物的5.0〜45.0g / m 2的粘合剂粘合到包含耐碱纤维的湿法成网非织造布上而获得的碱性电池用隔膜, 通过交联大分子化合物,其中将硅酸盐化合物加入到交联型的高吸湿性高分子化合物中,其量为1.0×10 -4至10mg / cm 2, 每单位面积的分离器。 通过添加硅酸盐化合物,电解质的吸收增加,电解质可以保持长时间,隔膜本身的电阻可以保持较小,可以抑制枝晶的生长,由于形成的枝晶可能导致短路 通过抑制吸收电解质后的隔板的厚度,可以提高负极材料的体积,可以耐受下降的冲击,能够抑制碱性干电池的氧化降解。 碱性一次电池可以使用隔膜来构造。
    • 2. 发明授权
    • Separator for battery and alkaline battery
    • 电池和碱性电池分离器
    • US07754387B2
    • 2010-07-13
    • US11570135
    • 2005-06-13
    • Toshimitsu HaradaHisashi NagiHiroyuki KawaiSeiji WadaEiji Tano
    • Toshimitsu HaradaHisashi NagiHiroyuki KawaiSeiji WadaEiji Tano
    • H01M4/68
    • H01M2/1666D21H13/16D21H17/37D21H17/56H01M2/1686H01M6/08Y10T428/2913
    • A separator for alkaline batteries which is obtained by bonding 5.0 to 45.0 g/m2 of a highly hygroscopic macromolecular compound of the crosslinking type having carboxyl group to a wetlaid nonwoven fabric comprising an alkali-resistant fiber, followed by crosslinking the macromolecular compound, wherein a silicate compound is added to the highly hygroscopic macromolecular compound of the crosslinking type in an amount of 1.0×10−4 to 10 mg/cm2 per unit area of the separator. By adding the silicate compound, absorption of the electrolyte is increased, the electrolyte can be held for a long time, the electric resistance of the separator itself can be kept small, growth of dendrite can be suppressed, short circuit due to the formed dendrite can be prevented, the volume of the negative electrode material can be increased by suppressing the thickness of the separator after absorbing the electrolyte, impact of dropping can be endured, and oxidative degradation in the alkaline dry cells can be suppressed. An alkaline primary battery can be constructed using the separator.
    • 一种碱性电池用隔膜,其通过将5.0〜45.0g / m 2的具有羧基的交联型高吸湿性高分子化合物粘合到含有耐碱纤维的湿法成网非织造布上,然后使所述高分子化合物交联而得到, 将硅酸盐化合物加入交联型的高吸湿性高分子化合物中,每单位面积的隔膜的量为1.0×10 -4〜10mg / cm 2。 通过添加硅酸盐化合物,电解质的吸收增加,电解质可以保持长时间,隔膜本身的电阻可以保持较小,可以抑制枝晶的生长,由于形成的枝晶可能导致短路 通过抑制吸收电解质后的隔板的厚度,可以提高负极材料的体积,可以耐受下降的冲击,能够抑制碱性干电池的氧化降解。 碱性一次电池可以使用隔膜来构造。
    • 3. 发明申请
    • Alkaline dry battery
    • 碱性干电池
    • US20080085448A1
    • 2008-04-10
    • US11907170
    • 2007-10-10
    • Seiji WadaEiji Tano
    • Seiji WadaEiji Tano
    • H01M4/38H01M4/50
    • H01M4/50H01M4/06H01M4/364H01M4/38H01M4/625H01M6/08H01M6/085
    • A high-quality alkaline dry battery with small variation in the internal resistance having suppressed variations in the heights of positive electrode mixture pellets in a manufacturing process is provided. In an alkaline dry battery including: at least one hollow cylindrical positive electrode mixture pellet containing manganese dioxide and graphite; a gel negative electrode containing zinc; and a separator interposed between the positive electrode mixture pellet and gel negative electrode; manganese dioxide containing at least manganese dioxide particles having a particle diameter of 10 μm or less of 25 to 35% and manganese dioxide particles having a particle diameter of 60 to 100 μm of 15 to 25% in a particle size distribution based on volume is used.
    • 提供了一种在制造过程中,正极混合物颗粒的高度变化抑制了内阻变化小的高品质碱性干电池。 在碱性干电池中,包括:含有二氧化锰和石墨的至少一个空心圆柱形正电极混合物颗粒; 含锌的凝胶负极; 以及插入正极混合物颗粒和凝胶负极之间的隔膜; 使用二氧化锰至少含有粒径为10μm以下的二氧化锰粒子为25〜35%,粒径为60〜100μm的二氧化锰粒子的体积分数为15〜25%。 。