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    • 1. 发明授权
    • Epoxy curing agent and one-component (type) epoxy resin composition
    • 环氧固化剂和单组分(型)环氧树脂组合物
    • US6040398A
    • 2000-03-21
    • US146075
    • 1998-09-02
    • Toshihiko KinshoMunekazu SatakeTadakazu Miyazaki
    • Toshihiko KinshoMunekazu SatakeTadakazu Miyazaki
    • C08G59/50C08G65/333C08L63/00C09K3/10C08F283/000
    • C09K3/10C08G59/5046C08G65/33306C08L63/00C09K2200/0647
    • An epoxy curing agent comprising a heterocycle-containing compound having a backbone chain selected from the group consisting of polyether, polyvinyl, polyester, polyamide, polycarbonate, and novolac chains and at least two heterocyclic groups of the following general formula (1) as side chains, and a one-component (type) epoxy resin composition comprising said epoxy curing agent and a polyepoxy compound, ##STR1## wherein R.sub.1 and R.sup.2 may be the same or different and each represents hydrogen, straight-chain or branched C.sub.1 to C.sub.6 alkyl or alkenyl, or C.sub.6 to C.sub.8 aryl; or R.sub.1 and R.sup.2, taken together with the adjacent carbon atom, represents C.sub.5 to C.sub.7 cycloalkyl; R.sup.3 represents C.sub.1 to C.sub.10 alkylene. The object is to provide the one-component (type) epoxy resin composition having fast-curing feature, an improved storage stability, and an improved degree of workability.
    • 环氧固化剂,其包含具有选自聚醚,聚乙烯,聚酯,聚酰胺,聚碳酸酯和酚醛清漆链的主链的含杂环化合物和作为侧链的以下通式(1)的至少两个杂环基 以及包含所述环氧固化剂和聚环氧化合物的单组分(型)环氧树脂组合物,其中R 1和R 2可以相同或不同,各自表示氢,直链或支链C 1至C 6烷基或链烯基,或 C6〜C8芳基; 或R 1和R 2与相邻碳原子一起表示C5至C7环烷基; R3表示C1〜C10亚烷基。 本发明的目的是提供具有快速固化特征的单组分(型)环氧树脂组合物,改进的储存稳定性和改进的可加工性程度。
    • 2. 发明授权
    • Epoxy curing agent and one-component (type) epoxy resin composition
    • 环氧固化剂和单组分(型)环氧树脂组合物
    • US5837785A
    • 1998-11-17
    • US683564
    • 1996-07-12
    • Toshihiko KinshoMunekazu SatakeTadakazu Miyazaki
    • Toshihiko KinshoMunekazu SatakeTadakazu Miyazaki
    • C08G59/50C08G65/333C08L63/00C09K3/10C08F283/00
    • C09K3/10C08G59/5046C08G65/33306C08L63/00C09K2200/0647
    • An epoxy curing agent comprising a heterocycle-containing compound having a backbone clain selected from the group consisting of polyether, polyvinyl, polyester, polyamide, polycarbonate, and novolac chains and at least two heterocyclic groups of the following general formula (1) as side chains, and a one-component (type) epoxy resin composition comprising said epoxy curing agent and a polyepoxy compound, ##STR1## wherein R.sup.1 and R.sup.2 may be the same or different and each represents hydrogen, straight-chain or branched C.sub.1 to C.sub.6 alkyl or alkenyl, or C.sub.6 to C.sub.8 aryl; or R.sup.1 and R.sup.2, taken together with the adjacent carbon atom, represents C.sub.5 to C.sub.7 cycloalkyl; R.sup.3 represents C.sub.1 to C.sub.10 alkylene. The object is to provide the one-component (type) epoxy resin composition having fast-curing feature, an improved storage stability, and an improved degree of workability.
    • 一种环氧固化剂,其包含具有选自聚醚,聚乙烯,聚酯,聚酰胺,聚碳酸酯和酚醛清漆链的骨架骨架的含杂环化合物和作为侧链的以下通式(1)的至少两个杂环基 ,以及包含所述环氧固化剂和聚环氧化合物的单组分(型)环氧树脂组合物,其中R1和R2可以相同或不同,各自表示氢,直链或支链C1至 C6烷基或烯基,或C6至C8芳基; 或R 1和R 2与相邻碳原子一起表示C5至C7环烷基; R3表示C1〜C10亚烷基。 本发明的目的是提供具有快速固化特征的单组分(型)环氧树脂组合物,改进的储存稳定性和改进的可加工性程度。
    • 5. 发明授权
    • Curable composition and cured article thereof
    • 固化性组合物及其固化物
    • US06495653B1
    • 2002-12-17
    • US09673374
    • 2000-12-08
    • Toshihiko Kinsho
    • Toshihiko Kinsho
    • C08G7500
    • C08G64/42C08G59/40C08G63/914C08G67/04C08G75/00
    • It is an object of the present invention to provide a curable composition retaining curability even at a low temperature of −20 to 5° C. and having a low viscosity at such low temperature, the cured product of which is an artifact having excellent water resistance, chemical resistance, mechanical strength and other physical properties. The present invention is directed to a curable composition which comprises a hetero ring-containing compound (A) of the following general formula (1), a compound (B) having 2 or more electrophilic groups reactive with thiol or —S— groups per molecule, and a compound (C) having 2 or more nucleophilic groups per molecule: wherein n represents an integer of 1 to 10; X1, Y1 and Z1 each represents an oxygen or sulfur atom; R1 represents the residue of a cyclic ether group-containing compound (D) or a hydrogen atom; R2 represents a hydrocarbon group of 2 to 10 carbon atoms.
    • 本发明的目的是提供即使在-20〜5℃的低温下也能保持固化性的固化性组合物,并且在这样低的温度下具有低粘度,其固化产物是具有优异耐水性的假象 ,耐化学性,机械强度等物理性能。 本发明涉及一种可固化组合物,其包含以下通式(1)的含杂环化合物(A),每分子具有与硫醇或-S-基反应的2个以上亲电子基团的化合物(B) 和每分子具有2个以上亲核基团的化合物(C):n表示1〜10的整数, X1,Y1和Z1各自表示氧或硫原子; R1表示含环状醚基的化合物(D)或氢原子的残基; R2表示2〜10个碳原子的烃基。
    • 6. 发明授权
    • Resin particle and method for preparation thereof
    • 树脂颗粒及其制备方法
    • US07163999B2
    • 2007-01-16
    • US10517971
    • 2003-06-17
    • Kazuhito KawakamiHidetoshi NodaToshihiko KinshoMasayuki Hatanaka
    • Kazuhito KawakamiHidetoshi NodaToshihiko KinshoMasayuki Hatanaka
    • C08F6/00
    • G03G9/0804C08J3/16G03G9/0806G03G9/08702G03G9/08753G03G9/08755G03G9/08764Y10T428/31663
    • A method for preparing a resin particle having a large surface area and a shape factor (SF-1) of 110 to 800, which comprises a step of applying a shear force to an aqueous dispersion having a viscosity of 300 to 100,000 mPa·s formed by adding a thickener to an aqueous dispersion containing resin particles, and a subsequent step of decreasing the viscosity of the aqueous dispersion to 200 mPa·s or less by adding a viscosity decreasing agent as necessary. Resin particles obtained by the method can be used as additives for paint, additives for coating materials, powder coatings, additives for cosmetics, resins for slush molding, spacers for use in manufacturing electronic components or devices, standard particles for electronic measuring instruments, toners for electrophotography, toners for electrostatic recording, toners for electrostatic printing, and hot-melt adhesives.
    • 一种制备表面积大,形状因子(SF-1)为110〜800的树脂颗粒的方法,包括对粘度为300〜100,000mPa.s的水性分散体施加剪切力的工序 通过向含有树脂颗粒的水性分散体中添加增稠剂,以及随后的步骤,通过根据需要添加降粘剂,将水分散体的粘度降低至200mPa·s以下。 通过该方法获得的树脂颗粒可以用作涂料添加剂,涂料添加剂,粉末涂料,化妆品添加剂,搪塑用树脂,用于制造电子元件或装置的间隔物,用于电子测量仪器的标准颗粒,用于电子测量仪器的标准颗粒 电子照相术,用于静电记录的调色剂,静电印刷用调色剂和热熔粘合剂。