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1. 发明申请

US20080108750A1 Thermoplastic Resin Composition 审中-公开
标题翻译：热塑性树脂组合物
公开(公告)号：US20080108750A1
公开(公告)日：2008-05-08
申请号：US11793530
申请日：2005-12-13
申请人： Toru Terada , Shinya Hongo , Hirotsugu Yamada , Takashi Ueda
发明人： Toru Terada , Shinya Hongo , Hirotsugu Yamada , Takashi Ueda
IPC分类号： C08L51/02 , C08G63/91
CPC分类号： C08L27/06 , C08L5/04 , C08L33/06 , C08L51/003 , C08L101/00 , C08L2666/02 , C08L2666/24
摘要： An object of the present invention is to propose a novel thermoplastic resin composition having high impact resistance without degrading weather resistance even when the content of an impact modifier is small. A thermoplastic resin composition includes 100 parts by weight of a thermoplastic resin (a) and 0.5 to 20 parts by weight of an impact modifier (b) containing a graft copolymer (b-1) containing at least one (meth)acrylate flexible polymer phase and a rigid polymer phase serving as the outermost part of the graft copolymer, a water-soluble polymer compound (b-2) having a physical gel-forming property, and a gelling agent (b-3). In the thermoplastic resin composition, the content of the water-soluble polymer compound (b-2) having the physical gel-forming property is 0.01 to 3.0 parts by weight relative to 100 parts by weight of the graft copolymer (b-1) and the content of the rigid polymer phase serving as the outermost part in the graft copolymer (b-1) is 0.5 to 10 percent by weight.
摘要翻译：本发明的目的是提出一种抗冲击性能好的新型热塑性树脂组合物，即使在抗冲击改性剂的含量少的情况下也不降低耐候性。热塑性树脂组合物包含100重量份的热塑性树脂（a）和0.5至20重量份的含有至少一种（甲基）丙烯酸酯柔性聚合物相的接枝共聚物（b-1）的抗冲改性剂（b）和作为接枝共聚物的最外部分的刚性聚合物相，具有物理凝胶形成性质的水溶性高分子化合物（b-2）和胶凝剂（b-3）。在热塑性树脂组合物中，具有物理凝胶形成性的水溶性高分子化合物（b-2）的含量相对于100重量份接枝共聚物（b-1）为0.01〜3.0重量份，作为接枝共聚物（b-1）中最外层的刚性聚合物相的含量为0.5〜10重量％。

2. 发明申请

US20100204404A1 LIQUID RESIN COMPOSITION AND CURED PRODUCT USING THE LIQUID RESIN COMPOSITION 有权
标题翻译：液体树脂组合物和固化产品使用液体树脂组合物
公开(公告)号：US20100204404A1
公开(公告)日：2010-08-12
申请号：US12733611
申请日：2008-09-09
申请人： Shinya Hongo
发明人： Shinya Hongo
IPC分类号： C08L51/00 , C08L101/00 , C08L71/00
CPC分类号： C08J3/005 , B33Y70/00 , C08F285/00 , C08L51/04 , C08L63/00 , C08L101/00 , C08L2666/02 , C08L2666/04
摘要： An object of the invention is to provide a liquid resin composition with low viscosity while containing polymer particles. Further, another object of the invention is to provide a liquid resin composition containing a large quantity of polymer particles without increasing the viscosity of the liquid resin composition. A liquid resin composition of the invention is comprising a liquid resin component and polymer particles each having an elastic core layer, an intermediate layer formed with a monomer having two or more double bonds and coated on the core layer, and a shell layer coated on the intermediate layer; wherein the polymer particles are dispersed at a ratio of their volume average particle diameter (Mv) to their number average particle diameter (Mn) of 3 or lower.
摘要翻译：本发明的目的是提供一种含有聚合物颗粒的低粘度液体树脂组合物。此外，本发明的另一个目的是提供一种含有大量聚合物颗粒的液体树脂组合物，而不增加液态树脂组合物的粘度。本发明的液体树脂组合物包括液体树脂组分和各自具有弹性芯层的聚合物颗粒，由具有两个或更多个双键的单体形成并涂覆在芯层上的中间层和涂覆在芯层上的壳层中间层其中聚合物颗粒的体积平均粒径（Mv）与其数均粒径（Mn）的比例为3或更低。

3. 发明授权

US08278388B2 Alicyclic epoxy resin composition, cured product thereof, production method thereof, and rubbery polymer-containing resin composition 有权
标题翻译：脂环族环氧树脂组合物，其固化产物，其制备方法和含橡胶聚合物的树脂组合物
公开(公告)号：US08278388B2
公开(公告)日：2012-10-02
申请号：US12864968
申请日：2009-01-27
申请人： Shinya Hongo , Kazuhiro Yoshida
发明人： Shinya Hongo , Kazuhiro Yoshida
IPC分类号： C08L33/06 , C08L51/04 , C08F265/06 , C08G59/48
CPC分类号： C08G59/24 , C08F265/06 , C08L27/06 , C08L33/14 , C08L51/003 , C08L51/04 , C08L63/00 , C08L2207/53 , C08L2666/24 , C08L2666/04
摘要： It is an object of the invention to provide a rubbery polymer-containing resin composition useful as a raw material for a molded article and a cured product having high transparency and excellent mechanical strength: namely, an object of the invention is to provide, for example, a cycloaliphatic epoxy resin composition capable of improving the toughness thereof while maintaining the mechanical strength and transparency of the cycloaliphatic epoxy resin without lowering the heat resistance, a production method thereof and a cured product thereof. A rubbery polymer-containing resin composition of the invention, for example, a cycloaliphatic epoxy resin composition of the invention is a cycloaliphatic epoxy resin composition comprising 100 parts by weight of a cycloaliphatic epoxy resin and 1 to 60 parts by weight of polymer particles with a volume average particle diameter (Mv) of not smaller than 0.01 μm and not larger than 0.5 μm, characterized in that each of the polymer particles comprises at least two layers of an elastic core layer present in the inside thereof and a shell layer present in the outermost side thereof, the elastic core layer consisting of a rubbery polymer with a glass transition temperature of lower than 10° C., and the composition is colorless and transparent.
摘要翻译：本发明的目的是提供一种可用作模制品的原料的含橡胶聚合物的树脂组合物和具有高透明度和优异的机械强度的固化产物，即本发明的目的是提供例如，能够在不降低耐热性的同时保持脂环族环氧树脂的机械强度和透明性的同时提高其韧性的脂环族环氧树脂组合物，其制备方法和其固化产物。本发明的含橡胶聚合物的树脂组合物，例如本发明的脂环族环氧树脂组合物是脂环族环氧树脂组合物，其包含100重量份的脂环族环氧树脂和1至60重量份的具有体积平均粒径（Mv）不小于0.01μm且不大于0.5μm，其特征在于，每个聚合物颗粒包含至少两层存在于其内部的弹性芯层和存在于其中的壳层其最外侧，弹性芯层由玻璃化转变温度低于10℃的橡胶状聚合物构成，组合物无色透明。

4. 发明授权

US08742014B2 Liquid resin composition and cured product using the liquid resin composition 有权
标题翻译：液体树脂组合物和使用液体树脂组合物的固化产物
公开(公告)号：US08742014B2
公开(公告)日：2014-06-03
申请号：US12733611
申请日：2008-09-09
申请人： Shinya Hongo
发明人： Shinya Hongo
IPC分类号： C08L33/08 , C08L33/10 , C08L61/10 , C08L63/00 , C08L63/02 , C08L63/10 , C08L67/06 , C08L101/06
CPC分类号： C08J3/005 , B33Y70/00 , C08F285/00 , C08L51/04 , C08L63/00 , C08L101/00 , C08L2666/02 , C08L2666/04
摘要： An object of the invention is to provide a liquid resin composition with low viscosity while containing polymer particles. Further, another object of the invention is to provide a liquid resin composition containing a large quantity of polymer particles without increasing the viscosity of the liquid resin composition. A liquid resin composition of the invention is comprising a liquid resin component and polymer particles each having an elastic core layer, an intermediate layer formed with a monomer having two or more double bonds and coated on the core layer, and a shell layer coated on the intermediate layer; wherein the polymer particles are dispersed at a ratio of their volume average particle diameter (Mv) to their number average particle diameter (Mn) of 3 or lower.
摘要翻译：本发明的目的是提供一种含有聚合物颗粒的低粘度液体树脂组合物。此外，本发明的另一个目的是提供一种含有大量聚合物颗粒的液体树脂组合物，而不增加液态树脂组合物的粘度。本发明的液体树脂组合物包括液体树脂组分和各自具有弹性芯层的聚合物颗粒，由具有两个或更多个双键的单体形成并涂覆在芯层上的中间层和涂覆在芯层上的壳层中间层其中聚合物颗粒的体积平均粒径（Mv）与其数均粒径（Mn）的比例为3或更低。

5. 发明申请

US20110015347A1 ALICYCLIC EPOXY RESIN COMPOSITION, CURED PRODUCT THEREOF, PRODUCTION METHOD THEREOF, AND RUBBERY POLYMER-CONTAINING RESIN COMPOSITION 有权
标题翻译： ALICYCLIC环氧树脂组合物，其固化产品，其生产方法和含橡胶聚合物的树脂组合物
公开(公告)号：US20110015347A1
公开(公告)日：2011-01-20
申请号：US12864968
申请日：2009-01-27
申请人： Shinya Hongo , Kazuhiro Yoshida
发明人： Shinya Hongo , Kazuhiro Yoshida
IPC分类号： C08L63/02
CPC分类号： C08G59/24 , C08F265/06 , C08L27/06 , C08L33/14 , C08L51/003 , C08L51/04 , C08L63/00 , C08L2207/53 , C08L2666/24 , C08L2666/04
摘要： It is an object of the invention to provide a rubbery polymer-containing resin composition useful as a raw material for a molded article and a cured product having high transparency and excellent mechanical strength: namely, an object of the invention is to provide, for example, a cycloaliphatic epoxy resin composition capable of improving the toughness thereof while maintaining the mechanical strength and transparency of the cycloaliphatic epoxy resin without lowering the heat resistance, a production method thereof and a cured product thereof. A rubbery polymer-containing resin composition of the invention, for example, a cycloaliphatic epoxy resin composition of the invention is a cycloaliphatic epoxy resin composition comprising 100 parts by weight of a cycloaliphatic epoxy resin and 1 to 60 parts by weight of polymer particles with a volume average particle diameter (Mv) of not smaller than 0.01 μm and not larger than 0.5 μm, characterized in that each of the polymer particles comprises at least two layers of an elastic core layer present in the inside thereof and a shell layer present in the outermost side thereof, the elastic core layer consisting of a rubbery polymer with a glass transition temperature of lower than 10° C., and the composition is colorless and transparent.
摘要翻译：本发明的目的是提供一种可用作模制品的原料的含橡胶聚合物的树脂组合物和具有高透明度和优异的机械强度的固化产物，即本发明的目的是提供例如，能够在不降低耐热性的同时保持脂环族环氧树脂的机械强度和透明性的同时提高其韧性的脂环族环氧树脂组合物，其制备方法和其固化产物。本发明的含橡胶聚合物的树脂组合物，例如本发明的脂环族环氧树脂组合物是脂环族环氧树脂组合物，其包含100重量份的脂环族环氧树脂和1至60重量份的具有体积平均粒径（Mv）不小于0.01μm且不大于0.5μm，其特征在于，每个聚合物颗粒包含至少两层存在于其内部的弹性芯层和存在于其中的壳层其最外侧，弹性芯层由玻璃化转变温度低于10℃的橡胶状聚合物构成，组合物无色透明。

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