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1. 发明授权

US06762325B2 Method for production of alkoxylated compound 失效
标题翻译：烷氧基化合物的制造方法
公开(公告)号：US06762325B2
公开(公告)日：2004-07-13
申请号：US10144491
申请日：2002-05-13
申请人： Toru Inaoka , Yasuhiko Sato , Yoshiyuki Onda , Hiromichi Tanaka , Tsuyoshi Hirata
发明人： Toru Inaoka , Yasuhiko Sato , Yoshiyuki Onda , Hiromichi Tanaka , Tsuyoshi Hirata
IPC分类号： C07C21300
CPC分类号： C04B24/267 , B01F7/18 , B01J19/006 , B01J19/0066 , B01J19/18 , B01J2219/00063 , B01J2219/00168 , B01J2219/00768 , B01J2219/00779 , C04B24/2647 , C04B2103/408 , C08G65/2609 , C08G65/2696 , C08G65/30
摘要： When the reaction solution formed during the addition of an alkylene oxide to an active hydrogen-containing compound has viscosity of not less than 10 mPa·s, this invention provides a method for stirring the reaction solution by the rotation of a vane or vanes continuously disposed in the vertical direction within an agitating reaction vessel in such a manner that the numerical value C represented by the following formula (1): C=A/(h2−h1) (1) (wherein A denotes the length (m) of the vane or the vanes newly immersed by the supply of alkylene oxide, h1 denotes the height (m) of the liquid level before the supply of alkylene oxide, and h2 denotes the height (m) of the liquid level after the supply of alkylene oxide) may be not less than 0.5. By employing the method of this invention, it is made possible to effect addition of an alkylene oxide to the active hydrogen-containing compound with high efficiency. Further, the use of this method allows repression of the content of a by-product which causes the degradation of the characteristic properties of the alkoxylated compound.
摘要翻译：当在含有活性氢的化合物中加入烯化氧时形成的反应溶液的粘度不低于10mPa.s，本发明提供一种通过连续设置的叶片或叶片的旋转来搅拌反应溶液的方法在搅拌反应容器内沿垂直方向以下式（1）表示的数值C :(其中A表示叶片或通过供给环氧烷而新浸入的叶片的长度（m） h1表示供给环氧烷前的液面的高度（m），h2表示供给环氧烷以后的液面高度（μm））可以为0.5以上。通过采用本发明的方法，可以高效率地向含活性氢的化合物中加入烯化氧。此外，使用该方法可抑制副产物的含量，这导致烷氧基化化合物的特征性质的降解。

2. 发明申请

US20050080298A1 Production processes for alkylene oxide addition product and its derivatives 有权
标题翻译：烯化氧加成产物及其衍生物的生产方法
公开(公告)号：US20050080298A1
公开(公告)日：2005-04-14
申请号：US10500554
申请日：2003-05-02
申请人： Toru Inaoka , Yoshiyuki Onda , Hiromichi Tanaka , Tsuyoshi Hirata
发明人： Toru Inaoka , Yoshiyuki Onda , Hiromichi Tanaka , Tsuyoshi Hirata
IPC分类号： C08F299/02 , C08G65/26 , C08G65/28 , C08G65/332 , C07C67/26 , C08G59/14
CPC分类号： C08G65/2609 , C08G65/2696 , C08G65/3322
摘要： The present invention provides: a production process for an alkylene oxide addition product, by which a high-molecular alkylene oxide addition product can be obtained with ordinary production facilities while the formation of by-products is suppressed; and production processes for derivatives from the alkylene oxide addition product. The present invention production process for an alkylene oxide addition product comprises the step of carrying out an addition reaction of an alkylene oxide to a hydroxyl-group-containing saturated compound in order to obtain the alkylene oxide addition product; with the production process being characterized by further comprising: the initial step of causing the alkylene oxide to add to the hydroxyl-group-containing saturated compound in an amount of not larger than 20 mols on average of the alkylene oxide per 1 mol of the hydroxyl-group-containing saturated compound to thereby obtain an alkylene oxide low-mol-addition product; and the molar-degree-of-polyaddition-adjusting step of causing the alkylene oxide to further add to the alkylene oxide low-mol-addition product as obtained in the initial step; wherein a portion of the entirety of the alkylene oxide low-mol-addition product as obtained in the initial step is used in the molar-degree-of-polyaddition-adjusting step.
摘要翻译：本发明提供：一种环氧烷加成物的制造方法，通过该方法可以获得具有普通生产设备的高分子量烯化氧加成产物，同时抑制副产物的形成; 以及来自烯化氧加成产物的衍生物的制备方法。本发明的烯化氧加成产物的制备方法包括进行烯化氧与含羟基的饱和化合物的加成反应以获得环氧烷烃加成产物的步骤; 其制备方法的特征还在于：使每1摩尔羟基的烯化氧的平均相对于含有羟基的饱和化合物不少于20摩尔的环氧烷加成的初始步骤含有饱和化合物，得到环氧烷低摩尔加成产物; 和加成摩尔加聚度调整步骤，使得氧化烯进一步添加到初始步骤中获得的环氧烷低摩尔加成产物; 其中在初始步骤中获得的全部烯化氧低摩尔加成产物的一部分用于加聚度加聚步骤。

3. 发明授权

US07402644B2 Production processes for alkylene oxide addition product and its derivatives 有权
标题翻译：烯化氧加成产物及其衍生物的生产方法
公开(公告)号：US07402644B2
公开(公告)日：2008-07-22
申请号：US10500554
申请日：2003-05-02
申请人： Toru Inaoka , Yoshiyuki Onda , Hiromichi Tanaka , Tsuyoshi Hirata
发明人： Toru Inaoka , Yoshiyuki Onda , Hiromichi Tanaka , Tsuyoshi Hirata
IPC分类号： C08F20/26 , C07C69/52 , C07C43/00
CPC分类号： C08G65/2609 , C08G65/2696 , C08G65/3322
摘要： The present invention provides: a production process for an alkylene oxide addition product, by which a high-molecular alkylene oxide addition product can be obtained with ordinary production facilities while the formation of by-products is suppressed; and production processes for derivatives from the alkylene oxide addition product. The present invention production process for an alkylene oxide addition product comprises the step of carrying out an addition reaction of an alkylene oxide to a hydroxyl-group-containing saturated compound in order to obtain the alkylene oxide addition product; with the production process being characterized by further comprising: the initial step of causing the alkylene oxide to add to the hydroxyl-group-containing saturated compound in an amount of not larger than 20 mols on average of the alkylene oxide per 1 mol of the hydroxyl-group-containing saturated compound to thereby obtain an alkylene oxide low-mol-addition product; and the molar-degree-of-polyaddition-adjusting step of causing the alkylene oxide to further add to the alkylene oxide low-mol-addition product as obtained in the initial step; wherein a portion of the entirety of the alkylene oxide low-mol-addition product as obtained in the initial step is used in the molar-degree-of-polyaddition-adjusting step.
摘要翻译：本发明提供：一种环氧烷加成物的制造方法，通过该方法可以获得具有普通生产设备的高分子量烯化氧加成产物，同时抑制副产物的形成; 以及来自烯化氧加成产物的衍生物的制备方法。本发明的烯化氧加成产物的制备方法包括进行烯化氧与含羟基的饱和化合物的加成反应以获得环氧烷烃加成产物的步骤; 其制备方法的特征还在于：使每1摩尔羟基的烯化氧的平均相对于含有羟基的饱和化合物不少于20摩尔的环氧烷加成的初始步骤含有饱和化合物，得到环氧烷低摩尔加成产物; 和加成摩尔加聚度调整步骤，使得氧化烯进一步添加到初始步骤中获得的环氧烷低摩尔加成产物; 其中在初始步骤中获得的全部烯化氧低摩尔加成产物的一部分用于加聚度加聚步骤。

4. 发明授权

US07405264B2 Polycarboxylic acid copolymer, production method and use thereof 失效
标题翻译：聚羧酸共聚物，其制备方法和用途
公开(公告)号：US07405264B2
公开(公告)日：2008-07-29
申请号：US10921148
申请日：2004-08-19
申请人： Tsutomu Yuasa , Tomotaka Nishikawa , Noboru Sakamoto , Tsuyoshi Hirata , Hiroko Izukashi , Tomiyasu Ueta , Hiromichi Tanaka , Yoshiyuki Onda , Toru Uno
发明人： Tsutomu Yuasa , Tomotaka Nishikawa , Noboru Sakamoto , Tsuyoshi Hirata , Hiroko Izukashi , Tomiyasu Ueta , Hiromichi Tanaka , Yoshiyuki Onda , Toru Uno
IPC分类号： C08F16/12 , C08F20/06
CPC分类号： C04B24/2658 , C04B2103/302 , C08F290/06 , C08F290/065 , C08G65/2624 , C08G2650/24 , C08L51/04 , C08L53/00 , C08L55/02 , C08L71/02 , C08L2666/24 , C08L2666/14 , C08L2666/02 , C08L2666/04
摘要： It is an object of the present invention to provide a polycarboxylic acid polpolymer which improves the water reducing capacity and workability of cement compositions and the like and making them easier to handle when the fluidity and water reducing capacity are at the same levels, a method of producing the copolymer, and a cement additive and a cement composition comprising the copolymer. The present invention is further to provide a polycarboxylic acid copolymer and a cement additive which are capable of improving the strength and durability of hardening products of cement compositions, hence can advantageously be used in ultrahigh strength concrete. The present invention is polycarboxylic acid copolymers having high water reducing capacity, reducing the viscosity of cement compositions and improving the workability in applying cement.The present invention is directed to a polycarboxylic acid copolymer which is obtained by copolymerization of monomer components comprising a polyalkyleneimine unsaturated monomer (A1) and an unsaturated carboxylic acid monomer (B).
摘要翻译：本发明的目的是提供一种改善水泥组合物等的减水能力和加工性的多元羧酸聚合物，并且当流动性和减水能力处于相同水平时使其更容易处理，制备共聚物，以及包含该共聚物的水泥添加剂和水泥组合物。本发明还提供能够提高水泥组合物的硬化物的强度和耐久性的聚羧酸共聚物和水泥添加剂，因此可以有利地用于超高强度混凝土中。本发明是具有高降水能力的聚羧酸共聚物，降低了水泥组合物的粘度并提高了施加水泥的可加工性。本发明涉及通过使包含聚亚烷基亚胺不饱和单体（A1）和不饱和羧酸单体（B）的单体成分共聚获得的多元羧酸共聚物。

5. 发明授权

US07304104B2 Cement admixture, cement composition and method for laying work the same, and method for producing cement hardened product 失效
标题翻译：水泥外加剂，水泥组合物和铺设工序的方法以及生产水泥硬化产品的方法
公开(公告)号：US07304104B2
公开(公告)日：2007-12-04
申请号：US10791729
申请日：2004-03-04
申请人： Akihiko Yamashita , Hiromichi Tanaka , Toru Uno , Yoshiyuki Onda , Tsuyoshi Hirata
发明人： Akihiko Yamashita , Hiromichi Tanaka , Toru Uno , Yoshiyuki Onda , Tsuyoshi Hirata
IPC分类号： C04B24/26 , C08K5/06
CPC分类号： C08F290/142 , C04B28/02 , C04B40/0039 , C04B2103/32 , C08F283/06 , C08F283/065 , C08F290/14 , C08L71/02 , Y10T24/1303 , Y10T24/3493 , Y10T24/3495 , C04B24/06 , C04B24/22 , C04B24/267 , C04B24/32 , C04B24/38 , C04B2103/12 , C08F222/06 , C08L2666/04
摘要： The cement admixture of the present invention can provide viscosity decreasing ability as well as a high dispersing ability and slump loss preventing ability even in a high water reducing ratio range. The above-mentioned cement admixture comprises three components of a copolymer (A) containing a constituent unit (I) derived from the unsaturated (poly)alkylene glycol ether monomer (a) and a constituent unit (II) derived from a maleic acid monomer (b), a specific unsaturated (poly)alkylene glycol ether monomer (a) and a non-polymerizable (poly)alkylene glycol (B) having no alkenyl group.
摘要翻译：本发明的水泥混合物即使在高的减水率范围内也能够提供粘度降低能力以及高的分散能力和坍落度损失防止能力。上述水泥混合物包含含有源自不饱和（聚）亚烷基二醇醚单体（a）的构成单元（I）和源自马来酸单体的构成单元（II）的共聚物（A）的三种组分 b），不饱和（聚）亚烷基二醇醚单体（a）和不具有烯基的不可聚合（聚）亚烷基二醇（B）。

6. 发明授权

US07125944B2 Cement admixture and cement composition 有权
公开(公告)号：US07125944B2
公开(公告)日：2006-10-24
申请号：US10332080
申请日：2002-05-28
申请人： Akihiko Yamashita , Hiromichi Tanaka , Tsuyoshi Hirata , Toru Uno , Yoshiyuki Onda
发明人： Akihiko Yamashita , Hiromichi Tanaka , Tsuyoshi Hirata , Toru Uno , Yoshiyuki Onda
IPC分类号： C04B24/26
CPC分类号： C08L51/08 , C04B24/2647 , C04B40/0039 , C04B2103/408 , C08F283/06 , C08F290/06 , C08F290/062 , C08L71/02 , C04B24/267 , C04B24/2694 , C04B28/02 , C08L2666/14 , C08L2666/24 , C08L2666/02 , C08L2666/04
摘要： It is an object of the present invention to provide a cement admixture capable of exhibiting high cement dispersing ability at low addition levels, in particular capable of displaying excellent initial dispersing ability and dispersion retaining ability even in a high water reducing ratio range, and a cement composition in which this admixture is used.A cement admixture comprising two polymers, namely a polymer (A) and a polymer (B), as essential constituents in a ratio of polymer (A) to polymer (B) between 1 to 99/99 to 1% by mass, wherein the polymer (A) is a polymer comprising, as essential constituent units, a constituent unit (I) derived from an unsaturated (poly)alkylene glycol ether monomer (a) and a constituent unit (II) derived from an unsaturated monocarboxylic acid monomer (b) and wherein the constituent units (I) and (II) each accounts for not less than 1% by mass relative to all constituent units but the constituent unit (I) accounts for not more than 50 mole percent relative to all constituent units and, wherein the polymer (B) is an oxyalkylene group- or polyoxyalkylene group- and carboxyl group-containing polymer.

7. 发明申请

US20050131110A1 Polycarboxylic acid copolymer, production method and use thereof 失效
标题翻译：聚羧酸共聚物，其制备方法和用途
公开(公告)号：US20050131110A1
公开(公告)日：2005-06-16
申请号：US10921148
申请日：2004-08-19
申请人： Tsutomu Yuasa , Tomotaka Nishikawa , Noboru Sakamoto , Tsuyoshi Hirata , Hiroko Izukashi , Tomiyasu Ueta , Hiromichi Tanaka , Yoshiyuki Onda , Toru Uno
发明人： Tsutomu Yuasa , Tomotaka Nishikawa , Noboru Sakamoto , Tsuyoshi Hirata , Hiroko Izukashi , Tomiyasu Ueta , Hiromichi Tanaka , Yoshiyuki Onda , Toru Uno
IPC分类号： C04B24/26 , C04B24/32 , C08F290/00 , C08F290/06 , C08G65/26 , C08L51/04 , C08L53/00 , C08L55/02 , C08L71/02 , C08K3/00
CPC分类号： C04B24/2658 , C04B2103/302 , C08F290/06 , C08F290/065 , C08G65/2624 , C08G2650/24 , C08L51/04 , C08L53/00 , C08L55/02 , C08L71/02 , C08L2666/24 , C08L2666/14 , C08L2666/02 , C08L2666/04
摘要： It is an object of the present invention to provide a polycarboxylic acid polpolymer which improves the water reducing capacity and workability of cement compositions and the like and making them easier to handle when the fluidity and water reducing capacity are at the same levels, a method of producing the copolymer, and a cement additive and a cement composition comprising the copolymer. The present invention is further to provide a polycarboxylic acid copolymer and a cement additive which are capable of improving the strength and durability of hardening products of cement compositions, hence can advantageously be used in ultrahigh strength concrete. The present invention is polycarboxylic acid copolymers having high water reducing capacity, reducing the viscosity of cement compositions and improving the workability in applying cement. The present invention is directed to a polycarboxylic acid copolymer which is obtained by copolymerization of monomer components comprising a polyalkyleneimine unsaturated monomer (A1) and an unsaturated carboxylic acid monomer (B).
摘要翻译：本发明的目的是提供一种改善水泥组合物等的减水能力和加工性的多元羧酸聚合物，并且当流动性和减水能力处于相同水平时使其更容易处理，制备共聚物，以及包含该共聚物的水泥添加剂和水泥组合物。本发明还提供能够提高水泥组合物的硬化物的强度和耐久性的聚羧酸共聚物和水泥添加剂，因此可以有利地用于超高强度混凝土中。本发明是具有高降水能力的聚羧酸共聚物，降低了水泥组合物的粘度并提高了施加水泥的可加工性。本发明涉及通过使包含聚亚烷基亚胺不饱和单体（A1）和不饱和羧酸单体（B）的单体成分共聚获得的多元羧酸共聚物。

8. 发明授权

US06569234B2 Cement dispersant and cement composition comprising this 有权
标题翻译：包含该水泥分散剂和水泥组合物
公开(公告)号：US06569234B2
公开(公告)日：2003-05-27
申请号：US09925863
申请日：2001-08-09
申请人： Akihiko Yamashita , Hiromichi Tanaka , Masaya Yamamoto , Toru Uno , Yoshiyuki Onda , Tsuyoshi Hirata
发明人： Akihiko Yamashita , Hiromichi Tanaka , Masaya Yamamoto , Toru Uno , Yoshiyuki Onda , Tsuyoshi Hirata
IPC分类号： C04B1128
CPC分类号： C04B24/2647 , C04B24/267 , C04B2103/32 , C04B2103/408 , C08F265/06 , C08F2220/286 , C08F220/06
摘要： A cement dispersant which displays high dispersibility with a small addition amount and excellent dispersibility particularly even in a high water-reducing ratio area, and a cement composition comprising this. A first cement dispersant includes a copolymer having a first constitutional unit derived from an unsaturated (poly)alkylene glycol ether monomer; and a second constitutional unit derived from an unsaturated monocarboxylic acid monomer, wherein the second constitutional unit includes at least one structure derived from an acrylic acid (salt).
摘要翻译：特别是即使在高的减水率区域中，也以小的添加量显示高分散性和优异的分散性的水泥分散剂，以及包含该水泥分散剂的水泥组合物。第一水泥分散剂包括具有源自不饱和（聚）亚烷基二醇醚单体的第一结构单元的共聚物; 和由不饱和一元羧酸单体衍生的第二结构单元，其中第二结构单元包括至少一种衍生自丙烯酸（盐）的结构。

9. 发明授权

US07253220B2 Cement admixture and cement composition 失效
标题翻译：水泥外加剂和水泥组成
公开(公告)号：US07253220B2
公开(公告)日：2007-08-07
申请号：US10791730
申请日：2004-03-04
申请人： Akihiko Yamashita , Hiromichi Tanaka , Toru Uno , Yoshiyuki Onda , Tsuyoshi Hirata
发明人： Akihiko Yamashita , Hiromichi Tanaka , Toru Uno , Yoshiyuki Onda , Tsuyoshi Hirata
IPC分类号： C04B24/26
CPC分类号： C08G65/3322 , C04B28/02 , C04B40/0039 , C08L71/02 , C08L2205/05 , C08L2666/04 , C04B24/267 , C04B24/32
摘要： The cement admixture of the present invention can improve the workability by displaying sufficient viscosity decreasing ability and initial dispersing ability even under a low temperature environment as well as high dispersing ability and dispersion retaining ability even in a high water reducing ratio range. The above-mentioned cement admixture comprises four components of a copolymer (A) containing a constituent unit (I) derived from the unsaturated (poly)alkylene glycol ether monomer (a) and a constituent unit (II) derived from a maleic acid monomer (b), a specific unsaturated (poly)alkylene glycol ether monomer (a), a non-polymerizable (poly)alkylene glycol (B) having no alkenyl group, and a polymer (C) having an oxyalkylene group or a polyoxyalkylene group and a carboxyl group, which is different from the copolymer (A).
摘要翻译：本发明的水泥外加剂即使在高的减水率范围内，即使在低温环境下也显示出足够的降粘能力和初始分散能力以及高分散能力和分散保持能力，可以提高加工性。上述水泥混合物包含含有源自不饱和（聚）亚烷基二醇醚单体（a）的构成单元（I）和源自马来酸单体的构成单元（II）的共聚物（A）的四种组分 b），不饱和（聚）亚烷基二醇醚单体（a），不具有烯基的不可聚合（聚）亚烷基二醇（B）和具有氧化烯基或聚氧化烯基的聚合物（C）和羧基，其不同于共聚物（A）。

10. 发明授权

US06727315B2 Copolymer for cement admixtures and its production process and use 有权
标题翻译：水泥外加剂共聚物及其生产工艺及用途
公开(公告)号：US06727315B2
公开(公告)日：2004-04-27
申请号：US10160757
申请日：2002-06-01
申请人： Masaya Yamamoto , Toru Uno , Yoshiyuki Onda , Hiromichi Tanaka , Akihiko Yamashita , Tsuyoshi Hirata , Naoko Hirano
发明人： Masaya Yamamoto , Toru Uno , Yoshiyuki Onda , Hiromichi Tanaka , Akihiko Yamashita , Tsuyoshi Hirata , Naoko Hirano
IPC分类号： C08F1602
CPC分类号： C04B24/2647 , C04B24/2641 , C04B24/32 , C04B2103/408 , C04B2111/00189 , C08F216/1416 , C08F290/062 , C08G65/2609 , C08L51/003 , C08L71/02 , C08L2666/02 , C08L2666/04
摘要： The present invention provides: a copolymer for cement admixtures which displays high dispersibility with a small adding amount and excellent dispersibility particularly even in a high water reducing ratio area, a cement admixture utilizing the copolymer, and a cement composition, and further, a production process for the copolymer. The copolymer for cement admixtures comprises: constitutional unit (I) derived from unsaturated polyalkylene glycol ether monomer (a) having an alkenyl group having 5 carbon atoms and an oxyalkylene group having 2 to 18 carbon atoms with an average addition number of moles of the oxyalkylene groups to be in the range of 10 to 300; and constitutional unit (II) derived from unsaturated monocarboxylic acid monomer (b). The cement admixture includes the copolymer for cement admixtures as an essential component, and may further include a defoaming agent. The cement composition includes the copolymer for cement admixtures, and cement as essential components. The production process for the copolymer comprises: copolymerizing comonomers including unsaturated polyalkylene glycol ether monomer (a) and unsaturated monocarboxylic monomer (b) as essential components by use of a chain-transfer agent, and/or adjusting pH of a resultant reaction mixture to not less than 5 after the copolymerization.
摘要翻译：本发明提供了一种用于水泥外加剂的共聚物，其特征在于即使在高减水率区域中也显示出高分散性，特别是具有小的添加量和优异的分散性，使用该共聚物的水泥混合物和水泥组合物，此外，对于共聚物。用于水泥混合物的共聚物包括：衍生自具有5个碳原子的烯基的不饱和聚亚烷基二醇醚单体（a）和具有2至18个碳原子的氧化烯基的结构单元（I），氧化烯的平均加成摩尔数组别在10至300范围内; 和由不饱和一元羧酸单体（b）衍生的结构单元（II）。水泥外加剂包括水泥外加剂作为必要成分的共聚物，还可以含有消泡剂。水泥组合物包括用于水泥混合物的共聚物和水泥作为必要组分。共聚物的制造方法包括：使用链转移剂使包含不饱和聚亚烷基二醇醚单体（a）和不饱和单羧酸单体（b）的共聚单体共聚为必要成分，和/或将所得反应混合物的pH调节为共聚后小于5。

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