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1. 发明授权

US08076396B2 Ultrarapid hardening cement composition and dispersant for ultrarapid hardening cement composition 有权
标题翻译：超硬硬化水泥组合物和分散剂用于超硬硬化水泥组成
公开(公告)号：US08076396B2
公开(公告)日：2011-12-13
申请号：US12065443
申请日：2006-08-30
申请人： Akira Ono , Hisashi Inokawa , Tsuyoshi Hirata , Hirokatsu Kawakami , Masami Hattori
发明人： Akira Ono , Hisashi Inokawa , Tsuyoshi Hirata , Hirokatsu Kawakami , Masami Hattori
IPC分类号： C04B24/26 , C04B7/00 , C04B7/02 , C08K3/00 , C08K5/092 , C08K5/11
CPC分类号： C04B28/06 , C04B24/2647 , C04B2111/00068 , C04B2103/22 , C04B24/06 , C04B24/32
摘要： To provide an ultrarapid hardening cement composition with high strength, the composition having: excellent fluidity; excellent usable time; and excellent initial strength under low temperature atmosphere as well as under general temperature atmosphere, and improving strength and durability of a hardening product of the composition. An ultrarapid cement hardening composition comprising: an ultrarapid hardening cement (A) comprising a calcium aluminate; and a cement dispersant (B), wherein the cement dispersant (B) comprises a copolymer having: a repeating unit derived from a monomer represented by the following formula (1) and formula (2) as defined in the specification.
摘要翻译：为了提供高强度的超硬硬化水泥组合物，其组成具有优异的流动性; 优秀的可用时间; 并且在低温气氛以及一般温度气氛下具有优异的初始强度，并提高组合物的硬化产物的强度和耐久性。一种超级水泥硬化组合物，其包含：包含铝酸钙的超硬硬化水泥（A）和水泥分散剂（B），其中所述水泥分散剂（B）包含共聚物，所述共聚物具有：由说明书中定义的由下式（1）和式（2）表示的单体衍生的重复单元。

2. 发明授权

US07304104B2 Cement admixture, cement composition and method for laying work the same, and method for producing cement hardened product 失效
标题翻译：水泥外加剂，水泥组合物和铺设工序的方法以及生产水泥硬化产品的方法
公开(公告)号：US07304104B2
公开(公告)日：2007-12-04
申请号：US10791729
申请日：2004-03-04
申请人： Akihiko Yamashita , Hiromichi Tanaka , Toru Uno , Yoshiyuki Onda , Tsuyoshi Hirata
发明人： Akihiko Yamashita , Hiromichi Tanaka , Toru Uno , Yoshiyuki Onda , Tsuyoshi Hirata
IPC分类号： C04B24/26 , C08K5/06
CPC分类号： C08F290/142 , C04B28/02 , C04B40/0039 , C04B2103/32 , C08F283/06 , C08F283/065 , C08F290/14 , C08L71/02 , Y10T24/1303 , Y10T24/3493 , Y10T24/3495 , C04B24/06 , C04B24/22 , C04B24/267 , C04B24/32 , C04B24/38 , C04B2103/12 , C08F222/06 , C08L2666/04
摘要： The cement admixture of the present invention can provide viscosity decreasing ability as well as a high dispersing ability and slump loss preventing ability even in a high water reducing ratio range. The above-mentioned cement admixture comprises three components of a copolymer (A) containing a constituent unit (I) derived from the unsaturated (poly)alkylene glycol ether monomer (a) and a constituent unit (II) derived from a maleic acid monomer (b), a specific unsaturated (poly)alkylene glycol ether monomer (a) and a non-polymerizable (poly)alkylene glycol (B) having no alkenyl group.
摘要翻译：本发明的水泥混合物即使在高的减水率范围内也能够提供粘度降低能力以及高的分散能力和坍落度损失防止能力。上述水泥混合物包含含有源自不饱和（聚）亚烷基二醇醚单体（a）的构成单元（I）和源自马来酸单体的构成单元（II）的共聚物（A）的三种组分 b），不饱和（聚）亚烷基二醇醚单体（a）和不具有烯基的不可聚合（聚）亚烷基二醇（B）。

3. 发明申请

US20070260046A1 Dispersant Using Kraft Lignin and Novel Lignin Derivative 失效
标题翻译：使用牛皮纸木质素和新型木质素衍生物的分散剂
公开(公告)号：US20070260046A1
公开(公告)日：2007-11-08
申请号：US11663536
申请日：2005-09-22
申请人： Takashi Tomita , Tsuyoshi Hirata
发明人： Takashi Tomita , Tsuyoshi Hirata
IPC分类号： C07G1/00
CPC分类号： C04B24/24 , B01F17/0028 , C04B2103/408 , C08F283/06 , C08F289/00 , C08G65/2606 , C08G65/3322 , C08H6/00 , C08K5/0008 , C08L71/02 , C08L97/005 , C08L2205/05 , C08F220/06 , C08L2666/26
摘要： The dispersant of the present invention comprises at least one component unit derived from kraft lignin and/or its salt and at least one component unit derived from at least one water-soluble monomer. The novel lignin derivative of the present invention comprises at least one component unit derived from kraft lignin and/or its salt, at least one polyoxyalkylene chain, and at least one anionic functional group.
摘要翻译：本发明的分散剂包含至少一种衍生自硫酸盐木质素和/或其盐的组分单元和至少一种衍生自至少一种水溶性单体的组分单元。本发明的新型木质素衍生物包含至少一种衍生自硫酸盐木质素和/或其盐的组分单元，至少一个聚氧化烯链和至少一个阴离子官能团。

4. 发明申请

US20070181042A1 Additive for hydraulic material 审中-公开
标题翻译：液压材料添加剂
公开(公告)号：US20070181042A1
公开(公告)日：2007-08-09
申请号：US10590480
申请日：2005-03-15
申请人： Mari Masanaga , Tsuyoshi Hirata
发明人： Mari Masanaga , Tsuyoshi Hirata
IPC分类号： C04B24/00
CPC分类号： C04B24/2652 , C04B24/121 , C04B24/163 , C04B24/2658 , C04B40/0039 , C04B2103/30 , C04B2111/34 , C04B2103/408
摘要： An additive for a hydraulic material which comprises a polyamine compound having a hydrocarbon group of 4-30 carbon atoms as a side chain as an essential component is provided. The additive can effectively reduce the drying shrinkage of a cement material.
摘要翻译：提供一种水硬性材料用添加剂，其包含具有4-30个碳原子的烃基作为侧链作为主要成分的多胺化合物。该添加剂能有效降低水泥材料的干燥收缩率。

5. 发明授权

US07125944B2 Cement admixture and cement composition 有权
公开(公告)号：US07125944B2
公开(公告)日：2006-10-24
申请号：US10332080
申请日：2002-05-28
申请人： Akihiko Yamashita , Hiromichi Tanaka , Tsuyoshi Hirata , Toru Uno , Yoshiyuki Onda
发明人： Akihiko Yamashita , Hiromichi Tanaka , Tsuyoshi Hirata , Toru Uno , Yoshiyuki Onda
IPC分类号： C04B24/26
CPC分类号： C08L51/08 , C04B24/2647 , C04B40/0039 , C04B2103/408 , C08F283/06 , C08F290/06 , C08F290/062 , C08L71/02 , C04B24/267 , C04B24/2694 , C04B28/02 , C08L2666/14 , C08L2666/24 , C08L2666/02 , C08L2666/04
摘要： It is an object of the present invention to provide a cement admixture capable of exhibiting high cement dispersing ability at low addition levels, in particular capable of displaying excellent initial dispersing ability and dispersion retaining ability even in a high water reducing ratio range, and a cement composition in which this admixture is used.A cement admixture comprising two polymers, namely a polymer (A) and a polymer (B), as essential constituents in a ratio of polymer (A) to polymer (B) between 1 to 99/99 to 1% by mass, wherein the polymer (A) is a polymer comprising, as essential constituent units, a constituent unit (I) derived from an unsaturated (poly)alkylene glycol ether monomer (a) and a constituent unit (II) derived from an unsaturated monocarboxylic acid monomer (b) and wherein the constituent units (I) and (II) each accounts for not less than 1% by mass relative to all constituent units but the constituent unit (I) accounts for not more than 50 mole percent relative to all constituent units and, wherein the polymer (B) is an oxyalkylene group- or polyoxyalkylene group- and carboxyl group-containing polymer.

6. 发明申请

US20050222301A1 Cement dispersant, its production process, and cement composition using the cement dispersant 失效
公开(公告)号：US20050222301A1
公开(公告)日：2005-10-06
申请号：US11137228
申请日：2005-05-25
申请人： Tsutomu Yuasa , Noboru Sakamoto , Tsuyoshi Hirata
发明人： Tsutomu Yuasa , Noboru Sakamoto , Tsuyoshi Hirata
IPC分类号： C04B24/26 , C04B24/32 , C08K3/00
CPC分类号： C04B24/2641 , C04B24/2647 , C04B2103/0053 , C04B2103/408
摘要： Disclosed are the following: a cement dispersant which is excellent in initial dispersibility and further in flow retainability of cement, because of using a polymer having a proper molecular weight distribution; a process for producing this cement dispersant; and a cement composition using this cement dispersant. The cement dispersant comprises a water-soluble polymer (P) as a main component, and is characterized by displaying an area proportion (a value (A−B) given by subtracting an area ratio B of a lower molecular weight side portion from an area ratio A of a higher molecular weight side portion) in the range of 13 to 60%.

7. 发明申请

US20050131110A1 Polycarboxylic acid copolymer, production method and use thereof 失效
标题翻译：聚羧酸共聚物，其制备方法和用途
公开(公告)号：US20050131110A1
公开(公告)日：2005-06-16
申请号：US10921148
申请日：2004-08-19
申请人： Tsutomu Yuasa , Tomotaka Nishikawa , Noboru Sakamoto , Tsuyoshi Hirata , Hiroko Izukashi , Tomiyasu Ueta , Hiromichi Tanaka , Yoshiyuki Onda , Toru Uno
发明人： Tsutomu Yuasa , Tomotaka Nishikawa , Noboru Sakamoto , Tsuyoshi Hirata , Hiroko Izukashi , Tomiyasu Ueta , Hiromichi Tanaka , Yoshiyuki Onda , Toru Uno
IPC分类号： C04B24/26 , C04B24/32 , C08F290/00 , C08F290/06 , C08G65/26 , C08L51/04 , C08L53/00 , C08L55/02 , C08L71/02 , C08K3/00
CPC分类号： C04B24/2658 , C04B2103/302 , C08F290/06 , C08F290/065 , C08G65/2624 , C08G2650/24 , C08L51/04 , C08L53/00 , C08L55/02 , C08L71/02 , C08L2666/24 , C08L2666/14 , C08L2666/02 , C08L2666/04
摘要： It is an object of the present invention to provide a polycarboxylic acid polpolymer which improves the water reducing capacity and workability of cement compositions and the like and making them easier to handle when the fluidity and water reducing capacity are at the same levels, a method of producing the copolymer, and a cement additive and a cement composition comprising the copolymer. The present invention is further to provide a polycarboxylic acid copolymer and a cement additive which are capable of improving the strength and durability of hardening products of cement compositions, hence can advantageously be used in ultrahigh strength concrete. The present invention is polycarboxylic acid copolymers having high water reducing capacity, reducing the viscosity of cement compositions and improving the workability in applying cement. The present invention is directed to a polycarboxylic acid copolymer which is obtained by copolymerization of monomer components comprising a polyalkyleneimine unsaturated monomer (A1) and an unsaturated carboxylic acid monomer (B).
摘要翻译：本发明的目的是提供一种改善水泥组合物等的减水能力和加工性的多元羧酸聚合物，并且当流动性和减水能力处于相同水平时使其更容易处理，制备共聚物，以及包含该共聚物的水泥添加剂和水泥组合物。本发明还提供能够提高水泥组合物的硬化物的强度和耐久性的聚羧酸共聚物和水泥添加剂，因此可以有利地用于超高强度混凝土中。本发明是具有高降水能力的聚羧酸共聚物，降低了水泥组合物的粘度并提高了施加水泥的可加工性。本发明涉及通过使包含聚亚烷基亚胺不饱和单体（A1）和不饱和羧酸单体（B）的单体成分共聚获得的多元羧酸共聚物。

8. 发明授权

US06716896B2 Method for production of esterified product and apparatus therefor 有权
标题翻译：酯化产品的生产方法及其设备
公开(公告)号：US06716896B2
公开(公告)日：2004-04-06
申请号：US10041372
申请日：2002-01-08
申请人： Tsuyoshi Hirata , Hiromichi Tanaka , Tsutomu Yuasa
发明人： Tsuyoshi Hirata , Hiromichi Tanaka , Tsutomu Yuasa
IPC分类号： C08K300
CPC分类号： C04B24/2647 , C04B24/2641 , C04B24/2688 , C04B24/32 , C04B2103/408 , C07C67/08 , C08F20/28 , C08G65/3322 , C07C69/54
摘要： A method for the production of an esterified product which can prevent the occurrence of a gel-like substance during the separation and removal of the water formed by the reaction in the esterification reaction or during the expulsion of a dehydrating solvent by distillation after the esterification reaction by causing an antigelling agent to act on the distillate and consequently permits efficient production of the esterified product of high quality, and an apparatus therefor are to be provided. To be specific, a method for the production of an esterified product of this invention relates to a method for the production of an esterified product by the esterification reaction of an alcohol represented by the following formula (1): R1O(R2O)nH (1) wherein R1 represents a hydrocarbon group of 1 to 30 carbon atoms, R2O represents an oxyalkylene group of 2 to 18 carbon atoms, providing that the repeating units, R2O, may be the same or different and that when the R2O's are in the form of a mixture of two or more species, the repeating units, R2O, may be added either in a block form or in a random form, and n represents an average addition mol number of oxyalkylene groups and is in the range of 0 to 300, with (meth)acrylic acid, wherein said method comprises acting an antigelling agent on a distillate.
摘要翻译：一种酯化产物的制备方法，其可以防止在酯化反应中分离和除去由酯化反应中的反应形成的水或在酯化反应后通过蒸馏排出脱水溶剂时发生凝胶状物质通过使抗凝胶剂作用于馏出物，从而能够有效地生产高质量的酯化产物，并提供其设备。具体而言，本发明的酯化产物的制造方法涉及通过下述式（1）表示的醇的酯化反应生产酯化产物的方法：其中R 1表示 1至30个碳原子的烃基，R 2 O表示2至18个碳原子的氧化烯基团，条件是重复单元R 2 O可以相同或不同，并且当R 2 > O是两种或更多种的混合物的形式，重复单元R 2 O可以以嵌段形式或无规形式加入，n表示氧化烯基的平均加成摩尔数并且与（甲基）丙烯酸在0至300的范围内，其中所述方法包括在馏出物上起抗凝胶剂的作用。

9. 发明授权

US06569234B2 Cement dispersant and cement composition comprising this 有权
标题翻译：包含该水泥分散剂和水泥组合物
公开(公告)号：US06569234B2
公开(公告)日：2003-05-27
申请号：US09925863
申请日：2001-08-09
申请人： Akihiko Yamashita , Hiromichi Tanaka , Masaya Yamamoto , Toru Uno , Yoshiyuki Onda , Tsuyoshi Hirata
发明人： Akihiko Yamashita , Hiromichi Tanaka , Masaya Yamamoto , Toru Uno , Yoshiyuki Onda , Tsuyoshi Hirata
IPC分类号： C04B1128
CPC分类号： C04B24/2647 , C04B24/267 , C04B2103/32 , C04B2103/408 , C08F265/06 , C08F2220/286 , C08F220/06
摘要： A cement dispersant which displays high dispersibility with a small addition amount and excellent dispersibility particularly even in a high water-reducing ratio area, and a cement composition comprising this. A first cement dispersant includes a copolymer having a first constitutional unit derived from an unsaturated (poly)alkylene glycol ether monomer; and a second constitutional unit derived from an unsaturated monocarboxylic acid monomer, wherein the second constitutional unit includes at least one structure derived from an acrylic acid (salt).
摘要翻译：特别是即使在高的减水率区域中，也以小的添加量显示高分散性和优异的分散性的水泥分散剂，以及包含该水泥分散剂的水泥组合物。第一水泥分散剂包括具有源自不饱和（聚）亚烷基二醇醚单体的第一结构单元的共聚物; 和由不饱和一元羧酸单体衍生的第二结构单元，其中第二结构单元包括至少一种衍生自丙烯酸（盐）的结构。

10. 发明授权

US5925184A Cement composition 失效
标题翻译：水泥组成
公开(公告)号：US5925184A
公开(公告)日：1999-07-20
申请号：US803759
申请日：1997-02-21
申请人： Tsuyoshi Hirata , Tsutomu Yuasa , Toru Uno , Koichiro Nagare , Hideyuki Tahara , Shogo Iwai
发明人： Tsuyoshi Hirata , Tsutomu Yuasa , Toru Uno , Koichiro Nagare , Hideyuki Tahara , Shogo Iwai
IPC分类号： C04B24/26 , C04B24/32 , C04B28/02 , C04B24/04
CPC分类号： C04B28/02 , C04B24/2647 , C04B24/2694 , C04B2103/308
摘要： A cement composition excelling in the slump retaining property which comprises at least cement admixture comprising as a main ingredient thereof (I) a copolymer (A) of short-chain polyalkylene glycol (meth)acrylate (a), a long-chain polyalkylene glycol (meth)acrylate (b), a carboxylic acid monomer (c), and a monomer copolymerizable with the monomers mentioned above or a salt of the copolymer (B), (II) a copolymer (A.sub.1) of the monomers (a), (c), and (d) mentioned above or a salt thereof, (III) a mixture of a copolymer (A.sub.1) of the monomers (a), (c), and (d) mentioned above or a salt (B.sub.1) of thereof with a known cement admixture, or (IV) a polycarboxylic acid based polymer (A.sub.3) manifesting to a calcium sulfoaluminate based expansive additive an adsorption ratio of not less than 90% in 5 minutes at room temperature when added in an amount of 0.1% by weight as solids or a salt (B.sub.3) thereof, or (V) a mixture of said polycarboxylic acid polymer with a known cement dispersant; cement; and water.
摘要翻译：坍落度保持性优异的水泥组合物至少包括水泥混合物，其包含主要成分（I）短链聚亚烷基二醇（甲基）丙烯酸酯（a）的共聚物（A），长链聚亚烷基二醇（甲基丙烯酸酯（b），羧酸单体（c）和可与上述单体共聚的单体或共聚物（B），（II）的单体（a）的共聚物（A1） c）和（d）或其盐，（III）上述单体（a），（c）和（d）的共聚物（A1）或其盐（B1）的混合物使用已知的水泥混合物，或（IV）表示基于硫铝酸钙的膨胀性添加剂的多元羧酸系聚合物（A3），当以0.1％的量加入时，在室温下5分钟内吸附率不小于90％重量为固体或其盐（B3），或（V）所述多元羧酸聚合物与已知的水泥分散剂的混合物; 水泥; 和水。

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