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    • 6. 发明申请
    • Preparation and use of iminodisuccinic acid ammonium metal salts
    • 亚氨基二琥珀酸铵金属盐的制备和应用
    • US20070118000A1
    • 2007-05-24
    • US11652837
    • 2007-01-12
    • Torsten GrothAlfred MitschkerRalf-Johann MoritzThomas KleinThomas MenzelWolfgang Wirth
    • Torsten GrothAlfred MitschkerRalf-Johann MoritzThomas KleinThomas MenzelWolfgang Wirth
    • C07C227/06
    • C07C229/76A01N37/44C05D9/02C07C227/08C07C229/24C05F11/00
    • The invention relates to a process for the preparation of iminodisuccinic acid ammonium metal salts, characterized in that, in a first stage, maleic anhydride (MA), alkali metal hydroxide and water are mixed in the molar ratio of 2:0-3:5-30 and then ammonia is metered in in the ratio MA:ammonia 2:1.5-8, in order to obtain iminodisuccinic acid ammonium salts which, in a second stage, are reacted with metal oxides, metal hydroxides (and) or other metal salts or their mixtures to give iminodisuccinic acid ammonium metal salts of the formula 8, IDA(NH4)x(Na)y(K)z(Me)m.(NH3)n  Formula 8 in which IDA represents iminodisuccinic acid anion, x=0.1-3.9 y=0-3 z=0-3 m=0.1-2 n=0-6 and Me represents metals of the IInd, IIIrd and IVth main groups and of the Ist to VIIIth subgroups as well as metals of the lanthanide series, of the Periodic Table, which can occur in the oxidation states 1, 2, 3 or 4, the compounds themselves and their intermediates, and the use.
    • 本发明涉及一种制备亚氨基二琥珀酸铵金属盐的方法,其特征在于,在第一阶段中,马来酸酐(MA),碱金属氢氧化物和水以2:0-3:5的摩尔比混合 -30,然后以MA:氨2:1.5-8的比例计量氨,以获得亚氨基二琥珀酸铵盐,其在第二阶段与金属氧化物反应,金属氢氧化物(和)或其它金属盐 或其混合物,得到式8的亚氨基二琥珀酸铵金属盐,<?in-line-formula description =“In-line Formulas”end =“lead”?> IDA(NH 4) (Na)y(K)z(Me)m(NH 3) 式8其中IDA表示亚氨基二琥珀酸阴离子,x = 0.1-3.9 y = 0,其中,式8是线内式描述=“In-line Formula”end =“tail” -3 z = 0-3 m = 0.1-2 n = 0-6,Me表示IInd,IIIrd和IVth主要和Ist至VIII族亚组的金属以及t 他的镧系元素周期表,其可以发生在氧化态1,2,3或4中,化合物本身及其中间体,以及其用途。
    • 7. 发明授权
    • Preparation and use of iminodisuccinic acid ammonium metal salts
    • 亚氨基二琥珀酸铵金属盐的制备和应用
    • US07183429B2
    • 2007-02-27
    • US10423326
    • 2003-04-25
    • Torsten GrothAlfred MitschkerRalf-Johann MoritzThomas KleinThomas MenzelWolfgang Wirth
    • Torsten GrothAlfred MitschkerRalf-Johann MoritzThomas KleinThomas MenzelWolfgang Wirth
    • C07C229/00
    • C07C229/76A01N37/44C05D9/02C07C227/08C07C229/24C05F11/00
    • The invention relates to a process for the preparation of iminodisuccinic acid ammonium metal salts, characterized in that, in a first stage, maleic anhydride (MA), alkali metal hydroxide and water are mixed in the molar ratio of 2:0–3:5–30 and then ammonia is metered in in the ratio MA: ammonia 2:1.5–8, in order to obtain iminodisuccinic acid ammonium salts which, in a second stage, are reacted with metal oxides, metal hydroxides (and) or other metal salts or their mixtures to give iminodisuccinic acid ammonium metal salts of the formula 8, IDA(NH4)x(Na)y(K)z(Me)m.(NH3)nFormula 8 in which IDA represents iminodisuccinic acid moiety, x=0.1–3.9 y=0–3 z=0–3 m=0.1–2 n=0–6 and Me represents metals of the IInd, IIIrd and IVth main groups and of the Ist to VIIIth subgroups as well as metals of the lanthanide series, of the Periodic Table, which can occur in the oxidation states 1, 2, 3 or 4, the compounds themselves and their intermediates and the use.
    • 本发明涉及一种制备亚氨基二琥珀酸铵金属盐的方法,其特征在于,在第一阶段中,马来酸酐(MA),碱金属氢氧化物和水以2:0-3:5的摩尔比混合 -30,然后以MA:氨2:1.5-8的比例计量氨,以获得亚氨基二琥珀酸铵盐,其在第二阶段与金属氧化物反应,金属氢氧化物(和)或其它金属盐 或其混合物,得到式8的亚氨基二琥珀酸铵金属盐,<?in-line-formula description =“In-line Formulas”end =“lead”?> IDA(NH 4) (Na)y(K)z(Me)m(NH 3) 式8其中IDA表示亚氨基二琥珀酸部分,x = 0.1-3.9y = 0,其中,式8 <?in-line-formula description =“In-line Formulas”end =“tail” -3 z = 0-3 m = 0.1-2 n = 0-6,Me表示IInd,IIIrd和IVth主要和Ist至VIII族亚组的金属以及t 他的镧系元素周期表,其可以发生在氧化态1,2,3或4中,化合物本身及其中间体及其用途。