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    • 3. 发明申请
    • Fluorine Gas Generating Device
    • 氟气发生装置
    • US20120031752A1
    • 2012-02-09
    • US13258954
    • 2010-03-29
    • Isamu MoriTatsuo MiyazakiAkifumi YaoTakuya Kita
    • Isamu MoriTatsuo MiyazakiAkifumi YaoTakuya Kita
    • C25B15/00C25B9/00C25B1/24
    • C25B1/245C01B7/20C25B15/08
    • A fluorine gas generating device 100 is provided which facilitates the maintenance operation of recovery and replacement of an adsorbing material that adsorbs hydrogen fluoride and supplies fluorine gas in a stable manner. The device comprises a refining line 20 that includes refining devices that, with the aid of adsorbing material, remove hydrogen fluoride gas that has been evaporated from a molten salt of an electrolytic tank 1 and mixed to fluorine gas generated at a positive pole 103a of the electrolytic tank. The refining line 20 comprises a first refining section 21 that includes at least two refining devices arranged in parallel and a second refining section 22 that includes at least two refining devices arranged in parallel and is positioned downstream of the first refining section 21. Fluorine gas that has passed through either one of the refining devices of the first refining section 21 is selectively led to either one of the refining devices of the second refining section.
    • 提供了一种氟气发生装置100,其有助于回收和更换吸附氟化氢并以稳定的方式供应氟气的吸附材料的维护操作。 该装置包括精炼管线20,其包括精炼装置,该装置借助于吸附材料除去从电解槽1的熔融盐蒸发的氟化氢气体,并混合到在正极103a处产生的氟气体 电解槽。 精炼生产线20包括第一精炼部分21,其包括平行布置的至少两个精炼装置和第二精炼部分22,该第二精炼部分22包括平行排列并且位于第一精炼部分21的下游的至少两个精炼装置。氟气 已经通过了第一精炼部21的精炼装置中的任一个选择性地被引导到第二精炼部的精炼装置中的任一个。
    • 6. 发明申请
    • Apparatus for Generating Fluorine Gas
    • 氟气产生装置
    • US20120318665A1
    • 2012-12-20
    • US13574177
    • 2011-02-24
    • Tatsuo MiyazakiAkifumi YaoTakuya Kita
    • Tatsuo MiyazakiAkifumi YaoTakuya Kita
    • C25B9/00C25B1/24
    • C25B1/245B01D53/0423B01D53/0446B01D53/685B01D2256/26B01D2257/2047C25B15/08
    • [Object] To provide a fluorine gas generating system which can stably supply high purity fluorine gas while preventing blockade of a purification apparatus for adsorbing and removing hydrogen fluoride.[Solving means] A fluorine gas generating system characterized by including a purification apparatus 20 for adsorbing and removing hydrogen fluoride vaporized from a molten salt of an electrolysis tank 1 and mixed in fluorine gas generated at an anode 7, in which the purification apparatus 20 includes a cylindrical member through which main-product gas containing fluorine gas generated in the electrolysis tank 1 flows, a temperature regulator for regulating temperature of the cylindrical member, and an adsorbent holder disposed inside the cylindrical member, the adsorbent holder being disposed to form an aperture for securing a flow passage of the main-product gas inside the cylindrical member.
    • 本发明提供一种能够稳定地供给高纯度氟气同时防止用于吸附除去氟化氢的净化装置的氟系气体发生系统。 [解决方案]一种氟气发生系统,其特征在于包括:净化装置20,其用于吸附除去由电解槽1的熔融盐蒸发的氟化氢,并混合在阳极7产生的氟气中,净化装置20包括 在电解槽1中产生的含有氟气的主要产物气体通过其流过的圆柱形构件,用于调节圆柱形构件温度的温度调节器和设置在圆柱形构件内部的吸附剂保持器,该吸附剂保持器设置成形成孔 用于将主产品气体的流路固定在圆柱形构件内。
    • 7. 发明申请
    • FLUORINE GAS GENERATING APPARATUS
    • 氟燃气发生装置
    • US20130008781A1
    • 2013-01-10
    • US13520237
    • 2010-11-30
    • Akiou KikuchiAkifumi YaoTatsuo MiyazakiNobuyuki Tokunaga
    • Akiou KikuchiAkifumi YaoTatsuo MiyazakiNobuyuki Tokunaga
    • C25B1/24
    • C25B1/245C01B7/20C25B9/00C25B15/08F17C7/04
    • A fluorine gas generating apparatus includes an electrolytic cell where the molten salt is retained and which is separated and divided above the liquid level of the molten salt into a first gas chamber where a product gas mainly containing a fluorine gas generated at an anode immersed in the molten salt is led and a second gas chamber where a byproduct gas mainly containing a hydrogen gas generated at a cathode immersed in the molten salt is led, and a refining device refining the fluorine gas by coagulating with a cooling medium and trapping a hydrogen fluoride gas evaporated from the molten salt in the electrolytic cell and mixed in the product gas generated from the anode. The cooling medium for coagulation of the hydrogen fluoride gas in the refining device and discharged is re-used as a utility gas used at spots in the fluorine gas generating apparatus.
    • 氟气发生装置包括电解池,其中熔融盐保持并且在熔融盐的液面之上分离和分割成第一气室,在第一气室中主要含有在阳极中产生的氟气的产物浸没在 引入熔融盐,引导第二气室,其中主要含有浸在熔盐中的阴极产生的氢气的副产物被引导,精炼装置通过用冷却介质凝结和捕获氟化氢气体来精炼氟气 从电解池中的熔融盐中蒸发出来并混合在从阳极产生的产物气体中。 精炼装置中的氟化氢气体的凝结用冷却介质被排出,作为在氟气发生装置的点处使用的有用气体。
    • 8. 发明申请
    • FLUORINE GAS GENERATING APPARATUS
    • 氟燃气发生装置
    • US20120241313A1
    • 2012-09-27
    • US13513812
    • 2010-11-25
    • Akifumi YaoTatsuo MiyazakiYosuke NakamuraKeita NakaharaNobuyuki Tokunaga
    • Akifumi YaoTatsuo MiyazakiYosuke NakamuraKeita NakaharaNobuyuki Tokunaga
    • C25B9/00C25B1/24
    • C25B1/245
    • A fluorine gas generating apparatus generating a fluorine gas by electrolyzing hydrogen fluoride in molten salt, includes: an electrolytic cell including, above a liquid level of molten salt, a first gas chamber into which a product gas mainly containing the fluorine gas generated at an anode immersed in the molten salt and a second gas chamber separated from the first gas chamber into which a byproduct gas mainly containing a hydrogen gas generated at a cathode immersed in the molten salt; a hydrogen fluoride supply source retaining hydrogen fluoride to be replenished in the electrolytic cell; a refining device trapping a hydrogen fluoride gas evaporated from the molten salt in the electrolytic cell and mixed in the product gas generated from the anode to refine the fluorine gas; and a recovery facility conveying and recovering the hydrogen fluoride trapped in the refining device in the electrolytic cell or the hydrogen fluoride supply source.
    • 一种通过在熔融盐中电解氟化氢产生氟气的氟气发生装置,包括:电解槽,其包括在熔融盐的液面以上的第一气室,主要含有在阳极产生的氟气的产物气体 浸入熔融盐和从第一气室分离的第二气室,在该第一气室中主要含有在浸入熔盐中的阴极产生的氢气的副产物气体; 氟化氢供应源,其保留在电解池中补充的氟化氢; 精炼装置捕集从电解槽中的熔融盐蒸发的氟化氢气体,并混合在由阳极产生的产物气体中,以精炼氟气; 以及回收设备,其输送和回收截留在电解池或氟化氢供应源中的精炼装置中的氟化氢。
    • 10. 发明授权
    • Fluorine gas generating apparatus
    • 氟气发生装置
    • US08864961B2
    • 2014-10-21
    • US13520237
    • 2010-11-30
    • Akiou KikuchiAkifumi YaoTatsuo MiyazakiNobuyuki Tokunaga
    • Akiou KikuchiAkifumi YaoTatsuo MiyazakiNobuyuki Tokunaga
    • C25B9/00C25B1/24C25B15/08C01B7/20F17C7/04
    • C25B1/245C01B7/20C25B9/00C25B15/08F17C7/04
    • A fluorine gas generating apparatus includes an electrolytic cell where the molten salt is retained and which is separated and divided above the liquid level of the molten salt into a first gas chamber where a product gas mainly containing a fluorine gas generated at an anode immersed in the molten salt is led and a second gas chamber where a byproduct gas mainly containing a hydrogen gas generated at a cathode immersed in the molten salt is led, and a refining device refining the fluorine gas by coagulating with a cooling medium and trapping a hydrogen fluoride gas evaporated from the molten salt in the electrolytic cell and mixed in the product gas generated from the anode. The cooling medium for coagulation of the hydrogen fluoride gas in the refining device and discharged is re-used as a utility gas used at spots in the fluorine gas generating apparatus.
    • 氟气发生装置包括电解池,其中熔融盐保持并且在熔融盐的液面之上分离和分割成第一气室,在第一气室中主要含有在阳极中产生的氟气的产物浸没在 引入熔融盐,引导第二气室,其中主要含有浸在熔盐中的阴极产生的氢气的副产物被引导,精炼装置通过用冷却介质凝结和捕获氟化氢气体来精炼氟气 从电解池中的熔融盐中蒸发出来并混合在从阳极产生的产物气体中。 精炼装置中的氟化氢气体的凝结用冷却介质被排出,作为在氟气发生装置的点处使用的有用气体。