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1. 发明授权

US5449416A Cold accumulating material and method of manufacturing the same 失效
标题翻译：蓄冷材料及其制造方法
公开(公告)号：US5449416A
公开(公告)日：1995-09-12
申请号：US383655
申请日：1995-02-03
申请人： Tomohisa Arai , Naoyuki Sori , Masashi Sahashi , Yoichi Tokai
发明人： Tomohisa Arai , Naoyuki Sori , Masashi Sahashi , Yoichi Tokai
IPC分类号： C09K5/00 , B22F1/00 , B22F9/08 , B22F9/10 , C09K5/08 , C09K5/14 , C22C1/04 , C22C28/00 , F25B9/00 , F25B9/14 , H01F1/01 , H01F1/053
CPC分类号： B22F9/082 , B22F1/0014 , B22F9/10 , C09K5/14 , C22C1/04 , C22C1/0441 , C22C28/00 , F25B9/14 , H01F1/015 , B22F2009/088 , F25B2309/003
摘要： The extremely low temperature cold accumulating material for use in refrigerators, for example, comprises particles containing at least one kind of rare earth element selected from a group consisting of Y, La, Ce, Pr, Nd, Pm, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, and Yb. The proportion of particles each having a particle size of 0.01 to 3 mm is 70% or greater by weight with respect to the whole particles and the proportion of particles each having a shape such that the ratio of the major diameter to the minor diameter is not greater than 5 is 70% or greater by weight with respect to the whole particles. The particles are manufactured by quenching and solidifying a molten metal containing at least one kind of rear earth element described above. The thus manufacured extremely low temperature cold accumulating material is improved in cold accumulating efficiency and is specifically improved in mechanical strength and in chemical stability.
摘要翻译：例如，用于冰箱的极低温蓄冷材料包括含有选自由Y，La，Ce，Pr，Nd，Pm，Sm，Eu，Gd等组成的组中的至少一种稀土元素的粒子， Tb，Dy，Ho，Er，Tm和Yb。粒径为0.01〜3mm的粒子的比例相对于整个粒子为70重量％以上，并且具有使得长径与小径的比例不成比例的粒子的比例相对于整个颗粒，大于5是70重量％以上。颗粒通过淬火和固化含有上述至少一种后置土元素的熔融金属来制造。这样制造的极低温蓄冷材料在蓄冷效率上得到提高，并且具体地提高了机械强度和化学稳定性。

2. 发明授权

US5186765A Cold accumulating material and method of manufacturing the same 失效
标题翻译：冷累积材料及其制造方法
公开(公告)号：US5186765A
公开(公告)日：1993-02-16
申请号：US558484
申请日：1990-07-27
申请人： Tomohisa Arai , Naoyuki Sori , Masashi Sahashi , Yoichi Tokai
发明人： Tomohisa Arai , Naoyuki Sori , Masashi Sahashi , Yoichi Tokai
IPC分类号： C09K5/00 , B22F1/00 , B22F9/08 , B22F9/10 , C09K5/08 , C09K5/14 , C22C1/04 , C22C28/00 , F25B9/00 , F25B9/14 , H01F1/01
CPC分类号： B22F9/082 , B22F1/0014 , B22F9/10 , C09K5/14 , C22C1/04 , C22C1/0441 , C22C28/00 , F25B9/14 , H01F1/015 , B22F2009/088 , F25B2309/003
摘要： The extremely low temperature cold accumulating material for use in refrigerators, for example, comprises particles containing at least one kind of rare earth element selected from a group consisting of Y, La, Ce, Pr, Nd, Pm, Sm Eu, Gd, Tb, Dy, Ho, Er, Tm, and Yb. The proportion of particles each having a particle size of 0.01 to 3 mm is 70% or greater by weight with respect to the whole particles and the proportion of particles each having a shape such that the ratio of the major diameter to the minor diameter is not greater than 5 is 70% or greater by weight with respect to the whole particles. The particles are manufactured by quenching and solidifying a molten metal containing at least one kind of rare earth element described above. The thus manufactured extremely low temperature cold accumulating material is improved in cold accumulating efficiency and is specifically improved in mechanical strength and in chemical stability.

3. 发明授权

US4578125A Permanent magnet 失效
标题翻译：永久磁铁
公开(公告)号：US4578125A
公开(公告)日：1986-03-25
申请号：US392593
申请日：1982-06-28
申请人： Masashi Sahashi , Koichiro Inomata , Naoyuki Sori , Hideki Yamamiya
发明人： Masashi Sahashi , Koichiro Inomata , Naoyuki Sori , Hideki Yamamiya
IPC分类号： C22C19/07 , H01F1/055 , C04B35/00
CPC分类号： C22C19/07 , H01F1/0557
摘要： Disclosed is a comprising a powdered alloy composed of 23 to about 29% by weight of samarium, 0.2 to about 7% by weight of titanium, 3 to about 9% by weight of copper, 10 to about 25% by weight of iron, and the balance of cobalt principally; said powdered alloy being sintered to obtain a sintered body, followed by(a) annealing the sintered body at a cooling rate of not more than 5.degree. C./min from an annealing-initiating temperature of from 600.degree. to 900.degree. C., or(b) subjecting the sintered body to a multi-stepwise aging processing initiated from a higher temperature to a lower temperature within the temperature range of from 350.degree. to 900.degree. C.The magnet is excellent in all the magnetic properties such as residual magnetic flux density, coercive force and maximum energy product, and also excellent in antioxidation property.
摘要翻译：公开了一种粉末状合金，其包含23至29重量％的钐，0.2至约7重量％的钛，3至约9重量％的铜，10至约25重量％的铁以及钴的余量主要为所述粉末状合金被烧结以获得烧结体，然后（a）从600℃至900℃的退火起始温度以不超过5℃/分钟的冷却速率对烧结体进行退火，或（b）使烧结体在350〜900℃的温度范围内从较高的温度开始进行多步骤老化处理。该磁体具有优异的磁性能，例如残余磁性磁通密度，矫顽力和最大能量乘积，抗氧化性也优异。

4. 发明授权

US5716462A Magnetic material and bonded magnet 失效
标题翻译：磁性材料和粘结磁铁
公开(公告)号：US5716462A
公开(公告)日：1998-02-10
申请号：US671595
申请日：1996-06-28
申请人： Shinya Sakurada , Akihiko Tsutai , Takahiro Hirai , Yoshitaka Yanagita , Masashi Sahashi , Tomohisa Arai , Keisuke Hashimoto
发明人： Shinya Sakurada , Akihiko Tsutai , Takahiro Hirai , Yoshitaka Yanagita , Masashi Sahashi , Tomohisa Arai , Keisuke Hashimoto
IPC分类号： C22C19/07 , C22C38/00 , H01F1/053 , H01F1/057 , H01F1/058 , H01F1/059 , H01F1/08
CPC分类号： H01F1/057 , H01F1/0578 , H01F1/058 , H01F1/059
摘要： There is provided a magnetic material having a TbCu.sub.7 phase as a principal phase and excellent in residual magnetic flux density. This magnetic material is formed of a composition represented by a general formula: R1.sub.x R2.sub.y B.sub.z A.sub.u M.sub.100-x-y-z-u wherein R1 is at least one element selected from rare earth elements including Y; R2 is at least one element selected from Zr, Hf and Sc; A is at least one element selected from H, N, C and P; M is at least one element selected from Fe and Co; x, y, z and u represent are atomic percent individually defined as 2.ltoreq.x, 2.ltoreq.x+y.ltoreq.20, 0.001.ltoreq.z.ltoreq.10, 0.ltoreq.u.ltoreq.20; and a principal phase of the magnetic material having a TbCu.sub.7 type crystal structure.
摘要翻译：提供了具有TbCu7相作为主相的磁性材料，并且剩余磁通密度优异。该磁性材料由通式R1xR2yBzAuM100-x-y-z-u表示的组合物形成，其中R1为选自包括Y在内的稀土元素中的至少一种元素; R2是选自Zr，Hf和Sc中的至少一种元素; A是选自H，N，C和P中的至少一种元素; M是选自Fe和Co中的至少一种元素; x，y，z和u表示的是原子百分比，分别定义为2，x，2，...，x，y = 20,0.001， 20; 以及具有TbCu7型晶体结构的磁性材料的主相。

5. 发明授权

US06336978B1 Heat regenerative material formed of particles or filaments 失效
标题翻译：由颗粒或细丝形成的热再生材料
公开(公告)号：US06336978B1
公开(公告)日：2002-01-08
申请号：US09419924
申请日：1999-10-18
申请人： Yoichi Tokai , Masashi Sahashi
发明人： Yoichi Tokai , Masashi Sahashi
IPC分类号： H01F1053
CPC分类号： F02G1/0445 , F02G2250/18 , F05C2225/08 , F25B9/14 , F25B2309/003 , H01F1/012 , H01F1/015
摘要： A heat regenerative material including AMz, where A is at least one rare earth element selected from the group consisting of Y, La, Ce, Pr, Nd, Pm, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm and Yb; M is at least one metal selected from the group consisting of Ni and Co; and z is 0.001 to 9.0; the heat regenerative material being formed of particles with an average diameter of 1-2,000 &mgr;m or filaments with an average diameter of 1-2,000 &mgr;m.
摘要翻译：包括AMz的热再生材料，其中A是选自Y，La，Ce，Pr，Nd，Pm，Sm，Eu，Gd，Tb，Dy，Ho，Er，Tm中的至少一种稀土元素，和 Yb; M是选自Ni和Co中的至少一种金属; z为0.001〜9.0; 热再生材料由平均直径为1-2,000μm的颗粒或平均直径为1-2,000μm的长丝形成。

6. 发明授权

US5223046A Super-magnetostrictive alloy 失效
标题翻译：超磁致伸缩合金
公开(公告)号：US5223046A
公开(公告)日：1993-06-29
申请号：US845827
申请日：1992-03-06
申请人： Tadahiko Kobayashi , Yoichi Tokai , Masashi Sahashi
发明人： Tadahiko Kobayashi , Yoichi Tokai , Masashi Sahashi
IPC分类号： H01L41/20
CPC分类号： H01L41/20
摘要： A super-magnetostrictive alloy has a high coefficient of magnetostriction and satisfactory toughness. The first type of the super-magnetostrictive alloy has a composition whose atomic ratio is expressed by (Tb.sub.x Dy.sub.1-x (Fe.sub.1-y Mn.sub.y).sub.z, where 0.35.ltoreq.x.ltoreq.0.9, 0.001.ltoreq.y.ltoreq.0.6, and 1.4.ltoreq.z.ltoreq.2.1. The second type of the super-magnetostrictive alloy has a composition whose atomic ratio is expressed by (Tb.sub.x Dy.sub.1-x (Fe.sub.1-y-w Mn.sub.y T.sub.w).sub.z, where 0.2.ltoreq.x.ltoreq.0.9, 0.05.ltoreq.y.ltoreq.0.4, 0.05.ltoreq.w.ltoreq.0.1, and 1.4.ltoreq.z.ltoreq.2.1, and where T is at least one of Co and Ni. The super-magnetostrictive alloys of both types have a Laves-type intermetallic compound phase as a main phase, and a rare earth metal phase is located between the portions having the main phase.
摘要翻译：超磁致伸缩合金的磁致伸缩系数高，韧性好。第一种类型的超磁致伸缩合金具有其原子比由（TbxDy1-x（Fe1-yMny）z）表示的组成，其中0.35

7. 发明授权

US5190599A Magnetic memory and magnetic alloy thereof 失效
标题翻译：磁记忆及其磁性合金
公开(公告)号：US5190599A
公开(公告)日：1993-03-02
申请号：US586983
申请日：1990-09-24
申请人： Masashi Sahashi , Yoichi Tokai , Tomomi Funayama
发明人： Masashi Sahashi , Yoichi Tokai , Tomomi Funayama
IPC分类号： C22C5/04 , G11B5/64 , H01F1/00 , H01F1/01 , H01F1/03 , H01F10/14
CPC分类号： G11B5/653 , H01F1/012 , H01F1/0306
摘要： A magnetic memory and a magnetic alloy thereof are disclosed, which comprise a magnetic alloy whose main phase is an iso-molar compound phase, the iso-molar compound phase being represented with general expression Pt(Fe.sub.1-x Mn.sub.x)Sn where the relationship of 0
摘要翻译：公开了一种磁记忆体及其磁性合金，它们包括主相为异摩尔化合物相的磁性合金，异摩尔化合物相以通式Pt（Fe1-x Mnx）Sn表示，其中， 0

8. 发明授权

US5110376A Super-magnetostrictive alloy 失效
标题翻译：超磁性合金
公开(公告)号：US5110376A
公开(公告)日：1992-05-05
申请号：US671074
申请日：1991-03-18
申请人： Tadahiko Kobayashi , Yoichi Tokai , Masashi Sahashi
发明人： Tadahiko Kobayashi , Yoichi Tokai , Masashi Sahashi
IPC分类号： H01L41/20
CPC分类号： H01L41/20
摘要： A super-magnetostrictive alloy has a high coefficient of magnetostriction and satisfactory toughness. The first type of the super-magnetostrictive alloy has a composition whose atomic ratio is expressed by (Tb.sub.x Dy.sub.1-x (Fe.sub.1-y Mn.sub.y).sub.z, where 0.35.ltoreq.x.ltoreq.0.9, 0.001.ltoreq.y.ltoreq.0.6, and 1.4.ltoreq.z.ltoreq.2.1. The second type of the supermagnetostrictive alloy has a composition whose atomic ratio is expressed by (Tb.sub.x Dy.sub.1-x (Fe.sub.1-y-w Mn.sub.y T.sub.w).sub.z, where 0.2.ltoreq.x.ltoreq.0.9, 0.05.ltoreq.y.ltoreq.0.4, 0.05.ltoreq.w.ltoreq.0.1, and 1.4.ltoreq.z.ltoreq.2.1, and where T is at least one of Co and Ni. The super-magnetostrictive alloys of both types have a Laves-type intermetallic compound phase as a main phase, and a rare earth metal phase is located between the portions having the main phase.

9. 发明授权

US06022486A Refrigerator comprising a refrigerant and heat regenerative material 失效
标题翻译：冰箱包括制冷剂和热再生材料
公开(公告)号：US06022486A
公开(公告)日：2000-02-08
申请号：US804501
申请日：1991-12-10
申请人： Yoichi Tokai , Masashi Sahashi
发明人： Yoichi Tokai , Masashi Sahashi
IPC分类号： F25B9/00 , F02G1/044 , F25B9/14 , H01F1/01 , C09K5/00 , F25B21/00
CPC分类号： F02G1/0445 , F25B9/14 , H01F1/012 , H01F1/015 , F02G2250/18 , F05C2225/08 , F25B2309/003
摘要： A magnetic substance represented by the following general formula (I):AMz (I)where A is at least one rare earth element selected from the group consisting of Y, La, Ce, Pr, Nd, Pm, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, and Yb, M is at least one metal selected from the group consisting of Ni, Co, and Cu, and z is 0.001 to 9.0. This magnetic substance has its maximal of specific heat, due to magnetocaloric effect, at extremely low temperatures, the maximal value of specific heat being great. It also has a great lattice specific heat. A regenerator filled with the magnetic substance exhibits an excellent heat regeneration efficiency at extremely low temperature.
摘要翻译：由以下通式（I）表示的磁性物质：AMz（I）其中A是选自Y，La，Ce，Pr，Nd，Pm，Sm，Eu，Gd中的至少一种稀土元素， Tb，Dy，Ho，Er，Tm和Yb，M是选自Ni，Co和Cu中的至少一种金属，z为0.001〜9.0。这种磁性物质由于磁热效应而具有最大的比热，在极低的温度下，比热的最大值很大。它也具有很大的晶格比热。填充有磁性物质的再生器在极低的温度下表现出优异的热再生效率。

10. 发明授权

US5593517A Regenerating material and refrigerator using the same 失效
标题翻译：再生材料和冰箱使用相同
公开(公告)号：US5593517A
公开(公告)日：1997-01-14
申请号：US305916
申请日：1994-09-15
申请人： Akiko Saito , Masashi Sahashi , Yoichi Tokai , Akihiko Tsutai , Masami Okamura , Yukiko Nishiyama , Michihiko Inaba
发明人： Akiko Saito , Masashi Sahashi , Yoichi Tokai , Akihiko Tsutai , Masami Okamura , Yukiko Nishiyama , Michihiko Inaba
IPC分类号： F25B9/14 , H01F1/00 , H01F1/01 , H01F1/055
CPC分类号： B82Y25/00 , F25B9/14 , H01F1/015 , F25B2309/003
摘要： The regenerating material according to the present invention comprises two alloy phases which differ in a content of rare earth elements. Of these alloy phases, a dominant phase in the regenerating material is defined as a main phase, and the other phase is defined as a sub-phase. A plurality of particles, each of which consists of a granular main phase and a sub-phase present on the surface of the main phase, gathers to form an aggregate. Otherwise, a sub-phase present in a main phase in the form of fiber. The refrigerator according to the present invention comprises a regenerator charged with above-mentioned regenerating material, a coolant gas and an expansion means for expanding the coolant gas.
摘要翻译：根据本发明的再生材料包括稀土元素含量不同的两个合金相。在这些合金相中，再生材料中的主相被定义为主相，另一相被定义为子相。多个颗粒，每个颗粒由存在于主相表面上的颗粒状主相和亚相组成，聚集形成聚集体。否则，以纤维形式存在于主相中的子阶段。根据本发明的冰箱包括装有上述再生材料的再生器，冷却剂气体和用于膨胀冷却剂气体的膨胀装置。

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