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1. 发明授权

US06645901B2 Prepolymerization catalyst for use in gas phase polymerization of olefins and process for producing the same 有权
标题翻译：用于烯烃气相聚合的预聚合催化剂及其制备方法
公开(公告)号：US06645901B2
公开(公告)日：2003-11-11
申请号：US09820977
申请日：2001-03-30
申请人： Tomoaki Goto , Kazuki Wakamatsu , Shinichi Kumamoto
发明人： Tomoaki Goto , Kazuki Wakamatsu , Shinichi Kumamoto
IPC分类号： B01J3100
CPC分类号： C08F10/00 , C08F210/16 , Y10S526/901 , Y10S526/908 , Y10S526/909 , C08F4/6565 , C08F4/6492 , C08F210/08 , C08F2500/18 , C08F2500/12 , C08F2500/17
摘要： A prepolymerization catalyst for use in a gas phase polymerization of an olefin or combinations of olefins which comprises (A) a solid catalyst component comprising magnesium, halogen, titanium and an electron donor and having a weight-average particle diameter of 15 to 45 &mgr;m, (B) at least one organoaluminum compound and (C) a prepolymer of an ethylene and/or at least one &agr;-olefin, wherein the molar ratio of aluminum to titanium in the prepolymerization catalyst (Al/Ti ratio) is 3 to 11 (mol/mol), the weight ratio of the prepolymerization catalyst to the solid catalyst component (prepolymerization catalyst/solid catalyst component) is 2 to 35 (g/g), the content of volatile materials (VM) in the prepolymerization catalyst is 2.0% by weight or less, and the intrinsic viscosity [&eegr;] measured in tetralin at 135° C. is 2.0 dl/g or less, and a process for a production thereof. According to the present invention, a prepolymerization catalyst for gas phase polymerization of olefins showing a high activity in gas phase polymerization, not forming aggregates and coarse particles markedly at the time of prepolymerization, having a high bulk density and an excellent fluidity, not causing a marked entraining of prepolymerization catalyst and product powder out of the fluidized bed and nearly completely free from a formation of aggregates, at the time of gas phase polymerization, and giving an olefin polymer having a low content of cold xylene-soluble fraction can be provided.
摘要翻译：一种用于烯烃或烯烃组合的气相聚合的预聚合催化剂，其包含（A）包含镁，卤素，钛和电子给体的固体催化剂组分，其重均粒径为15至45μm，（B）至少一种有机铝化合物和（C）乙烯和/或至少一种α-烯烃的预聚物，其中预聚合催化剂中铝与钛的摩尔比（Al / Ti比）为3-11（ mol / mol），预聚合催化剂与固体催化剂组分（预聚合催化剂/固体催化剂组分）的重量比为2〜35（g / g），预聚合催化剂中挥发物（VM）的含量为2.0％以下，在135℃下在四氢化萘中测定的特性粘度η为2.0dl / g以下，以及其制造方法。根据本发明，提供了一种气相聚合用预聚合催化剂烯烃聚合物在气相聚合中具有高活性，在预聚合时不显着形成聚集体和粗颗粒，具有高堆积密度和优异的流动性，不会引起预聚合催化剂和产物粉末明显夹带在流化床之外，几乎在气相聚合时完全没有聚集体的形成，并且可以提供具有低二甲苯可溶成分含量低的烯烃聚合物。

2. 发明申请

US20100197865A1 PROPYLENE-ETHYLENE-BUTENE BLOCK COPOLYMER AND MOLDED ARTICLE THEREOF 有权
标题翻译：丙烯 - 乙烯 - 嵌段共聚物及其成型品
公开(公告)号：US20100197865A1
公开(公告)日：2010-08-05
申请号：US12064647
申请日：2006-08-29
申请人： Hideki Oshima , Takashi Sanada , Kazuki Wakamatsu
发明人： Hideki Oshima , Takashi Sanada , Kazuki Wakamatsu
IPC分类号： C08F255/04
CPC分类号： C08F297/08 , C08F297/083 , C08L23/12 , C08L53/00 , C08L2666/06
摘要： A propylene-ethylene-butene block copolymer is provided which includes from 60 to 85% by weight of a polypropylene portion and from 15 to 40% by weight of a propylene-ethylene-butene random copolymer portion, wherein the copolymer satisfies the requirements (1) and (2) given below. In addition, a molded article including such a propylene-ethylene-butene block copolymer is provided. (1) The random copolymer portion includes a propylene-ethylene random copolymer component (EP) and a propylene-ethylene-butene random copolymer component (EPB) and the copolymer component (EP) has an intrinsic viscosity of from 1.5 to 8 dl/g and an ethylene unit content of from 20 to 50% by weight, and the copolymer component (EPB) has an intrinsic viscosity of from 0.5 to 8 dl/g, an ethylene unit content of from 47 to 77% by weight and a butene unit component of from 3 to 33% by weight and the total of the ethylene unit content and the butene unit content is from 50 to 80% by weight. (2): The propylene-ethylene-butene block copolymer has a melt flow rate of from 5 to 120 g/10 min.
摘要翻译：提供了丙烯 - 乙烯 - 丁烯嵌段共聚物，其包含60至85重量％的聚丙烯部分和15至40重量％的丙烯 - 乙烯 - 丁烯无规共聚物部分，其中所述共聚物满足要求（1 ）和（2）给出。此外，提供了包含这种丙烯 - 乙烯 - 丁烯嵌段共聚物的模塑制品。（1）无规共聚物部分包括丙烯 - 乙烯无规共聚物组分（EP）和丙烯 - 乙烯 - 丁烯无规共聚物组分（EPB），共聚物组分（EP）的特性粘度为1.5至8dl / g 乙烯单元含量为20〜50重量％，共聚物成分（EPB）的特性粘度为0.5〜8dl / g，乙烯单元含量为47〜77重量％，丁烯单元组分为3至33重量％，乙烯单元含量和丁烯单元含量的总和为50至80重量％。（2）：丙烯 - 乙烯 - 丁烯嵌段共聚物的熔体流动速率为5〜120g / 10分钟。

3. 发明授权

US06613850B1 Method for feeding boron compounds, fine particles of boron compounds, catalyst components for the polymerization of olefins comprising them, and processes for the production of the particles 有权
标题翻译：硼化合物的供给方法，硼化合物的微粒，包含它们的烯烃聚合的催化剂成分，以及粒子的制造方法
公开(公告)号：US06613850B1
公开(公告)日：2003-09-02
申请号：US09125518
申请日：1998-11-23
申请人： Hideki Sato , Hiroaki Katayama , Kazuki Wakamatsu
发明人： Hideki Sato , Hiroaki Katayama , Kazuki Wakamatsu
IPC分类号： C08F444
CPC分类号： C07F5/027 , B01J21/02 , B01J31/14 , C08F4/65908 , C08F4/65912 , C08F4/6592 , C08F10/00 , C08F210/16 , C08F2420/02 , C08J5/18 , C08J2323/02 , C08F4/603 , C08F4/61908 , C08F210/14 , C08F2500/12 , C08F2500/08 , C08F210/08 , C08F2500/03 , C08F2500/02 , C08F2500/10
摘要： A method for feeding a boron compound, which comprises feeding at least one boron compound selected from (1) to (3) described below in the state suspended or slurried in a solvent continuously to a reactor; a boron compound in the form of fine particles being one or more boron compounds selected from (1) to (3) described below and having a maximum particle diameter of 50 &mgr;m or less; a catalyst component for olefin polymerization consisting of said boron compound in the form of fine particles; a method for producing a boron compound in the form of fine particles which comprises dissolving one or more boron compounds selected from (1) to (3) described below in an aromatic hydrocarbon solvent and then precipitating in an aliphatic hydrocarbon solvent; and a method for producing a boron compound in the form of fine particles which comprises pulverizing one or more boron compounds selected from (1) to (3) described below so that their maximum particle diameter is 50 &mgr;m or less. (1) a boron compound represented by the general formula: BQ1Q2Q3, (2) a boron compound represented by the general formula: G+(BQ1Q2Q3Q4)−, and (3) a boron compound represented by the general formula: (L-H)+(BQ1Q2Q3Q4)−.
摘要翻译：一种硼化合物的供给方法，其特征在于，将至少一种选自下述（1）〜（3）的硼化合物以在溶剂中悬浮或浆化至反应器的状态; 微粒形式的硼化合物是选自下述（1）至（3）中并且最大粒径为50μm或更小的一种或多种硼化合物; 用于由细颗粒形式的所述硼化合物组成的用于烯烃聚合的催化剂组分; 一种制备细颗粒形式的硼化合物的方法，包括将一种或多种选自下述（1）至（3）的硼化合物溶解在芳烃溶剂中，然后在脂族烃溶剂中沉淀; 以及一种微细颗粒形式的硼化合物的制造方法，其中包括粉碎一种或多种选自下述（1）至（3）的硼化合物，使其最大粒径为50μm以下。（1）由通式：BQ1Q2Q3表示的硼化合物，（2）由通式G +（BQ1Q2Q3Q4） - 表示的硼化合物，和（3）由通式（LH）+（ BQ1Q2Q3Q4） - 。

4. 发明授权

US5381827A Gas distributor for use in gas phase polymerization apparatus 失效
标题翻译：用于气相聚合装置的气体分配器
公开(公告)号：US5381827A
公开(公告)日：1995-01-17
申请号：US157294
申请日：1993-11-26
申请人： Hiroyuki Koura , Yoshizumi Sasaki , Kazuki Wakamatsu , Kazuyuki Takemura
发明人： Hiroyuki Koura , Yoshizumi Sasaki , Kazuki Wakamatsu , Kazuyuki Takemura
IPC分类号： B01J8/44 , C08F2/34 , B01J8/20
CPC分类号： C08F2/34 , B01J8/44 , Y10T137/85938
摘要： For use in gas phase polymerization apparatus having an agitator in a fluidized bed polymerization reactor, the present invention provides a gas distributor which has holes, and caps covering the respective holes from above and each having an opening oriented in a substantially horizontal direction at an angle of about 90 to about 135 deg with, and outwardly of, a tangent to a circle centered about the center of the reactor whereby an increase in the gas solid ratio can be prevented in the region above the distributor to ensure efficient discharge of the polymer produced, and the polymer particles can be prevented from falling into a gas room thereunder.
摘要翻译：为了在流化床聚合反应器中具有搅拌器的气相聚合装置中使用，本发明提供了一种具有孔的气体分配器和从上方覆盖相应孔的盖，每个孔具有在大致水平方向上以一定角度定向的开口约90度至约135度，并且向外以与反应器中心为中心的圆相切，从而可以在分配器上方的区域中防止气体固体比率的增加，以确保生产的聚合物的有效排放，并且可以防止聚合物颗粒落入其中的气室中。

5. 发明授权

US5268425A Thermoplastic resin composition 失效
标题翻译：热塑性树脂组合物
公开(公告)号：US5268425A
公开(公告)日：1993-12-07
申请号：US890221
申请日：1992-05-29
申请人： Motonobu Furuta , Kazuki Wakamatsu , Takashi Maruyama , Mitsuji Tsuji
发明人： Motonobu Furuta , Kazuki Wakamatsu , Takashi Maruyama , Mitsuji Tsuji
IPC分类号： C08L23/12 , C08L51/04 , C08L51/06 , C08L61/06 , C08L63/00 , C08L67/00 , C08L69/00 , C08L71/12 , C08L77/00 , C08L79/08 , C08L81/02 , C08L83/04
CPC分类号： C08L51/06 , C08L23/12 , C08L51/04 , C08L71/123 , C08L61/06 , C08L63/00 , C08L67/00 , C08L69/00 , C08L77/00 , C08L79/08 , C08L81/02 , C08L83/04 , Y10S525/905
摘要： Disclosed are thermoplastic resin compositions, comprising:(a) a polyphenylene ether resin or a resin composition containing a poplyphenylene ether,(b) a modified propylene polymer, or a propylene based resin composition containing the modified propylene polymer and/or a propylene polymer, and(c) optionally, a rubbery substance,wherein the proportion of the component (a) to the sum of the components (a) and (b) is 1 to 90% by weight, and that of the component (b) to the sum of the components (a) and (b) is 99 to 10% by weight, and when the component (c) is present, the proportion of the component (c) to the sum of the components (a) and (b) is 1 to 50 parts by weight per 100 parts by weight of (a) plus (b).
摘要翻译：公开了热塑性树脂组合物，其包含：（a）聚苯醚树脂或含有苯撑醚的树脂组合物，（b）改性丙烯聚合物或含有改性丙烯聚合物和/或丙烯聚合物的丙烯类树脂组合物，和（c）任选的橡胶状物质，其中成分（a）与成分（a）和（b）之和的比例为1〜90重量％，成分（b）相对于组分（a）和（b）的总和为99至10重量％，当存在组分（c）时，组分（c）与组分（a）和（b）之和的比例相对于（a）加（b）每100重量份为1〜50重量份。

6. 发明授权

US4883842A Resin composition 失效
标题翻译：树脂组成
公开(公告)号：US4883842A
公开(公告)日：1989-11-28
申请号：US172786
申请日：1988-03-28
申请人： Shigeo Tanaka , Jiro Sakai , Tomohisa Fukao , Kizuku Wakatsuki , Kazuki Wakamatsu
发明人： Shigeo Tanaka , Jiro Sakai , Tomohisa Fukao , Kizuku Wakatsuki , Kazuki Wakamatsu
IPC分类号： C08L23/02 , C08L23/24 , C09K9/02
CPC分类号： C09K9/02 , C08L23/02 , C08L23/24
摘要： There is disclosed resin composition comprising 1 to 99% by weight of a polymer A and 1 to 99% by weight of a polymer B, the polymer A and B having refractive indexes which permit satisfaction of the relation:a.ltoreq.0.015 and b-a.gtoreq.0.005wherein a and b are the minimum and the maximum, respectively, of absolute value of the difference between the refractive indexes of the polymers A and B in the temperature range of 20.degree. to 100.degree. C.; said composition being useful as a functional resin for buildings, etc.

7. 发明授权

US4801650A Process for producing 4-methylpentene-1 copolymer and resin composition containing the same 失效
标题翻译：制备4-甲基戊烯-1共聚物的方法和含有它们的树脂组合物
公开(公告)号：US4801650A
公开(公告)日：1989-01-31
申请号：US93286
申请日：1987-09-04
申请人： Kizuku Wakatsuki , Kazuki Wakamatsu
发明人： Kizuku Wakatsuki , Kazuki Wakamatsu
IPC分类号： C08F2/00 , C08F2/04 , C08F2/06 , C08F8/50 , C08F10/00 , C08F210/14 , C08F255/00 , C08F255/08 , C08F297/08 , C08L23/18
CPC分类号： C08F210/14
摘要： A process for producing a 4-methylpentene-1 copolymer comprising copolymerizing 4-methylpentene-1 with other .alpha.-olefin in a hydrocarbon solvent in the presence of a Ziegler-Natta catalyst and a resin composition containing the 4-methylpentene-1 copolymer are disclosed. The copolymerization comprises a first stage in which (A) a homopolymer or random copolymer of 4-methylpentene-1 having an .alpha.-olefin content of not more than 3 mol % and an intrinsic viscosity of at least 2.5 dl/g is prepared and a second stage in which (B) a random copolymer having an .alpha.-olefin content higher than that of the polymer (A) and no higher than 9 mol % and an intrinsic viscosity of at least 2.5 dl/g is prepared, and the produced copolymer insoluble in the solvent is separated to recover a 4-methylpentene-1 copolymer containing from 5 to 80% by weight of the polymer (A). The process produces a solvent-insoluble copolymer in an increased yield without impairing transparency of the copolymer.

8. 发明授权

US4254237A Process for producing propylene-ethylene block copolymers 失效
标题翻译：制备丙烯 - 乙烯嵌段共聚物的方法
公开(公告)号：US4254237A
公开(公告)日：1981-03-03
申请号：US30523
申请日：1979-04-16
申请人： Akinobu Shiga , Masahiro Kakugo , Hajime Sadatoshi , Kazuki Wakamatsu , Hiroshi Yoshioka
发明人： Akinobu Shiga , Masahiro Kakugo , Hajime Sadatoshi , Kazuki Wakamatsu , Hiroshi Yoshioka
IPC分类号： C08F297/00 , C08F297/08
CPC分类号： C08F297/086
摘要： A process for producing propylene-ethylene block copolymers by a three-step polymerization technique using a stereoregular catalyst, characterized in that the first-step polymerization is carried out by supplying propylene alone or a propylene/ethylene mixture so that the ethylene/propylene reaction ratio is 6/94 or less, thereby polymerizing 60 to 95% by weight of the total polymerization amount, the second-step polymerization is carried out by supplying a propylene/ethylene mixture so that the ethylene/propylene reaction ratio is 15/85 to 79/21, thereby polymerizing 1 to 20% by weight of the total polymerization amount, and the third-step polymerization is carried out by supplying a propylene/ethylene mixture so that the ethylene/propylene reaction ratio is 50/50 to 89/11, thereby polymerizing 4 to 35% by weight of the total polymerization amount, with the ethylene/propylene reaction ratio in the third step made larger than that in the second step. Said process can give propylene-ethylene block copolymers markedly well balanced in impact strength, stiffness, transparency and impact blushing.
摘要翻译：一种通过使用立体规则催化剂的三步聚合技术制备丙烯 - 乙烯嵌段共聚物的方法，其特征在于第一步聚合是通过仅供应丙烯或丙烯/乙烯混合物进行的，以使乙烯/丙烯反应比为6/94以下，由此聚合60〜95重量％的总聚合量，第二步聚合是通过供给丙烯/乙烯混合物进行的，以使乙烯/丙烯反应比为15/85〜79 / 21，由此聚合1至20重量％的总聚合量，第三步聚合通过供应丙烯/乙烯混合物进行，使得乙烯/丙烯反应比为50/50至89/11，从而聚合4〜35重量％的总聚合量，第3步骤中的乙烯/丙烯反应比例大于第2步骤。所述方法可以使丙烯 - 乙烯嵌段共聚物在冲击强度，刚度，透明度和冲击冲刷中显着地平衡。

9. 发明申请

US20050154131A1 Propylene-based polymer, polypropylene resin composition, and injection molded article 有权
标题翻译：丙烯类聚合物，聚丙烯树脂组合物和注模制品
公开(公告)号：US20050154131A1
公开(公告)日：2005-07-14
申请号：US10988520
申请日：2004-11-16
申请人： Susumu Kanzaki , Kazuki Wakamatsu
发明人： Susumu Kanzaki , Kazuki Wakamatsu
IPC分类号： B29C45/00 , C08F2/00 , C08F2/01 , C08F2/34 , C08F4/654 , C08F10/00 , C08F10/06 , C08F210/02 , C08F210/06 , C08J5/00 , C08L23/14 , C08L23/16 , C08L53/00
CPC分类号： C08F10/00 , C08F210/06 , C08L23/14 , C08L2205/02 , C08L2314/02 , C08F4/6492 , C08L2666/06 , C08F210/16 , C08F2500/17 , C08F2500/12
摘要： Disclosed is a propylene-based polymer including from 51 to 75% by weight of a propylene-ethylene random copolymer component (A) having an intrinsic viscosity [η]A, measured in tetralin at 135° C., of 5 dl/g or more and an ethylene content of not less than 8% by weight but less than 20% by weight, and from 25 to 49% by weight of a propylene-based polymer component (B) obtained by polymerizing monomers mainly including propylene, the component having an intrinsic viscosity [η]B, measured in tetralin at 135° C., of 1.2 dl/g or less, wherein said amounts of the components (A) and (B) are each based on the combined weight of these components.
摘要翻译：公开了一种丙烯类聚合物，其包含51至75重量％的在135℃下在四氢化萘中测量的特性粘度ηA SUP的丙烯 - 乙烯无规共聚物组分（A），5dl / g以上，乙烯含量为8重量％以上且20重量％以下，25〜49重量％的丙烯系聚合物成分（B），其通过聚合单体主要包括丙烯，在135℃下在四氢化萘中测得的特性粘度ηB的组分为1.2dl / g或更低，其中组分（A）和（ B）各自基于这些组件的组合重量。

10. 发明授权

US06573332B2 Propylene-based copolymer, process for producing the same and film comprising the same 有权
公开(公告)号：US06573332B2
公开(公告)日：2003-06-03
申请号：US09938501
申请日：2001-08-27
申请人： Takanori Kume , Shigeki Kishiro , Kazuki Wakamatsu
发明人： Takanori Kume , Shigeki Kishiro , Kazuki Wakamatsu
IPC分类号： C08F1000
CPC分类号： C08L23/14 , C08L2205/02 , C08L2308/00 , Y10T428/31855 , Y10T428/31909 , C08L2666/04
摘要： A propylene-based copolymer obtained by copolymerizing propylene with ethylene and/or an &agr;-olefins having 4 or more carbon atoms in the presence of a polymerization catalyst in a first step to produce a copolymer having a content of the &agr;-olefins of 1 mol % or more and less than 15 mol % and an ethylene content of 5 mol % or less in amount of 1 to 30% by weight as a copolymer component (A), and subsequently copolymerizing propylene with ethylene and/or an &agr;-olefins having 4 or more carbon atoms in a second step or later steps to produce a copolymer having a content of the &agr;-olefins of 15 to 30 mol % and an ethylene content of 5 mol % or less in amount of 70 to 99% by weight as a copolymer component (B).

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