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    • 1. 发明授权
    • Transparent electroconductive material and process for preparation
thereof
    • 透明导电材料及其制备方法
    • US4758464A
    • 1988-07-19
    • US906444
    • 1986-09-12
    • Tokihiko MasuzawaMasatoshi TakesueYukio KobayashiMitsuo Mori
    • Tokihiko MasuzawaMasatoshi TakesueYukio KobayashiMitsuo Mori
    • C08J7/18C23C14/02C23C14/08G02F1/1333C09K19/00
    • C23C14/024C08J7/18C23C14/086G02F1/133305Y10S428/917Y10T428/31855
    • Described is a transparent electroconductive material composed of a transparent synthetic resin substrate and a transparent electroconductive film formed on the resin substrate. At least a surface portion of the resin substrate on which the electroconductive film is formed satisfies a requirement represented by the formula: F x Hv=0.4 wherein F is the mole number (.mu.mole/cm.sup.2) of a basic dye that can react with or adhere to the unit area of the surface of the synthetic resin, and Hv is the Vickers hardness as determined according to JIS Z-2244. The absolute value of the photoelasticity constant of the resin substrate below the glass transition temperature thereof is not larger than 15 Brewsters. A preferred transparent electroconductive material is prepared by coating an active energy ray-curing composition satisfying a requirement represented by the above formula on a surface of the transparent synthetic resin substrate having the above-mentioned absolute value of the photoelasticity constant; curing the composition with active energy rays; and forming a transparent electroconductive film on the coating layer by a low-temperature sputtering method at a temperature lower than 100.degree. C.
    • 描述了由透明合成树脂基板和形成在树脂基板上的透明导电膜构成的透明导电材料。 至少形成有导电膜的树脂基板的表面部分满足以下公式所示的要求:F x Hv = 0.4其中F是可以与...反应的碱性染料的摩尔数(μmol/ cm 2) 附着在合成树脂表面的单位面积上,Hv为根据JIS Z-2244测定的维氏硬度。 树脂基板的玻璃化转变温度以下的光弹性常数的绝对值不大于15个布鲁斯特。 优选的透明导电材料是通过将满足上述式所示要求的活性能量射线固化组合物涂布在具有上述光弹性常数绝对值的透明合成树脂基材的表面上来制备的; 用活性能量射线固化组合物; 并在低于100℃的温度下通过低温溅射法在涂层上形成透明导电膜。