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1. 发明授权

US07358295B2 Hybrid polymer composition, and article therefrom 失效
标题翻译：杂化聚合物组合物及其制品
公开(公告)号：US07358295B2
公开(公告)日：2008-04-15
申请号：US10849582
申请日：2004-05-20
申请人： Timothy D. Miller , Yona Eckstein , Alexander V. Lubnin , Gary A. Anderle , Shui-Jen Raymond Hsu
发明人： Timothy D. Miller , Yona Eckstein , Alexander V. Lubnin , Gary A. Anderle , Shui-Jen Raymond Hsu
IPC分类号： C08J3/00 , C08K3/20 , C08L75/00 , C08F8/30 , B32B27/00
CPC分类号： C08G18/0823 , C08G18/0866 , C08G18/12 , C08G18/4018 , C08G18/4808 , C08G18/4833 , C08G18/4854 , C08G18/6677 , C08G18/6692 , C08G18/755 , C08L25/14 , C08L33/00 , C08L33/18 , C09D133/14 , C09D175/04 , Y10T428/13 , Y10T428/1352 , Y10T428/1355 , Y10T428/1386 , Y10T428/1397 , Y10T428/31551 , C08G18/3231 , C08L2666/14 , C08L75/00 , C08L2666/04
摘要： An anti-static polymer composition comprises a thermoformable, moldable, hybrid urethane-vinyl polymer composition which exhibits relatively low surface and volume resistivities and good toughness. The hybrid polymer composition can be made without volatile organic compounds such as solvents, neutralizing amines, or both.
摘要翻译：抗静电聚合物组合物包含可热成形的可成型的杂化聚氨酯 - 乙烯基聚合物组合物，其具有相对低的表面和体积电阻率以及良好的韧性。杂化聚合物组合物可以在无挥发性有机化合物如溶剂，中和胺或两者的情况下制备。

2. 发明授权

US06794475B1 Antistatic polymers, blends, and articles 失效
标题翻译：抗静电聚合物，共混物和制品
公开(公告)号：US06794475B1
公开(公告)日：2004-09-21
申请号：US09609077
申请日：2000-06-30
申请人： Julie Vaughn Bialke , John B. Canady , Shui-Jen Raymond Hsu , Alexander V. Lubnin , William F. Masler, III , Beth A. Valentino
发明人： Julie Vaughn Bialke , John B. Canady , Shui-Jen Raymond Hsu , Alexander V. Lubnin , William F. Masler, III , Beth A. Valentino
IPC分类号： C08F22068
CPC分类号： C09D155/005 , C08F290/062
摘要： This invention relates to latex polymers and blends of such latex polymers used to produce articles having superior electrostatic dissipative properties. The polymers and blends comprise one or more (1) polymers, in latex, or dispersion form, of (a) at least one reactive macromer of at least one alkylene oxide having at least one functional group capable of free-radical transformation, (b) optionally, at least one ethylenically unsaturated monomer having at least one carboxylic acid group, and (c) optionally, one or more free radically polymerizable comonomers, and (2) one or more other polymer latexes or dispersions of such polymers as natural rubber, conjugated-diene-containing polymers, hydrogenated styrene-butadiene triblock copolymers, chlorosulfonated polyethylenes, ethylene copolymers, acrylic and/or methacrylic ester copolymers, vinyl chloride copolymers, vinylidene chloride copolymers, polyisobutylenes, polyurethanes, polyureas, and poly-urethane-urea)s.
摘要翻译：本发明涉及用于制备具有优异的静电耗散性能的物品的胶乳聚合物和这种胶乳聚合物的共混物。聚合物和共混物包含一种或多种（1）聚合物，胶乳或分散体形式，（a）至少一种至少一种具有至少一个能够进行自由基转化的官能团的环氧烷的反应性大分子单体，（b ）任选的至少一种具有至少一个羧酸基团的烯键式不饱和单体，和（c）任选的一种或多种可自由基聚合的共聚单体，和（2）一种或多种其它聚合物胶乳或天然橡胶，含共轭二烯的聚合物，氢化苯乙烯 - 丁二烯三嵌段共聚物，氯磺化聚乙烯，乙烯共聚物，丙烯酸和/或甲基丙烯酸酯共聚物，氯乙烯共聚物，偏二氯乙烯共聚物，聚异丁烯，聚氨酯，聚脲和聚氨酯脲）。

3. 发明授权

US06576702B2 Plasticized waterborne polyurethane dispersions and manufacturing process 有权
标题翻译：增塑水性聚氨酯分散体及制造工艺
公开(公告)号：US06576702B2
公开(公告)日：2003-06-10
申请号：US09908045
申请日：2001-07-18
申请人： Gary A. Anderle , Susan L. Lenhard , Alexander V. Lubnin , George E. Snow , Krishnan Tamareselvy
发明人： Gary A. Anderle , Susan L. Lenhard , Alexander V. Lubnin , George E. Snow , Krishnan Tamareselvy
IPC分类号： C08J300
CPC分类号： A61Q5/06 , A61K8/87 , A61Q17/04 , A61Q19/00 , C08G18/0823 , C08G18/0866 , C08G18/10 , C08G18/12 , C08G18/4202 , C08G18/6659 , C08G18/6692 , C08G18/68 , C08G18/722 , C08G18/724 , C08G18/73 , C08K5/11 , C08K5/521 , C08G18/3225 , C08G18/3271 , C08G18/3231 , C08L75/04
摘要： Waterborne polyurethane dispersions are prepared by reacting (1) at least one polyisocyanate; (2) at least one active hydrogen containing compound, such as a polyol or a polyamide; and (3) preferably also at least one water-dispersability enhancing compound having water-dispersion enhancing groups, in order to form an isocyanate terminated prepolymer. The prepolymer subsequently is (1) optionally neutralized by reaction with at least one neutralizing agent, (2) dispersed in water, and then (3) chain extended by reaction with at least one of water, inorganic or organic polyamine having an average of about 2 or more primary and/or secondary amine groups, or combinations thereof. At least one plasticizer is introduced into the reaction mixture at any time during prepolymer formation or before the prepolymer is dispersed in water. The plasitcizer substantially or completely replaces other organic diluents or solvents. Various types of plasticizers may be employed, including reactive plasticizers.
摘要翻译：水性聚氨酯分散体是通过使（1）至少一种多异氰酸酯与（2）至少一种含活性氢的化合物，例如多元醇或聚酰胺; 和（3）优选还有至少一种具有水分散增强基团的水分散性增强化合物，以形成异氰酸酯封端的预聚物。随后将预聚物（1）任选地通过与至少一种中和剂反应中和，（2）分散在水中，然后（3）通过与至少一种水，无机或有机多胺的平均约为 2个或更多个伯和/或仲胺基团，或其组合。在预聚物形成期间或预聚物分散在水中之前的任何时间，至少一种增塑剂被引入反应混合物中。该改性剂基本上或完全替代其它有机稀释剂或溶剂。可以使用各种类型的增塑剂，包括反应性增塑剂。

4. 发明申请

US20100267299A1 Vinyl Chloride, Acrylate, And Urethane Polymers With Increased Moisture Vapor Permeability And Static Dissipative Properties 审中-公开
标题翻译：氯乙烯，丙烯酸酯和聚氨酯聚合物具有增加的水分蒸汽渗透性和静态耗散性
公开(公告)号：US20100267299A1
公开(公告)日：2010-10-21
申请号：US12744126
申请日：2008-11-14
申请人： Gary A. Anderle , Alexander V. Lubnin , George E. Snow , Ronald D. Varn
发明人： Gary A. Anderle , Alexander V. Lubnin , George E. Snow , Ronald D. Varn
IPC分类号： B32B27/12 , C08L75/04 , C08L27/06 , C08L63/00 , C08L33/08
CPC分类号： C08J5/18 , C08G18/10 , C08G18/283 , C08G18/4833 , C08J5/02 , C08J2327/06 , C08L27/06 , C08L33/06 , C08L71/02 , C08L75/04 , C09D175/04 , D06N3/141 , D06N3/144 , Y10T428/249921 , Y10T442/20 , C08L2666/14 , C08L2666/04
摘要： Vinyl chloride polymer compositions, optionally plasticized, containing a hydrophilic polymer (e.g., a hydrophilic polyurethane or hydrophilic vinyl polymer) are described for use as coatings and films with increased moisture vapor transmission and/or static dissipative properties. Films from this material are useful as fluid barriers that allow diffusion of moisture vapors. Similar modifications can be made to acrylate and urethane polymers.
摘要翻译：描述了含有亲水性聚合物（例如，亲水性聚氨酯或亲水性乙烯基聚合物）的任选地增塑的氯乙烯聚合物组合物用作具有增加的水汽传输和/或静电耗散性质的涂层和膜。来自该材料的膜可用作允许水分蒸气扩散的流体屏障。可以对丙烯酸酯和聚氨酯聚合物进行类似的改进。

5. 发明授权

US06897281B2 Breathable polyurethanes, blends, and articles 有权
标题翻译：透气聚氨酯，混合物和制品
公开(公告)号：US06897281B2
公开(公告)日：2005-05-24
申请号：US10174899
申请日：2002-06-19
申请人： Alexander V. Lubnin , George E. Snow , Ronald D. Varn , Gary A. Anderle
发明人： Alexander V. Lubnin , George E. Snow , Ronald D. Varn , Gary A. Anderle
IPC分类号： C08L75/08 , C08G18/08 , C08G18/12 , C08G18/40 , C08G18/48 , C08G18/66 , C08L33/00 , C08L33/18 , C08L101/00 , C09D175/04 , C08J3/00 , C08G18/00 , C08G18/32 , C08K3/20 , C08L75/00
CPC分类号： C08G18/758 , C08G18/0823 , C08G18/0866 , C08G18/12 , C08G18/4018 , C08G18/4808 , C08G18/4854 , C08G18/6677 , C08G18/6692 , C08L33/00 , C08L33/18 , C09D175/04 , Y10T428/31551 , Y10T442/2492 , C08G18/3231 , C08L2666/04
摘要： A breathable polyurethane having an upright moisture vapor transmission rate (MVTR) of more than about 500 gms/m2/24 hr comprises: (a) poly(alkylene oxide) side-chain units in an amount comprising about 12 wt. % to about 80 wt. % of said polyurethane, wherein (i) alkylene oxide groups in said poly(alkylene oxide) side-chain units have from 2 to 10 carbon atoms and are unsubstituted, substituted, or both unsubstituted and substituted, (ii) at least about 50 wt. % of said alkylene oxide groups are ethylene oxide, and (iii) said amount of said side-chain units is (i) at least about 30 wt. % when the molecular weight of said side-chain units is less than about 600 grams/mole, (ii) at least about 15 wt. % when the molecular weight of said side-chain units is from about 600 to about 1,000 grams/mole, and at least about 12 wt. % when the molecular weight of said side-chain units is more than about 1,000 grams/mole, and (b) poly(ethylene oxide) main-chain units in an amount comprising less than about 25 wt. % of said polyurethane. Coatings and films for textiles and other articles and applications using such polyurethanes have excellent breathability, i.e., high moisture vapor transmission rates (MVTR).
摘要翻译：具有超过约500gms / m 2 / 24hr的直立水蒸汽透过率（MVTR）的透气聚氨酯包括：（a）包含以下量的聚（环氧烷）侧链单元：约12重量％％至约80wt。％的所述聚氨酯，其中（i）所述聚（环氧烷）侧链单元中的氧化烯基团具有2至10个碳原子，并且是未取代的，取代的或未取代的和取代的，（ii）至少约50重量％。所述环氧烷基团的％为环氧乙烷，（iii）所述侧链单元的量为（i）至少约30wt。当所述侧链单元的分子量小于约600克/摩尔时，（ii）至少约15重量％当所述侧链单元的分子量为约600至约1,000克/摩尔时，和至少约12重量％当所述侧链单元的分子量大于约1,000克/摩尔时，和（b）包含小于约25重量％的量的聚（环氧乙烷）主链单元。％的所述聚氨酯。使用这种聚氨酯的用于纺织品和其它制品和应用的涂料和薄膜具有优异的透气性，即高水蒸气透过率（MVTR）。

6. 发明授权

US09527328B2 Aqueous cationic polyurethane dispersions 有权
标题翻译：水性阳离子聚氨酯分散体
公开(公告)号：US09527328B2
公开(公告)日：2016-12-27
申请号：US13881919
申请日：2011-10-28
申请人： Alexander V. Lubnin , Dennis Malaba
发明人： Alexander V. Lubnin , Dennis Malaba
IPC分类号： B41M5/00 , B41M5/52 , C08F283/00 , C08G18/08 , C08G18/12 , C08G18/28 , C08G18/32 , C08G18/36 , C08G18/40 , C08G18/42 , C08G18/48 , C08G18/66 , C08G18/72 , C08G18/75 , C09D175/04 , C09D175/08 , C08L75/00 , C08J3/00 , C08K3/20
CPC分类号： B41M5/52 , B41M5/508 , B41M5/5245 , B41M5/5281 , C08F283/006 , C08G18/0814 , C08G18/12 , C08G18/2875 , C08G18/3275 , C08G18/36 , C08G18/4018 , C08G18/4238 , C08G18/4808 , C08G18/4825 , C08G18/4833 , C08G18/4854 , C08G18/6688 , C08G18/6696 , C08G18/722 , C08G18/755 , C08G18/758 , C08G2270/00 , C08J3/00 , C08K3/20 , C08L75/00 , C09D175/04 , C09D175/08 , D21H11/00 , D21H13/00 , C08G18/302
摘要： An aqueous cationic polyurethane dispersion for waterborne digital print and other applications comprising an aqueous dispersion of polyurethane having properly positioned tertiary amino groups, e.g., tethered tertiary amino group separated from backbone by at least two intervening atoms or terminal tertiary amino groups with multiple tertiary amino groups per terminus, where said amino groups are optionally partially quaternized and/or neutralized.
摘要翻译：一种用于水性数字印刷和其它应用的水性阳离子聚氨酯分散体，其包含具有适当定位的叔氨基的聚氨酯的水性分散体，例如通过至少两个插入原子或具有多个叔氨基的末端叔氨基与主链分离的连接的叔氨基其中所述氨基任选地被部分季铵化和/或中和。

7. 发明授权

US07598315B2 Aqueous dispersions of nanoparticle/polyurethane composites 有权
标题翻译：纳米颗粒/聚氨酯复合材料的水分散体
公开(公告)号：US07598315B2
公开(公告)日：2009-10-06
申请号：US11813686
申请日：2006-01-24
申请人： Alexander V. Lubnin
发明人： Alexander V. Lubnin
IPC分类号： C08L75/04 , C08K3/22 , C08G18/08 , C08G18/12 , C08G18/66
CPC分类号： C08G18/6692 , C08G18/0823 , C08G18/12 , C08G18/4854 , C08G18/6659 , C09D175/06 , Y10S977/773 , C08G18/3231
摘要： An aqueous dispersion of nanoparticle/polyurethane composites is made by forming a mixture of nanoparticles and a continuous mass of a polyurethane prepolymer in the substantial absence of water and dispersing the mixture so made in aqueous medium. Alternatively, a polyurethane prepolymer or a mixture of nanoparticles and a continuous mass of a polyurethane prepolymer is dispersed into an aqueous dispersion of nanoparticles.
摘要翻译：纳米颗粒/聚氨酯复合材料的水分散体通过在基本上不存在水的情况下通过形成纳米颗粒和连续质量的聚氨酯预聚物的混合物来制备，并将如此制备的混合物在水性介质中分散。或者，将聚氨酯预聚物或纳米颗粒和连续质量的聚氨酯预聚物的混合物分散到纳米颗粒的水性分散体中。

8. 发明申请

US20080153975A1 Nanoparticle/Vinyl Polymer Composites 失效
标题翻译：纳米颗粒/乙烯基聚合物复合材料
公开(公告)号：US20080153975A1
公开(公告)日：2008-06-26
申请号：US11816217
申请日：2006-03-16
申请人： Alexander V. Lubnin
发明人： Alexander V. Lubnin
IPC分类号： C08L23/06
CPC分类号： C08J3/212 , C08F2/18 , C08F2/44 , C08J3/205 , C08J3/2053
摘要： Vinyl polymers formed by bulk or solution polymerization techniques are combined with nanoparticles to produce aqueous dispersions of nanoparticle/vinyl polymer composites.
摘要翻译：通过本体或溶液聚合技术形成的乙烯基聚合物与纳米颗粒组合以产生纳米颗粒/乙烯基聚合物复合材料的水分散体。

9. 发明授权

US06316107B1 Multiple phase polymeric vinyl chloride systems and related core-shell particles 失效
标题翻译：多相聚合氯乙烯体系和相关的核 - 壳颗粒
公开(公告)号：US06316107B1
公开(公告)日：2001-11-13
申请号：US09287918
申请日：1999-04-07
申请人： Alexander V. Lubnin , Vic Stanislawczyk
发明人： Alexander V. Lubnin , Vic Stanislawczyk
IPC分类号： B32B516
CPC分类号： C08F259/04 , Y10T428/2998
摘要： An emulsion or suspension polymer comprising a vinyl chloride polymeric core and an acrylic ester-acrylonitrile polymeric shell is disclosed. The emulsion polymer is preferably prepared using a two-stage process. In the first stage, a vinyl chloride monomer is polymerized or copolymerized to form a first phase of a polymeric hard core having a relatively high chlorine content. In a second stage, the soft acrylic ester—acrylonitrile copolymer is made in situ in a reaction mixture comprising the first phase. The product provides both flame retardancy and low MFFT, and is useful in a variety of coating and binding applications.
摘要翻译：公开了一种包含氯乙烯聚合物芯和丙烯酸酯 - 丙烯腈聚合物壳的乳液或悬浮聚合物。乳液聚合物优选使用两阶段方法制备。在第一阶段中，将氯乙烯单体聚合或共聚以形成具有较高氯含量的聚合物硬核的第一相。在第二阶段中，软质丙烯酸酯 - 丙烯腈共聚物在包含第一相的反应混合物中原位制备。该产品提供阻燃性和低MFFT，并且可用于各种涂层和结合应用。

10. 发明授权

US5340881A Aldehyde-telechelic polyisobutylenes, catalytic method for preparing the same with high conversion and selectivity, and block copolymers made thereform 失效
标题翻译：醛 - 遥爪聚异丁烯，具有高转化率和选择性的催化方法，以及由其制备的嵌段共聚物
公开(公告)号：US5340881A
公开(公告)日：1994-08-23
申请号：US976532
申请日：1992-11-16
申请人： Joseph P. Kennedy , Brian L. Goodall , Alexander V. Lubnin
发明人： Joseph P. Kennedy , Brian L. Goodall , Alexander V. Lubnin
IPC分类号： C08F8/28 , C08F8/00
CPC分类号： C08F8/00 , C08F110/10 , C08F8/26 , C08F2810/30 , C08F2810/40
摘要： Aldehyde-telechelic polyisobutylenes free of other end groups such as alcohols, olefins, etc., are made by the hydroformylation of polyisobutylene having one or more olefinic end groups in the presence of a rhodium catalyst in combination with an organic phosphorus ligand. Very high conversions of olefin to aldehyde are obtained. Depending upon the number of aldehyde end groups per macromolecule, the telechelic polyisobutylene polymers can be utilized as precursors to form various types of block copolymers, e.g., AB, ABA, or radial block copolymers, with other polymers such as polyurethanes, polyesters, polyamines, and the like.
摘要翻译：通过在铑催化剂与有机磷配体的组合的存在下，具有一个或多个烯属端基的聚异丁烯的加氢甲酰基化来制备不含其它端基的醇 - 遥爪聚异丁烯，例如醇，烯烃等。获得非常高的烯烃与醛的转化率。根据每个大分子的醛端基的数目，遥爪聚异丁烯聚合物可以用作前体以形成各种类型的嵌段共聚物，例如AB，ABA或径向嵌段共聚物，与其它聚合物如聚氨酯，聚酯，聚胺，等等。

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