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1. 发明授权

US4127728A Preparation of 1-phenyl-2,2,2-trihalogeno-ethanol esters 失效
标题翻译： 1-苯基-2,2,2-三卤代乙醇酯的制备
公开(公告)号：US4127728A
公开(公告)日：1978-11-28
申请号：US717302
申请日：1976-08-24
申请人： Thomas Schmidt , Wolfgang Kramer , Eckart Kranz
发明人： Thomas Schmidt , Wolfgang Kramer , Eckart Kranz
IPC分类号： C07C69/007 , C07C29/68 , C07C33/46 , C07C67/00 , C07C67/08 , C07C67/14 , C07C68/00 , C07C201/00 , C07C205/42 , C07C253/00 , C07C255/55 , C07C313/00 , C07C319/20 , C07C323/19 , C07C381/14 , C07D317/46 , C07D317/54
CPC分类号： C07C67/08 , C07C29/68 , C07C33/46 , C07C381/14 , C07C67/14
摘要： A process for the preparation of a substituted 1-phenyl-2,2,2-trihalo-ethanol ester of the formula ##STR1## in which R is alkyl, halogenoalkyl, alkoxy, cycloalkyl or optionally substituted phenyl, benzyl, phenoxy, or phenylsulfonyl,X is halogenoalkyl with 1-3 carbon atoms and 1-3 halogen atoms,Y is halogen, cyano, nitro, alkyl, alkoxy, alkylmercapto, sulfoalkoxy or optionally substituted methylenedioxy, andn is an integer from 0 to 3,Comprising reacting a compound of the formula ##STR2## WITH A HALOGENATED ALDEHYDE OF THE FORMULAX CHO in the presence of a Friedel-Crafts catalyst at a temperature of about -70 to +100.degree. C thereby to form a complex alcoholate, and reacting the complex alcoholate with an acid halide of the formula ##STR3## OR WITH A CORRESPONDING ACID ANHYDRIDE AT A TEMPERATURE OF ABOUT -70 TO +100.degree. C. The reaction with the acid halide or anhydride is preferably carried out in the presence of a solvent or diluent, sodium sulfate hydrate is added to the final reaction solution and the resulting mixture of sodium sulfate and basic aluminum halide is filtered off. The products are known insecticides.
摘要翻译：制备式“IMAGE”的取代的1-苯基-2,2,2-三卤代 - 乙醇酯的方法，其中R是烷基，卤代烷基，烷氧基，环烷基或任选取代的苯基，苄基，苯氧基或苯基磺酰基 X是具有1-3个碳原子和1-3个卤素原子的卤代烷基，Y是卤素，氰基，硝基，烷基，烷氧基，烷基巯基，磺基烷氧基或任选取代的亚甲二氧基，N是0至3的整数，包含反应A 在Fried-Crafts催化剂存在下，在约-70至+ 100℃的温度下，使用式（ⅩⅩⅩⅤ）化合物与式（ⅩⅤ）化合物反应，从而形成复合醇化物，并使复合醇化物与在-70至+ 100℃的温度下，与酰基卤或酸酐的反应优选在溶剂或稀释剂钠的存在下进行。将硫酸盐水合物加入到最终的反应物中并将所得的硫酸钠和碱式卤化铝的混合物滤出。产品是已知的杀虫剂。

2. 发明授权

US4921967A Novel alkylcycloalkyl triazolylmethyl ketones as fungicide intermediates 失效
标题翻译：新型烷基环烷基三唑甲基酮作为杀真菌剂中间体
公开(公告)号：US4921967A
公开(公告)日：1990-05-01
申请号：US54551
申请日：1987-05-27
申请人： Wolfgang Kramer , Manfred Jautelat , Eckart Kranz
发明人： Wolfgang Kramer , Manfred Jautelat , Eckart Kranz
IPC分类号： A01N43/653 , C07C17/26 , C07C43/225 , C07C45/51 , C07C49/327 , C07D249/08 , C07D521/00
CPC分类号： C07D249/08 , A01N43/653 , C07C17/269 , C07C43/225 , C07C45/513 , C07C49/327 , C07D231/12 , C07D233/56 , C07C2101/08
摘要： New alkylcycloalkyl triazolylmethyl ketones of the general formula ##STR1## in which R represents an alkyl group andn is 3, 4, 5, 6 and 7,are produced as described and find use as intermediate products for the preparation of cycloalkyl (.alpha.-triazolyl-.beta.-hydroxy)-ketones, which possess fungicidal and plant growth-regulating properties.
摘要翻译：其中R表示烷基且n为3,4,5,6和7的通式为“IMAGE”（I）的新的烷基环烷基三唑基甲基酮如所述制备，可用作制备环烷基的中间产物（ α-三唑基-β-羟基） - 酮，其具有杀真菌和植物生长调节性质。

3. 发明授权

US4316932A Combating fungi with .alpha.-azolyl-keto derivatives 失效
标题翻译：抗真菌与α-唑基 - 酮衍生物
公开(公告)号：US4316932A
公开(公告)日：1982-02-23
申请号：US54067
申请日：1979-07-02
申请人： Eckart Kranz , Wolfgang Kramer , Karl H. Buchel , Wilhelm Brandes , Paul-Ernst Frohberger
发明人： Eckart Kranz , Wolfgang Kramer , Karl H. Buchel , Wilhelm Brandes , Paul-Ernst Frohberger
IPC分类号： A01N43/50 , A01N43/653 , C07D233/60 , C07D249/08 , C07D521/00 , A01N43/82
CPC分类号： C07D231/12 , A01N43/50 , A01N43/653 , C07D233/56 , C07D249/08
摘要： An .alpha.-azolyl-keto derivative of the formula ##STR1## in which R.sup.1 represents optionally substituted alkyl or optionally substituted phenyl,R.sup.2 represents the grouping --CX.sup.1 X.sup.2 R.sup.3 or alkoxy-carbonyl,R.sup.3 represents halogen, halogenoalkyl or optionally substituted phenyl,R.sup.4 represents the grouping --O--CO--R.sup.5, --O(S)--R.sup.6 or --O--S(O).sub.n --R.sup.7, or alkylamino, dialkylamino, optionally substituted phenylamino or halogen,R.sup.5 represents alkyl, halogenoalkyl, alkenyl, alkynyl, cycloalkyl, optionally substituted phenyl, optionally substituted phenylalkyl, alkylamino, dialkylamino or optionally substituted phenylamino,R.sup.6 represents alkyl, alkenyl, alkynyl, cycloalkyl, optionally substituted phenyl or optionally substituted benzyl,R.sup.7 represents alkyl, halogenoalkyl, optionally substituted phenyl or dialkylamino,n represents 1 or 2,X.sup.1 and X.sup.2 each independently represents hydrogen or halogen, andY represents a nitrogen atom or the CH group, or a physiologically acceptable acid addition salt or metal salt complex thereof, which possesses fungicidal properties.
摘要翻译：其中R 1表示任意取代的烷基或任意取代的苯基，R 2代表基团-CX 1 X 2 R 3或烷氧基 - 羰基，R 3表示卤素，卤代烷基或任意取代的苯基，R 4代表基团 -O-CO-R 5，-O（S）-R 6或-OS（O）n -R 7或烷基氨基，二烷基氨基，任选取代的苯基氨基或卤素，R 5表示烷基，卤代烷基，烯基，炔基，环烷基，任选取代的苯基，任选取代的苯基烷基，烷基氨基，二烷基氨基或任选取代的苯基氨基，R 6表示烷基，烯基，炔基，环烷基，任选取代的苯基或任选取代的苄基，R 7表示烷基，卤代烷基，任选取代的苯基或二烷基氨基，n表示1或2，和X2各自独立地表示氢或卤素，Y表示氮原子或CH基团，或生理上可接受的酸加成盐或金属盐c 其复合物具有杀真菌性能。

4. 发明授权

US5010208A Novel alkylcycloalkyl triazolylmethyl ketones as fungicide intermediates 失效
标题翻译：新型烷基环烷基三唑甲基酮作为杀真菌剂中间体
公开(公告)号：US5010208A
公开(公告)日：1991-04-23
申请号：US482106
申请日：1990-02-16
申请人： Wolfgang Kramer , Manfred Jautelat , Eckart Kranz
发明人： Wolfgang Kramer , Manfred Jautelat , Eckart Kranz
IPC分类号： A01N43/653 , C07C17/26 , C07C43/225 , C07C45/51 , C07C49/327 , C07D249/08 , C07D521/00
CPC分类号： C07D249/08 , A01N43/653 , C07C17/269 , C07C43/225 , C07C45/513 , C07C49/327 , C07D231/12 , C07D233/56 , C07C2101/08
摘要： New alkylcycloalkyl triazolylmethyl ketones of the general formula ##STR1## in which R represents an alkyl group andn is 3, 4, 5, 6 and 7,are produced as described and find use as intermediate products for the preparation of cycloalkyl (.alpha.-triazolyl-.beta.-hydroxy)-ketones, which possess fungicidal and plant growth-regulating properties.

5. 发明授权

US4492795A Alkylcycloalkyl imidazolylmethyl ketones as fungicide intermediates 失效
标题翻译：烷基环烷基咪唑甲基酮作为杀真菌剂中间体
公开(公告)号：US4492795A
公开(公告)日：1985-01-08
申请号：US438087
申请日：1982-11-01
申请人： Wolfgang Kramer , Manfred Jautelat , Eckart Kranz
发明人： Wolfgang Kramer , Manfred Jautelat , Eckart Kranz
IPC分类号： A01N43/50 , C07C17/26 , C07C43/225 , C07C45/51 , C07C49/327 , C07D233/60 , C07D521/00
CPC分类号： C07D249/08 , C07C17/269 , C07C43/225 , C07C45/513 , C07C49/327 , C07D231/12 , C07D233/56
摘要： New alkylcycloalkyl imidazolylmethyl ketones of the general formula ##STR1## in which R represents an alkyl group andn is 3, 4, 5, 6 or 7,are produced as described and find use as intermediate products for the preparation of imidazolyl-vinyl-dithioacetals, which possess fungicidal properties.
摘要翻译：其中R表示烷基且n为3,4,5,6或7的通式为“IMAGE”的新的烷基环烷基咪唑基甲基酮如所述制备，可用作制备咪唑基 - 乙烯基 - 二硫代缩醛的中间产物，具有杀菌性。

6. 发明授权

US4229580A Preparation of 1-azolyl-3,3-dimethyl-1-phenoxy-butan-2-ones 失效
标题翻译： 1-噻唑基-3,3-二甲基-1-苯氧基 - 丁-2-酮的制备
公开(公告)号：US4229580A
公开(公告)日：1980-10-21
申请号：US885053
申请日：1978-03-09
申请人： Hermann Arold , Hans-Ludwig Elbe , Eckart Kranz , Wolfgang Kramer , Jorg Stetter , Claus Stolzer , Rudolf Thomas
发明人： Hermann Arold , Hans-Ludwig Elbe , Eckart Kranz , Wolfgang Kramer , Jorg Stetter , Claus Stolzer , Rudolf Thomas
IPC分类号： A01N43/50 , A01N43/836 , C07D233/60 , C07D249/08 , C07D521/00
CPC分类号： C07D231/12 , C07D233/56 , C07D249/08
摘要： In the reaction of 1-chloro-3,3-dimethylbutan-2-one with a phenol to form an ether-ketone, halogenating it to form a halogenoether-ketone and reacting it with imidazole or 1,2,4-triazole to form a 1-azolyl-3,3-dimethyl-1-phenoxybutan-2-one of the formula ##STR1## in which X is N or CH,n is an integer from 0 to 4, andY each independently is halogen, phenyl, phenoxy, nitro, alkyl, alkoxy or cycloalkyl,the improvement which comprises effecting all steps successively in an aromatic hydrocarbon or chlorinated aliphatic or aromatic hydrocarbon as solvent without intermediate isolation. The products are obtained in high yield.
摘要翻译：在1-氯-3,3-二甲基丁-2-酮与苯酚反应形成醚 - 酮的反应中，将其卤化形成卤代醚 - 酮并与咪唑或1,2,4-三唑反应形成其中X为N或CH，n为0至4的整数，并且Y各自独立地为卤素，苯基，环烷基，环烷基，苯氧基，硝基，烷基，烷氧基或环烷基，其改进包括在芳族烃或氯化脂族或芳族烃作为溶剂中连续进行所有步骤而不中间分离。以高产率获得产品。

7. 发明授权

US4386088A Combating fungi with .alpha.-azolyl-keto derivatives 失效
标题翻译：抗真菌与α-唑基 - 酮衍生物
公开(公告)号：US4386088A
公开(公告)日：1983-05-31
申请号：US304128
申请日：1981-09-21
申请人： Eckart Kranz , Wolfgang Kramer , Karl H. Buchel , Wilhelm Brandes , Paul-Ernst Frohberger
发明人： Eckart Kranz , Wolfgang Kramer , Karl H. Buchel , Wilhelm Brandes , Paul-Ernst Frohberger
IPC分类号： A01N43/50 , A01N43/653 , C07D233/60 , C07D249/08 , C07D521/00 , A01N43/82
CPC分类号： C07D231/12 , A01N43/50 , A01N43/653 , C07D233/56 , C07D249/08
摘要： An .alpha.-azolyl-keto derivative of the formula ##STR1## in which R.sup.1 represents optionally substituted alkyl or optionally substituted phenyl,R.sup.2 represents the grouping --CX.sup.1 X.sup.2 R.sup.3 or alkoxycarbonyl,R.sup.3 represents halogen, halogenoalkyl or optionally substituted phenyl,R.sup.4 represents the grouping --O--CO--R.sup.5, --O(S)--R.sup.6 or --O--S(O).sub.n --R.sup.7, or alkylamino, dialkylamino, optionally substituted phenylamino or halogen,R.sup.5 represents alkyl, halogenoalkyl, alkenyl, alkynyl, cycloalkyl, optionally substituted phenyl, optionally substituted phenylalkyl, alkylamino, dialkylamino or optionally substituted phenylamino,R.sup.6 represents alkyl, alkenyl, alkynyl, cycloalkyl, optionally substituted phenyl or optionally substituted benzyl,R.sup.7 represents alkyl, halogenoalkyl, optionally substituted phenyl or dialkylamino,n represents 1 or 2,X.sup.1 and X.sup.2 each independently represents hydrogen or halogen, andY represents a nitrogen atom or the CH group, or a physiologically acceptable acid addition salt or metal salt complex thereof, which possesses fungicidal properties.
摘要翻译：其中R 1表示任选取代的烷基或任选取代的苯基，R 2表示分组-C X 1 X 2 R 3或烷氧基羰基，R 3表示卤素，卤代烷基或任选取代的苯基，R 4表示基团-O -CO-R 5，-O（S）-R 6或-OS（O）n -R 7或烷基氨基，二烷基氨基，任选取代的苯基氨基或卤素，R 5表示烷基，卤代烷基，烯基，炔基，环烷基，任选取代的苯基，取代的苯基烷基，烷基氨基，二烷基氨基或任选取代的苯基氨基，R 6表示烷基，烯基，炔基，环烷基，任选取代的苯基或任选取代的苄基，R 7表示烷基，卤代烷基，任选取代的苯基或二烷基氨基，n表示1或2，各自独立地表示氢或卤素，Y表示氮原子或CH基团，或生理上可接受的酸加成盐或金属盐共其复合物具有杀真菌性能。

8. 发明授权

US4291047A Combating fungi with .alpha.-azolyl-.beta.-hydroxy-ketones 失效
标题翻译：抗真菌与α-唑基-β-羟基酮
公开(公告)号：US4291047A
公开(公告)日：1981-09-22
申请号：US54061
申请日：1979-07-02
申请人： Eckart Kranz , Wolfgang Kramer , Karl H. Buchel , Wilhelm Brandes , Paul-Ernst Frohberger
发明人： Eckart Kranz , Wolfgang Kramer , Karl H. Buchel , Wilhelm Brandes , Paul-Ernst Frohberger
IPC分类号： A01N43/50 , A01N43/653 , C07D233/60 , C07D249/08 , C07D521/00 , A01N43/64
CPC分类号： C07D231/12 , A01N43/50 , A01N43/653 , C07D233/56 , C07D249/08
摘要： .alpha.-Azolyl-.beta.-hydroxy-ketones of the formula ##STR1## in which R.sup.1 represents optionally substituted alkyl or optionally substituted phenyl,R.sup.2 represents the grouping --CX.sup.1 X.sup.2 R.sup.3 or alkoxycarbonyl,R.sup.3 represents halogen, halogenoalkyl or optionally substituted phenyl,X.sup.1 and X.sup.2, which may be identical or different, each represents hydrogen or halogen, andY represents a nitrogen atom or the CH group, or physiologically acceptable acid-addition salts or metal-salt complexes thereof which possess fungicidal properties.
摘要翻译：其中R 1表示任选取代的烷基或任选取代的苯基，R 2表示基团-CX 1 X 2 R 3或烷氧基羰基，R 3表示卤素，卤代烷基或任选取代的苯基，X 1和X 2，其可以相同或不同，各自表示氢或卤素，Y表示具有杀真菌性质的氮原子或CH基团或其生理上可接受的酸加成盐或其金属盐络合物。

9. 发明授权

US4386953A Herbicidally active substituted 6-halogeno-tert.-butyl-1,2,4-triazin-5-ones 失效
标题翻译：除草活性的取代的6-卤代叔丁基-1,2,4-三嗪-5-酮
公开(公告)号：US4386953A
公开(公告)日：1983-06-07
申请号：US299919
申请日：1981-09-08
申请人： Eckart Kranz , Kurt Findeisen , Robert Schmidt , Ludwig Eue
发明人： Eckart Kranz , Kurt Findeisen , Robert Schmidt , Ludwig Eue
IPC分类号： C07D253/06 , A01N43/707 , C07D253/075 , A01N43/64
CPC分类号： C07D253/075 , A01N43/707
摘要： A substituted 6-halogeno-tert.-butyl-1,2,4-triazin-5-one of the formula ##STR1## in which R.sup.1 is an amino or methyl group,R.sup.2 is an alkylmercapto, alkylamino or dialkylamino group,X is a halogen atom, andY and Z each independently is a hydrogen or halogen atom,which possesses selective herbicidal activity. A synthesis involving the novel intermediates ##STR2## in which X, Y and Z have the above-mentioned meaning andQ is CN, CONH.sub.2 or COOH,is also shown.
摘要翻译： R 1为氨基或甲基的取代的6-卤代叔丁基-1,2,4-三嗪-5-酮，其中R 1为烷基巯基，烷基氨基或二烷基氨基，X为卤素原子，Y和Z各自独立地为具有选择性除草活性的氢或卤素原子。涉及其中X，Y和Z具有上述含义且Q为CN，CONH 2或COOH的新中间体“IMAGE”的合成也显示。

10. 发明授权

US4162280A Preparation of phosphorylated amidines 失效
标题翻译：磷酸化脒的制备
公开(公告)号：US4162280A
公开(公告)日：1979-07-24
申请号：US887899
申请日：1978-03-17
申请人： Eckart Kranz
发明人： Eckart Kranz
IPC分类号： A01N57/26 , B01J27/00 , B01J31/00 , C07F9/24 , C07F9/44
CPC分类号： A01N57/26 , C07F9/2458
摘要： Preparation of a phosphorylated amidine of the formula ##STR1## wherein X is oxygen or sulfur and R, R.sup.1, R.sup.2, R.sup.3 and R.sup.4 are various organic radicals, which comprises reacting a phosphoric acid ester-amide of the formula ##STR2## with a carboxamide of the formula ##STR3## at a temperature between about 0.degree. and 50.degree. C., and then reacting the mixture with a base. Advantageously the reaction is effected at about 0.degree. to 15.degree. C. in the presence of an aliphatic or aromatic optionally chlorinated hydrocarbon or an alcohol as an inert solvent, and in the presence of a catalyst.
摘要翻译：制备式IMAMA的磷酸化脒，其中X是氧或硫，R，R 1，R 2，R 3和R 4是各种有机基团，其包括使下式的磷酸酯 - 酰胺与羧酰胺在约0℃至50℃之间的温度下，使式“IMAGE”进行反应，然后使该混合物与碱反应。有利地，反应在约0℃至15℃下在脂族或芳族任选氯化烃或作为惰性溶剂的醇存在下进行，并在催化剂存在下进行。

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