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1. 发明授权

US6109018A Electrically-heated combustion catalyst structure and method for start-up of a gas turbine using same 失效
标题翻译：电加热燃烧催化剂结构及使用其的燃气轮机起动方法
公开(公告)号：US6109018A
公开(公告)日：2000-08-29
申请号：US688075
申请日：1996-07-26
申请人： Thomas Rostrup-Nielsen , Ralph A. Dalla Betta , Toru Shoji , Scott A. Magno , David K. Yee
发明人： Thomas Rostrup-Nielsen , Ralph A. Dalla Betta , Toru Shoji , Scott A. Magno , David K. Yee
IPC分类号： F01N3/20 , F01N3/28 , F23C13/00 , F23R3/40 , F02C7/26
CPC分类号： F23R3/40 , F01N3/2013 , F01N3/2026 , F01N3/281 , F02C7/26 , F23C13/00 , F23C13/02 , F01N2330/323 , F01N2610/03 , F05D2220/76 , F05D2260/85 , F23D2206/10 , Y02T10/26
摘要： This invention relates to an electrically-heated catalyst (EHC) and a start-up method of a gas turbine engine for combusting a hydrocarbonaceous fuel/oxygen-containing gas mixture using this electrically-heated catalyst. The catalytic structure is electrically heated to a predetermined temperature prior to start up of the turbine so as to reduce emissions during the start-up of the system. The EHC unit is a stacked or spirally wound layering of flat and corrugated thin metal foils which forms a plurality of axially-extending, longitudinal channels. The channels are preferably coated on one surface with a catalytic material, leaving the other surface free from the reaction to act as a heat sink, making the design an IHE (integral heat exchange) catalytic unit. The preferred embodiment of the EHC has electrodes outside of the fuel/oxygen-containing mixture stream, and uses electrical power having a predetermined voltage in the range of 100 to 200 volts to heat the unit. A method for using the EHC in the start-up of a gas turbine is also disclosed wherein an electrical power is applied to heat the EHC a predetermined temperature prior to the fuel/oxygen-containing mixture being introduced and may be left on for a certain period of time after the introduction of the fuel/oxygen-containing mixture. The EHC may be maintained at the desired predetermined temperature by modulating the applied voltage. The electrical power is terminated when any one of several conditions are met including when the heat of the catalytic reaction is sufficient to maintain the catalyst at its steady-state condition or when a certain period of time has elapsed.
摘要翻译：本发明涉及使用该电加热催化剂燃烧含烃燃料/含氧气体混合物的燃气涡轮发动机的电加热催化剂（EHC）和起动方法。催化结构在涡轮启动之前被电加热至预定温度，以便在系统启动期间减少排放。 EHC单元是形成多个沿轴向延伸的纵向通道的平坦且波浪形的薄金属箔的层叠或螺旋卷绕的层。通道优选在一个表面上用催化材料涂布，使另一个表面没有反应作为散热器，使得设计成为IHE（整体式热交换）催化单元。 EHC的优选实施例具有位于燃料/含氧混合物流之外的电极，并且使用具有在100至200伏特范围内的预定电压的电力来加热该单元。还公开了在燃气轮机起动中使用EHC的方法，其中在引入燃料/含氧混合物之前施加电功率以将EHC加热到预定温度，并且可以保持一定的在引入燃料/含氧混合物之后的时间段。可以通过调制所施加的电压将EHC保持在所需的预定温度。当满足几个条件中的任何一个时，电力终止，包括当催化反应的热量足以使催化剂保持在其稳定状态或当经过一定时间段时。

2. 发明授权

US5518697A Process and catalyst structure employing intergal heat exchange with optional downstream flameholder 失效
标题翻译：使用与可选择的下游阻燃器进行间隔热交换的工艺和催化剂结构
公开(公告)号：US5518697A
公开(公告)日：1996-05-21
申请号：US378206
申请日：1995-01-25
申请人： Ralph A. Dalla Betta , David K. Yee , Scott A. Magno , Toru Shoji
发明人： Ralph A. Dalla Betta , David K. Yee , Scott A. Magno , Toru Shoji
IPC分类号： F01N3/10 , B01J23/40 , B01J35/04 , F01N3/28 , F23C6/04 , F23C9/00 , F23C13/00 , F23D11/40 , F23D14/18 , F23R3/40 , F23D3/40
CPC分类号： F23C13/00 , F01N3/28 , F01N3/281 , F01N3/2814 , F01N3/2821 , F01N3/2882 , F23C6/045 , F23C9/006 , F23R3/40 , F01N2240/02 , F01N2330/321 , F01N2330/323 , F01N2330/42 , F23C2900/13002 , F23R2900/00002
摘要： This invention is an improved catalyst structure and its use in highly exothermic processes like catalytic combustion. This improved catalyst structure employs integral heat exchange in an array of longitudinally disposed adjacent reaction passage-ways or channels, which are either catalyst-coated or catalyst-free, wherein the configuration of the catalyst-coated channels differs from the non-catalyst channels such that, when applied in exothermic reaction processes, such as catalytic combustion, the desired reaction is promoted in the catalytic channels and substantially limited in the non-catalyst channels. The invention further comprises an improved reaction system and process for combustion of a fuel wherein catalytic combustion using a catalyst structure employing integral heat exchange, preferably the improved structures of the invention, affords a partially-combusted, gaseous product which is passed to a homogeneous combustion zone where complete combustion is promoted by means of a flameholder.
摘要翻译：本发明是改进的催化剂结构及其在高度放热过程如催化燃烧中的应用。这种改进的催化剂结构在纵向设置的相邻反应通道或通道的阵列中采用整体热交换，其是催化剂涂覆的或不含催化剂的，其中催化剂涂覆的通道的构型与非催化剂通道的构型不同，当用于放热反应过程如催化燃烧时，在催化通道中促进所需的反应，并且在非催化剂通道中基本上受限制。本发明还包括改进的燃料燃烧反应系统和方法，其中使用采用整体热交换的催化剂结构，优选本发明的改进结构的催化燃烧提供了部分燃烧的气态产物，其被传递到均匀燃烧通过火焰稳定器促进完全燃烧的区域。

3. 发明授权

US5512250A Catalyst structure employing integral heat exchange 失效
标题翻译：催化剂结构采用整体热交换
公开(公告)号：US5512250A
公开(公告)日：1996-04-30
申请号：US205279
申请日：1994-03-02
申请人： Ralph A. D. Betta , Toru Shoji , David K. Yee , Scott A. Magno
发明人： Ralph A. D. Betta , Toru Shoji , David K. Yee , Scott A. Magno
IPC分类号： F01N3/10 , B01J23/40 , B01J35/04 , F01N3/28 , F23C6/04 , F23C9/00 , F23C13/00 , F23D11/40 , F23D14/18 , F23R3/40 , F23D3/40
CPC分类号： F23C13/00 , F01N3/28 , F01N3/281 , F01N3/2814 , F01N3/2821 , F01N3/2882 , F23C6/045 , F23C9/006 , F23R3/40 , F01N2240/02 , F01N2330/321 , F01N2330/323 , F01N2330/42 , F23C2900/13002 , F23R2900/00002
摘要： This invention is an improved catalyst structure and its use in highly exothermic processes like catalytic combustion. This improved catalyst structure employs integral heat exchange in an array of longitudinally disposed, adjacent reaction passage-ways or channels, which are either catalyst-coated or catalyst-free, wherein the configuration of the catalyst-coated channels differs from the non-catalyst channels such that, when applied in exothermic reaction processes, such as catalytic combustion, the desired reaction is promoted in the catalytic channels and substantially limited in the non-catalyst channels.
摘要翻译：本发明是改进的催化剂结构及其在高度放热过程如催化燃烧中的应用。这种改进的催化剂结构在纵向设置的相邻的反应通道或通道的阵列中采用整体热交换，其是催化剂涂覆的或不含催化剂的，其中催化剂涂覆的通道的构型不同于非催化剂通道使得当用于放热反应过程如催化燃烧时，在催化通道中促进所需的反应，并且在非催化剂通道中基本上受限制。

4. 发明授权

US07121097B2 Control strategy for flexible catalytic combustion system 有权
标题翻译：柔性催化燃烧系统的控制策略
公开(公告)号：US07121097B2
公开(公告)日：2006-10-17
申请号：US09942976
申请日：2001-08-29
申请人： David K. Yee , Marco A. Velasco , Sarento G. Nickolas , Ralph A. Dalla Betta
发明人： David K. Yee , Marco A. Velasco , Sarento G. Nickolas , Ralph A. Dalla Betta
IPC分类号： F02C7/22 , F02C7/26
CPC分类号： F23C13/00 , F23C2900/13002 , F23D2208/10 , F23L15/04 , F23R3/40 , Y02E20/348
摘要： A control system for a catalytic combustion system on a gas turbine includes a flame preburner, a fuel injector positioned downstream of the preburner and a catalyst positioned downstream of the fuel injector. In such systems, a portion of the fuel combusts within the catalyst itself and the remainder of the fuel combusts in a homogeneous combustion process wave downstream of the catalyst. A sensor in communication with the control system monitors the homogeneous combustion process wave and adjusts the gas temperature at the catalyst inlet to a preferred value based on a predetermined schedule that relates the catalyst inlet gas temperature to operating fundamentals such as adiabatic combustion temperature or the gas turbine's exhaust gas temperature.
摘要翻译：用于燃气轮机上的催化燃烧系统的控制系统包括火焰预燃器，位于预燃机下游的燃料喷射器和位于燃料喷射器下游的催化剂。在这种系统中，一部分燃料在催化剂本身内燃烧，其余的燃料在均匀的燃烧过程中在催化剂下游燃烧。与控制系统通信的传感器监测均匀的燃烧过程波，并且基于将催化剂入口气体温度与诸如绝热燃烧温度或气体的操作基准相关联的预定时间表将催化剂入口处的气体温度调节到优选值涡轮机的废气温度。

5. 发明授权

US06718772B2 Method of thermal NOx reduction in catalytic combustion systems 失效
标题翻译：催化燃烧系统中热还原NOx的方法
公开(公告)号：US06718772B2
公开(公告)日：2004-04-13
申请号：US10040208
申请日：2001-10-26
申请人： Ralph A. Dalla Betta , Marco A. Velasco , David K. Yee , Sarento G. Nickolas
发明人： Ralph A. Dalla Betta , Marco A. Velasco , David K. Yee , Sarento G. Nickolas
IPC分类号： F02C722
CPC分类号： F23R3/40
摘要： Methods and apparatus, both devices and systems, for control of Zeldovich (thermal) NOx production in catalytic combustion systems during combustion of liquid or gaseous fuels in the post catalytic sections of gas turbines by reducing combustion residence time in the HC zone through control of the HC Wave, principally by adjusting the catalyst inlet temperature. As the fuel/air mixture inlet temperature (to the catalyst) is reduced, the HC Wave moves downstream (longer ignition delay time), shortens the residence time at high temperature, thereby reducing thermal NOx production. The countervailing increase in CO production by longer ignition delay times can be limited by selectively locating the HC Wave so that thermal NOx is reduced while power output and low CO production is maintained. NOx is reduced to on the order of
摘要翻译：用于控制在燃气涡轮机的后催化部分中燃烧液体或气体燃料期间的催化燃烧系统中的Zeldovich（热）NOx生成的方法和装置，通过控制HC区域中的燃烧停留时间来减少 HC Wave主要通过调节催化剂入口温度。随着燃料/空气混合物入口温度（催化剂）减少，HC波向下游移动（点火延迟时间较长），缩短了高温下的停留时间，从而降低了NOx的产生。通过选择性地定位HC波，可以限制由较长的点火延迟时间产生的CO生产的反补贴增加，使得在输出功率和低CO生产时保持热NOx。当CO保持在<100ppm，典型地<50ppm，优选<5-10PPM时，NOx降低到大约<3ppm，优选<2ppm。

6. 发明授权

US5424264A Process and catalyst for partially hydrogenating aromatics to produce cycloolefins 失效
标题翻译：用于部分氢化芳族化合物以制备环烯烃的方法和催化剂
公开(公告)号：US5424264A
公开(公告)日：1995-06-13
申请号：US212344
申请日：1994-03-11
申请人： Michael A. Richard , Jacques De Deken , David K. Yee
发明人： Michael A. Richard , Jacques De Deken , David K. Yee
IPC分类号： B01J23/10 , B01J23/46 , B01J23/60 , B01J23/63 , B01J23/89 , B01J27/13 , B01J27/25 , B01J35/00 , B01J37/02 , C07B61/00 , C07C5/11 , C07C13/20 , B01J21/04 , B01J21/18
CPC分类号： B01J23/10 , B01J23/462 , B01J23/63 , B01J35/0006 , B01J37/024 , C07C5/11 , C07C2521/04 , C07C2521/08 , C07C2521/12 , C07C2523/46
摘要： This is a catalyst and a process for partially hydrogenating polycyclic and monocyciic aromatic hydrocarbons such as benzene, naphthalenes, biphenyls, and alkylbenzenes to produce the corresponding cyclooiefins. The catalyst is a hydrogenation catalyst comprising ruthenium on a composite support. It is a process in which the product cycloolefin is produced in high yield and with high selectivity.
摘要翻译：这是一种催化剂和用于部分氢化多环和单性氨基芳烃如苯，萘，联苯和烷基苯的方法，以产生相应的环糊精。催化剂是在复合载体上包含钌的氢化催化剂。这是以高产率和高选择性生产产物环烯烃的方法。

7. 发明授权

US5334790A Process and catalyst for partially hydrogenating aromatics to produce cycloolefins 失效
标题翻译：用于部分氢化芳族化合物以制备环烯烃的方法和催化剂
公开(公告)号：US5334790A
公开(公告)日：1994-08-02
申请号：US841850
申请日：1992-02-26
申请人： Michael A. Richard , Jacques De Deken , David K. Yee
发明人： Michael A. Richard , Jacques De Deken , David K. Yee
IPC分类号： B01J23/10 , B01J23/46 , B01J23/60 , B01J23/63 , B01J23/89 , B01J27/13 , B01J27/25 , B01J35/00 , B01J37/02 , C07B61/00 , C07C5/11 , C07C13/20 , C07C5/05
CPC分类号： B01J23/10 , B01J23/462 , B01J23/63 , B01J35/0006 , B01J37/024 , C07C5/11 , C07C2521/04 , C07C2521/08 , C07C2521/12 , C07C2523/46
摘要： This is a catalyst and a process for partially hydrogenating polycyclic and monocyclic aromatic hydrocarbons such as benzene, naphthalenes, biphenyls, and alkylbenzenes to produce the corresponding cycloolefins. The catalyst is a hydrogenation catalyst comprising ruthenium on a composite support. It is a process in which the product cycloolefin is produced in high yield and with high selectivity.
摘要翻译：这是一种用于部分氢化多环和单环芳烃如苯，萘，联苯和烷基苯的催化剂和方法，以产生相应的环烯烃。催化剂是在复合载体上包含钌的氢化催化剂。这是以高产率和高选择性生产产物环烯烃的方法。

8. 发明授权

US5414171A Process and washed catalyst for partially hydrogenating aromatics to produce cycloolefins 失效
标题翻译：用于部分氢化芳族化合物以生产环烯烃的方法和洗涤的催化剂
公开(公告)号：US5414171A
公开(公告)日：1995-05-09
申请号：US843347
申请日：1992-02-26
申请人： Michael A. Richard , Jacques C. De Deken , David K. Yee
发明人： Michael A. Richard , Jacques C. De Deken , David K. Yee
IPC分类号： B01J23/50 , B01J23/10 , B01J23/46 , B01J23/52 , B01J23/60 , B01J23/63 , B01J23/89 , B01J35/00 , B01J37/02 , C07B61/00 , C07C5/10 , C07C5/11 , C07C13/18 , C07C13/28 , C07C13/50
CPC分类号： B01J35/0006 , B01J23/10 , B01J23/462 , B01J23/63 , B01J37/024 , C07C5/11 , B01J35/006 , C07C2521/04 , C07C2521/08 , C07C2521/12 , C07C2523/46
摘要： This is a catalyst and a process for partially hydrogenating polycyclic and monocyclic aromatic hydrocarbons such as benzene, naphthalenes, biphenyls, and alkylbenzenes to produce the corresponding cycloolefins. The catalyst is a hydrogenation catalyst comprising ruthenium and a promoter metal, such as cobalt, on a composite support. It is a process in which the product cycloolefin is produced in high yield and with high selectivity.
摘要翻译：这是一种用于部分氢化多环和单环芳烃如苯，萘，联苯和烷基苯的催化剂和方法，以产生相应的环烯烃。催化剂是在复合载体上包含钌和助催化剂金属如钴的氢化催化剂。这是以高产率和高选择性生产产物环烯烃的方法。

9. 发明授权

US07152409B2 Dynamic control system and method for multi-combustor catalytic gas turbine engine 失效
标题翻译：多燃烧器催化燃气轮机的动态控制系统及方法
公开(公告)号：US07152409B2
公开(公告)日：2006-12-26
申请号：US10758879
申请日：2004-01-16
申请人： David K. Yee , Dag Reppen
发明人： David K. Yee , Dag Reppen
IPC分类号： F02C9/00 , F23R3/40
CPC分类号： F23C13/00 , F23C13/02 , F23C2900/13002 , F23D2208/10 , F23N2037/12 , F23N2041/20 , F23R3/40
摘要： According to one aspect, a method of controlling a multi-combustor catalytic combustion system is provided for determining a characteristic of a fuel-air mixture downstream of a preburner associated with a catalytic combustor and adjusting the fuel flow to the preburner based on the characteristic. The characteristic may include, for example, a measurement of the preburner or catalyst outlet temperature or a determination of the position of the homogeneous combustion wave in the burnout zone of the combustor.
摘要翻译：根据一个方面，提供一种控制多燃烧器催化燃烧系统的方法，用于基于特征确定与催化燃烧器相关联的预燃器下游的燃料 - 空气混合物的特性并调节到预燃室的燃料流量。特征可以包括例如预燃器或催化剂出口温度的测量或确定燃烧器的燃烧区域中的均匀燃烧波的位置。

10. 发明授权

US06796129B2 Design and control strategy for catalytic combustion system with a wide operating range 有权
标题翻译：具有广泛工作范围的催化燃烧系统设计与控制策略
公开(公告)号：US06796129B2
公开(公告)日：2004-09-28
申请号：US10071749
申请日：2002-02-07
申请人： David K. Yee , Robert Anthony Corr, II , Sarento George Nickolas
发明人： David K. Yee , Robert Anthony Corr, II , Sarento George Nickolas
IPC分类号： F02C916
CPC分类号： F23C13/00 , F23C13/02 , F23C2900/13002 , F23N5/003 , F23N2025/10 , F23N2037/12 , F23R3/40
摘要： The present additional control strategy has been developed to allow the gas turbine to operate at lower load or at other conditions where the total fuel required by the gas turbine is not optimum for full combustion of the fuel. The present invention manages air that bypasses the catalytic combustor and air that bleeds off of the compressor discharge. The bypass system changes the fuel air ratio of the catalytic combustor without affecting the overall gas turbine power output. The bleed system also changes the fuel air ratio of the catalytic combustor but at the cost of reducing the overall gas turbine efficiency. The key advantage of a catalytic combustor with a bypass and bleed system and the inventive control strategy is that it can maintain the catalyst at optimum low emissions operating conditions over a wider load range than a catalytic combustor without such a system.
摘要翻译：已经开发了本附加控制策略，以允许燃气轮机以较低的负载或在燃气轮机所需的总燃料对于燃料的完全燃烧不是最佳的其他条件下运行。本发明管理绕过催化燃烧器的空气和从压缩机排出口流出的空气。旁路系统改变催化燃烧器的燃料空气比，而不影响整个燃气轮机功率输出。排气系统还改变催化燃烧器的燃料空气比，但是以降低总体燃气轮机效率为代价。具有旁路和排气系统的催化燃烧器的关键优点是本发明的控制策略是，在不具有这种系统的情况下，其能够在比不含催化燃烧器的更宽的负载范围内将催化剂保持在最佳的低排放操作条件。

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