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    • 10. 发明申请
    • PROCESS FOR THE PREPARATION OF DIMETHYL ETHER
    • 二甲醚的制备方法
    • US20100216897A1
    • 2010-08-26
    • US12663058
    • 2008-07-10
    • Thomas Rostrup-Nielsen
    • Thomas Rostrup-Nielsen
    • C07C31/00
    • C07C41/01C07C43/043
    • Process for the preparation of dimethyl ether by catalytic conversion of synthesis gas to dimethyl ether comprising contacting a stream of synthesis gas comprising carbon dioxide with one or more catalysts active in the formation of methanol and the dehydration of methanol to dimethyl ether, to form a product mixture comprising the components dimethyl ether, carbon dioxide and unconverted synthesis gas, washing the product mixture comprising carbon dioxide and unconverted synthesis gas in a first scrubbing zone with a first solvent rich in dimethyl ether and subsequently washing the effluent from the first scrubbing zone in a second scrubbing zone with a second solvent rich in methanol to form a vapour stream comprising unconverted synthesis gas stream with reduced content of carbon dioxide, transferring the vapour stream comprising unconverted synthesis gas stream with reduced carbon dioxide content for further processing to dimethyl ether.
    • 通过将合成气催化转化成二甲醚来制备二甲醚的方法,包括使包含二氧化碳的合成气流与一种或多种在甲醇形成中有活性的催化剂和将甲醇脱水成二甲醚接触的产物 混合物,其包含二甲醚,二氧化碳和未转化的合成气的组分,在第一洗涤区中用含有二甲醚的第一溶剂洗涤包含二氧化碳和未转化的合成气的产物混合物,随后在第一洗涤区中洗涤流出物, 第二洗涤区与富含甲醇的第二溶剂形成包含具有降低的二氧化碳含量的未转化的合成气流的蒸汽流,将含有还原二氧化碳含量的未转化的合成气流的蒸气流转移到二甲醚中进一步处理。