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1. 发明授权

US4263176A Color-stable brighteners for detergents 失效
标题翻译：用于洗涤剂的颜色稳定的增白剂
公开(公告)号：US4263176A
公开(公告)日：1981-04-21
申请号：US94830
申请日：1979-11-16
申请人： Thomas Martini , Helmut Mengler , Gunter Rosch , Gunter Hohlfeld
发明人： Thomas Martini , Helmut Mengler , Gunter Rosch , Gunter Hohlfeld
IPC分类号： C11D3/42 , D06L3/12 , C09K11/06 , C11D1/14 , C11D3/28
CPC分类号： D06L3/125 , C11D3/42
摘要： Brighteners for detergents consisting of a mixture of 4,4'-bis-(2-morpholino-4-anilino-1,3,5-triazinylamino)-stilbene-2,2'-disulfonic acid-di-Na salt and from 5 to 50% by weight, calculated on said brightener, of another brightener of the formula ##STR1## in the above formula, M is an alkali metal cation, preferably sodium, X is a group of the formula --COR.sub.2 or --SO.sub.2 R.sub.3, R.sub.2 being C.sub.1 -C.sub.8 -alkyl and R.sub.3 being C.sub.1 -C.sub.5 -alkyl, C.sub.4 -C.sub.8 -cycloalkyl, phenyl or toluyl, Y is hydrogen or C.sub.1 -C.sub.5 -alkyl, A is C.sub.3 -C.sub.6 -alkylene, R.sub.1 is hydrogen, C.sub.1 -C.sub.5 -alkyl, C.sub.4 -C.sub.8 -cycloalkyl, or a group of the formula ##STR2## and Z is an anilino group, a chloroanilino group or a morpholino group. Said brightener mixtures are color-stable and do not show any green discoloration even after a prolonged storage in a moist atmosphere.
摘要翻译：用于由4,4'-双 - （2-吗啉代-4-苯胺基-1,3,5-三嗪基氨基） - 茋-2,2'-d-磺酸二钠盐的混合物组成的洗涤剂增白剂和在所述光亮剂中计算5-50重量％的另一种上式中的式“IMAGE”+ TR 的光亮剂，M是碱金属阳离子，优选钠，X是式-COR 2的基团或-SO 2 R 3，R 2是C 1 -C 8 - 烷基，R 3是C 1 -C 5 - 烷基，C 4 -C 8 - 环烷基，苯基或甲苯基，Y是氢或C 1 -C 5 - 烷基，A是C 3 -C 6亚烷基，R 1是氢，C 1 -C 5 - 烷基，C 4 -C 8 - 环烷基或式IMA IMA的基团，Z是苯胺基，氯苯胺基或吗啉代基。所述增白剂混合物是颜色稳定的，并且即使在潮湿的气氛中长时间储存后也不显示任何绿色变色。

2. 发明授权

US4330427A Mixtures of optical brighteners 失效
标题翻译：荧光增白剂的混合物
公开(公告)号：US4330427A
公开(公告)日：1982-05-18
申请号：US169296
申请日：1980-07-16
申请人： Thomas Martini , Rudiger Erckel , Horst Fruhbeis , Gunter Rosch , Heinz Probst
发明人： Thomas Martini , Rudiger Erckel , Horst Fruhbeis , Gunter Rosch , Heinz Probst
IPC分类号： C09B57/00 , C09B67/22 , D06L3/12 , D06P1/00 , D06P3/52 , C09K11/06
CPC分类号： D06L3/125
摘要： Mixtures of optical brighteners consisting of 5 to 95 parts by weight of a mixture consisting of 0 to 80% by weight of the compound of the formula 1 ##STR1## 20 to 100% by weight of the compound of the formula 2 ##STR2## and 0 to 80% by weight of the compound of the formula 3 ##STR3## and 95 to 5% by weight of one or more other optical brighteners.
摘要翻译：由5至95重量份由0至80重量％的式1化合物组成的混合物的组合物（1）20至100重量％的式2化合物 IMAGE>（2）和0至80重量％的式3化合物（3）和95至5重量％的一种或多种其它荧光增白剂。

3. 发明授权

US4309551A Quaternized, bridged benzimidazolylbenzimidazoles, processes for their preparation and their use 失效
标题翻译：季铵化的桥联苯并咪唑基苯并咪唑，其制备方法及其用途
公开(公告)号：US4309551A
公开(公告)日：1982-01-05
申请号：US191709
申请日：1980-09-29
申请人： Norbert Schonberger , Erich Schinzel , Thomas Martini , Gunter Rosch
发明人： Norbert Schonberger , Erich Schinzel , Thomas Martini , Gunter Rosch
IPC分类号： C09B57/00 , C07D235/02 , C07D235/20 , C07D235/24 , C07D487/14 , C07D235/30 , C07D235/04
CPC分类号： C07D235/02 , C07D235/20 , C07D235/24 , C07D487/14
摘要： Compounds of the general formula (1) ##STR1## wherein R.sub.1 denotes hydrogen, halogen, alkyl, alkoxy or, conjointly with R.sub.2, a fused benzo ring, R.sub.2 denotes hydrogen, alkyl, alkoxy, halogen, phenyl, cyano, carboalkoxy, carboxyl, carbonamido, monoalkylcarbonamido, dialkylcarbonamido, sulfo, alkylsulfonyl, alkyloxysulfonyl, sulfonamido, monoalkylsulfonamido or dialkylsulfonamido or, conjointly with R.sub.3, a fused benzo ring, R.sub.3 has the same meaning as R.sub.2, R.sub.4 denotes hydrogen, alkyl, alkoxy, halogen or, conjointly with R.sub.3, a fused benzo ring, R.sub.5 denotes alkyl, hydroxyalkyl, alkoxyalkyl, optionally substituted aralkyl, cyanoethyl, cycloalkyl or a group of the formulae --CH.sub.2 CN, --CH.sub.2 CONH.sub.2 or --CH.sub.2 COO--alkyl, A denotes a group of the formulae ##STR2## or--(CH.sub.2).sub.4 --R.sub.6 denotes hydrogen, alkyl, hydroxyalkyl, alkoxyalkyl, aralkyl or optionally substituted phenyl, n denotes 1, 2 or 3 and X.sup.(-) denotes a halide, alkylsulfonate, alkylsulfate, alkylphenylsulfonate or phenylsulfonate ion, and processes for their preparation and their use as optical brighteners.
摘要翻译：通式（1）的化合物其中R1表示氢，卤素，烷基，烷氧基或与R2稠合的苯并环，R2表示氢，烷基，烷氧基，卤素，苯基，氰基，烷氧羰基，羧基，碳酰氨基，单烷基碳酰氨基，二烷基碳酰氨基，磺基，烷基磺酰基，烷氧基磺酰基，亚磺酰氨基，烷基磺酰氨基或二烷基磺酰氨基，或与R3稠合的苯并环，R3与R2相同，R4表示氢，烷基，烷氧基，卤素或 R 3表示烷基，羟基烷基，烷氧基烷基，任选取代的芳烷基，氰基乙基，环烷基或式-CH 2 CN，-CH 2 CONH 2或-CH 2 COO - 烷基的基团，A表示式或 - （CH 2）4 -R 6表示氢，烷基，羟基烷基，烷氧基烷基，芳烷基或任选取代的苯基，n表示1,2或3，X（ - ）表示卤素，烷基磺酸酯，烷基硫酸酯，烷基苯基磺酸酯或苯基磺酸根离子，过程为制备及其作为荧光增白剂的用途。

4. 发明授权

US4508900A Cationic compounds of the naphthalimide series, process for their preparation and their use 失效
公开(公告)号：US4508900A
公开(公告)日：1985-04-02
申请号：US417052
申请日：1982-09-13
申请人： Norbert Schonberger , Erich Schinzel , Thomas Martini , Gunter Rosch
发明人： Norbert Schonberger , Erich Schinzel , Thomas Martini , Gunter Rosch
IPC分类号： C07D221/14 , C09B17/04 , D06P1/649
CPC分类号： C07D221/14
摘要： Cationic compounds of the formula (1) ##STR1## in which R denotes alkyl, hydroxyalkyl, alkoxyalkyl, phenylalkyl, or phenoxyalkyl,R' denotes alkyl, hydroxyalkyl, benzyl, or allyl andX.sup.(-) denotes a colorless anion,process for their manufacture and their use.

5. 发明授权

US4336155A Mixtures of optical brighteners 失效
标题翻译：荧光增白剂的混合物
公开(公告)号：US4336155A
公开(公告)日：1982-06-22
申请号：US169873
申请日：1980-07-16
申请人： Thomas Martini , Rudiger Erckel , Horst Fruhbeis , Gunter Rosch , Heinz Probst
发明人： Thomas Martini , Rudiger Erckel , Horst Fruhbeis , Gunter Rosch , Heinz Probst
IPC分类号： C09B67/22 , C09B57/00 , D06L3/12 , D06P1/00 , D06P3/52 , C09K11/06
CPC分类号： D06L3/125
摘要： Mixtures of optical brighteners consisting of 5 to 95% by weight of a compound of the formula ##STR1## in which A denotes a o- or p-cyanophenyl group, and 95 to 5% by weight of one or more further optical brighteners.
摘要翻译：由5至95重量％的式（IMAGE）化合物（其中A表示邻 - 或对 - 氰基苯基）和95至5重量％的一种或多种另外的荧光增白剂组成的荧光增白剂的混合物。

6. 发明授权

US4323675A Novel stilbene compounds: process for their manufacture and their use as optical brighteners 失效
标题翻译：新型二苯乙烯化合物：其制造方法及其作为荧光增白剂的用途
公开(公告)号：US4323675A
公开(公告)日：1982-04-06
申请号：US162930
申请日：1980-06-25
申请人： Helmut Eckes , Rudiger Erckel , Thomas Martini , Gunter Rosch
发明人： Helmut Eckes , Rudiger Erckel , Thomas Martini , Gunter Rosch
IPC分类号： C07D249/24 , C09B57/00 , C07D401/14 , C07D413/10 , C07D413/14
CPC分类号： C09B57/00 , C07D249/24
摘要： Triazolyl stilbene compounds of the formula ##STR1## wherein A is a benzene or naphthalene ring optionally substituted by non-chromophoric substituents and B is a substituted 1,2,4-oxdiazole (3) or 1,3,5-oxdiazole (2) group, as well as a procedure for their manufacture and their use as optical brighteners.
摘要翻译：其中A是任选被非发色取代基取代的苯或萘环，B是取代的1,2,4-恶二唑（3）或1,3,5-氧代二唑（2）的三唑基二苯乙烯化合物，组，以及其制造和用作荧光增白剂的程序。

7. 发明授权

US4595756A Cationic compounds of the naphthalimide series, process for their preparation and their use 失效
标题翻译：萘酰亚胺系列的阳离子化合物，其制备方法及其用途
公开(公告)号：US4595756A
公开(公告)日：1986-06-17
申请号：US613461
申请日：1984-05-24
申请人： Norbert Schonberger , Erich Schinzel , Thomas Martini , Gunter Rosch
发明人： Norbert Schonberger , Erich Schinzel , Thomas Martini , Gunter Rosch
IPC分类号： C07D221/14 , C09B17/04 , D06P1/649
CPC分类号： C07D221/14
摘要： Cationic compounds of the formula (1) ##STR1## in which R denotes alkyl, hydroxyalkyl, alkoxyalkyl, phenylalkyl, or phenoxyalkyl,R' denotes alkyl, hydroxyalkyl, benzyl, or allyl andX.sup.(-) denotes a colorless anion, process for their manufacture and their use.
摘要翻译：式（1）的阳离子化合物其中R表示烷基，羟烷基，烷氧基烷基，苯基烷基或苯氧基烷基，R'表示烷基，羟基烷基，苄基或烯丙基，X（ - ）表示无色阴离子，其制造及其使用过程。

8. 发明授权

US4400294A Mixtures of optical brighteners 失效
标题翻译：荧光增白剂的混合物
公开(公告)号：US4400294A
公开(公告)日：1983-08-23
申请号：US439946
申请日：1982-11-08
申请人： Thomas Martini , Gunter Rosch
发明人： Thomas Martini , Gunter Rosch
IPC分类号： C09B57/00 , C09B67/22 , D06L3/12 , C11D7/26
CPC分类号： D06L3/125
摘要： Mixtures of optical brighteners consisting of(a) 1 to 99 weight % of one or several compounds of the formula 1 ##STR1## (b) 99 to 1 weight % of one or several compounds of the formula 2 ##STR2## wherein n is 0 or 1,X is oxygen or sulfur,B is a group of the formulae ##STR3## and the other substituents are defined a specified in the description.
摘要翻译：由（a）1至99重量％的一种或几种式1化合物（1）（b）组成的荧光增白剂的混合物99至1重量％的一种或几种式2化合物（IMAGE） 2）其中n是0或1，X是氧或硫，B是式“IMAGE”+ TR“IMA”的基团，其它取代基是在说明书中规定的。

9. 发明授权

US4246403A 1,3,4-Oxadiazolone-(2) compounds and process for their manufacture 失效
标题翻译： 1,3,4-恶二酮 - （2）化合物及其制备方法
公开(公告)号：US4246403A
公开(公告)日：1981-01-20
申请号：US60823
申请日：1979-07-25
申请人： Gunter Prossel , Erich Schinzel , Norbert Schonberger , Thomas Martini , Gunter Rosch
发明人： Gunter Prossel , Erich Schinzel , Norbert Schonberger , Thomas Martini , Gunter Rosch
IPC分类号： C09B57/00 , C07D271/10 , C07D271/113 , C07F9/653 , C07D413/10 , C07D413/14
CPC分类号： C07D271/113 , C07F9/65312
摘要： Novel 1,3,4-oxadiazolone-(2) compounds of the formula ##STR1## wherein Y denotes carboxy optionally functionally modified or optionally substituted phenyl or a five-membered heterocycle optionally substituted and selected from the group consisting of: furan, thiophen, oxazole, imidazole, oxadiazole, oxadiazolone, triazole, benzofuran, thionaphthalene, benzoxazole, benzimidazole, and benzotriazole, R denotes hydrogen, alkyl or optionally substituted phenyl, n denotes 0 and 1 and the rings A and B carry optionally further non-chromophoric substituents. These compounds may be used as optical brighteners.
摘要翻译：式（1）的新的1,3,4-恶二酮 - （2）化合物，其中Y表示任选官能修饰的或任选取代的苯基或任选取代并选自以下的五元杂环：呋喃，噻吩，恶唑，咪唑，恶二唑，恶二唑酮，三唑，苯并呋喃，噻二唑，苯并恶唑，苯并咪唑和苯并三唑，R表示氢，烷基或任选取代的苯基，n表示0和1，环A和B任选进一步携带非 - 发色取代基。这些化合物可以用作荧光增白剂。

10. 发明授权

US5131913A Production of pattern effects when dyeing or printing textile material in the absence of alkali or reducing agents: cationization and oxidized in a pattern before dyeing 失效
标题翻译：在碱性或还原剂无法染色或印刷纺织材料时生产图案效果：染色前的图案和氧化
公开(公告)号：US5131913A
公开(公告)日：1992-07-21
申请号：US538102
申请日：1990-06-14
申请人： Thomas Martini
发明人： Thomas Martini
IPC分类号： D06P1/52 , D06P3/60
CPC分类号： D06P3/60 , D06P1/5278 , Y10S8/918
摘要： Process for producing pattern effects when dyeing or printing textile material in the absence of alkali or reducing agents, which comprises pretreating the textile material with a cationizing agent, drying, applying an oxidizing agent in the form of a pattern, drying and dyeing or printing with reactive, direct, acid, water-soluble sulfur dyes or pigment dyes in the absence of any alkali or reducing agent.
摘要翻译：在不存在碱或还原剂的情况下染色或印刷纺织品材料时产生图案效果的方法，其包括用阳离子化剂预处理织物材料，干燥，以图案形式施用氧化剂，干燥和染色或印刷，反应性，直接，酸性，水溶性硫化染料或颜料染料，不存在任何碱或还原剂。

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