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1. 发明授权

US5189070A Process for preparing low density porous crosslinked polymeric materials 失效
标题翻译：制备低密度多孔交联聚合物材料的方法
公开(公告)号：US5189070A
公开(公告)日：1993-02-23
申请号：US891322
申请日：1992-05-29
申请人： Thomas F. Brownscombe , William P. Gergen , Ronald M. Bass , Maryanne Mores , Pui K. Wong
发明人： Thomas F. Brownscombe , William P. Gergen , Ronald M. Bass , Maryanne Mores , Pui K. Wong
IPC分类号： C08F2/24 , C08F2/22 , C08F2/32 , C08F212/00 , C08F212/36 , C08F220/10 , C08F220/18 , C08J9/28
CPC分类号： C08F2/32 , C08J9/283
摘要： In a process for the preparation of a low density porous crosslinked polymeric material by polymerizing a water-in-oil high internal phase emulsion, curing time of the monomers in the emulsion can be reduced without adversely affecting polymer properties or substantially affecting the emulsion by carrying out the curing in multiple-stages. The emulsion is first pre-cured at a temperature less than about 65.degree. C. until the emulsion reaches a Rheometrics dymanic shear modulus of at least about 500 and subsequently curing at a temperature above about 70.degree. C.
摘要翻译：在通过聚合油包水高内相乳液制备低密度多孔交联聚合物材料的方法中，可以降低乳液中单体的固化时间，而不会不利地影响聚合物性能或通过携带在多个阶段进行固化。首先将乳液在低于约65℃的温度下预固化，直到乳液达到至少约500的流变测定剪切模量，然后在高于约70℃的温度下固化。

2. 发明授权

US5340842A Low density porous crosslinked polymeric materials 失效
标题翻译：低密度多孔交联聚合材料
公开(公告)号：US5340842A
公开(公告)日：1994-08-23
申请号：US185537
申请日：1994-01-19
申请人： Robert P. Adamski , Maryanne Mores , Pui K. Wong , Diana D. Davis
发明人： Robert P. Adamski , Maryanne Mores , Pui K. Wong , Diana D. Davis
IPC分类号： C08F2/22 , C08F2/32 , C08F12/00 , C08F20/10 , C08F212/00 , C08F212/08 , C08F212/36 , C08F220/10 , C08F220/12 , C08F220/20 , C08J9/28 , G01N13/00 , G01N13/02
CPC分类号： G01N13/00 , C08F2/32 , C08J9/28 , C08J2201/0504 , G01N2013/025
摘要： Stable high internal phase water-in-oil emulsions containing polymerizable vinyl monomers, crosslinking monomers and polymerization initiators are obtained by using saccharide fatty acid esters as surfactants. The amount of surfactants necessary to form stable high internal phase water-in-oil emulsions is decreased by using saccharide fatty acid esters as surfactants. Further, hydrophobic foams can be obtained by using saccharide fatty acid esters.
摘要翻译：通过使用糖类脂肪酸酯作为表面活性剂，得到含有可聚合乙烯基单体，交联单体和聚合引发剂的稳定的高内相油包水乳液。通过使用糖类脂肪酸酯作为表面活性剂，可以降低形成稳定的高内相油包水乳液所需的表面活性剂的量。此外，通过使用糖类脂肪酸酯可以获得疏水性泡沫。

3. 发明授权

US5306733A Low density porous crosslinked polymeric materials 失效
公开(公告)号：US5306733A
公开(公告)日：1994-04-26
申请号：US114557
申请日：1993-08-30
申请人： Robert P. Adamski , Maryanne Mores , Pui K. Wong , Diana D. Davis
发明人： Robert P. Adamski , Maryanne Mores , Pui K. Wong , Diana D. Davis
IPC分类号： C08F2/22 , C08F2/32 , C08F12/00 , C08F20/10 , C08F212/00 , C08F212/08 , C08F212/36 , C08F220/10 , C08F220/12 , C08F220/20 , C08J9/28 , G01N13/00 , G01N13/02 , C08J9/26
CPC分类号： G01N13/00 , C08F2/32 , C08J9/28 , C08J2201/0504 , G01N2013/025
摘要： Stable high internal phase water-in-oil emulsions containing polymerizable vinyl monomers, crosslinking monomers and polymerization initiators are obtained by using saccharide fatty acid esters as surfactants. The amount of surfactants necessary to form stable high internal phase water-in-oil emulsions is decreased by using saccharide fatty acid esters as surfactants. Further, hydrophobic foams can be obtained by using saccharide fatty acid esters.

4. 发明授权

US5646193A Process to prepare two phase foam compositions and two phase foam compositions 失效
标题翻译：制备两相泡沫组合物和两相泡沫组合物的方法
公开(公告)号：US5646193A
公开(公告)日：1997-07-08
申请号：US560140
申请日：1995-11-17
申请人： Thomas Fairchild Brownscombe , Ronald Marshall Bass , Pui Kwan Wong , George Constantine Blytas , William Peter Gergen , Maryanne Mores
发明人： Thomas Fairchild Brownscombe , Ronald Marshall Bass , Pui Kwan Wong , George Constantine Blytas , William Peter Gergen , Maryanne Mores
IPC分类号： A61F13/15 , A61L15/42 , C08J9/28
CPC分类号： C08J9/283 , A61F13/15203 , A61L15/425
摘要： A process is provided for the production of a porous crosslinked polymeric foam comprising the steps of: (a) providing a first water-in-oil emulsion comprising (i) a first mixture of polymerizable monomers comprising at least one oil-soluble vinyl monomer and from about 2 to about 70 weight percent, based on the mixture, of a multifunctional unsaturated crosslinking monomer, (ii) at least 70 weight percent, based on the emulsion, of water as the internal phase (iii) an effective amount to produce the water-in-oil emulsion of a first surfactant, and (iv) a first polymerization initiator; (b) providing a second water-in-oil emulsion comprising (i) a mixture of polymerizable monomers comprising at least one oil-soluble vinyl monomer and from about 2 to about 70 weight percent, based on the mixture, of a second multifunctional unsaturated crosslinking monomer, (ii) at least 70 weight percent, based on the emulsion, of water as the internal phase (iii) an effective amount to produce the water-in-oil emulsion of a second surfactant, and (iv) a second polymerization initiator; (c) combining the first and second emulsions; and (d) curing said polymerizable monomers under conditions effective to polymerize and crosslink the polymer prior to significant diffusion between the emulsions. Polymeric foams can be prepared by this process that exhibit positive attributes of foams formed by curing of each of the emulsions individually.
摘要翻译：提供了一种生产多孔交联聚合物泡沫体的方法，包括以下步骤：（a）提供第一种油包水乳液，其包含（i）包含至少一种油溶性乙烯基单体的可聚合单体的第一混合物和基于该混合物，约2至约70重量％的多官能不饱和交联单体，（ii）基于乳液的至少70重量％的作为内相的水（iii）有效量的产生第一表面活性剂的油包水乳液，和（iv）第一聚合引发剂; （b）提供第二种油包水乳液，其包含（i）包含至少一种油溶性乙烯基单体的可聚合单体和基于该混合物的约2-约70重量％的第二多官能不饱和单体的混合物交联单体，（ii）基于乳液至少70重量％的作为内相的水（iii）有效量的产生第二表面活性剂的油包水乳液，和（iv）第二聚合发起者（c）组合第一和第二乳液; 和（d）在有效聚合和交联聚合物的条件下，在乳液显着扩散之前，使所述可聚合单体固化。聚合物泡沫可以通过这种方法制备，其显示了通过单独固化每种乳液形成的泡沫的阳性。

5. 发明授权

US4918153A Copoly(imidine-amide) 失效
标题翻译：共聚（亚胺酰胺）
公开(公告)号：US4918153A
公开(公告)日：1990-04-17
申请号：US323594
申请日：1989-03-14
申请人： Patrick E. Cassidy , James M. Farley , Maryanne Mores
发明人： Patrick E. Cassidy , James M. Farley , Maryanne Mores
IPC分类号： C08G73/06 , C08G73/14
CPC分类号： C08G73/14
摘要： The present invention relates to a copoly(imidineamide) consisting of a copolymer of polyamidines and polyimides having, in the basic chain structure of the polymer, imidine structures represented by formula [I] and the amide structures represented by formula [II]: ##STR1## The copoly(imidine-amide) of the present invention is a polymeric material of excellent heat resistance and processability useful for a wide range of industrial applications.
摘要翻译：本发明涉及由聚酰胺和聚酰亚胺的共聚物组成的共聚（亚胺酰胺），其在聚合物的基本链结构中由式[I]表示的亚胺基结构和由式[II]表示的酰胺结构：

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