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1. 发明授权

US5382702A Process for the production of 5-alkoxy-2,4-dinitro-alkylbenzenes 失效
标题翻译： 5-烷氧基-2,4-二硝基 - 烷基苯的制备方法
公开(公告)号：US5382702A
公开(公告)日：1995-01-17
申请号：US142383
申请日：1993-11-19
申请人： Wolfgang R. Balzer , Thomas Clausen , Alexa Weinges
发明人： Wolfgang R. Balzer , Thomas Clausen , Alexa Weinges
IPC分类号： C07C201/08 , C07C201/12 , C07C205/12 , C07C205/37 , C07C43/205
CPC分类号： C07C201/08 , C07C201/12
摘要： Process for producing 5-alkoxy-2,4-dinitroalkylbenzenes of the general formula (I) ##STR1## R.sup.1 =C.sub.1 to C.sub.4 alkyl; R=C.sub.1 to C.sub.6 alkyl group, C.sub.2 to C.sub.4 hydroxyalkyl, C.sub.3 to C.sub.4 dihydroxyalkyl,in which a 3-fluoroalkylbenzene is nitrated and the obtained 2,4-dinitro-5-fluoroalkylbenzene is then reacted with a suitable alcohol at -5.degree. C. to +25.degree. C. with the addition of sodium hydroxide or potassium hydroxide.
摘要翻译： PCT No.PCT / EP93 / 00678 Sec。 371日期：1993年11月19日 102（e）1993年11月19日PCT 1993年3月20日PCT PCT。出版物WO93 / 2551200 日本1993年12月23日。通式（I）的5-烷氧基-2,4-二硝基烷基苯的制备方法（Ⅰ）R1 = C1〜C4烷基; R = C1至C6烷基，C2至C4羟基烷基，C3至C4二羟基烷基，其中3-氟烷基苯被硝化，所得2,4-二硝基-5-氟烷基苯然后与适当的醇在-5℃下反应至+ 25℃，加入氢氧化钠或氢氧化钾。

2. 发明授权

US5542953A 5-halogen-2,4-Bis (alkylamino)-1-alkylbenzenes and hair dye compositions containing same 失效
标题翻译： 5-卤代-2,4-双（烷基氨基）-1-烷基苯和含有它们的染发剂组合物
公开(公告)号：US5542953A
公开(公告)日：1996-08-06
申请号：US142492
申请日：1993-10-22
申请人： Wolfgang R. Balzer , Thomas Clausen , Anke Frank , Alexa Weinges
发明人： Wolfgang R. Balzer , Thomas Clausen , Anke Frank , Alexa Weinges
IPC分类号： A61K8/00 , A61K8/33 , A61K8/40 , A61K8/41 , A61K8/49 , A61Q5/10 , C07C211/52 , C07C215/16 , A61K7/13 , C07C211/51
CPC分类号： A61Q5/10 , A61K8/411 , A61K8/69 , C07C211/52 , C07C215/16
摘要： The composition for the oxidative dyeing of hair contains at least one coupler of the general formula ##STR1## where R is a straight-chain or branched C.sub.1 - to C.sub.4 -alkyl group, X is chlorine or fluorine, and R.sup.1 is a straight-chain or branched C.sub.1 - to C.sub.4 -alkyl group or a straight-chain or branched C.sub.2 - to C.sub.4 -hydroxyalkyl group. The 5-halogen-2,4-bis(alkylamino)-1-alkylbenzenes of the formula (I) are novel. The couplers of the general formula (I) may be obtained through simple chemical reactions, are easily soluble in water and have an outstanding shelf stability, in particular as a constituent of the hair dye composition described here. The dyeing results which can be achieved with the hair dye composition according to the invention are particularly distinguished by the color intensity of the red hues, in addition to the multitude of shades, and by a good purity of color with respect to blue hues.
摘要翻译： PCT No.PCT / EP93 / 00011 Sec。 371日期：1993年10月22日 102（e）日期1993年10月22日PCT 1993年1月7日PCT PCT。出版物WO93 / 16677 日本1993年9月2日头发的氧化染色组合物含有至少一种通式为（I）的成色剂，其中R是直链或支链的C 1 -C 4烷基，X是氯或氟，R 1为直链或支链C 1至C 4烷基或直链或支链C 2至C 4 - 羟基烷基。式（I）的5-卤代-2,4-二（烷基氨基）-1-烷基苯是新颖的。通式（I）的成色剂可以通过简单的化学反应获得，易溶于水并具有优异的贮存稳定性，特别是作为本文所述的染发剂组合物的成分。通过根据本发明的染发剂组合物可以实现的染色结果特别地除了多种色调之外的红色调的颜色强度以及相对于蓝色色调的良好的颜色纯度。

3. 发明授权

US5224965A Composition for the oxidative dyeing of hair and new 5-halogen-2,4-diamino alkylbenzenes 失效
标题翻译：头发和新5-卤代-2,4-二氨基亚苄基氧化剂的组合物
公开(公告)号：US5224965A
公开(公告)日：1993-07-06
申请号：US847080
申请日：1992-04-07
申请人： Thomas Clausen , Alexa Weinges , Wolfgang R. Balzer
发明人： Thomas Clausen , Alexa Weinges , Wolfgang R. Balzer
IPC分类号： C07C205/12 , C07C211/52 , D06P1/32 , D06P3/08
CPC分类号： A61Q5/10 , A61K8/411 , C07C205/12 , C07C211/52
摘要： The composition for the oxidative dyeing of hair contains at least one coupler substance of the formula ##STR1## where R is a straight-chain or branched C.sub.1 - to C.sub.4 -alkyl group and X is fluorine or bromine, and new 5-halogen-2,4-diaminoalkylbenzenes.The coupler substances of formula (I) are obtainable by simple chemical reactions, easily soluble in water and have a good shelf stability particularly as constituents of the hair dye composition described here.In addition to the multitude of color shades, the dye results which can be achieved with the hair dye composition according to the invention are distinguished particularly by the intensity of color of the red tones and good uniformity of color of the blue tones.
摘要翻译： PCT No.PCT / EP91 / 01565 Sec。 371日期：1992年4月7日 102（e）日期1992年4月7日PCT 1991年8月17日PCT PCT。出版物WO92 / 04005 头发氧化染色的组合物含有至少一种式（I）的成色剂物质，其中R是直链或支链的C 1〜C 4 - 烷基，X是氟或溴，以及新的5-卤代-2,4-二氨基烷基苯。式（I）的成色剂物质可以通过简单的化学反应获得，易溶于水并且具有良好的贮存稳定性，特别是作为本文所述的染发组合物的成分。除了多种色调之外，根据本发明的染发组合物可以实现的染色结果特别地由红色调的颜色强度和蓝色色调的良好均匀性区分开来。

4. 发明授权

US5718731A Oxidation hair dye composition based on 4,5-diaminopyrazole and m-phenylenediamine derivatives 失效
标题翻译：基于4,5-二氨基吡唑和间苯二胺衍生物的氧化染发剂组合物
公开(公告)号：US5718731A
公开(公告)日：1998-02-17
申请号：US696327
申请日：1996-08-13
申请人： Isolde Loewe , Alexa Weinges , Wolfgang R. Balzer , Stefan Gerstung
发明人： Isolde Loewe , Alexa Weinges , Wolfgang R. Balzer , Stefan Gerstung
IPC分类号： A61K8/00 , A61K8/41 , A61K8/49 , A61Q5/10 , C07D231/38 , D06P1/32 , D06P3/08 , A61K7/13
CPC分类号： A61Q5/10 , A61K8/494 , D06P1/32
摘要： The oxidation hair dye composition contains from 0.01 to 4.0 percent by weight of a developer substance including at least one diaminopyrazole of the formula (I) ##STR1## wherein R.sup.1 is selected from the group consisting of hydrogen, an alkyl group having from 1 to 6 carbon atoms, a hydroxyalkyl group having from 2 to 4 carbon atoms and a substituted or unsubstituted benzyl group, and R.sup.2 and R.sup.3, independently, are each selected from the group consisting of hydrogen, an alkyl group having from 1 to 6 carbon atoms and a hydroxyalkyl group having from 2 to 4 carbon atoms; and from 0.01 to 4.0 percent by weight of a coupler substance including at least one m-phenylenediamine selected from the group consisting of N-(3-dimethylamino)phenyl urea and 3-(N-methylsulfonyl)amino-N,N-dimethylaniline.
摘要翻译：氧化染发剂组合物含有0.01至4.0重量％的显影剂物质，其包含至少一种式（I）的二氨基吡唑其中R 1选自氢，烷基，其具有 1至6个碳原子，具有2至4个碳原子的羟烷基和取代或未取代的苄基，R 2和R 3各自独立地选自氢，具有1至6个碳原子的烷基原子和具有2至4个碳原子的羟烷基; 和0.01至4.0重量％的包含至少一种选自N-（3-二甲基氨基）苯基脲和3-（N-甲基磺酰基）氨基-N，N-二甲基苯胺的间苯二胺的成色剂物质。

5. 发明授权

US5645610A Substituted 2-alkylamino-4-amino-1-alkylbenzene compounds and oxidation hair dye compositions based on said compounds 失效
标题翻译：基于所述化合物的取代的2-烷基氨基-4-氨基-1-烷基苯化合物和氧化染发组合物
公开(公告)号：US5645610A
公开(公告)日：1997-07-08
申请号：US450476
申请日：1995-05-26
申请人： Wolfgang R. Balzer , Anke Frank , Alexa Weinges
发明人： Wolfgang R. Balzer , Anke Frank , Alexa Weinges
IPC分类号： A61K8/00 , A61K8/33 , A61K8/41 , A61K8/49 , A61Q5/10 , C07C211/50 , C07C211/52 , C07C215/16 , C07C217/84 , C07D213/73 , C07D231/38 , C07D239/46 , D06P1/32 , D06P3/08 , A61K7/13 , C07C209/00
CPC分类号： A61Q5/10 , A61K8/411 , C07C217/84
摘要： The new coupler compounds of the invention are 4-amino-2 -(2'-hydroxyethyl)-amino-5-methoxytoluene and/or 4-amino-2-(2'-hydroxyethyl)amino-5-chlorotoluene. The invention also includes an oxidation hair dye composition including an effective amount, advantageously from 0.01 to 5 percent by weight, of the above-mentioned new coupler compounds together with one or more known developer compounds and optionally certain direct dyes.
摘要翻译：本发明的新的成色剂化合物是4-氨基-2-（2'-羟乙基） - 氨基-5-甲氧基甲苯和/或4-氨基-2-（2'-羟乙基）氨基-5-氯甲苯。本发明还包括氧化染发剂组合物，其包含有效量，有利地为0.01至5重量％的上述新的成色剂化合物以及一种或多种已知的显影剂化合物和任选的某些直接染料。

6. 发明授权

US5380340A Hair dye containing aminopyrazole derivatives as well as pyrazole derivatives 失效
标题翻译：含有氨基吡唑衍生物的染发剂以及吡唑衍生物
公开(公告)号：US5380340A
公开(公告)日：1995-01-10
申请号：US27171
申请日：1993-03-04
申请人： Hans Neunhoeffer , Stefan Gerstung , Thomas Clausen , Wolfgang R. Balzer
发明人： Hans Neunhoeffer , Stefan Gerstung , Thomas Clausen , Wolfgang R. Balzer
IPC分类号： A61K8/49 , A61Q5/10 , C07D487/04 , A61K7/13 , C07D487/02
CPC分类号： A61Q5/10 , A61K8/494 , C07D487/04
摘要： The composition for oxidative dyeing of hair contains at least one coupler and 0.010 to 3.0 percent by weight of at least one developer selected from the group consisting of aminopyrazole derivatives of the formula (I): ##STR1## wherein R is selected from the group consisting of hydrogen and alkyl groups having one to four carbon atoms; n=2 or 3; and physiologically tolerated, water-soluble salts thereof. The developer and coupler substances are present in the composition in a total amount of from 0.1 to 5.0 percent. New pyrazole derivative compounds are also part of the invention.
摘要翻译： PCT No.PCT / EP92 / 01887第 371日期：1993年3月4日 102（e）1993年3月4日PCT提交1992年8月19日PCT公布。出版物WO93 / 07849 日期：1993年4月29日。头发氧化染色组合物含有至少一种成色剂和0.010-3.0％重量的至少一种显影剂，其选自式（I）的氨基吡唑衍生物：（ I）其中R选自氢和具有1-4个碳原子的烷基; n = 2或3; 和其生理上耐受的水溶性盐。显影剂和成色剂物质在组合物中的总量为0.1-5.0％。新的吡唑衍生物化合物也是本发明的一部分。

7. 发明授权

US5409503A Oxidation hair dye with a content of 5-aminophenyl derivatives, process for oxidative dyeing of hair and new 5-aminophenol derivatives 失效
标题翻译：含有5-氨基苯基衍生物的氧化染发剂，毛发氧化染色方法及新型5-氨基苯酚衍生物
公开(公告)号：US5409503A
公开(公告)日：1995-04-25
申请号：US140769
申请日：1993-10-21
申请人： Thomas Clausen , Wolfgang R. Balzer , Helmut Keller
发明人： Thomas Clausen , Wolfgang R. Balzer , Helmut Keller
IPC分类号： C07C211/28 , C07C211/29 , A61K7/13
CPC分类号： A61K8/415 , A61K8/69 , A61Q5/10
摘要： The composition for oxidative dyeing of hair contains 0.01 to 5.0 percent by weight of at least one 5-aminophenol compound of the formula ##STR1## wherein R is an alkyl group having 1 to 4 carbon atoms, X is fluorine or OR.sup.1 and R.sup.1 is an alkyl group having 2 to 4 carbon atoms, a monohydroxyalkyl group with 2 to 4 carbon atoms or a dihydroxyalkyl group with 3 and 4 carbon atoms, and physiologically tolerated water-soluble salts thereof as coupler substance; and 0.1 to 6.1 percent by weight of a total amount of the coupler substance and at least one developer substance. The developer substance can be 1,4-diaminobenzene, 2,5-diaminotoluene, 2,5-diaminobenzyl alcohol, 2-(2'-hydroxyethyl)-1,4-diaminobenzene, 4-aminophenol, 4-amino-3-methylphenol, 4-amino-2-methoxymethylphenol, 4-amino-2-ethoxy-methylphenol and tetraaminophyrimidine and physiologically tolerated water-soluble salts thereof. The invention also concerns certain new substituted 2-alkyl-5-aminophenols including 5-amino-4-ethoxy-2-methylphenol, 5-amino-4-(2'-hydroxyethyl)oxy-2-methylphenol and 5-amino-2-ethyl-4-fluorophenol.
摘要翻译：用于头发氧化染色的组合物含有0.01至5.0重量％的至少一种式（I）的至少一种5-氨基苯酚化合物，其中R是具有1至4个碳原子的烷基，X是氟或OR 1， R1是碳原子数2〜4的烷基，碳原子数2〜4的单羟基烷基或碳原子数3〜4的二羟基烷基，作为成色剂物质的生理学耐受性水溶性盐; 和0.1至6.1重量％的成色剂物质和至少一种显影剂物质的总量。显影剂物质可以是1,4-二氨基苯，2,5-二氨基甲苯，2,5-二氨基苄醇，2-（2'-羟乙基）-1,4-二氨基苯，4-氨基苯酚，4-氨基-3-甲基苯酚，4-氨基-2-甲氧基甲基苯酚，4-氨基-2-乙氧基 - 甲基苯酚和四氨基间二嘧啶及其生理上耐受的水溶性盐。本发明还涉及某些新的取代的2-烷基-5-氨基苯酚，包括5-氨基-4-乙氧基-2-甲基苯酚，5-氨基-4-（2'-羟乙基）氧基-2-甲基苯酚和5-氨基-2 - 乙基-4-氟苯酚。

8. 发明授权

US5246019A Process for bleaching hair under the influence of light 失效
标题翻译：在光影响下漂白发型的过程
公开(公告)号：US5246019A
公开(公告)日：1993-09-21
申请号：US691051
申请日：1991-06-24
申请人： Robin E. Godfrey , Thomas Clausen , Wolfgang R. Balzer
发明人： Robin E. Godfrey , Thomas Clausen , Wolfgang R. Balzer
IPC分类号： A45D7/04 , A45D19/00 , A45D19/02 , A45D24/00 , A45D24/10 , A61K8/00 , A61K8/02 , A61K8/33 , A61K8/34 , A61K8/35 , A61K8/36 , A61K8/368 , A61K8/41 , A61N5/06 , A61Q5/08
CPC分类号： A45D19/00 , A45D19/02 , A45D24/10 , A61K8/02 , A61N5/0617 , A61Q5/08 , A45D2019/0066 , A61K2800/434 , A61N5/062
摘要： The process for bleaching hair using light includes first, applying a sufficient quantity of a composition containing at least one optical photosensitizer and a compound capable of providing a hydrogen radical to strands of the hair to be bleached and allowing the composition to act for up to 60 minutes on those strands; then, irradiating them with light of a wavelength or wavelengths selected from visible and ultraviolet wavelength ranges capable of activating the at least one optical photosensitizer and having an intensity sufficient for bleaching them, and subsequently rinsing and drying the bleached hair. This process does not require excess hydrogen peroxide and is thus particularly gentle to the hair.
摘要翻译： PCT No.PCT / EP90 / 01917 371日期1991年6月24日 102（e）1991年6月24日PCT 1990年10月26日PCT PCT。出版物WO91 / 06279 日期：1991年5月16日。使用光漂白毛发的方法首先应用足量的含有至少一种光学光敏剂和能够提供氢自由基的化合物的组合物，所述化合物能够将待漂白的毛发的链条提供，在这些线上行动长达60分钟; 然后用选自能够激活至少一种光学光敏剂并且具有足以使其漂白的强度的可见光和紫外线波长范围的波长或波长的光照射，随后漂洗和干燥漂白的头发。该方法不需要过量的过氧化氢，因此对头发特别柔和。

9. 发明授权

US5674476A Process for making a persulfate-containing granulate for decolorizing or bleaching hair 失效
标题翻译：制造含过硫酸盐的颗粒以脱色或漂白毛发的方法
公开(公告)号：US5674476A
公开(公告)日：1997-10-07
申请号：US612533
申请日：1996-03-08
申请人： Thomas Clausen , Wolfgang R. Balzer , Volker Port , Jolanthe Kujawa
发明人： Thomas Clausen , Wolfgang R. Balzer , Volker Port , Jolanthe Kujawa
IPC分类号： A61K8/00 , A45D19/00 , A61K8/04 , A61K8/21 , A61K8/34 , A61K8/86 , A61Q5/08 , B01J2/10 , C08L39/06 , C08L71/02 , A61K7/135
CPC分类号： A61Q5/08 , A61K8/0275 , A61K2800/51
摘要： The method of making a granulate composition for decolorizing or bleaching hair consists of preparing a powdery mixture consisting of from 30 to 65% by weight of one or more inorganic persulfates, from 1 to 20% by weight of a binding agent selected from the group consisting of polyvinylpyrrolidone and polyethylene glycols having molecular weights of 200 to 10,000; of 15 to 45% by weight of at least one salt selected from the group consisting of alkali metal carbonates, alkaline earth metal carbonates, alkali metal hydrogen carbonates, alkali metal silicates and from 0.1 to 3 percent by weight of a chelating agent, and one or more auxiliary and additive substance selected from the group consisting of perfume oils, hair dyes, amphoteric, anionic, cationic and nonionic surface-active substances and water-soluble thickeners; after making this powdery mixture, spraying ethanol and/or isopropanol in a weight ratio from 13:1 to 4:1 (powdery mixture to alcohol) into the powdery mixture to form a moistened mixture; granulating the moistened mixture formed during the spraying in a granulating apparatus to form a moist granulate; and after the granulating, drying the moist granulate to remove the alcohol or alcohols and to form the granulate composition.
摘要翻译：制备用于脱色或漂白毛发的颗粒组合物的方法包括制备由30至65重量％的一种或多种无机过硫酸盐，1至20重量％的选自以下的粘合剂组成的粉末混合物：的聚乙烯吡咯烷酮和分子量为200至10,000的聚乙二醇; 15至45重量％的至少一种选自碱金属碳酸盐，碱土金属碳酸盐，碱金属碳酸氢盐，碱金属硅酸盐和0.1至3重量％螯合剂的盐，以及一种或更多选自香水油，染发剂，两性，阴离子，阳离子和非离子表面活性物质和水溶性增稠剂的辅助和添加剂物质; 在制备该粉末混合物之后，将重量比为13:1至4:1的乙醇和/或异丙醇（粉末混合物至醇）喷入粉末混合物中以形成润湿的混合物; 将在喷雾期间形成的润湿混合物造粒在造粒设备中以形成湿颗粒; 在造粒后，干燥湿颗粒以除去醇或醇并形成颗粒组合物。

10. 发明授权

US5430159A N-phenylaminopyrazole derivatives as well as composition and process for the dyeing of hair 失效
标题翻译： N-苯基氨基吡唑衍生物以及头发染色的组成和方法
公开(公告)号：US5430159A
公开(公告)日：1995-07-04
申请号：US244069
申请日：1994-05-09
申请人： Hans Neunhoeffer , Stefan Gerstung , Thomas Clausen , Wolfgang R. Balzer
发明人： Hans Neunhoeffer , Stefan Gerstung , Thomas Clausen , Wolfgang R. Balzer
IPC分类号： A61K8/00 , A61K8/49 , A61Q5/10 , C07D231/38 , C09B57/00 , D06P3/08 , A61K7/13
CPC分类号： A61Q5/10 , A61K8/494 , C07D231/38
摘要： The hair dye composition includes at least one N-phenylaminopyrazole compound of the formula (V) ##STR1## wherein R.sup.1 is hydrogen, an alkyl group having from one to four carbon atoms or a hydroxyalkyl group having from two to four carbon atoms; R.sup.2 and R.sup.3 are each independently either a hydrogen, an amino groups or an alkyl group having from one to four carbon atoms; and R.sup.4 is hydrogen, an alkyl group having from one to four carbon atoms, an alkoxy group having from one to four carbon atoms or a halogen; and at least one conventional ingredient for hair dye compositions selected from the group consisting of emollients; preservatives; perfume oils; solvents; anionic, cationic, amphoteric and nonionic surfactants; thickeners; starch derivatives; cellulose derivatives; petrolatum; paraffin oil; fatty acids; conditioners; lanolin derivatives; cholesterol; pantothenic acid and betaines.
摘要翻译：染发剂组合物包含至少一种式（V）的N-苯基氨基吡唑化合物其中R1是氢，具有1-4个碳原子的烷基或具有2-4个碳原子的羟基烷基 ; R2和R3各自独立地为氢，氨基或具有1-4个碳原子的烷基; R4是氢，具有1-4个碳原子的烷基，具有1-4个碳原子的烷氧基或卤素; 和至少一种用于染发组合物的常规成分，其选自润肤剂; 防腐剂香水油; 溶剂阴离子，阳离子，两性和非离子表面活性剂; 增稠剂淀粉衍生物; 纤维素衍生物; 凡士林石蜡油; 脂肪酸; 调理器羊毛脂衍生物; 胆固醇; 泛酸和甜菜碱。

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