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    • 4. 发明授权
    • Dishwashing detergent compositions containing mixtures or crystallinity-disrupted surfactants
    • 含有混合物或结晶破坏的表面活性剂的餐具洗涤剂组合物
    • US06774099B1
    • 2004-08-10
    • US09889632
    • 2001-07-19
    • Jeffrey John ScheibelThomas Anthony CripeKevin Lee KottDaniel Stedman ConnorJames Charles Theophile Roger Burckett-St. LaurentPhillip Kyle VinsonWilliam Michael ScheperChandrika Kasturi
    • Jeffrey John ScheibelThomas Anthony CripeKevin Lee KottDaniel Stedman ConnorJames Charles Theophile Roger Burckett-St. LaurentPhillip Kyle VinsonWilliam Michael ScheperChandrika Kasturi
    • C11D1700
    • C11D3/0084C11D1/22C11D1/75C11D1/83C11D3/044C11D3/046C11D3/30C11D3/38618C11D3/38627
    • A hand dishwashing compositions comprising; a) about 0.1% to about 99.9% by weight of said composition of an alkylarylsulfonate surfactant system comprising from about 10% to about 100% by weight of said surfactant system of two or more crystallinity-disrupted alkylarylsulfonate surfactants of formula (B—Ar—D)a(Mq+)b wherein D is SO3—, M is a cation or cation mixture, q is the valence of said cation, a and b are numbers selected such that said composition is electroneutral; Ar is selected from benzene, toluene, and combinations thereof; and B comprises the sum of at least one primary hydrocarbyl moiety containing from 5 to 20 carbon atoms and one or more crystallinity-disrupting moieties, wherein said crystallinity-disrupting moieties interrupt or branch from said hydrocarbyl moiety; and wherein said alkylarylsulfonate surfactant system has crystallinity disruption to the extent that its Sodium Critical Solubility Temperature, as measured by the CST Test, is no more than about 40° C.; and wherein further said alkylarylsulfonate surfactant system has at least one of the following properties: percentage biodegradation, as measured by the modified SCAS test, that exceeds tetrapropylene benzene sulfonate; and weight ratio of nonquaternary to quaternary carbon atoms in B of at least about 5:1; and b) from about 0.00001% to about 99.9% by weight of said composition of a conventional hand dishwashing adjunct; c) from about 0.01% to about 7% by weight of composition of a divalent ion selected from the group consisting of magnesium, calcium and mixtures thereof.
    • 一种手洗餐具组合物,其包含: a)约0.1重量%至约99.9重量%的所述组合物的烷基芳基磺酸盐表面活性剂体系,其包含约10重量%至约100重量%的所述表面活性剂体系的两种或更多种结晶度破坏的烷基芳基磺酸盐表面活性剂(B-Ar- D)a(M )b其中D是SO 3 - ,M是阳离子或阳离子混合物,q是所述阳离子的化合价,a和b是选择的数字,使得所述组合物是电中性的; Ar选自苯,甲苯及其组合; 和B包含至少一个含有5至20个碳原子的一级烃基部分和一种或多种结晶破坏部分的总和,其中所述结晶破坏部分中断或从所述烃基部分分支; 并且其中所述烷基芳基磺酸盐表面活性剂体系具有结晶度破坏程度,其通过CST试验测量的其钠临界溶解度温度不超过约40℃; 并且其中所述烷基芳基磺酸盐表面活性剂体系具有以下特性中的至少一个:通过改性SCAS测试测量的超过四丙烯苯磺酸盐的百分比生物降解; 并且B中非季铵碳原子的重量比至少约为5:1; 和b)所述组合物的常规手洗餐具辅料的约0.00001重量%至约99.9重量% c)约0.01重量%至约7重量%的组合物,选自镁,钙及其混合物的二价离子。