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1. 发明授权

US07683214B2 Method of producing benzophenoneimines 有权
标题翻译：生产二苯甲酮亚胺的方法
公开(公告)号：US07683214B2
公开(公告)日：2010-03-23
申请号：US12282277
申请日：2007-03-01
申请人： Thilo Hahn , Frank Haese , Ulrich Köhler , Ekkehard Schwab , Johann-Peter Melder , Jan Eberhardt
发明人： Thilo Hahn , Frank Haese , Ulrich Köhler , Ekkehard Schwab , Johann-Peter Melder , Jan Eberhardt
IPC分类号： C07C249/02
CPC分类号： C07C249/02 , C07C251/16
摘要： A process for the preparation of benzophenonimine (BPI) of the general formula I where R1 and R2 are C1- to C4-alkoxy, C1- to C2-alkylamine and C2- to C4-dialkylamine and m and n are integers from 0 to 5 and R1 and R2, independently of one another, may be identical or different, by reacting benzophenone (BP) of the general formula II where R1, R2, m and n have the abovementioned meanings, in ammonia and in the presence of titanium dioxide, the titanium dioxide being present substantially in the anatase modification.
摘要翻译：制备通式I的二苯甲酮亚胺（BPI）的方法，其中R 1和R 2是C 1 -C 4 - 烷氧基，C 1至C 2 - 烷基胺和C 2 -C 4 - 二烷基胺，m和n是0至5的整数并且R 1和R 2可以相同或不同，通过使其中R1，R2，m和n具有上述含义的通式II的二苯甲酮（BP）在氨和二氧化钛存在下反应，二氧化钛基本上存在锐钛矿改性。

2. 发明申请

US20090093654A1 METHOD OF PRODUCING BENZOPHENONEIMINES 有权
标题翻译：生产苯并噻吩酮的方法
公开(公告)号：US20090093654A1
公开(公告)日：2009-04-09
申请号：US12282277
申请日：2007-03-01
申请人： Thilo Hahn , Frank Haese , Ulrich Koehler , Ekkehard Schwab , Johann-Peter Melder , Jan Eberhardt
发明人： Thilo Hahn , Frank Haese , Ulrich Koehler , Ekkehard Schwab , Johann-Peter Melder , Jan Eberhardt
IPC分类号： C07C251/24
CPC分类号： C07C249/02 , C07C251/16
摘要： A process for the preparation of benzophenonimine (BPI) of the general formula I where R1 and R2 are C1- to C4-alkoxy, C1- to C2-alkylamine and C2- to C4-dialkylamine and m and n are integers from 0 to 5 and R1 and R2, independently of one another, may be identical or different, by reacting benzophenone (BP) of the general formula II where R1, R2, m and n have the abovementioned meanings, in ammonia and in the presence of titanium dioxide, the titanium dioxide being present substantially in the anatase modification.
摘要翻译：制备通式I的二苯甲酮亚胺（BPI）的方法，其中R 1和R 2是C 1 -C 4 - 烷氧基，C 1至C 2 - 烷基胺和C 2 -C 4 - 二烷基胺，m和n是0至5的整数并且R 1和R 2可以相同或不同，通过使其中R1，R2，m和n具有上述含义的通式II的二苯甲酮（BP）在氨和二氧化钛存在下反应，二氧化钛基本上存在锐钛矿改性。

3. 发明授权

US08017808B2 Process for preparing an amine 有权
标题翻译：制备胺的方法
公开(公告)号：US08017808B2
公开(公告)日：2011-09-13
申请号：US12293609
申请日：2007-03-13
申请人： Jan Eberhardt , Bram Willem Hoffer , Frank Haese , Johann-Peter Melder , Bernd Stein , Michael Stang , Thomas Hill , Ekkehard Schwab
发明人： Jan Eberhardt , Bram Willem Hoffer , Frank Haese , Johann-Peter Melder , Bernd Stein , Michael Stang , Thomas Hill , Ekkehard Schwab
IPC分类号： C07C209/16
CPC分类号： C07C209/26 , C07C2601/14 , C07D295/023 , C07C211/35 , C07C211/08
摘要： A process for preparing an amine by reacting an aldehyde and/or ketone with hydrogen and a nitrogen compound selected from the group of primary and secondary amines in the presence of a heterogeneous catalyst, wherein the catalyst is a coated catalyst which comprises at least one metal of group VIII of the Periodic Table of the Elements as a hydrogenating metal and additionally a promoter on an oxidic support, at least 80% of the metal of group VIII of the Periodic Table of the Elements being present in a layer between the surface of the catalyst and a penetration depth which is not more than 80% of the radius of the catalyst, calculated from the surface of the catalyst.
摘要翻译：一种通过在多相催化剂存在下使醛和/或酮与氢和选自伯胺和仲胺的氮化合物反应制备胺的方法，其中催化剂是包含至少一种金属作为氢化金属的元素周期表第Ⅷ族，另外是氧化载体上的助催化剂，元素周期表第VIII族金属的至少80％存在于催化剂和渗透深度不超过催化剂半径的80％，由催化剂的表面计算。

4. 发明申请

US20090082562A1 PROCESS FOR PREPARING AN AMINE 有权
标题翻译：制备胺的方法
公开(公告)号：US20090082562A1
公开(公告)日：2009-03-26
申请号：US12293609
申请日：2007-03-13
申请人： Jan Eberhardt , Bram Willem Hoffer , Frank Haese , Johann-Peter Melder , Bernd Stein , Michael Stang , Thomas Hill , Ekkehard Schwab
发明人： Jan Eberhardt , Bram Willem Hoffer , Frank Haese , Johann-Peter Melder , Bernd Stein , Michael Stang , Thomas Hill , Ekkehard Schwab
IPC分类号： C07D295/033
CPC分类号： C07C209/26 , C07C2601/14 , C07D295/023 , C07C211/35 , C07C211/08
摘要： A process for preparing an amine by reacting an aldehyde and/or ketone with hydrogen and a nitrogen compound selected from the group of primary and secondary amines in the presence of a heterogeneous catalyst, wherein the catalyst is a coated catalyst which comprises at least one metal of group VIII of the Periodic Table of the Elements as a hydrogenating metal and additionally a promoter on an oxidic support, at least 80% of the metal of group VIII of the Periodic Table of the Elements being present in a layer between the surface of the catalyst and a penetration depth which is not more than 80% of the radius of the catalyst, calculated from the surface of the catalyst.
摘要翻译：一种通过在多相催化剂存在下使醛和/或酮与氢和选自伯胺和仲胺的氮化合物反应制备胺的方法，其中催化剂是包含至少一种金属元素周期表第VIII族作为氢化金属，另外是氧化载体上的助催化剂，元素周期表第VIII族金属的至少80％存在于催化剂和渗透深度不超过催化剂半径的80％，由催化剂的表面计算。

5. 发明授权

US08734617B2 Process for preparing N,N-dimethylaminoethoxyethanol 有权
标题翻译：制备N，N-二甲基氨基乙氧基乙醇的方法
公开(公告)号：US08734617B2
公开(公告)日：2014-05-27
申请号：US13421249
申请日：2012-03-15
申请人： Frank-Friedrich Pape , Alfred Krause , Johann-Peter Melder , Bernd Stein , Joachim-Thierry Anders , Frank Haese
发明人： Frank-Friedrich Pape , Alfred Krause , Johann-Peter Melder , Bernd Stein , Joachim-Thierry Anders , Frank Haese
IPC分类号： B01D3/34
CPC分类号： C07C213/04 , B01J2219/00006 , C07C217/08
摘要： Processes comprising: (a) reacting dimethylamine and ethylene oxide to form a product mixture comprising N,N-dimethylethanolamine and N,N-dimethylaminoethoxyethanol; (b) distilling the product mixture to obtain a bottom fraction comprising N,N-dimethylaminoethoxyethanol; and (c) distilling the bottom fraction to separate at least a portion of the N,N-dimethylaminoethoxyethanol from the bottom fraction; and apparatus for carrying out said processes.
摘要翻译：方法包括：（a）使二甲胺和环氧乙烷反应以形成包含N，N-二甲基乙醇胺和N，N-二甲基氨基乙氧基乙醇的产物混合物; （b）蒸馏产物混合物以获得包含N，N-二甲基氨基乙氧基乙醇的底部馏分; 和（c）蒸馏塔底部分以从底部馏分分离至少一部分N，N-二甲基氨基乙氧基乙醇; 以及用于执行所述处理的装置。

6. 发明申请

US20080200726A1 Method For the Continuous Production of an Amine 有权
标题翻译：连续生产胺的方法
公开(公告)号：US20080200726A1
公开(公告)日：2008-08-21
申请号：US11993891
申请日：2006-06-21
申请人： Frank Haese , Joachim Wulff-Doring , Ulrich Kohler , Peter Gaa , Frank-Friedrich Pape , Johann-Peter Melder , Manfred Julius
发明人： Frank Haese , Joachim Wulff-Doring , Ulrich Kohler , Peter Gaa , Frank-Friedrich Pape , Johann-Peter Melder , Manfred Julius
IPC分类号： C07C211/44
CPC分类号： C07C209/18 , Y02P20/582 , C07C211/45
摘要： Processes comprising: providing an aromatic alcohol; and reacting the aromatic alcohol with ammonia at a temperature of 80 to 350° C. in the presence of hydrogen and a heterogeneous catalyst to form a crude reaction product comprising a corresponding primary aromatic amine, wherein the heterogeneous catalyst comprises a catalytically active composition which, prior to reduction with hydrogen, comprises 90 to 99.8% by weight of zirconium dioxide (ZrO2), 0.1 to 5.0% by weight of an oxygen-comprising compound of palladium, and 0.1 to 5.0% by weight of an oxygen-comprising compound of platinum.
摘要翻译：方法包括：提供芳族醇; 并在80至350℃的温度下在氢气和非均相催化剂存在下使芳族醇与氨反应形成包含相应的伯芳族胺的粗反应产物，其中非均相催化剂包含催化活性组合物，在用氢还原之前，包含90-99.8重量％的二氧化锆（ZrO 2/2），0.1-5.0重量％的含氧化合物的钯和0.1-5.0重量％的含氧化合物的铂。

7. 发明授权

US07405327B2 Method for the continuous production of an amine 失效
标题翻译：连续生产胺的方法
公开(公告)号：US07405327B2
公开(公告)日：2008-07-29
申请号：US11596292
申请日：2005-05-04
申请人： Frank Haese , Arnd Bottcher , Bernd Stein , Wolfgang Reif , Johann-Peter Melder , Karl-Heinz Roβ , Heinz Rutter , Shelue Liang , Stefan Rittinger
发明人： Frank Haese , Arnd Bottcher , Bernd Stein , Wolfgang Reif , Johann-Peter Melder , Karl-Heinz Roβ , Heinz Rutter , Shelue Liang , Stefan Rittinger
IPC分类号： C07C209/26
CPC分类号： C07C209/26 , C07C209/16 , C07C213/02 , C07D295/027 , C07D295/03 , C07D295/088 , C08G59/50 , Y02P20/582 , C07C211/06 , C07C211/08 , C07C211/35 , C07C217/08
摘要： Process for the continuous preparation of an amine by reaction of a primary or secondary alcohol, aldehyde and/or ketone with hydrogen and a nitrogen compound selected from the group consisting of ammonia, primary and secondary amines at a temperature in the range from 60 to 300° C. in the presence of a copper-containing catalyst, wherein the catalytically active composition of the catalyst prior to reduction with hydrogen comprises from 20 to 85% by weight of aluminum oxide (Al2O3), zirconium dioxide (ZrO2), titanium dioxide (TiO2) and/or silicon dioxide (SiO2), from 1 to 70% by weight of oxygen-containing compounds of copper, calculated as CuO, from 0 to 50% by weight of oxygen-containing compounds of magnesium, calculated as MgO, oxygen-containing compounds of chromium, calculated as Cr2O3, oxygen-containing compounds of zinc, calculated as ZnO, oxygen-containing compounds of barium, calculated as BaO, and/or oxygen-containing compounds of calcium, calculated as CaO, and less than 30% by weight of oxygen-containing compounds of nickel, calculated as NiO, based on the oxygen-containing compounds of copper, calculated as CuO, and the reaction is carried out isothermally in the gas phase in a tube reactor.
摘要翻译：通过伯醇或仲醇，醛和/或酮与氢和选自氨，伯胺和仲胺的氮化合物在60至300℃的温度下反应来连续制备胺的方法在含铜催化剂存在下，其中催化剂在用氢还原之前的催化活性组合物包含20至85重量％的氧化铝（Al 2 O 3 > 3），二氧化锆（ZrO 2），二氧化钛（TiO 2）和/或二氧化硅（SiO 2）），1至70重量％的以CuO计的铜的含氧化合物，0至50重量％的以MgO计的含氧化合物的镁，含氧化合物的铬，其计算为Cr 以ZnO计算的含氧化合物锌，以BaO表示的含氧化合物的钡，以BaO计算， /或以CaO计的钙的含氧化合物，以NiO计，以CuO计的含铜化合物计，小于30重量％的含氧化合物的镍，反应为在管式反应器中在气相中等温进行。

8. 发明申请

US20090234163A1 Method for producing an ethylamine 失效
标题翻译：乙胺的制造方法
公开(公告)号：US20090234163A1
公开(公告)日：2009-09-17
申请号：US11908820
申请日：2006-03-14
申请人： Till Gerlach , Frank Haese , Anton Meier , Johann-Peter Melder , Heinz Rütter
发明人： Till Gerlach , Frank Haese , Anton Meier , Johann-Peter Melder , Heinz Rütter
IPC分类号： C07C209/16
CPC分类号： C07C209/16 , C07C211/05
摘要： Processes comprising: (a) providing a first reactant comprising a bioethanol; and (b) reacting the first reactant with a second reactant comprising a component selected from the group consisting of ammonia, primary amines, secondary amines and mixtures thereof, in the presence of hydrogen and a catalytically effective amount of a heterogeneous hydrogenation/dehydrogenation catalyst to form an ethylamine; wherein the catalyst has been activated at a temperature of 100 to 500° C. for at least 25 minutes; wherein prior to activation the catalyst comprises: (i) 20 to 65% by weight of a support material comprising one or both of zirconium dioxide (ZrO2) and aluminum oxide (Al2O3), (ii) 1 to 30% by weight of oxygen-comprising compounds of copper, calculated as CuO, and (iii) 21 to 70% by weight of oxygen-comprising compounds of nickel, calculated as NiO; and wherein after activation the catalyst has a CO uptake capacity of >110 μmol of CO/g of the catalyst.
摘要翻译：方法包括：（a）提供包含生物乙醇的第一反应物; 和（b）使第一反应物与包含选自氨，伯胺，仲胺及其混合物的组分的第二反应物在氢气和催化有效量的非均相氢化/脱氢催化剂存在下反应至形成乙胺; 其中所述催化剂已经在100至500℃的温度下活化至少25分钟; 其中在活化之前，催化剂包括：（i）20至65重量％的包含二氧化锆（ZrO 2）和氧化铝（Al 2 O 3）中的一种或两种的载体材料，（ii）1至30重量％包括以CuO计算的铜化合物，和（iii）以NiO计算的含有21重量％的含氧化合物的镍; 并且其中在活化后，催化剂的CO吸收能力为> 110molol的CO / g催化剂。

9. 发明授权

US07550632B2 Methods of treating triethanolamine with acid components and basic components, and triethanolamine compositions containing the same 失效
标题翻译：用酸组分和碱性组分处理三乙醇胺的方法和含有它们的三乙醇胺组合物
公开(公告)号：US07550632B2
公开(公告)日：2009-06-23
申请号：US11661544
申请日：2005-08-04
申请人： Frank Haese , Johann-Peter Melder , Roman Dostalek , Manfred Julius
发明人： Frank Haese , Johann-Peter Melder , Roman Dostalek , Manfred Julius
IPC分类号： C07C209/84
CPC分类号： C07C213/10 , C07C215/08
摘要： Methods for improving color properties of triethanolamine, and triethanolamine compositions treated thereby, are disclosed, wherein the methods comprise: (a) providing a composition comprising triethanolamine; and (b) contacting the composition with an acid component and a basic component; wherein the acid component comprises an acid selected from the group consisting of phosphorous acid, hypophosphorous acid and mixtures thereof; and wherein the basic component comprises a compound selected from the group consisting of alkali metal hydroxides, alkaline earth metal hydroxides, ammonium hydroxides according to general formula (I), and mixtures thereof: [R1R2R3(2-hydroxyethyl)ammonium] hydroxide (I) wherein R1, R2 and R3 each independently represents a C1-30 alkyl or a C2-10 hydroxyalkyl; with the proviso that where the basic component comprises an alkali metal hydroxide, the molar ratio of acid component: basic component is 1:0.1 to 1:1, and where the basic component comprises an alkaline earth metal hydroxide, the molar ratio of acid component: basic component is 1:0.05 to 1:0.5.
摘要翻译：公开了用于改善三乙醇胺的颜色特性和由此处理的三乙醇胺组合物的方法，其中所述方法包括：（a）提供包含三乙醇胺的组合物; 和（b）使组合物与酸组分和碱性组分接触; 其中所述酸组分包含选自亚磷酸，次磷酸及其混合物的酸; 并且其中所述碱性组分包括选自碱金属氢氧化物，碱土金属氢氧化物，根据通式（I）的氢氧化铵的化合物及其混合物：<？在线公式描述=“在线公式“end =”lead“→> [R1R2R3（2-羟乙基）铵]氢氧化物（I）<？in-line-formula description =”In-line Formulas“end =”tail“？>其中R1，R2和R3 各自独立地表示C1-30烷基或C2-10羟基烷基; 条件是碱性成分含有碱金属氢氧化物时，酸成分：碱成分的摩尔比为1:0.1〜1:1，碱性成分为碱土金属氢氧化物时，酸成分基本成分为1:0.05〜1:0.5。

10. 发明申请

US20090076306A1 PROCESS FOR CONTINUOUS PREPARATION OF A PRIMARY AROMATIC AMINE 审中-公开
标题翻译：连续制备主要芳香胺的方法
公开(公告)号：US20090076306A1
公开(公告)日：2009-03-19
申请号：US12159099
申请日：2006-12-21
申请人： Frank Haese , Joachim Wulff-Doring , Ulrich Kohler , Peter Gaa , Frank-Friedrich Pape , Johann-Peter Melder , Manfred Julius
发明人： Frank Haese , Joachim Wulff-Doring , Ulrich Kohler , Peter Gaa , Frank-Friedrich Pape , Johann-Peter Melder , Manfred Julius
IPC分类号： C07C209/00 , C07C211/46
CPC分类号： C07C209/18 , C07C211/45
摘要： A process for continuously preparing a primary aromatic amine by reacting a corresponding cycloaliphatic alcohol with ammonia in the presence of hydrogen at a temperature in the range from 80 to 350° C. in the presence of a heterogeneous catalyst, wherein the catalytically active composition of the catalyst, before its reduction with hydrogen, comprises from 90 to 99.8% by weight of zirconium dioxide (ZrO2), from 0.1 to 5.0% by weight of oxygen compounds of palladium and from 0.1 to 5.0% by weight of oxygen compounds of platinum.
摘要翻译：一种在多异性催化剂存在下，在80-350℃的温度下，在氢气存在下使相应的脂环族醇与氨反应连续制备伯芳香胺的方法，其中催化活性组合物催化剂在用氢还原之前包含90-99.8重量％的二氧化锆（ZrO 2），0.1-5.0重量％的氧化合物钯和0.1-5.0重量％的氧化合物铂。

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