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    • 3. 发明授权
    • Method of producing elastomeric silicone foam
    • 生产弹性硅酮泡沫的方法
    • US4593049A
    • 1986-06-03
    • US787857
    • 1985-10-16
    • Therese M. BaumanChi-Long LeeJames A. Rabe
    • Therese M. BaumanChi-Long LeeJames A. Rabe
    • C08J9/02C08L83/04C08L83/07C08J9/14
    • C08J9/02C08J2383/04
    • A method of producing elastomeric silicone foams from a two-part system is disclosed. The method mixes the ingredients then allows a froth to form and cure at ambient temperature to an elastomeric silicone foam. The method mixes a vinyl-containing polydiorganosiloxane (1), a hydroxylated polydiorganosiloxane (2), a platinum catalyst (3), an organohydrogensiloxane (4) and a profoamer (5). The profoamer is a resinous, benzene-soluble organosiloxane copolymer consisting essentially of SiO.sub.4/2 units, silicone bonded hydroxyl groups, (CH.sub.3).sub.3 SiO.sub.1/2 units, and fluorine-containing units. An embodiment of the method includes a liquified blowing agent and stores the mixture under superatmospheric pressure, forming a foam by releasing the mixture to atmospheric pressure. Another embodiment includes an alcohol in the mixture to provide a foam of lower density. When lauryl alcohol is used and the alcohol is mixed with (1), (3), and (5) before (2) is admixed, the foam has a Bashore resiliency of less than 20.
    • 公开了一种从两部分系统生产弹性硅酮泡沫的方法。 该方法混合成分,然后允许泡沫在环境温度下形成和固化成弹性硅酮泡沫。 该方法混合含乙烯基的聚二有机硅氧烷(1),羟基化聚二有机硅氧烷(2),铂催化剂(3),有机氢硅氧烷(4)和溶剂(5)。 溶剂是基于SiO 4/2单元,硅氧烷键合羟基,(CH3)3SiO1 / 2单元和含氟单元组成的树脂,可溶于苯的有机硅氧烷共聚物。 该方法的一个实施方案包括液化发泡剂并将混合物储存在超大气压下,通过将混合物释放到大气压来形成泡沫。 另一个实施方案包括混合物中的醇以提供较低密度的泡沫。 当使用月桂醇并将醇与(1),(3)和(5)混合在(2)之前混合时,泡沫的底部弹性小于20。
    • 4. 发明授权
    • Method of producing elastomeric silicone foam
    • 生产弹性硅酮泡沫的方法
    • US4608396A
    • 1986-08-26
    • US825494
    • 1986-02-03
    • Therese M. BaumanChi-Long LeeJames A. Rabe
    • Therese M. BaumanChi-Long LeeJames A. Rabe
    • C08J9/02C08L83/05C08J9/14
    • C08J9/02C08J2383/04
    • A method of producing elastomeric silicone foams from a two-part system is disclosed. The method mixes the ingredients then allows a froth to form and cure at ambient temperature to an elastomeric silicone foam. The method mixes a vinyl-containing polydiorganosiloxane (1), a hydroxylated polydiorganosiloxane (2), a platinum catalyst (3), an organohydrogensiloxane (4) and a profoamer (5). The profoamer is a resinous, benzene-soluble organosiloxane copolymer consisting essentially of SiO.sub.4/2 units, silicone bonded hydroxyl groups, (CH.sub.3).sub.3 SiO.sub.1/2 units, and fluorine-containing units. An embodiment of the method includes a liquified blowing agent and stores the mixture under superatmospheric pressure, forming a foam by releasing the mixture to atmospheric pressure. Another embodiment includes an alcohol in the mixture to provide a foam of lower density. when lauryl alcohol is used and the alcohol is mixed with (1), (3), and (5) before (2) is admixed, the foam has a Bashore resiliency of less than 20.
    • 公开了一种从两部分系统生产弹性硅酮泡沫的方法。 该方法混合成分,然后允许泡沫在环境温度下形成和固化成弹性硅酮泡沫。 该方法混合含乙烯基的聚二有机硅氧烷(1),羟基化聚二有机硅氧烷(2),铂催化剂(3),有机氢硅氧烷(4)和溶剂(5)。 溶剂是基于SiO 4/2单元,硅氧烷键合羟基,(CH3)3SiO1 / 2单元和含氟单元组成的树脂,可溶于苯的有机硅氧烷共聚物。 该方法的一个实施方案包括液化发泡剂并将混合物储存在超大气压下,通过将混合物释放到大气压来形成泡沫。 另一个实施方案包括混合物中的醇以提供较低密度的泡沫。 当使用月桂醇并将醇与(1),(3)和(5)在(2)之前混合时混合时,泡沫的底部弹性小于20。
    • 5. 发明授权
    • Foamable polyorganosiloxane compositions
    • 可发泡聚有机硅氧烷组合物
    • US4572918A
    • 1986-02-25
    • US766621
    • 1985-08-19
    • Chi-Long LeeJames A. Rabe
    • Chi-Long LeeJames A. Rabe
    • C08J9/00C08J9/12C08J9/14C08J9/08C08J9/10
    • C08J9/0061C08J9/122C08J9/14C08J2207/04C08J2383/04C08J2483/00
    • Polyorganosiloxane foams exhibiting a desirable combination of low density, an average cell size below 4 mm. and an average cell concentration greater than 4 per linear centimeter are obtained by dispensing oxygen curable mercaptoorganosiloxane compositions containing a cobaltocene catalyst, a dispersed liquid or gaseous blowing agent and, as a foam stabilizer, a resinous organosiloxane copolymer comprising trimethylsiloxy units, SiO.sub.4/2 units and specified fluorine-containing organosiloxane units. The polymer portion of the composition includes at least one polyorganosiloxane containing at least 20 mole percent of dimethylsiloxane units and an average of more than 2 mercaptoalkyl or mercaptoalkylene groups per molecule.
    • 表现出低密度,平均泡孔尺寸低于4mm的期望组合的聚有机硅氧烷泡沫。 并且通过分配含有可待因催化剂,分散液体或气体发泡剂的氧可固化巯基有机硅氧烷组合物和作为泡沫稳定剂的包含三甲基甲硅烷氧基单元的SiO 4/2单元的树脂有机硅氧烷共聚物,获得大于4每线性厘米的平均电池浓度 并指定含氟有机硅氧烷单元。 组合物的聚合物部分包含至少一种含有至少20摩尔百分数的二甲基硅氧烷单元的聚有机硅氧烷,每个分子平均含有多于2个巯基烷基或巯基亚烷基。