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    • 2. 发明授权
    • Method of and apparatus for removing sulfur oxides from exhaust gases
formed by combustion
    • 从燃烧形成的废气中除去硫氧化物的方法和设备
    • US4247525A
    • 1981-01-27
    • US36683
    • 1979-05-07
    • Theodor Voeste
    • Theodor Voeste
    • B01D53/50B01D53/81C01D7/18C01F11/46F23J15/04C01B17/00
    • B01D53/501C01D7/18C01F11/46F23J15/04
    • A process for removing sulfur oxides from exhaust gas formed by combustion particularly exhaust gas from an electricity-generating power plant. The exhaust gas flows through a reaction zone which operates like a spray dryer. A purifying liquor consisting of an aqueous solution of sodium carbonate and/or sodium bicarbonate is sprayed into the reaction zone, in which the heat content of the exhaust gases causes virtually all of the water content of the purifying liquor to be evaporated. The exhaust gas is subsequently passed through a filter. Anhydrous solids are withdrawn from the reaction zone and the filter and contain at least 75% of sodium sulfite, sodium sulfate and sodium chloride and are processed to form sodium carbonate. To that end the solids are dissolved and sulfite is oxidized to form sulfate so that a solution that contains sodium sulfate and sodium chloride is formed. The sulfate is separated from that solution and the remaining solution is used in the recovery of sodium carbonate by the Solvay process.
    • 从燃烧特别是来自发电厂的废气形成的废气中除去硫氧化物的方法。 废气流过像喷雾干燥器那样工作的反应区。 将由碳酸钠和/或碳酸氢钠的水溶液组成的纯化液体喷射到反应区中,其中废气的热含量几乎导致纯化液的所有水含量蒸发。 废气随后通过过滤器。 从反应区和过滤器中取出无水固体,并含有至少75%的亚硫酸钠,硫酸钠和氯化钠,并加工形成碳酸钠。 为此,固体被溶解,亚硫酸盐被氧化形成硫酸盐,从而形成含有硫酸钠和氯化钠的溶液。 硫酸盐与该溶液分离,剩余的溶液用于通过溶剂法回收碳酸钠。