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1. 发明授权

US4170559A Hollow fiber separatory device 失效
标题翻译：中空纤维分离装置
公开(公告)号：US4170559A
公开(公告)日：1979-10-09
申请号：US783086
申请日：1977-03-31
申请人： Thaddeus F. Kroplinski , Barton C. Case
发明人： Thaddeus F. Kroplinski , Barton C. Case
IPC分类号： B01D63/02 , C08G18/10 , C08G18/12 , B01D31/00
CPC分类号： C08G18/10 , B01D63/023 , C08G18/12
摘要： A hollow fiber separatory device is provided wherein a polyurethane prepolymer is cross-linked or cured with an ester of a polyhydric alcohol which contains two or three hydroxyl groups, e.g., propylene glycol monoricinoleate, and an aliphatic acid of at least 12 carbon atoms and one or more epoxy and/or hydroxy groups per molecule.
摘要翻译：提供了一种中空纤维分离装置，其中聚氨酯预聚物与含有两个或三个羟基的多元醇的酯交联或固化，例如丙二醇单蓖麻醇酸酯和至少12个碳原子的脂族酸和一个或更多的环氧基和/或羟基。

2. 再颁专利

USRE31389E Non-wicking polyurethane casting systems 失效
标题翻译：非芯吸聚氨酯浇注系统
公开(公告)号：USRE31389E
公开(公告)日：1983-09-20
申请号：US298675
申请日：1981-09-02
申请人： Melvin Brauer , Barton C. Case , Thaddeus F. Kroplinski
发明人： Melvin Brauer , Barton C. Case , Thaddeus F. Kroplinski
IPC分类号： B01D63/02 , C08G18/10
CPC分类号： C08G18/10 , B01D63/023
摘要： A non-wicking polyurethane casting system has been developed which comprises the reaction product obtained by admixing a polyol containing N-N-N'-N'-tetrakis (2-hydroxypropyl) ethylene diamine, (hereafter referred to as QUADROL) with an isocyanate terminated polyurethane based prepolymer. This non-wicking casting system is useful as a potting compound in biomedical applications such as dialysis and hemoultrafiltration devices and the like.

3. 发明授权

US4267044A Thixotropic polyurethane compositions as sealants for membrane separatory devices 失效
标题翻译：触变性聚氨酯组合物作为膜分离装置的密封剂
公开(公告)号：US4267044A
公开(公告)日：1981-05-12
申请号：US894845
申请日：1978-04-10
申请人： Thaddeus F. Kroplinski , Barton C. Case
发明人： Thaddeus F. Kroplinski , Barton C. Case
IPC分类号： B01D63/14 , C08G18/10 , C08G18/12 , C08G18/80 , C08J3/24 , C08L75/04 , C09K3/10 , B01D31/00
CPC分类号： B01D63/023 , C08G18/10 , C08G18/12 , C08G18/8051
摘要： Novel thixotropic polyurethane compositions particularly useful as sealants for the edges of folded membrane separatory devices are provided which comprise;(a) a prepolymer comprising the reaction product of a polyol having a hydroxyl functionality of at least 2 with one mole per hydroxy group of said polyol of an organic diisocyanate; and(b) a crosslinking agent comprising a polyether polyol having a hydroxyl functionality of at least 2 and a primary amine-terminated polyether having an amine functionality of at least 2.To accelerate curing of the composition, the crosslinking agent can be modified by employing primary hydroxyl-terminated polyethers and/or adding hydroxyl-containing tertiary amines.
摘要翻译：提供特别用作折叠膜分离装置边缘的密封剂的新型触变性聚氨酯组合物，其包含：（a）包含羟基官能度至少为2的多元醇与有机二异氰酸酯的所述多元醇的每个羟基的摩尔数为1摩尔的反应产物的预聚物; 和（b）包含羟基官能度至少为2的聚醚多元醇和胺官能度至少为2的伯胺封端的聚醚的交联剂。为了加速组合物的固化，交联剂可以通过使用伯羟基封端的聚醚和/或加入含羟基的叔胺。

4. 发明授权

US4256617A Catalyzed non-toxic polyurethane forming compositions and separatory devices employing the same 失效
标题翻译：催化无毒的聚氨酯形成组合物和采用其的分离装置
公开(公告)号：US4256617A
公开(公告)日：1981-03-17
申请号：US90206
申请日：1979-11-01
申请人： Thaddeus F. Kroplinski , Barton C. Case
发明人： Thaddeus F. Kroplinski , Barton C. Case
IPC分类号： C08G18/10 , C08G18/12 , C08G18/16
CPC分类号： C08G18/168 , C08G18/10 , C08G18/12 , Y10S524/906
摘要： The present invention is directed to improvements in non-toxic polyurethane compositions and separatory devices employing the same, such as hollow fiber separatory devices intended to be used in biomedical applications. The separatory device employs at least one separatory membrane suitable for the intended end use application which is secured, potted or sealed in a housing using a cured flexible polyurethane composition. The improvement in the polyurethane composition employed in the separatory device is achieved by reacting at least one NCO-terminated prepolymer and at least one polyol in the presence of a ricinoleic acid reactive catalyst. The catalyst reduces the curing time of the polyurethane resin and because it is sufficiently reactive with the NCO-terminated prepolymer, it is incorporated into the structure of the polyurethane and cannot be released during operation of the separatory device.
摘要翻译：本发明涉及无毒聚氨酯组合物的改进和使用该组合物的分离装置，例如旨在用于生物医学应用的中空纤维分离装置。分离装置使用至少一种适用于预期最终用途应用的分离膜，其使用固化的柔性聚氨酯组合物固定，盆或密封在壳体中。在分离装置中使用的聚氨酯组合物的改进通过在蓖麻油酸反应催化剂存在下使至少一种NCO-封端的预聚物和至少一种多元醇反应来实现。该催化剂降低了聚氨酯树脂的固化时间，并且由于其与NCO封端的预聚物具有足够的反应性，所以其结合到聚氨酯的结构中，并且在分离装置的操作期间不能释放。

5. 发明授权

US4224164A Non-wicking polyurethane casting systems 失效
标题翻译：非芯吸聚氨酯浇注系统
公开(公告)号：US4224164A
公开(公告)日：1980-09-23
申请号：US953112
申请日：1978-10-20
申请人： Melvin Brauer , Barton C. Case , Thaddeus F. Kroplinski
发明人： Melvin Brauer , Barton C. Case , Thaddeus F. Kroplinski
IPC分类号： B01D63/02 , C08G18/10 , B01D31/00
CPC分类号： B01D63/023 , C08G18/10
摘要： A non-wicking polyurethane casting system has been developed which comprises the reaction product obtained by admixing a polyol containing N-N-N'-N'-tetrakis (2-hydroxypropyl) ethylene diamine, (hereafter referred to as QUADROL) with an isocyanate terminated polyurethane based prepolymer. This non-wicking casting system is useful as a potting compound in biomedical applications such as dialysis and hemoultrafiltration devices and the like.
摘要翻译：已经开发了一种非吸湿聚氨酯浇注体系，其包括通过将含有N，N'-N'-四（2-羟丙基）乙二胺（以下称为QUADROL）的多元醇与异氰酸酯封端的聚氨酯基于预聚物。这种非芯吸铸造系统可用作生物医学应用中的灌封化合物，例如透析和渗滤装置等。

6. 发明授权

US4281210A Electrical devices containing a grease compatible, mineral oil extended polyurethane 失效
标题翻译：含有润滑脂的电气设备，矿物油延长聚氨酯
公开(公告)号：US4281210A
公开(公告)日：1981-07-28
申请号：US27820
申请日：1979-04-06
申请人： Melvin Brauer , Thaddeus F. Kroplinski
发明人： Melvin Brauer , Thaddeus F. Kroplinski
IPC分类号： C08G18/36 , C08G18/69 , C08L75/04 , H01B3/30 , H01B7/28
CPC分类号： H01B3/302 , C08G18/36 , C08G18/69 , C08L75/04 , C10M2203/10 , C10M2203/102 , C10M2203/104 , C10M2203/106 , C10M2203/108 , Y10T428/2933 , Y10T428/294
摘要： A cured, cross-linked, mineral oil extended polyurethane which is non-spewing. The mineral oil extended polyurethane is further characterized by being grease compatible in that the tendency of the mineral oil to migrate is substantially reduced or eliminated. The mineral oil extended polyurethane is comprised of a defined polyurethane, mineral oil, and coupling agent. In other aspects, the present invention relates to a process for reclaiming or sealing an insulated electrical device and to an insulated electrical device which is formed by such process.
摘要翻译：固化的，交联的矿物油延长的聚氨酯是不喷出的。矿物油延长的聚氨酯的特征还在于与润滑脂相容，因为矿物油迁移的趋势显着降低或消除。矿物油延伸的聚氨酯由定义的聚氨酯，矿物油和偶联剂组成。在其他方面，本发明涉及一种用于回收或密封绝缘电气装置的方法以及由这种方法形成的绝缘电气装置。

7. 发明授权

US4171998A Method for decontaminating and sealing the interior spaces of an insulated electrical device utilizing mineral oil-extended polyurethanes 失效
标题翻译：使用矿物油延伸聚氨酯对绝缘电气设备的内部空间进行净化和密封的方法
公开(公告)号：US4171998A
公开(公告)日：1979-10-23
申请号：US728665
申请日：1976-09-30
申请人： Melvin Brauer , Thaddeus F. Kroplinski
发明人： Melvin Brauer , Thaddeus F. Kroplinski
IPC分类号： C08G18/69 , C08G18/75 , H01B3/30 , H02G1/16
CPC分类号： C08G18/755 , C08G18/69 , H01B3/302
摘要： This invention provides a method of sealing and purging contaminants from the internal free spaces of an insulated electrical device by forcing into said free spaces a low viscosity material that acts to displace fluid contaminants from within said free spaces. The material later cures in situ to form a hydrophobic seal with good electrical properties. Also disclosed herein is a method for rehabilitating waterlogged plastic insulated multiconductor communications cables of the type employed in telephone systems.
摘要翻译：本发明提供了一种从绝缘电气装置的内部自由空间中密封和清除污染物的方法，该方法通过将所述自由空间中的低粘度物质强制从而在所述自由空间内移动流体污染物。该材料随后在现场固化以形成具有良好电性能的疏水密封。本文还公开了一种用于恢复在电话系统中使用的防水塑料绝缘多导体通信电缆的方法。

8. 发明授权

US4125545A Stabilized diphenylmethane diisocyanate prepolymer 失效
标题翻译：稳定二苯甲烷二异氰酸酯预聚物
公开(公告)号：US4125545A
公开(公告)日：1978-11-14
申请号：US836834
申请日：1977-09-26
申请人： Thaddeus F. Kroplinski , Melvin Brauer
发明人： Thaddeus F. Kroplinski , Melvin Brauer
IPC分类号： C08G18/00 , C08G18/10 , C08G18/72 , C09F7/06 , C07C118/00 , C08L91/00
CPC分类号： C08G18/724 , C08G18/10
摘要： Liquid 4,4'diphenylmethane diisocyanate (MDI) prepolymers have been produced which remain fluid and do not crystallize at temperatures below 40.degree. F. These prepolymers comprise the reaction product of a polyol, 4,4'diphenylmethane diisocyanate (MDI) and an aliphatic and/or cycloaliphatic diisocyanate. The polyol employed is selected from the group consisting of castor oil, polyoxypropylene glycol, polyhydric alcohol mono- and di-esters of hydroxyacids of at least 12 carbon atoms and mixtures thereof.The reaction product contains the polyol in amount from about 10% to about 40%, the 4,4'diphenylmethane diisocyanate in amount from about 50% to about 70% and the aliphatic or cycloaliphatic isocyanate in amount from about 10% to about 20%. The prepolymer should be prepared such that the NCO/OH ratio should fall within the range of about 3 to about 7.
摘要翻译：已经制备了液体4,4'-二苯基甲烷二异氰酸酯（MDI）预聚物，其保持流体并且在低于40°F的温度下不结晶。这些预聚物包括多元醇，4,4'-二苯基甲烷二异氰酸酯（MDI）和脂族和/或脂环族二异氰酸酯。所使用的多元醇选自蓖麻油，聚氧丙烯二醇，至少12个碳原子的羟基酸的多元醇单酯和二酯及其混合物。

9. 发明授权

US4168258A Grease compatible, mineral oil extended polyurethane 失效
标题翻译：润滑脂相容，矿物油延长聚氨酯
公开(公告)号：US4168258A
公开(公告)日：1979-09-18
申请号：US877905
申请日：1978-02-15
申请人： Melvin Brauer , Thaddeus F. Kroplinski
发明人： Melvin Brauer , Thaddeus F. Kroplinski
IPC分类号： C08G18/00 , C08G18/36 , C08G18/69 , C08G18/75 , C08L7/00 , C08L21/00 , C08L75/00 , C08L75/04 , H01B3/30 , C08K5/01
CPC分类号： H01B3/302 , C08G18/36 , C08G18/69 , C08G18/75 , C08L75/04 , C10M2203/10 , C10M2203/102 , C10M2203/104 , C10M2203/106 , C10M2203/108
摘要： A cured, cross-linked, mineral oil extended polyurethane which is non-spewing. The mineral oil extended polyurethane is further characterized by being grease compatible in that the tendency of the mineral oil to migrate is substantially reduced or eliminated. The mineral oil extended polyurethane is comprised of a defined polyurethane, mineral oil and coupling agent. In other aspects, the present invention relates to a process for reclaiming or sealing an insulated electrical device and to an insulated electrical device which is formed by such process.
摘要翻译：固化的，交联的矿物油延长的聚氨酯是不喷出的。矿物油延长的聚氨酯的特征还在于与润滑脂相容，因为矿物油迁移的趋势显着降低或消除。矿物油膨胀聚氨酯由定义的聚氨酯，矿物油和偶联剂组成。在其他方面，本发明涉及一种用于回收或密封绝缘电气装置的方法以及由这种方法形成的绝缘电气装置。

10. 发明授权

US4231986A Grease compatible mineral oil extended polyurethane 失效
标题翻译：润滑脂相容矿物油延长聚氨酯
公开(公告)号：US4231986A
公开(公告)日：1980-11-04
申请号：US027819
申请日：1979-04-06
申请人： Melvin Brauer , Thaddeus F. Kroplinski
发明人： Melvin Brauer , Thaddeus F. Kroplinski
IPC分类号： C08K5/01 , H01B7/285 , B29H9/00
CPC分类号： H01B7/285 , C08K5/01 , C08K5/07 , C08K5/10 , C08K5/52
摘要： A cured, cross-linked, mineral oil extended polyurethane which is non-spewing. The mineral oil extended polyurethane is further characterized by being grease compatible in that the tendency of the mineral oil to migrate is substantially reduced or eliminated. The mineral oil extended polyurethane is comprised of a defined polyurethane, mineral oil, and coupling agent. In other aspects, the present invention relates to a process for reclaiming or sealing an insulated electrical device and to an insulated electrical device which is formed by such process.
摘要翻译：固化的，交联的矿物油延长的聚氨酯是不喷出的。矿物油延长的聚氨酯的特征还在于与润滑脂相容，因为矿物油迁移的趋势显着降低或消除。矿物油延伸的聚氨酯由定义的聚氨酯，矿物油和偶联剂组成。在其他方面，本发明涉及一种用于回收或密封绝缘电气装置的方法以及由这种方法形成的绝缘电气装置。

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