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    • 1. 发明授权
    • Polymer polyol composition, process for producing the same, and process for producing polyurethane resin
    • 聚合物多元醇组合物,其制造方法以及聚氨酯树脂的制造方法
    • US06624209B2
    • 2003-09-23
    • US10068182
    • 2002-02-06
    • Tetsuji KawamotoTomio KawazoeKiyoshi IkedaMunekazu SatakeFutoshi KitataniTsuyoshi TomosadaTakeshi FurutaTakayuki Tsuji
    • Tetsuji KawamotoTomio KawazoeKiyoshi IkedaMunekazu SatakeFutoshi KitataniTsuyoshi TomosadaTakeshi FurutaTakayuki Tsuji
    • C08G1863
    • C08F283/006C08F283/06C08G18/632C08G2101/00C08G2101/005C08G2101/0083
    • This invention provides a polymer polyol composition (I) comprising a polyol (A) and polymer particles (B) dispersed in (A), the polymer particles (B) being formed by polymerizing an ethylenically unsaturated compound (b) in a polyol, wherein the content of (B) in (I) is from 35 to 75 mass %, based on the mass of (I), and the amount of soluble polymers (P) dissolved in (A) is not more than 5 mass %, based on the mass of (A), and provides methods for producing the polymer polyol composition (I). Further, this invention provides a method for producing a foamed or non-foamed polyurethane resin, which method comprises reacting a polyol component with a polyisocyanate component in the presence or absence of a blowing agent, wherein the above polymer polyol composition is used at least as a portion of the polyol component. A polymer polyol having a low viscosity and excellent dispersion is stability is provided even when having a high concentration of polymer particles, and is used advantageously to produce polyurethane resins having excellent 25% ILD (hardness) and compression set, or foams thereof, with good operation efficiency.
    • 本发明提供一种包含分散在(A)中的多元醇(A)和聚合物颗粒(B))的聚合物多元醇组合物(I),聚合物颗粒(B)通过在多元醇中聚合烯属不饱和化合物(b)而形成,其中 基于(I)的质量,(I)中的(B)的含量为35〜75质量%,溶解在(A)中的可溶性聚合物(P)的量为5质量%以下 (A)的质量,并且提供了制备聚合物多元醇组合物(I)的方法。 此外,本发明提供一种发泡或非发泡聚氨酯树脂的制造方法,其特征在于,在发泡剂的存在或不存在下,使多元醇成分与多异氰酸酯成分反应,其中上述聚合物多元醇组合物至少使用 一部分多元醇组分。 具有低粘度和优异分散性的聚合物多元醇即使当具有高浓度聚合物颗粒时也是稳定的,并且有利地用于制备具有优异的25%ILD(硬度)和压缩永久变形或其泡沫的优异的聚氨酯树脂,具有良好的 运行效率。
    • 2. 发明授权
    • Polymer polyol composition, process for producing the same, and process for producing polyurethane resin
    • 聚合物多元醇组合物,其制造方法以及聚氨酯树脂的制造方法
    • US06756414B2
    • 2004-06-29
    • US10463644
    • 2003-06-17
    • Tetsuji KawamotoTomio KawazoeKiyoshi IkedaMunekazu SatakeFutoshi KitataniTsuyoshi TomosadaTakeshi FurutaTakayuki Tsuji
    • Tetsuji KawamotoTomio KawazoeKiyoshi IkedaMunekazu SatakeFutoshi KitataniTsuyoshi TomosadaTakeshi FurutaTakayuki Tsuji
    • C08G1810
    • C08G18/632C08F2/06C08F283/006C08F283/06C08G2101/00C08G2101/005C08G2101/0083
    • This invention provides a polymer polyol composition (I) comprising a polyol (A) and polymer particles (B) dispersed in (A), the polymer particles (B) being formed by polymerizing an ethylenically unsaturated compound (b) in a polyol, wherein the content of (B) in (I) is from 35 to 75 mass %, based on the mass of (I), and the amount of soluble polymers (P) dissolved in (A) is not more than 5 mass %, based on the mass of (A), and provides methods for producing the polymer polyol composition (I). Further, this invention provides a method for producing a foamed or non-foamed polyurethane resin, which method comprises reacting a polyol component with a polyisocyanate component in the presence or absence of a blowing agent, wherein the above polymer polyol composition is used at least as a portion of the polyol component. A polymer polyol having a low viscosity and excellent dispersion stability is provided even when having a high concentration of polymer particles, and is used advantageously to produce polyurethane resins having excellent 25% ILD (hardness) and compression set, or foams thereof, with good operation efficiency.
    • 本发明提供一种包含分散在(A)中的多元醇(A)和聚合物颗粒(B))的聚合物多元醇组合物(I),聚合物颗粒(B)通过在多元醇中聚合烯属不饱和化合物(b)而形成,其中 基于(I)的质量,(I)中的(B)的含量为35〜75质量%,溶解在(A)中的可溶性聚合物(P)的量为5质量%以下 (A)的质量,并且提供了制备聚合物多元醇组合物(I)的方法。 此外,本发明提供一种发泡或非发泡聚氨酯树脂的制造方法,其特征在于,在发泡剂的存在或不存在下,使多元醇成分与多异氰酸酯成分反应,其中上述聚合物多元醇组合物至少使用 一部分多元醇组分。 即使具有高浓度的聚合物颗粒,也提供了具有低粘度和优异的分散稳定性的聚合物多元醇,并且有利地生产具有优异的25%ILD(硬度)和压缩永久变形或其泡沫的优异的操作的聚氨酯树脂 效率。
    • 4. 发明授权
    • Epoxy curing agent and one-component (type) epoxy resin composition
    • 环氧固化剂和单组分(型)环氧树脂组合物
    • US6040398A
    • 2000-03-21
    • US146075
    • 1998-09-02
    • Toshihiko KinshoMunekazu SatakeTadakazu Miyazaki
    • Toshihiko KinshoMunekazu SatakeTadakazu Miyazaki
    • C08G59/50C08G65/333C08L63/00C09K3/10C08F283/000
    • C09K3/10C08G59/5046C08G65/33306C08L63/00C09K2200/0647
    • An epoxy curing agent comprising a heterocycle-containing compound having a backbone chain selected from the group consisting of polyether, polyvinyl, polyester, polyamide, polycarbonate, and novolac chains and at least two heterocyclic groups of the following general formula (1) as side chains, and a one-component (type) epoxy resin composition comprising said epoxy curing agent and a polyepoxy compound, ##STR1## wherein R.sub.1 and R.sup.2 may be the same or different and each represents hydrogen, straight-chain or branched C.sub.1 to C.sub.6 alkyl or alkenyl, or C.sub.6 to C.sub.8 aryl; or R.sub.1 and R.sup.2, taken together with the adjacent carbon atom, represents C.sub.5 to C.sub.7 cycloalkyl; R.sup.3 represents C.sub.1 to C.sub.10 alkylene. The object is to provide the one-component (type) epoxy resin composition having fast-curing feature, an improved storage stability, and an improved degree of workability.
    • 环氧固化剂,其包含具有选自聚醚,聚乙烯,聚酯,聚酰胺,聚碳酸酯和酚醛清漆链的主链的含杂环化合物和作为侧链的以下通式(1)的至少两个杂环基 以及包含所述环氧固化剂和聚环氧化合物的单组分(型)环氧树脂组合物,其中R 1和R 2可以相同或不同,各自表示氢,直链或支链C 1至C 6烷基或链烯基,或 C6〜C8芳基; 或R 1和R 2与相邻碳原子一起表示C5至C7环烷基; R3表示C1〜C10亚烷基。 本发明的目的是提供具有快速固化特征的单组分(型)环氧树脂组合物,改进的储存稳定性和改进的可加工性程度。
    • 6. 发明授权
    • Toner and method for image formation
    • 调色剂和成像方法
    • US06461782B1
    • 2002-10-08
    • US09623740
    • 2000-11-22
    • Shinya SasadaHideo NakanishiMunekazu SatakeNobuaki KameiMasakazu Iwata
    • Shinya SasadaHideo NakanishiMunekazu SatakeNobuaki KameiMasakazu Iwata
    • G03G9087
    • G03G9/08791G03G9/08793G03G9/08795G03G9/08797G03G13/20
    • A toner with a glass transition point (Tg) before curing of not lower than 35° C., said toner comprising: a toner binder composed of a resin (I) selected from the group consisting of a cation-polymerizable thermoplastic resin (A) and a radical-polymerizable thermoplastic resin (B); and a colorant. The resins making up the toner binder are polymerizable ones and are cured in fixing the image on the support so that the number average molecular weight can be increased after the fixing step. That is, a toner binder with a low number average molecular weight can be used, and fixed at a low temperature and with low energy. Because of the low number average molecular weight, the toner is low in viscosity and excellent in gloss development and can produce high-quality multi-color images. Since the toner polymerizes and cures to increase in number average molecular weight while fixing, the hot offset is hardly caused, with a high fixing strength and an excellent wear resistance developed.
    • 一种固化前的玻璃化转变温度(Tg)不低于35℃的调色剂,所述调色剂包括:由选自阳离子聚合性热塑性树脂(A)的树脂(I)组成的调色剂粘合剂, 和可自由基聚合的热塑性树脂(B); 和着色剂。 构成调色剂粘合剂的树脂是可聚合的树脂,并且在将图像固定在载体上时固化,使得在固定步骤之后可以增加数均分子量。 也就是说,可以使用具有低数均分子量的调色剂粘合剂,并且在低温和低能量下固定。 由于数均分子量低,调色剂的粘度低,光泽发展优异,可以制造出高质量的多色图像。 由于调色剂在固定时聚合和固化以增加数均分子量,所以难以产生热偏移,具有高定影强度和优异的耐磨性。
    • 8. 发明授权
    • Epoxy curing agent and one-component (type) epoxy resin composition
    • 环氧固化剂和单组分(型)环氧树脂组合物
    • US5837785A
    • 1998-11-17
    • US683564
    • 1996-07-12
    • Toshihiko KinshoMunekazu SatakeTadakazu Miyazaki
    • Toshihiko KinshoMunekazu SatakeTadakazu Miyazaki
    • C08G59/50C08G65/333C08L63/00C09K3/10C08F283/00
    • C09K3/10C08G59/5046C08G65/33306C08L63/00C09K2200/0647
    • An epoxy curing agent comprising a heterocycle-containing compound having a backbone clain selected from the group consisting of polyether, polyvinyl, polyester, polyamide, polycarbonate, and novolac chains and at least two heterocyclic groups of the following general formula (1) as side chains, and a one-component (type) epoxy resin composition comprising said epoxy curing agent and a polyepoxy compound, ##STR1## wherein R.sup.1 and R.sup.2 may be the same or different and each represents hydrogen, straight-chain or branched C.sub.1 to C.sub.6 alkyl or alkenyl, or C.sub.6 to C.sub.8 aryl; or R.sup.1 and R.sup.2, taken together with the adjacent carbon atom, represents C.sub.5 to C.sub.7 cycloalkyl; R.sup.3 represents C.sub.1 to C.sub.10 alkylene. The object is to provide the one-component (type) epoxy resin composition having fast-curing feature, an improved storage stability, and an improved degree of workability.
    • 一种环氧固化剂,其包含具有选自聚醚,聚乙烯,聚酯,聚酰胺,聚碳酸酯和酚醛清漆链的骨架骨架的含杂环化合物和作为侧链的以下通式(1)的至少两个杂环基 ,以及包含所述环氧固化剂和聚环氧化合物的单组分(型)环氧树脂组合物,其中R1和R2可以相同或不同,各自表示氢,直链或支链C1至 C6烷基或烯基,或C6至C8芳基; 或R 1和R 2与相邻碳原子一起表示C5至C7环烷基; R3表示C1〜C10亚烷基。 本发明的目的是提供具有快速固化特征的单组分(型)环氧树脂组合物,改进的储存稳定性和改进的可加工性程度。
    • 9. 发明授权
    • Water absorbing agent, process for its production, and absorbers and absorbent articles made by using the agent
    • 吸水剂,其生产方法,以及使用该试剂制成的吸收剂和吸收制品
    • US07361712B2
    • 2008-04-22
    • US10495174
    • 2002-11-18
    • Munekazu SatakeYoshihisa Ohta
    • Munekazu SatakeYoshihisa Ohta
    • C08F20/06C08F120/02
    • C08L101/14A61L15/24A61L15/60C08F2/44C08J3/24C08J2300/14C08L29/04
    • A water absorbing agent comprising a crosslinked polymer including a water-soluble vinyl monomer (a1) and/or a vinyl monomer (a2) that is formed into the water-soluble vinyl monomer (a1) by hydrolysis, and a crosslinking agent (b) as an essential constituting unit, wherein the following formulae (1) and (2) are satisfied; a process for its production, and absorbers and absorbent articles made by the water absorbing agent. (Y)≧−1.14(X)+69.5   (1) (X)=((x1)2+4×(x2)2)1/2   (2) wherein (x1) denotes a water-retention amount (g/g) of the water absorbing agent after being soaked in a physiological saline for one hour; (x2) denotes an absorption amount (g/g) of the water absorbing agent after being soaked in a physiological saline under loading of 0.9 psi for one hour; and (Y) denotes a liquid permeation speed (ml/min) of a physiological saline after the water absorbing agent is soaked in a physiological saline under loading of 0.3 psi for one hour. The water-absorbing agent enables easy production of absorbent articles exhibiting high absorption performance in any state, and is suitable for use in disposable diapers, sanitary napkins, and other sanitary goods.
    • 包含通过水解形成在水溶性乙烯基单体(a1)中的水溶性乙烯基单体(a1)和/或乙烯基单体(a2)的交联聚合物和交联剂(b)的吸水剂, 作为基本构成单元,其中满足下式(1)和(2); 其制造方法,由吸水剂制成的吸收体和吸收性物品。 (Y)> = - 1.14(X)+69.5(1)<?in-line-formula description =“In-line-formula description =”In-line-formula (X)=((x1))<2> + 4x(公式“end =”tail“?> <?in-line-formula description =”In-line Formulas“end =”lead“ (2)<?in-line-formula description =“In-line Formulas”end =“tail”?>其中(x1) 表示在生理盐水中浸泡1小时后的吸水剂的保水量(g / g) (x2)表示在0.9psi负载下在生理盐水中浸泡1小时后吸水剂的吸收量(g / g) 和(Y)表示在0.3psi负载下将吸水剂浸泡在生理盐水中1小时后的生理盐水的液体渗透速度(ml / min)。 吸水剂能够容易地生产在任何状态下表现出高吸收性能的吸收制品,并且适用于一次性尿布,卫生巾和其它卫生用品。
    • 10. 发明授权
    • Charge controller, toner binder composition and electrophotographic toner
    • 充电控制器,调色剂粘合剂组合物和电子照相调色剂
    • US5728501A
    • 1998-03-17
    • US621065
    • 1996-03-22
    • Hideo NakanishiTohru OhamaNaoki TakaseAkira KodaniMunekazu Satake
    • Hideo NakanishiTohru OhamaNaoki TakaseAkira KodaniMunekazu Satake
    • G03G9/087G03G9/097
    • G03G9/08711G03G9/08704G03G9/08726G03G9/08728G03G9/09733
    • A charge controller for a toner, containing a polymer of an ethylenically unsaturated monomer, where the polymer has a dielectric loss tangent (tan .delta.) at 100 kHz of 0.008 to 0.3 and a water absorbency of at most 10% by weight, and selected from the group consisting of: (1) a polymer (A1) having units resulting from a monomer (1) having an aromatic ring substituted with at least one electron-attracting group (X) selected from the group consisting of halogen, a nitro group and a cyano group; and (2) a copolymer (A2) of a monomer (2) having an organic acid group or salt thereof, with one or more copolymerizable monomers, a toner binder and toner containing the same are provided which give excellent properties with respect to electrostatic charge amount, charging rate and environmental stability, as well as providing an essentially colorless charge controller containing no metal and improved dispersing properties and transparency.
    • 用于调色剂的电荷控制器,其含有烯属不饱和单体的聚合物,其中所述聚合物在100kHz下的介电损耗角正切(tanδ)为0.008至0.3,吸水率为至多10重量%,并且选自 由以下组成的组:(1)具有由具有被至少一个吸电子基团(X)取代的芳环的单体(1)得到的单元的聚合物(A1),所述吸电子基团选自卤素,硝基和 氰基; 和(2)具有有机酸基团或其盐的单体(2)与一种或多种可共聚单体的共聚物(A2),调色剂粘合剂和含有它们的调色剂粘合剂和调色剂粘合剂和静电电荷具有优异的性能 量,充电速率和环境稳定性,以及提供基本上无色的充电控制器,不含金属和改进的分散性能和透明度。