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1. 发明授权

US4070447A Process for preparing anhydrous aluminum fluoride 失效
标题翻译：无水氟化铝的制备方法
公开(公告)号：US4070447A
公开(公告)日：1978-01-24
申请号：US696715
申请日：1976-06-16
申请人： Tetsuhiro Ono , Minoru Aramaki , Etuo Ushirogouthi
发明人： Tetsuhiro Ono , Minoru Aramaki , Etuo Ushirogouthi
IPC分类号： C01F7/50 , C01C1/02 , C01C1/16
CPC分类号： C01F7/50
摘要： Ammonium tetrafluoroaluminate particles having an average particle size above 50.mu. are reacted with an aluminum compound such as aluminum hydroxide or oxide first at a temperature of 250.degree. C to 300.degree. C and then at a temperature of 350.degree. to 500.degree. C to form crystalline particles of anhydrous aluminum fluoride (II) with an average particle size almost corresponding to the starting ammonium tetrafluoroaluminate. The heating of the crystalline particles to a temperature above 550.degree. C results in formation of aluminum fluoride (I) with a large average particle size.
摘要翻译：将平均粒径大于50μm的四氟铝酸铵颗粒与铝化合物如氢氧化铝或氧化物首先在250℃至300℃的温度下反应，然后在350至500℃的温度下反应，形成晶体无水氟化铝（II）的颗粒，其平均粒度几乎对应于起始的四氟铝酸铵。将结晶粒子加热至550℃以上的温度导致形成平均粒径大的氟化铝（I）。

2. 发明授权

US4160012A Process of refining sodium hexafluorosilicate containing gypsum 失效
标题翻译：精制含六氟硅酸盐的石膏的工艺
公开(公告)号：US4160012A
公开(公告)日：1979-07-03
申请号：US856134
申请日：1977-11-30
申请人： Tetsuhiro Ono , Minoru Aramaki , Tamotsu Mizuno , Masao Fujinaga
发明人： Tetsuhiro Ono , Minoru Aramaki , Tamotsu Mizuno , Masao Fujinaga
IPC分类号： C01B33/10
CPC分类号： C01B33/103
摘要： Crude sodium hexafluorosilicate containing gypsum as a principal impurity can be refined economically with a minimized loss of fluorine by first making the crude fluorosilicate in the form of an aqueous slurry react with an alkali metal compound such as sodium carbonate or sodium hydroxide to form a soluble sulfate, and then treating the solid component of the reaction product with an acid solution in the presence of sodium ion, preferably at elevated temperatures near boiling point, to form a soluble calcium salt and crystallize sodium hexafluorosilicate. Sea water may be used both as the aqueous medium for the slurry in the first step and as the source of the sodium ions in the second step.
摘要翻译：含有石膏作为主要杂质的六氟硅酸钠可以通过首先使含水浆料形式的粗制氟硅酸盐与碱金属化合物如碳酸钠或氢氧化钠反应形成可溶性硫酸盐然后在钠离子存在下用酸溶液处理反应产物的固体组分，优选在沸点附近的升高的温度下，形成可溶性钙盐并结晶六氟硅酸钠。海水可以同时用作第一步中浆料的水性介质和第二步中钠离子的来源。

3. 发明授权

US4057614A Process for producing sodium fluoride from sodium silicofluoride 失效
标题翻译：从氟硅酸钠生产氟化钠的方法
公开(公告)号：US4057614A
公开(公告)日：1977-11-08
申请号：US738626
申请日：1976-11-03
申请人： Tetsuhiro Ono , Minoru Aramaki , Tamotsu Mizuno , Masao Fujinaga
发明人： Tetsuhiro Ono , Minoru Aramaki , Tamotsu Mizuno , Masao Fujinaga
IPC分类号： C01B33/10 , C01B33/18 , C01C1/16 , C01D3/02 , C01B33/00 , C01B33/12
CPC分类号： C01D3/02 , C01B33/103 , C01B33/186 , C01C1/162 , C01P2006/80 , C01P2006/82
摘要： A process for producing sodium fluoride from sodium silicofluoride in which sodium silicofluoride is added to an ammonium fluoride solution for double decomposition reaction to obtain a slurry containing sodium fluoride as crystals and ammonium silicofluoride in dissolved form, and the solution from which the sodium fluoride crystals have been removed is added with ammonia to decompose the ammonium silicofluoride into silica and ammonium fluoride. The ammonium fluoride obtained by the decomposition is recycled to the double decomposition step. Alternatively, the ammonium fluoride is reacted with a sodium salt for recovery as sodium fluoride.
摘要翻译：一种从氟硅化钠中生产氟化钠的方法，其中将氟化钠加入到氟化氢溶液中用于双重分解反应，得到溶解形式的含有氟化钠和含氟硅酸铵的浆料，以及氟化钠晶体具有的溶液加入氨，将硅酸铵分解成二氧化硅和氟化铵。通过分解得到的氟化铵被再循环到双重分解步骤。或者，氟化铵与钠盐反应，作为氟化钠回收。

4. 发明授权

US4863762A Method of forming coating film of fluororesin by physical vapor deposition 失效
标题翻译：通过物理气相沉积法形成氟树脂涂膜的方法
公开(公告)号：US4863762A
公开(公告)日：1989-09-05
申请号：US169834
申请日：1988-03-18
申请人： Minoru Aramaki , Masahiro Kubo , Hisaji Nakano , Hiroyuki Kurashige
发明人： Minoru Aramaki , Masahiro Kubo , Hisaji Nakano , Hiroyuki Kurashige
IPC分类号： C23C14/12 , B05D7/24 , C23C14/34
CPC分类号： B05D1/60
摘要： In forming a coating film of a fluororesin, e.g. polytetrafluoroethylene, on a metallic or nonmetallic surface by a physical vapor deposition technique, problems attributed to the necessity of intensely heating or bombarding the fluororesin as the evaporating source or target material are solved by using a molecular weight reduced fluororesin not higher than 5000 in molecular weight. It is best to use a low molecular weight fluororesin powder obtained by heating a high molecular weight fluororesin in presence of a fluorine source and precipitating the molecular weight reduced polymer from the reaction gas.
摘要翻译：在形成氟树脂的涂膜时，例如，聚四氟乙烯通过物理气相沉积技术在金属或非金属表面上，通过使用分子量不高于5000的分子量降低的氟树脂来解决归因于强烈加热或轰击氟树脂作为蒸发源或靶材料的问题。最好使用通过在氟源存在下加热高分子量氟树脂而得到的低分子量氟树脂粉末，并从反应气体中沉淀分子量降低的聚合物。

5. 发明授权

US4438086A Method for preparation of graphite fluoride by contact reaction between carbon and fluorine gas 失效
标题翻译：通过碳氟与氟气接触反应制备氟化石墨的方法
公开(公告)号：US4438086A
公开(公告)日：1984-03-20
申请号：US413889
申请日：1982-09-01
申请人： Minoru Aramaki , Yasushi Kita , Hishagi Nakano , Shiro Moroi
发明人： Minoru Aramaki , Yasushi Kita , Hishagi Nakano , Shiro Moroi
IPC分类号： C01B31/04 , B01J8/02 , C01B31/00 , C01B9/08 , C01B31/30
CPC分类号： B01J8/02 , C01B31/005 , B01J2208/00194 , B01J2208/00407 , B01J2208/0053 , B01J2208/00548 , B01J2219/182
摘要： A method and apparatus for preparation of a graphite fluoride such as (CF).sub.n or (C.sub.2 F).sub.n by heterogeneous contact reaction between a carbon material such as graphite or petroleum coke and fluorine gas at about 200.degree.-550.degree. C. The carbon material in the form of small pieces such as granules or powder particles is kept in a holder having a number of openings so as to form a carbon material layer in the holder, which is placed in a reactor so as to leave gas passages around the holder. With heating, fluorine gas is forcibly passed through the gas passages without agitating the carbon material in the holder. The openings of the holder are shaped and arranged such that the fluorine gas permeates through the carbon material layer in the holder. For example, the holder is an open-type box made of either a wire screen or a perforated metal plate, or a conveyor belt made of a wire screen. This method is effective for prevention of spontaneous decomposition of the formed graphite fluoride attributed to accumulation of the heat of reaction within the reacting carbon material layer and/or mechanical shocks or vibrations to the fluorinated carbon.
摘要翻译：一种用于在约200-550℃之间的诸如石墨或石油焦炭等碳材料与氟气之间的非均相接触反应来制备（CF）n或（C2F）n等氟化石墨的方法和装置。将小颗粒或粉末颗粒的形式保持在具有多个开口的保持器中，以便在保持器中形成碳材料层，该碳材料层放置在反应器中，以使得气体通道围绕保持器。通过加热，氟气被强制地通过气体通道，而不会搅动保持器中的碳材料。保持器的开口被成形和布置成使得氟气渗透通过保持器中的碳材料层。例如，保持器是由丝网或穿孔金属板或由丝网制成的输送带制成的开放式箱体。该方法对于防止由于反应碳材料层内的反应热的积累和/或对氟化碳的机械冲击或振动而导致的形成的氟化石墨的自发分解是有效的。

6. 发明授权

US4069266A Process for the preparation of fluorine-rich organic compounds containing one or two carbon atoms 失效
标题翻译：制备含有一个或两个碳原子的富含氟有机化合物的方法
公开(公告)号：US4069266A
公开(公告)日：1978-01-17
申请号：US762339
申请日：1977-01-25
申请人： Tadaaki Komatsu , Hirokazu Takeda , Hideki Oshio , Kimiaki Matsuoka , Minoru Aramaki
发明人： Tadaaki Komatsu , Hirokazu Takeda , Hideki Oshio , Kimiaki Matsuoka , Minoru Aramaki
IPC分类号： C07C17/20 , B01J27/125 , C07B61/00 , C07C17/00 , C07C17/37 , C07C19/08 , C07C19/10 , C07C19/12 , C07C67/00
CPC分类号： C07C17/37 , C07C17/00
摘要： A process for preparing fluorine-rich organic compounds containing one or two carbon atoms from organic fluoro compounds of lower fluorine content in which starting partially or completely halogenated fluoro carbon compounds having at least one halogen atom other than fluorine, e.g., CHCl.sub.2 F, CHClF.sub.2, CCl.sub.2 F.sub.2, CCl.sub.3 F, C.sub.2 Cl.sub.3 F.sub.3, C.sub.2 Cl.sub.2 F.sub.4 and C.sub.2 Cl.sub.4 F.sub.2, are contacted under disproportionation conditions with a catalyst system of a specific type which comprises 0.1 - 5% by weight, as metal, of a nickel(II) halide, titanium(III) chloride or titanium(III) fluoride and a balance of an aluminum compound such as activated alumina, silica, alumina or aluminum fluoride.
摘要翻译：一种制备含氟低级有机化合物的方法，该有机氟化合物含氟低于氟含量的有机氟化合物，其中起始部分或完全卤代氟化碳具有至少一个除氟以外的卤素原子，例如CHCl 2 F，CHClF 2，CCl 2 F 2 ，CCl 3 F，C 2 Cl 3 F 3，C 2 Cl 2 F 4和C 2 Cl 4 F 2在歧化条件下与特定类型的催化剂体系接触，所述催化剂体系包含0.1-5重量％的金属，卤化镍（II），氯化钛（III） III）氟化物和余量的铝化合物如活性氧化铝，二氧化硅，氧化铝或氟化铝。

7. 发明授权

US4964137A Method of refining rare gas fluoride excimer laser gas 失效
标题翻译：精炼稀有气体氟化物准分子激光气体的方法
公开(公告)号：US4964137A
公开(公告)日：1990-10-16
申请号：US466930
申请日：1990-01-18
申请人： Minoru Aramaki , Shinsuke Nakagawa , Hisaji Nakano , Hiroshi Ichimura , Masahiro Tainaka
发明人： Minoru Aramaki , Shinsuke Nakagawa , Hisaji Nakano , Hiroshi Ichimura , Masahiro Tainaka
IPC分类号： H01S3/097 , H01S3/036 , H01S3/223 , H01S3/225
CPC分类号： H01S3/036 , H01S3/225
摘要： A laser gas used in a rare gas fluoride excimer laser is efficiently refined with little loss of the principal rare gas such as Ar, Kr or Xe by sequential contact of the laser gas first with a reactive metal, e.g. Si or Fe, for conversion of the fluorine source gas such as F.sub.2 or NF.sub.3 to a metal fluoride, then with a solid alkaline compound, e.g. Ca(OH).sub.2, for conversion of gaseous fluorides to solid metal fluorides, next with zeolite which is adsorbent of most of the remaining impurities and finally with an alkaline metal, e.g. Ca or Na, for decomposition of CF.sub.4 to form a solid metal fluoride and carbon. CF.sub.4 is formed during operation of the excimer laser by reaction of fluorine with a fluororesin used as electrical insulator in the laser apparatus, and accumulation of CF.sub.4 in the laser gas caused significal lowering of the laser output power.
摘要翻译：在稀有气体氟化物准分子激光器中使用的激光气体通过先将激光气体与活性金属例如反应性金属顺序接触而有效地精制而不损失诸如Ar，Kr或Xe的主要稀有气体。 Si或Fe，用于将氟源气体如F2或NF3转化为金属氟化物，然后用固体碱性化合物，例如， Ca（OH）2，用于将气态氟化物转化为固体金属氟化物，接下来是沸石，其是大部分剩余杂质的吸附剂，最后是碱金属，例如碱金属。 Ca或Na，用于分解CF4以形成固体金属氟化物和碳。在激光装置中通过氟与用作电绝缘体的氟树脂反应而在准分子激光器的操作期间形成CF4，并且CF4在激光气体中的积聚导致激光输出功率的显着降低。

8. 发明授权

US4925975A Method of preparing alkali metal fluoroalkylsulfonates of high purity 失效
标题翻译：制备高纯度碱金属氟代烷基磺酸盐的方法
公开(公告)号：US4925975A
公开(公告)日：1990-05-15
申请号：US342348
申请日：1989-04-21
申请人： Minoru Aramaki , Kimitaka Okamoto , Hiroaki Sakaguchi , Tamio Nakamura
发明人： Minoru Aramaki , Kimitaka Okamoto , Hiroaki Sakaguchi , Tamio Nakamura
IPC分类号： C07C303/32 , C07C67/00 , C07C301/00 , C07C303/00 , C07C309/06
CPC分类号： C07C303/22 , C07C303/32
摘要： In preparing a fluoroalkylsulfonate RfSO.sub.3 M, where Rf is a perfluoroalkyl gruop having not more than 6 carbon atoms and M is an alkali metal, by neutralization reaction between a fluoroalkylsulfonic acid RfSO.sub.3 H and an alkali metal carbonate or hydroxide, the reaction is carried out under acidic conditions such that at the end of the reaction pH of the reaction liquid is lower than 6, and preferably not higher than 3. By so maintaining the reaction liquid acidic, the obtained RfSO.sub.3 M becomes very low in the concentrations of anionic impurities such as free fluorine, free chlorine and carbonate radical and, besides becomes low in moisture absorbency.
摘要翻译：在制备氟代烷基磺酸盐RfSO 3 M的情况下，其中Rf是不大于6个碳原子的全氟烷基，M是碱金属，通过氟代烷基磺酸RfSO 3 H与碱金属碳酸盐或氢氧化物之间的中和反应，反应在酸性条件下进行使得在反应结束时，反应液的pH低于6，优选不高于3.通过使反应液体保持酸性，所得到的RfSO 3 M的离子浓度变得非常低，如游离氟，游离氯和碳酸根，并且除了吸湿性低。

9. 发明授权

US4312718A Method for producing fluorine 失效
标题翻译：生产氟的方法
公开(公告)号：US4312718A
公开(公告)日：1982-01-26
申请号：US161593
申请日：1980-06-20
申请人： Nobuatsu Watanabe , Minoru Aramaki , Yasushi Kita
发明人： Nobuatsu Watanabe , Minoru Aramaki , Yasushi Kita
IPC分类号： C04B35/52 , C04B35/532 , C25B1/24 , C25B11/12
CPC分类号： C25B1/245 , C04B35/532 , C25B11/12
摘要： The use of an isotropic carbon block having an anisotropy of not more than 1.2 in terms of an anisotropic ratio of specific resistance as an anode in the production of fluorine by the electrolysis of an electrolyte comprising a mixed molten salt system of potassium fluoride and hydrogen fluoride has been found to be extremely useful for attaining increase in critical current density so that occurrence of the unfavorable anode effect can be effectively prevented. With such an isotropic carbon block anode, even if the anode effect occurs, the electrolysis can be stably continued again by lowering the potential of the electrode. Further, the incorporation of a fluoride into the isotropic carbon block anode and/or the addition of a fluoride into the electrolyte is effective for further increasing critical current density.
摘要翻译：使用通过电解电解生产氟的电阻率的各向异性比不大于1.2的各向同性碳块，其包含氟化钾和氟化氢的混合熔融盐体系已经发现对于获得临界电流密度的增加是非常有用的，从而可以有效地防止出现不利的阳极效应。使用这种各向同性的碳块阳极，即使发生阳极效应，也可以通过降低电极的电位来再次稳定地进行电解。此外，将氟化物并入各向同性碳嵌段阳极和/或向电解质中添加氟化物对于进一步提高临界电流密度是有效的。

10. 发明授权

US4927962A Process of preparing fluorocarbon carboxylic or sulfonic acid from its fluoride 失效
标题翻译：从其氟化物制备氟碳羧酸或磺酸的方法
公开(公告)号：US4927962A
公开(公告)日：1990-05-22
申请号：US237072
申请日：1988-08-29
申请人： Minoru Aramaki , Hiroaki Sakaguchi , Tamio Nakamura
发明人： Minoru Aramaki , Hiroaki Sakaguchi , Tamio Nakamura
IPC分类号： C07C51/04 , C07C51/58 , C07C303/00
CPC分类号： C25B3/08 , C07C303/02 , C07C303/32 , C07C51/04 , C07C51/58
摘要： A fluorocarbon carboxylic acid Rf(COOH).sub.m (Rf is C.sub.1 -C.sub.10 perfluoroalkyl group, m is 1 or 2) is prepared by the steps of hydrolyzing Rf(COF).sub.m with water to obtain an acidic solution, neutralizing the acidic solution with aqueous solution of KOH to form Rf(COOK).sub.m, precipitating and separating Rf(COOK).sub.m from the solution and converting Rf(COOK).sub.m into Rf(COOH).sub.m by acid decomposition. The content of free fluorine can extremely be reduced by treating Rf(COOK).sub.m with sulfuric acid and silica. The mother liquor is recycled after removing KF by treatment with a metal hydroxide and replenishing with KOH. In preparing a fluorocarbon sulfonic acid RfSO.sub.3 H (Rf is C.sub.1 -C.sub.3 perfluoroalkyl group) in substantially the same way, RfSO.sub.3 K is formed in aqueous solution of KOH by bringing gaseous RfSO.sub.2 F into contact with the KOH solution under normal pressure, while controlling the feed rate of RfSO.sub.2 F per unit area of gas-liquid contact at a sufficiently low level.
摘要翻译：氟化碳羧酸Rf（COOH）m（Rf为C1-C10全氟烷基，m为1或2）通过以下步骤制备：用水水解Rf（COF）m，得到酸性溶液，用水溶液中和酸性溶液 KOH溶液形成Rf（COOK）m，沉淀并从溶液中分离Rf（COOK）m，并通过酸分解将Rf（COOK）m转化为Rf（COOH）m。通过用硫酸和二氧化硅处理Rf（COOK）m可以极大地降低游离氟的含量。通过用金属氢氧化物处理除去KF后再加入母液并用KOH补充。在以相同的方式制备氟碳磺酸RfSO 3 H（Rf为C 1 -C 3全氟烷基）时，通过在常压下使气态RfSO 2 F与KOH溶液接触，在KOH的水溶液中形成RfSO 3 K，同时控制每单位面积的气 - 液接触的RfSO 2 F足够低。

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