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1. 发明授权

US4880877A Method for producing rubber modified thermoplastic resins 失效
标题翻译：橡胶改性热塑性树脂的制造方法
公开(公告)号：US4880877A
公开(公告)日：1989-11-14
申请号：US946058
申请日：1986-12-24
申请人： Teruhiko Sugimori , Noriyuki Tajiri , Fumio Suzuki , Hideaki Habara , Yutaro Fukuda , Haruki Sato
发明人： Teruhiko Sugimori , Noriyuki Tajiri , Fumio Suzuki , Hideaki Habara , Yutaro Fukuda , Haruki Sato
IPC分类号： C08J3/00 , C08L51/04
CPC分类号： C08J3/005 , C08L51/04
摘要： Disclosed is a method for producing a rubber modified thermoplastic resin which comprises carrying out all or a part of the following steps (I)-(VI):(I) a setp of mixing the following (A), (B), (C) and thermoplastic resin (2):(A) a latex of gfart rubber polymer (1),(B) an organic agent which is capable of dissolving thermoplastic resin (2) and has a solubility in water of 5% by weight or less t a temperature at which (A), (B), (C) and thermoplastic resin (2) are mixed, amount of the organic agent being 10-600% by weight of polymer (4) which is the sum of graft rubber polymer (1) and thermoplastic resin (2) and(C) a warer soluble agent capable of coagulating latex (A), amount of this agent being 10% by weight or less of graft rubber polymer (1),(II) a step of separating and removing aqueous phase from a two-phase mixture obtained in the mixing step (I),(III) a step of mixing the mixture from which the aqueous phase hsa been removed at step (II) and the whole or a part of thermoplastic resin (3),(IV) a step of removing a part or the whole of ogranic agent (B) and remaining water from the mixture obtained at step (III) by a thermal means,(V) a step of mixing the remainder of thermoplastic resin (3) in case a part of thermoplastic resin (3) has been mixed at step (III), and(VI) a step of removing the remainder of organic agent (B) in case only a part of organic agent (B) has been removed at step (IV).
摘要翻译：公开了一种橡胶改性热塑性树脂的制造方法，其特征在于，进行以下（I）〜（VI）的全部或一部分步骤（I）：（I）将下述（A），（B），（C ）和热塑性树脂（2）：（A）gfart橡胶聚合物（1）的胶乳，（B）能够溶解热塑性树脂（2）并且在水中的溶解度为5重量％以下的有机试剂（A），（B），（C）和热塑性树脂（2）混合时，有机试剂的量为聚合物（4）的10-600重量％，其为接枝橡胶聚合物 1）和热塑性树脂（2）和（C）能够凝固胶乳（A）的较易溶解剂，该试剂的量为接枝橡胶聚合物（1）的10重量％以下，（II）分离步骤以及从混合步骤（I），（III）中获得的两相混合物中除去水相的步骤是将在步骤（II）中除去水相hsa的混合物与热塑性树脂的全部或部分混合的步骤苯乙烯树脂（3），（Ⅳ）通过加热方法从步骤（III）获得的混合物中除去部分或全部异味剂（B）和剩余水的步骤，（Ⅴ）在热塑性树脂（3）的一部分已经在步骤（III）中混合的情况下，热塑性树脂（3）的热塑性树脂（3），和（VI）在仅有一部分有机试剂的情况下去除剩余的有机试剂（B）的步骤 B）已经在步骤（IV）被去除。

2. 发明授权

US4690975A Method for producing rubber modified thermoplastic resins 失效
标题翻译：橡胶改性热塑性树脂的制造方法
公开(公告)号：US4690975A
公开(公告)日：1987-09-01
申请号：US867204
申请日：1986-05-27
申请人： Teruhiko Sugimori , Noriyuki Tajiri , Yutaro Fukuda
发明人： Teruhiko Sugimori , Noriyuki Tajiri , Yutaro Fukuda
IPC分类号： C08J3/00 , C08L101/00 , C08L51/00
CPC分类号： C08J3/005 , C08L101/00
摘要： Disclosed is a method for producing a rubber modified thermoplastic resin excellent in surface appearance and various properties and high in commercial values which comprises removing an aqueous phase from a two-phase mixture comprises a graft rubber polymer latex (1) obtained by graft polymerization of vinyl monomer on a rubber latex, a thermoplastic resin (2) and an organic agent in an amount of 0.2 to 6 times the weight of all the polymers (3) which is capable of dissolving said thermoplastic resin (2) and has a solubility in water of 5 to 50% by weight at 25.degree. C. and then removing said organic agent and remaining water from the remaining organic phase by a thermal means.
摘要翻译：公开了一种表面外观和各种性能和商业价值高的橡胶改性热塑性树脂的制造方法，其包括从两相混合物中除去水相，包括通过乙烯基接枝聚合获得的接枝橡胶聚合物胶乳（1）橡胶胶乳上的单体，热塑性树脂（2）和有机试剂的量为所有能够溶解所述热塑性树脂（2）的所有聚合物（3）的重量的0.2至6倍，并且在水中具有溶解度在25℃下为5至50重量％，然后通过热方法从剩余的有机相中除去所述有机物和剩余的水。

3. 发明授权

US4992510A Method for producing rubber modified thermoplastic resins 失效
标题翻译：橡胶改性热塑性树脂的制造方法
公开(公告)号：US4992510A
公开(公告)日：1991-02-12
申请号：US394720
申请日：1989-08-16
申请人： Teruhiko Sugimori , Noriyuki Tajiri , Fumio Suzuki , Hideaki Habara , Yutaro Fukuda , Haruki Sato
发明人： Teruhiko Sugimori , Noriyuki Tajiri , Fumio Suzuki , Hideaki Habara , Yutaro Fukuda , Haruki Sato
IPC分类号： C08J3/00 , C08L51/04
CPC分类号： C08J3/005 , C08L51/04
摘要： Disclosed is method for producing a rubber modified thermoplastic reins which comprises carrying out all or a part of the following setps (I) - (VI):(I) a step of mixing the following (A), (B), (C) and thermoplastic resin (2):(A) a latex of graft rubber polymer (1),(B) an organic agent which is capable of dissolving thermoplastic resin (2) and has a solubility in water of 5% by weight or less at a temperature at which (A), (B), (C) and thermoplastic resin (2) are mixed, amount of the organic agent being 10-600% by weight of polymer (4) which is the sum of graft rubber polymer (1) and thermoplastic resin (2) and(C) a water soluble agent capable of coagulating latex (A), amount of this agent being 10% by weight or less of graft rubber polymer (1),(II) a step of separating and removing aqueous phase from a two-phase mixture obtained in the mixing step (I),(III) a step of mixing the mixture from which the aqueous phase has been removed at step (II) and the whole or a part of thermoplastic resin (3),(IV) a step of removing a part or the whole of organic agent (B) and remaining water from the mixture obtained at step (III) by a thermal means,(V) a step of mixing the remainder of thermoplastic resin (3) in case a part of thermoplastic resin (3) has been mixed at step (III), and(VI) a step of removing the remainder of organic agent (B) in case only a part of organic agent (B) has been removed at step (IV).

4. 发明授权

US4921909A Method for producing thermoplastic resins 失效
标题翻译：热塑性树脂的制造方法
公开(公告)号：US4921909A
公开(公告)日：1990-05-01
申请号：US946057
申请日：1986-12-24
申请人： Teruhiko Sugimori , Noriyuki Tajiri , Yutaro Fukuda
发明人： Teruhiko Sugimori , Noriyuki Tajiri , Yutaro Fukuda
IPC分类号： C08J3/00 , C08L51/04
CPC分类号： C08J3/005 , C08L51/04
摘要： Emulsion polymerization type thermoplastic resin of high performance can be produced by the following methods: namely, a method which comprises removing an aqueous phase from a two-phase mixture comprising a latex of polymer (1) produced by emulsion polymerization, a water soluble agent (2) in an amount of 10% by weight or less of said polymer (1) which is capable of coagulating the latex of polymer (1) and an organic agent (3) in an amount of 0.1 to 6 times the weight of said polymer (1) which is capable of dissolving both an uncrosslinked polymer contained in said polymer (1) and thermoplastic polymer (4) mentioned hereinbelow and has a solubility in water of 5% by weight or less at 25.degree. C., then melt-mixing molten polymer which has been subjected to a first devolatilization by a thermal means with thermoplastic resin (4) and then subjecting the mixture to a second devolatilization; and a method which comprises removing an aqueous phase from a two-phase mixture comprising a latex of polymer (1) produced by emulsion polymerization, a water soluble agent ( 2) in an amount of 10% by weight or less of said polymer (1) which is capable of coagulating the latex of polymer (1) and an organic agent (3) in an amount of 0.1 to 6 times the weight of said polymer (1) which is capable of dissolving an uncrosslinked polymer contained in said polymer (1) and has a solubility in water of 5% by weight or less at 25.degree. C. and then melt-mixing the molten polymer from which volatile component has been devolatilized by a thermal means with thermoplastic polymer (4').
摘要翻译：可以通过以下方法制备高性能的乳液聚合型热塑性树脂：即包括从包含通过乳液聚合制备的聚合物（1）的胶乳的两相混合物中除去水相的方法，水溶性试剂（ 2）的量为所述聚合物（1）的10重量％以下，其能够将聚合物（1）和有机试剂（3）的胶乳凝集为所述聚合物的重量的0.1至6倍（1），其能够溶解所述聚合物（1）中所含的未交联的聚合物和下述热塑性聚合物（4），并且在25℃下在水中的溶解度为5重量％以下，然后熔融混合熔融聚合物，其已经用热塑性树脂（4）进行了第一次脱挥发分化，然后使混合物进行第二脱挥发分; 以及包括从包含通过乳液聚合制备的聚合物（1）的胶乳的两相混合物中除去水相的方法，所述聚合物（1）的10重量％以下的水溶性试剂（2）），其能够将聚合物（1）的胶乳和有机试剂（3）的量以能够溶解在所述聚合物（1）中所含的未交联的聚合物的所述聚合物（1）的重量的0.1至6倍的量），并且在25℃下在水中的溶解度为5重量％以下，然后将熔融聚合物熔融混合，其中挥发性组分已经通过热方式与热塑性聚合物（4'）脱挥发分。

5. 发明授权

US4690974A Method for producing rubber modified thermoplastic resins 失效
标题翻译：橡胶改性热塑性树脂的制造方法
公开(公告)号：US4690974A
公开(公告)日：1987-09-01
申请号：US864868
申请日：1986-05-20
申请人： Teruhiko Sugimori , Noriyuki Tajiri , Yutaro Fukuda
发明人： Teruhiko Sugimori , Noriyuki Tajiri , Yutaro Fukuda
IPC分类号： C08J3/00 , C08L51/04 , C08L101/00 , C08L51/00
CPC分类号： C08L51/04 , C08J3/005 , C08L101/00
摘要： Disclosed is a method for producing a rubber modified thermoplastic resin excellent in surface appearance and various properties and high in commercial values which comprises removing an aqueous phase from a two-phase mixture comprising a graft rubber polymer latex (1) obtained by graft polymerization of vinyl monomer on a rubber latex, a thermoplastic resin (2), an organic agent in an amount of 0.1 to 6 times the weight of all the polymers (3) which is capable of dissolving said thermoplastic resin (2) and has a solubility in water of 5% by weight or less at 25.degree. C. and a water soluble agent in an amount of 10% by weight or less of said graft rubber polymer which can coagulate said latex and then removing said organic agent and remaining water from the remaining organic phase by a thermal means.
摘要翻译：公开了一种表面外观和各种性能和商业价值高的橡胶改性热塑性树脂的制造方法，其包括从包含通过乙烯基接枝聚合获得的接枝橡胶聚合物胶乳（1）的两相混合物中除去水相，橡胶胶乳上的单体，热塑性树脂（2），能够溶解所述热塑性树脂（2）的所有聚合物（3）的重量的0.1至6倍并且在水中具有溶解度的有机试剂在25℃下为5重量％以下的水溶性试剂和10重量％以下的所述接枝橡胶聚合物的水溶性试剂，其可以凝结所述胶乳，然后从剩余的有机物中除去所述有机试剂和剩余的水通过热方式进行相。

6. 发明授权

US5064938A Continuous production process of particulate polymer and control method of the particle size of said polymer 失效
标题翻译：颗粒聚合物的连续生产过程和合成聚合物颗粒尺寸的控制方法
公开(公告)号：US5064938A
公开(公告)日：1991-11-12
申请号：US617265
申请日：1990-11-23
申请人： Fumio Suzuki , Hideaki Habara , Yutaro Fukuda , Haruki Sato , Hiromasa Inada
发明人： Fumio Suzuki , Hideaki Habara , Yutaro Fukuda , Haruki Sato , Hiromasa Inada
IPC分类号： C08F6/22 , C08J3/16
CPC分类号： C08J3/16 , C08F6/22
摘要： The invention discloses a process for the production of a particulate polymer which contains few fine particles and has a narrow particle size distribution and a controlled bulk specific gravity. Characteristic features of the process of this invention reside in that a polymer latex obtained by emulsion polymerization is successively processed through the following steps (I) and (II):Step (I) The polymer latex is coagulated into a slurry in which particles thus coagulated are dispersed in water.Step (II) The slurry obtained in Step (I), an organic liquid almost insoluble in water and incapable of dissolving the polymer and water are mixed for granulation under the conditions that(a) The proportion of water in the whole mixture is 50-85 wt. %,(b) The amount of the organic liquid is 15-150 parts by weight per 100 parts by weight of the polymer in the polymer latex, and(c) The temperature T (.degree.C.) of the whole mixture is maintained for 0.5 minute to 1 hour on average within the range of the following equation:A-40.ltoreq.T.ltoreq.A wherein A means the azeotropic temperature (.degree.C.) of the mixture.In the above process, control of the interfacial tension between the organic liquid and the dispersion medium of the slurry within a specific range has made it possible to control the particle size of the resulting particulate polymer to a desired level.
摘要翻译：本发明公开了一种生产微粒聚合物的方法，该颗粒聚合物含有很少的细颗粒，并且具有窄的粒度分布和受控的体积比重。本发明方法的特征在于通过乳液聚合获得的聚合物胶乳通过以下步骤（I）和（II）连续加工：步骤（I）将聚合物胶乳凝结成浆料，其中由此凝结的颗粒分散在水中。步骤（II）将步骤（I）中获得的浆料，几乎不溶于水并且不能溶解聚合物和水的有机液体在以下条件下混合制粒，（a）整个混合物中的水的比例为50- 85重量％％，（b）有机液体的量相对于聚合物胶乳中的聚合物每100重量份为15-150重量份，（c）保持整个混合物的温度T（℃）为在下列等式的范围内平均0.5分钟至1小时：A-40

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