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1. 发明授权

US5089112A Electrochemical biosensor based on immobilized enzymes and redox polymers 失效
标题翻译：基于固定化酶和氧化还原聚合物的电化学生物传感器
公开(公告)号：US5089112A
公开(公告)日：1992-02-18
申请号：US463540
申请日：1990-01-11
申请人： Terje A. Skotheim , Yoshiyuki Okamoto , Paul D. Hale
发明人： Terje A. Skotheim , Yoshiyuki Okamoto , Paul D. Hale
IPC分类号： C12Q1/00 , G01N27/416
CPC分类号： C12Q1/004 , Y10S435/817
摘要： The present invention relates to an electrochemical enzyme biosensor for use in liquid mixtures of components for detecting the presence of, or measuring the amount of, one or more select components. The enzyme electrode of the present invention is comprised of an enzyme, an artificial redox compound covalently bound to a flexible polymer backbone and an electron collector.
摘要翻译：本发明涉及用于检测一种或多种选择组分的存在或测量量的组分的液体混合物中的电化学酶生物传感器。本发明的酶电极由酶，与弹性聚合物骨架共价结合的人造氧化还原化合物和电子收集体构成。

2. 发明授权

US5362493A Preparation of redox polymer cathodes for thin film rechargeable batteries 失效
标题翻译：制备用于薄膜可充电电池的氧化还原聚合物阴极
公开(公告)号：US5362493A
公开(公告)日：1994-11-08
申请号：US913412
申请日：1992-07-15
申请人： Terje A. Skotheim , Hung S. Lee , Yoshiyuki Okamoto
发明人： Terje A. Skotheim , Hung S. Lee , Yoshiyuki Okamoto
IPC分类号： H01M4/137 , H01M4/60 , H01M10/052 , H01M10/0565 , H01M4/04
CPC分类号： H01M4/137 , H01M10/052 , H01M10/0565 , H01M4/60
摘要： The present invention relates to the manufacture of thin film solid state electrochemical devices using composite cathodes comprising a redox polymer capable of undergoing oxidation and reduction, a polymer solid electrolyte and conducting carbon. The polymeric cathode material is formed as a composite of radiation crosslinked polymer electrolytes and radiation crosslinked redox polymers based on polysiloxane backbones with attached organosulfur side groups capable of forming sulfur-sulfur bonds during electrochemical oxidation.
摘要翻译：本发明涉及使用包含能够进行氧化和还原的氧化还原聚合物，聚合物固体电解质和导电碳的复合阴极的薄膜固态电化学装置的制造。聚合阴极材料形成为辐射交联聚合物电解质和基于聚硅氧烷主链的辐射交联氧化还原聚合物的复合物，其具有在电化学氧化期间能够形成硫 - 硫键的连接的有机硫侧基。

3. 发明授权

US4882243A Preparation of metallic cation conducting polymers based on sterically hindered phenols containing polymeric systems 失效
标题翻译：基于含有聚合体系的空间位阻酚的金属阳离子导电聚合物的制备
公开(公告)号：US4882243A
公开(公告)日：1989-11-21
申请号：US275013
申请日：1988-11-22
申请人： Terje A. Skotheim , Yoshiyuki Okamoto , Hung S. Lee
发明人： Terje A. Skotheim , Yoshiyuki Okamoto , Hung S. Lee
IPC分类号： C08L101/00 , C08G18/02 , G02F1/15 , H01B1/12 , H01M10/052 , H01M10/0565
CPC分类号： H01M10/052 , C08G18/02 , G02F1/1525 , H01B1/122 , H01M10/0565
摘要： The present invention relates to ion-conducting solvent-free polymeric systems characterized as being cationic single ion conductors. The solvent-free polymer electrolytes comprise a flexible polymer backbone to which is attached a metal salt, such as a lithium, sodium or potassium salt, of a sterically hindered phenol. The solid polymer electrolyte may be prepared either by (1) attaching the hindered phenol directly to a flexible polymeric backbone, followed by neutralization of the phenolic OH's or (2) reacting the hindered phenol with a polymer precursor which is then polymerized to form a flexible polymer having phenolic OH's which are subsequently neutralized. Preferably the hindered phenol-modified polymeric backbone contains a polyether segment. The ionic conductivity of these solvent-free polymer electrolytes has been measured to be in the range of 10.sup.-4 to 10.sup.-7 S cm.sup.-1 at room temperature.

4. 发明申请

US20100104948A1 PROTECTION OF ANODES FOR ELECTROCHEMICAL CELLS 审中-公开
标题翻译：保护电化学细胞的阳极
公开(公告)号：US20100104948A1
公开(公告)日：2010-04-29
申请号：US12180379
申请日：2008-07-25
申请人： Terje A. Skotheim , Christopher J. Sheehan , Yuriy V. Mikhaylik , John Affinito
发明人： Terje A. Skotheim , Christopher J. Sheehan , Yuriy V. Mikhaylik , John Affinito
IPC分类号： H01M6/18 , H01M6/04 , H01M4/36 , H01M4/58 , H01M4/04
CPC分类号： H01M10/0562 , H01M4/02 , H01M4/13 , H01M4/366 , H01M4/38 , H01M4/385 , H01M4/66 , H01M4/661 , H01M10/052 , H01M10/36 , H01M10/4235 , H01M2004/021 , H01M2004/027 , H01M2300/0002 , H01M2300/0091
摘要： Provided is an anode for use in electrochemical cells, wherein the anode active layer has a first layer comprising lithium metal and a multi-layer structure comprising single ion conducting layers and polymer layers in contact with the first layer comprising lithium metal or in contact with an intermediate protective layer, such as a temporary protective metal layer, on the surface of the lithium-containing first layer. Another aspect of the invention provides an anode active layer formed by the in-situ deposition of lithium vapor and a reactive gas. The anodes of the current invention are particularly useful in electrochemical cells comprising sulfur-containing cathode active materials, such as elemental sulfur.
摘要翻译：提供一种用于电化学电池的阳极，其中阳极活性层具有包括锂金属的第一层和包含单一离子传导层和与包含锂金属的第一层接触的聚合物层的多层结构或与中间保护层，例如临时保护金属层，在含锂的第一层的表面上。本发明的另一方面提供了通过锂蒸气和反应性气体的原位沉积形成的阳极活性层。本发明的阳极在包含含硫阴极活性材料如元素硫的电化学电池中特别有用。

5. 发明授权

US06410182B1 Method of making separators for electrochemical cells comprising a microporous pseudo-boehmite layer 有权
标题翻译：制造用于包含微孔假勃姆石层的电化学电池的隔板的方法
公开(公告)号：US06410182B1
公开(公告)日：2002-06-25
申请号：US09641539
申请日：2000-08-18
申请人： Qicong Ying , Steven A. Carlson , Terje A. Skotheim
发明人： Qicong Ying , Steven A. Carlson , Terje A. Skotheim
IPC分类号： H01M214
CPC分类号： H01M10/05 , H01G11/52 , H01M2/16 , H01M2/1646 , H01M2/1653 , H01M2/166 , H01M2/1686 , H01M6/16 , H01M10/052 , H01M10/056 , H01M10/0585 , H01M2300/0094 , Y02E60/13
摘要： This invention pertains to separators for electrochemical cells which comprise (i) a microporous pseudo-boehmite layer and (ii) a protective coating layer comprising a polymer; electrolyte elements comprising such separators; electrical current producing cells comprising such separators; and methods of making such separators, electrolyte elements and cells.
摘要翻译：本发明涉及用于电化学电池的隔板，其包括（i）微孔假勃姆石层和（ii）包含聚合物的保护涂层; 包括这种分离器的电解质元件; 包括这种分离器的电流产生电池; 以及制造这种分离器，电解质元件和电池的方法。

6. 发明授权

US4190950A Dye-sensitized solar cells 失效
标题翻译：染料敏化太阳能电池
公开(公告)号：US4190950A
公开(公告)日：1980-03-04
申请号：US889688
申请日：1978-03-24
申请人： Terje A. Skotheim
发明人： Terje A. Skotheim
IPC分类号： H01L31/07 , B01J17/00
CPC分类号： H01L31/07 , H01L51/4226 , Y02E10/542 , Y02E10/549
摘要： A low-cost dye-sensitized Schottky barrier solar cell comprised of a substrate of semiconductor with an ohmic contact on one face, a sensitizing dye adsorbed onto the opposite face of the semiconductor, a transparent thin-film layer of a reducing agent over the dye, and a thin-film layer of metal over the reducing agent. The ohmic contact and metal layer constitute electrodes for connection to an external circuit and one or the other or both are made transparent to permit light to penetrate to the dye and be absorbed therein for generating electric current. The semiconductor material chosen to be the substrate is one having a wide bandgap and which therefore is transparent; the dye selected is one having a ground state within the bandgap of the semiconductor to generate carriers in the semiconductor, and a first excited state above the conduction band edge of the semiconductor to readily conduct electrons from the dye to the semiconductor; the reducing agent selected is one having a ground state above the ground state of the sensitizer to provide a plentiful source of electrons to the dye during current generation and thereby enhance the generation; and the metal for the thin-film layer of metal is selected to have a Fermi level in the vicinity of or above the ground state of the reducing agent to thereby amply supply electrons to the reducing agent.
摘要翻译：一种低成本染料敏化肖特基势垒太阳能电池，由一面上具有欧姆接触的半导体衬底，吸附在半导体的相对面上的敏化染料，在染料上的还原剂的透明薄膜层和还原剂上的金属薄膜层。欧姆接触和金属层构成用于连接到外部电路的电极，并且一个或另一个或两者均为透明的，以允许光穿透染料并被吸收以产生电流。选择为基板的半导体材料是具有宽带隙的半导体材料，因此是透明的; 选择的染料是在半导体的带隙内具有基态以在半导体中产生载流子的染料，并且在半导体的导带边缘之上的第一激发态能够容易地将电子从染料导入半导体; 选择的还原剂是具有高于敏化剂的基态的基态的电荷，在电流产生期间向染料提供充足的电子源，从而增强产生; 并且金属薄膜层的金属被选择为在还原剂的基态附近或高于还原剂的基态具有费米能级，从而向还原剂供应电子。

7. 发明授权

US08415054B2 Lithium anodes for electrochemical cells 有权
公开(公告)号：US08415054B2
公开(公告)日：2013-04-09
申请号：US11452445
申请日：2006-06-13
申请人： Terje A. Skotheim , Christopher J. Sheehan , Yuriy V. Mikhaylik , John Affinito
发明人： Terje A. Skotheim , Christopher J. Sheehan , Yuriy V. Mikhaylik , John Affinito
IPC分类号： H01M2/16
CPC分类号： H01M4/628 , H01M2/1673 , H01M4/04 , H01M4/0404 , H01M4/0421 , H01M4/0426 , H01M4/134 , H01M4/136 , H01M4/1395 , H01M4/366 , H01M4/38 , H01M4/382 , H01M4/387 , H01M4/581 , H01M4/5815 , H01M4/625 , H01M6/14 , H01M6/18 , H01M6/40 , H01M10/052 , H01M10/0525 , H01M10/056 , H01M10/0585 , H01M10/4235 , H01M2004/021 , H01M2004/027 , H01M2220/30 , Y02E60/122 , Y02P70/54
摘要： Provided is an anode for use in electrochemical cells, wherein the anode active layer has a first layer comprising lithium metal and a multi-layer structure comprising single ion conducting layers and polymer layers in contact with the first layer comprising lithium metal or in contact with an intermediate protective layer, such as a temporary protective metal layer, on the surface of the lithium-containing first layer. Another aspect of the invention provides an anode active layer formed by the in-situ deposition of lithium vapor and a reactive gas. The anodes of the current invention are particularly useful in electrochemical cells comprising sulfur-containing cathode active materials, such as elemental sulfur.

8. 发明授权

US06936382B2 Lithium batteries 有权
标题翻译：锂电池
公开(公告)号：US06936382B2
公开(公告)日：2005-08-30
申请号：US10390516
申请日：2003-03-17
申请人： Yuriy V. Mikhaylik , Terje A. Skotheim , Boris A. Trofimov
发明人： Yuriy V. Mikhaylik , Terje A. Skotheim , Boris A. Trofimov
IPC分类号： H01M6/16 , B41J2/365 , H01M4/06 , H01M4/134 , H01M4/136 , H01M4/38 , H01M4/40 , H01M4/58 , H01M4/60 , H01M10/052 , H01M10/0567 , H01M10/36 , H01M10/42 , H01M10/40
CPC分类号： H01M10/4235 , B41J2/3555 , B41J2/365 , H01M4/134 , H01M4/136 , H01M4/38 , H01M4/5815 , H01M4/60 , H01M4/602 , H01M6/168 , H01M10/052 , H01M10/0567 , Y10T29/49108
摘要： Provided is a lithium battery in which the cathode comprises an electroactive sulfur-containing material and the electrolyte comprises a lithium salt, a non-aqueous solvent, and one or more capacity-enhancing reactive components. Suitable reactive components include electron transfer mediators. Also are provided methods for making the lithium battery.
摘要翻译：提供了一种锂电池，其中阴极包含电活性含硫材料，电解质包含锂盐，非水溶剂和一种或多种增强能量的反应性组分。合适的反应性组分包括电子转移介质。还提供了制造锂电池的方法。

9. 发明授权

US06406814B1 Method of forming cathodes comprising electroactive sulfur materials 失效
标题翻译：形成包含电活性硫材料的阴极的方法
公开(公告)号：US06406814B1
公开(公告)日：2002-06-18
申请号：US09703348
申请日：2000-10-31
申请人： Alexander Gorkovenko , Terje A. Skotheim , Zhe-Sheng Xu , Leonid I. Boguslavsky , Zhongyi Deng , Shyama P. Mukherjee
发明人： Alexander Gorkovenko , Terje A. Skotheim , Zhe-Sheng Xu , Leonid I. Boguslavsky , Zhongyi Deng , Shyama P. Mukherjee
IPC分类号： H01M404
CPC分类号： H01M4/136 , H01M4/0485 , H01M4/137 , H01M4/36 , H01M4/40 , H01M4/581 , H01M4/5815 , H01M4/583 , H01M4/587 , H01M4/60 , H01M4/602 , H01M4/62 , H01M4/622 , H01M4/623 , H01M4/624 , H01M10/052 , H01M10/3909 , H01M2004/027 , H01M2004/028 , Y10S977/753 , Y10S977/948 , Y10T29/49108
摘要： The present invention pertains to solid composite cathodes which comprise (a) an electroactive sulfur-containing cathode material which, in its oxidized state, comprises a polysulfide moiety of the formula, —Sm—, wherein m is an integer from 3 to 10; and (b) a non-electroactive particulate material having a strong adsorption of soluble polysulfides. The present invention also pertains to electric current producing cells comprising such solid composite cathodes, and methods of making such solid composite cathodes and electric current producing cells.
摘要翻译：本发明涉及固体复合阴极，其包含（a）电活性含硫阴极材料，其在其氧化态中包含下式的多硫化物部分-Sm-，其中m为3至10的整数; 和（b）具有强吸附可溶性多硫化物的非电活性颗粒材料。本发明还涉及包含这种固体复合阴极的电流产生电池，以及制备这种固体复合阴极和电流产生电池的方法。

10. 发明授权

US06306545B1 Separators for electrochemical cells 有权
标题翻译：电化学电池分离器
公开(公告)号：US06306545B1
公开(公告)日：2001-10-23
申请号：US09215112
申请日：1998-12-17
申请人： Steven A. Carlson , Qicong Ying , Zhongyi Deng , Terje A. Skotheim
发明人： Steven A. Carlson , Qicong Ying , Zhongyi Deng , Terje A. Skotheim
IPC分类号： H01M216
CPC分类号： H01M10/0525 , B01D71/025 , H01M2/16 , H01M2/1646 , H01M2/1673 , H01M4/136 , H01M6/14 , H01M10/05 , H01M10/052 , H01M10/0563 , H01M10/0565 , H01M2300/0017 , H01M2300/0068 , Y10T29/49115
摘要： This invention pertains to separators for electrochemical cells which comprise a microporous pseudo-boehmite layer; electrolyte elements comprising such separators; electrical current producing cells comprising such separators; and methods of making such separators, electrolyte elements and cells.
摘要翻译：本发明涉及包含微孔假勃姆石层的电化学电池隔板; 包括这种分离器的电解质元件; 包括这种分离器的电流产生电池; 以及制造这种分离器，电解质元件和电池的方法。

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