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1. 发明授权

US4842940A Electrodeposition coating composition, electrodeposition process and electrodeposited article 失效
标题翻译：电沉积涂料组合物，电沉积工艺和电沉积制品
公开(公告)号：US4842940A
公开(公告)日：1989-06-27
申请号：US935418
申请日：1986-11-26
申请人： Tatsushiro Yoshimura , Nobuyuki Tomihashi , Tsutomu Terada
发明人： Tatsushiro Yoshimura , Nobuyuki Tomihashi , Tsutomu Terada
IPC分类号： C09D5/44 , C09D127/12 , C25D13/06
CPC分类号： C09D5/4407 , Y10S524/901 , Y10T428/31544
摘要： An electrodeposition coating composition comprising a fluorine-containing copolymer having an anionic functional group, a curing agent and water, said copolymer comprising:(a) 20 to 80% by mole of the structural unit of the formula (1):--CFX--CF.sub.2 -- (1)(b) 5 to 60% by mole of the structural unit of the formula (2): ##STR1## (c) 0 to 40% by mole of the structural unit of the formula (3): ##STR2## (d) 0 to 40% by mole of the structural unit of the formula (4): ##STR3## the total amount of the structural units (a), (b), (c) and (d) being 100% by mole. The composition of the invention can be baked to substrates at a low temperature in comparison with compositions containing conventional fluorine-containing copolymers, and the films obtained by electrodepositing the composition are excellent in gloss, weatherability, adhesion to the substrates, alkali resistance and smoothness.
摘要翻译：一种电沉积涂料组合物，其包含具有阴离子官能团的含氟共聚物，固化剂和水，所述共聚物包含：（a）20至80摩尔％的式（1）的结构单元：-CFX-CF 2 - （1）（b）式（2）的结构单元为5〜60摩尔％：（2）（c）式（3）的结构单元为0〜40摩尔％（3）（d）式（4）的结构单元为0〜40摩尔％：（4）结构单元（a），（b），（c）的总量，（d）为100摩尔％。与含有常规含氟共聚物的组合物相比，本发明的组合物可以在低温下烘烤至基材，并且通过电沉积该组合物获得的膜具有优异的光泽度，耐候性，对基材的粘附性，耐碱性和平滑性。

2. 发明授权

US5066747A Vinyl ethers and fluorine-containing copolymers prepared therefrom 失效
标题翻译：乙烯和含氟聚合物的制备
公开(公告)号：US5066747A
公开(公告)日：1991-11-19
申请号：US588872
申请日：1990-09-27
申请人： Tatsushiro Yoshimura , Nobuyuki Tomihashi , Tsutomu Terada , Masayuki Yamana , Kazuhiro Nakai , Takayuki Araki
发明人： Tatsushiro Yoshimura , Nobuyuki Tomihashi , Tsutomu Terada , Masayuki Yamana , Kazuhiro Nakai , Takayuki Araki
IPC分类号： C08F216/14 , C07C69/01 , C07C69/353 , C07C69/40 , C07C69/593 , C07C69/74 , C07C69/743 , C07C69/75 , C07C69/76 , C07C69/767 , C08F2/00 , C08F14/18 , C08F16/14 , C08F16/26 , C08F20/10 , C08F32/00 , C08F214/18 , C08F220/40 , C08F232/06 , C08F232/08
CPC分类号： C08F214/184 , C07C69/40 , C07C69/60 , C07C69/74 , C07C69/75 , C07C69/753 , C08F16/26 , C07C2101/14 , C07C2102/42
摘要： Vinyl ethers having a carboxyl group in a form of salt are stable and is usable as materials for fluorine-containing copolymers. The vinyl ethers can provide stable monomer compositions by mixing with vinyl ethers having a free carboxyl group when the former vinyl ethers are present in an amount of not less than 1% by mole of the latter vinyl ethers. The fluorine-containing copolymer prepared by copolymerizing fluoroolefins with the vinyl ethers are useful as aqueous coatings particularly electro dip coatings.

3. 发明授权

US4970331A Vinyl ethers and fluorine-containing copolymers prepared therefrom 失效
标题翻译：由其制备的乙烯基醚和含氟共聚物
公开(公告)号：US4970331A
公开(公告)日：1990-11-13
申请号：US168073
申请日：1988-03-09
申请人： Tatsushiro Yoshimura , Nobuyuki Tomihashi , Tsutomu Terada , Masayuki Yamana , Kazuhiro Nakai , Takayuki Araki
发明人： Tatsushiro Yoshimura , Nobuyuki Tomihashi , Tsutomu Terada , Masayuki Yamana , Kazuhiro Nakai , Takayuki Araki
IPC分类号： C08F216/14 , C07C69/01 , C07C69/353 , C07C69/40 , C07C69/593 , C07C69/74 , C07C69/743 , C07C69/75 , C07C69/76 , C07C69/767 , C08F2/00 , C08F14/18 , C08F16/14 , C08F16/26 , C08F20/10 , C08F32/00 , C08F214/18 , C08F220/40 , C08F232/06 , C08F232/08
CPC分类号： C08F214/184 , C07C69/40 , C07C69/60 , C07C69/74 , C07C69/75 , C07C69/753 , C08F16/26 , C07C2101/14 , C07C2102/42
摘要： Vinyl ethers having a carboxyl group in a form of salt are stable and is usable as materials for fluorine-containing copolymers. The vinyl ethers can provide sable monomer compositions by mixing with vinyl ethers having a free carboxyl group when the former vinyl ethers are present in an amount of not less than 1% by mole of the latter vinyl ethers. The fluorine-containing copolymer prepared by copolymerizing fluoroolefins with the vinyl ethers are useful as aqueous coatings particularly electro dip coatings.

4. 发明授权

US4977221A Powders of tetrafluoroethylene copolymer and process for preparing the same 失效
公开(公告)号：US4977221A
公开(公告)日：1990-12-11
申请号：US458480
申请日：1989-12-28
申请人： Tatsushiro Yoshimura , Nobuyuki Tomihashi , Shuhei Simasaki
发明人： Tatsushiro Yoshimura , Nobuyuki Tomihashi , Shuhei Simasaki
IPC分类号： B29B9/04 , B29B9/00 , C08F214/26 , C08J3/12
CPC分类号： C08J3/12 , B29B9/00 , C08J3/122 , C08J2327/18 , Y10T428/2982
摘要： Powders of tetrafluoroethylene copolymer having a non-spherical particle shape, a frictional packing ratio of 20 to 200% and an average particle size of 5 to 500 .mu.m. The powders are useful for powder coatings, particularly roto-molding, roto-lining and electrostatic coating.

5. 发明授权

US5130201A Vinylidene fluoride resin composition 失效
标题翻译：乙烯基氟化物树脂组合物
公开(公告)号：US5130201A
公开(公告)日：1992-07-14
申请号：US511899
申请日：1990-04-23
申请人： Tatsushiro Yoshimura , Nobuyuki Tomihashi , Akira Chida
发明人： Tatsushiro Yoshimura , Nobuyuki Tomihashi , Akira Chida
IPC分类号： C08L27/12 , C08L27/14 , C08L27/16 , C08L63/00 , C09D127/04 , C09D127/06 , C09D127/12 , C09D127/16 , C09D161/04 , C09D161/20 , C09D161/34 , C09D163/00 , C09D167/00 , C09D175/00 , C09D175/02 , C09D179/08
CPC分类号： C08L27/16 , C08L63/00 , Y10T428/31511 , Y10T428/31515 , Y10T428/31522 , Y10T428/3154
摘要： A vinylidene fluoride resin composition which comprises (A) 10 to 95 parts by weight of a vinylidene fluoride resin, (B) 1 to 80 parts by weight of a resin having a poor compatibility with said vinylidene fluoride resin (A), and (C) 1 to 30 parts by weight of a resin having an excellent compatibility with both said vinylidene fluoride resin (A) and said resin (B), total amount of said resins (A), (B) and (C) being 100 parts by weight. The film obtained by baking the composition of the present invention has the structure that the surface side is rich in the VdF resin, and the excellent adhesion to the substrate. Consequently, the film has the excellent chemical resistance, adhesion to a substrate, and the like.

6. 发明授权

US4853425A Melt-processable fluorine-containing resin composition 失效
标题翻译：可熔融加工的含氟树脂组合物
公开(公告)号：US4853425A
公开(公告)日：1989-08-01
申请号：US122084
申请日：1987-11-17
申请人： Tatsushiro Yoshimura , Nobuyuki Tomihashi , Shuhei Shimasaki
发明人： Tatsushiro Yoshimura , Nobuyuki Tomihashi , Shuhei Shimasaki
IPC分类号： C08K3/04 , C08F16/14 , C08F214/26 , C08F216/14 , C08K3/00 , C08K3/08 , C08K3/22 , C08K5/00 , C08K5/04 , C08K5/09 , C08K5/13 , C08K5/17 , C08K5/36 , C08K5/37 , C08K5/49 , C08K5/57 , C08K13/02 , C08L27/12 , C08L27/18 , C08L29/10
CPC分类号： C08K5/005 , C08K13/02 , C08K3/08
摘要： 1. A melt-processable fluorine-containing resin composition comprising:(A) a fluorovinyl ether-tetrafluoroethylene copolymer and(B) a thermal stabilizer in an amount of not less than 0.01 to less than 500 ppm of said copolymer (A). When using the composition of the present invention, the bubbles formation is not caused upon sintering and the obtained product is not colored.

7. 发明授权

US4898779A Powders of tetrafluoroethylene copolymer and process for preparing the same 失效
标题翻译：四氟乙烯共聚物粉末及其制备方法
公开(公告)号：US4898779A
公开(公告)日：1990-02-06
申请号：US135217
申请日：1987-12-21
申请人： Tatsushiro Yoshimura , Nobuyuki Tomihashi , Shuhei Simasaki
发明人： Tatsushiro Yoshimura , Nobuyuki Tomihashi , Shuhei Simasaki
IPC分类号： B29B9/04 , B29B9/00 , C08F214/26 , C08J3/12
CPC分类号： C08J3/12 , B29B9/00 , C08J3/122 , C08J2327/18 , Y10T428/2982
摘要： Powders of tetrafluoroethylene copolymer having a non-spherical particle shape, a frictional packing ratio of 20 to 100% and an average particle size of 5 to 500 .mu.m. The powders are useful for powder coatings, particularly roto-moulding, roto-lining and electrostatic coating.

8. 发明授权

US4503179A Aqueous fluorine-containing rubber coating composition and article coated therewith 失效
标题翻译：水性含氟橡胶涂料组合物及其制品
公开(公告)号：US4503179A
公开(公告)日：1985-03-05
申请号：US348370
申请日：1982-02-12
申请人： Tatsushiro Yoshimura , Tsutomu Terada , Shozo Nakayama
发明人： Tatsushiro Yoshimura , Tsutomu Terada , Shozo Nakayama
IPC分类号： C08L27/12 , C08K5/49 , C08K5/544 , C08L1/00 , C08L27/00 , C09D115/02 , C09D127/12 , C09K3/10 , C08K5/54
CPC分类号： C08K5/544 , C09D127/12 , C08L2205/02 , C08L27/12
摘要： An aqueous fluorine-containing rubber coating composition comprising (a) fluorine-containing rubber, (b) fluorine-containing resin, (c) an aminosilane compound of the formula: ##STR1## wherein R is methyl or ethyl; X is a single bond or --(CH.sub.2).sub.2 --NH--, --CONH-- or --(CH.sub.2).sub.2 --NH--(CH.sub.2).sub.2 --NH--; and n is 2 or 3, and (d) an aqueous liquid vehicle, the weight ratio of the component (a) and the component (b) being from 95:5 to 35:65, which makes the resultant coating film non-adherent and more lubricous.
摘要翻译：一种含氟橡胶涂料组合物，其包含（a）含氟橡胶，（b）含氟树脂，（c）下式的氨基硅烷化合物：其中R是甲基或乙基; X是单键或 - （CH 2）2 -NH-，-CONH-或 - （CH 2）2 -NH-（CH 2）2 -NH-; n为2或3，和（d）水性液体载体，组分（a）和组分（b）的重量比为95:5至35:65，这使得所得涂膜不粘附和更多的润滑。

9. 发明授权

US4482476A Fluoroelastomer-containing non-tacky electrically conductive coating composition 失效
标题翻译：含氟弹性体的非粘性导电涂料组合物
公开(公告)号：US4482476A
公开(公告)日：1984-11-13
申请号：US440172
申请日：1982-11-08
申请人： Tatsushiro Yoshimura , Norimasa Honda , Tsutomu Terada
发明人： Tatsushiro Yoshimura , Norimasa Honda , Tsutomu Terada
IPC分类号： C08L27/12 , C08L1/00 , C08L27/00 , C08L57/00 , C09D5/24 , C09D127/12 , H01B1/20 , H01B1/22 , H01B1/24 , H01B1/06
CPC分类号： H01B1/20 , C09D5/24 , H01B1/22 , H01B1/24
摘要： A fluoroelastomer-containing non-tacky electrically conductive coating composition which comprises (a) a fluoroelastomer, (b) a fluororesin, (c) a coupling agent, (d) an electrically conducting material, (e) a liquid vehicle and optionally (f) an inorganic fibrous material, the weight ratio of the fluoroelastomer (a) and the fluororesin (b) being from 95:5 to 35:65, a coating film formed from which has electrical conductivity as well as the properties inherent to the fluoroelastomer.
摘要翻译：一种含氟弹性体的非粘性导电涂料组合物，其包含（a）含氟弹性体，（b）氟树脂，（c）偶联剂，（d）导电材料，（e）液体载体和任选的）无机纤维材料，含氟弹性体（a）和氟树脂（b）的重量比为95:5至35:65，由其形成的涂膜具有导电性以及含氟弹性体固有的性质。

10. 发明授权

US4521596A Fluororesin-containing coating composition 失效
标题翻译：含氟树脂的涂料组合物
公开(公告)号：US4521596A
公开(公告)日：1985-06-04
申请号：US423189
申请日：1982-09-24
申请人： Tatsushiro Yoshimura , Shigetake Tominaga
发明人： Tatsushiro Yoshimura , Shigetake Tominaga
IPC分类号： C08L27/12 , C08K3/00 , C08K3/22 , C08K3/24 , C08K3/28 , C08K3/32 , C08K3/36 , C08L1/00 , C08L27/00 , C09D5/08 , C09D127/12 , C23C22/42 , C08K3/10
CPC分类号： C23C22/42 , C09D127/12 , C09D5/08
摘要： An aqueous coating composition comprising a fluororesin, and (a) molybdic acid or its salt, (b) phosphoric acid or its salt, (c) ammonium hydroxide and (d) colloidal silica, the weight ratio of the fluororesin to the total amount of the ingredients (a), (b), (c) and (d) being 90:10 to 20:80 and the molar ratio of (a) molybdic acid or its salt as converted to MoO.sub.3, (b) phosphoric acid or its salt as converted to orthophosphoric acid, (c) ammonium hydroxide and (d) colloidal silica being 1:1:1:1 to 1:20:15:20 has good adhesivity, good corrosion resistance and heat resistance without exerting any toxicity and causing any pollution problem.
摘要翻译：包含氟树脂和（a）钼酸或其盐的水性涂料组合物，（b）磷酸或其盐，（c）氢氧化铵和（d）胶体二氧化硅，氟树脂与总氟化物的总重量比成分（a），（b），（c）和（d）为90:10至20:80，（a）钼酸或其盐转化为MoO 3的摩尔比，（b）磷酸或其盐转化为正磷酸，（c）氢氧化铵和（d）胶体二氧化硅的1:1:1:1至1:20:15:20具有良好的粘合性，良好的耐腐蚀性和耐热性，而不产生任何毒性并引起任何污染问题。

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