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1. 发明授权

US4853425A Melt-processable fluorine-containing resin composition 失效
标题翻译：可熔融加工的含氟树脂组合物
公开(公告)号：US4853425A
公开(公告)日：1989-08-01
申请号：US122084
申请日：1987-11-17
申请人： Tatsushiro Yoshimura , Nobuyuki Tomihashi , Shuhei Shimasaki
发明人： Tatsushiro Yoshimura , Nobuyuki Tomihashi , Shuhei Shimasaki
IPC分类号： C08K3/04 , C08F16/14 , C08F214/26 , C08F216/14 , C08K3/00 , C08K3/08 , C08K3/22 , C08K5/00 , C08K5/04 , C08K5/09 , C08K5/13 , C08K5/17 , C08K5/36 , C08K5/37 , C08K5/49 , C08K5/57 , C08K13/02 , C08L27/12 , C08L27/18 , C08L29/10
CPC分类号： C08K5/005 , C08K13/02 , C08K3/08
摘要： 1. A melt-processable fluorine-containing resin composition comprising:(A) a fluorovinyl ether-tetrafluoroethylene copolymer and(B) a thermal stabilizer in an amount of not less than 0.01 to less than 500 ppm of said copolymer (A). When using the composition of the present invention, the bubbles formation is not caused upon sintering and the obtained product is not colored.

2. 发明授权

US5130201A Vinylidene fluoride resin composition 失效
标题翻译：乙烯基氟化物树脂组合物
公开(公告)号：US5130201A
公开(公告)日：1992-07-14
申请号：US511899
申请日：1990-04-23
申请人： Tatsushiro Yoshimura , Nobuyuki Tomihashi , Akira Chida
发明人： Tatsushiro Yoshimura , Nobuyuki Tomihashi , Akira Chida
IPC分类号： C08L27/12 , C08L27/14 , C08L27/16 , C08L63/00 , C09D127/04 , C09D127/06 , C09D127/12 , C09D127/16 , C09D161/04 , C09D161/20 , C09D161/34 , C09D163/00 , C09D167/00 , C09D175/00 , C09D175/02 , C09D179/08
CPC分类号： C08L27/16 , C08L63/00 , Y10T428/31511 , Y10T428/31515 , Y10T428/31522 , Y10T428/3154
摘要： A vinylidene fluoride resin composition which comprises (A) 10 to 95 parts by weight of a vinylidene fluoride resin, (B) 1 to 80 parts by weight of a resin having a poor compatibility with said vinylidene fluoride resin (A), and (C) 1 to 30 parts by weight of a resin having an excellent compatibility with both said vinylidene fluoride resin (A) and said resin (B), total amount of said resins (A), (B) and (C) being 100 parts by weight. The film obtained by baking the composition of the present invention has the structure that the surface side is rich in the VdF resin, and the excellent adhesion to the substrate. Consequently, the film has the excellent chemical resistance, adhesion to a substrate, and the like.

3. 发明授权

US5066747A Vinyl ethers and fluorine-containing copolymers prepared therefrom 失效
标题翻译：乙烯和含氟聚合物的制备
公开(公告)号：US5066747A
公开(公告)日：1991-11-19
申请号：US588872
申请日：1990-09-27
申请人： Tatsushiro Yoshimura , Nobuyuki Tomihashi , Tsutomu Terada , Masayuki Yamana , Kazuhiro Nakai , Takayuki Araki
发明人： Tatsushiro Yoshimura , Nobuyuki Tomihashi , Tsutomu Terada , Masayuki Yamana , Kazuhiro Nakai , Takayuki Araki
IPC分类号： C08F216/14 , C07C69/01 , C07C69/353 , C07C69/40 , C07C69/593 , C07C69/74 , C07C69/743 , C07C69/75 , C07C69/76 , C07C69/767 , C08F2/00 , C08F14/18 , C08F16/14 , C08F16/26 , C08F20/10 , C08F32/00 , C08F214/18 , C08F220/40 , C08F232/06 , C08F232/08
CPC分类号： C08F214/184 , C07C69/40 , C07C69/60 , C07C69/74 , C07C69/75 , C07C69/753 , C08F16/26 , C07C2101/14 , C07C2102/42
摘要： Vinyl ethers having a carboxyl group in a form of salt are stable and is usable as materials for fluorine-containing copolymers. The vinyl ethers can provide stable monomer compositions by mixing with vinyl ethers having a free carboxyl group when the former vinyl ethers are present in an amount of not less than 1% by mole of the latter vinyl ethers. The fluorine-containing copolymer prepared by copolymerizing fluoroolefins with the vinyl ethers are useful as aqueous coatings particularly electro dip coatings.

4. 发明授权

US4970331A Vinyl ethers and fluorine-containing copolymers prepared therefrom 失效
标题翻译：由其制备的乙烯基醚和含氟共聚物
公开(公告)号：US4970331A
公开(公告)日：1990-11-13
申请号：US168073
申请日：1988-03-09
申请人： Tatsushiro Yoshimura , Nobuyuki Tomihashi , Tsutomu Terada , Masayuki Yamana , Kazuhiro Nakai , Takayuki Araki
发明人： Tatsushiro Yoshimura , Nobuyuki Tomihashi , Tsutomu Terada , Masayuki Yamana , Kazuhiro Nakai , Takayuki Araki
IPC分类号： C08F216/14 , C07C69/01 , C07C69/353 , C07C69/40 , C07C69/593 , C07C69/74 , C07C69/743 , C07C69/75 , C07C69/76 , C07C69/767 , C08F2/00 , C08F14/18 , C08F16/14 , C08F16/26 , C08F20/10 , C08F32/00 , C08F214/18 , C08F220/40 , C08F232/06 , C08F232/08
CPC分类号： C08F214/184 , C07C69/40 , C07C69/60 , C07C69/74 , C07C69/75 , C07C69/753 , C08F16/26 , C07C2101/14 , C07C2102/42
摘要： Vinyl ethers having a carboxyl group in a form of salt are stable and is usable as materials for fluorine-containing copolymers. The vinyl ethers can provide sable monomer compositions by mixing with vinyl ethers having a free carboxyl group when the former vinyl ethers are present in an amount of not less than 1% by mole of the latter vinyl ethers. The fluorine-containing copolymer prepared by copolymerizing fluoroolefins with the vinyl ethers are useful as aqueous coatings particularly electro dip coatings.

5. 发明授权

US4977221A Powders of tetrafluoroethylene copolymer and process for preparing the same 失效
公开(公告)号：US4977221A
公开(公告)日：1990-12-11
申请号：US458480
申请日：1989-12-28
申请人： Tatsushiro Yoshimura , Nobuyuki Tomihashi , Shuhei Simasaki
发明人： Tatsushiro Yoshimura , Nobuyuki Tomihashi , Shuhei Simasaki
IPC分类号： B29B9/04 , B29B9/00 , C08F214/26 , C08J3/12
CPC分类号： C08J3/12 , B29B9/00 , C08J3/122 , C08J2327/18 , Y10T428/2982
摘要： Powders of tetrafluoroethylene copolymer having a non-spherical particle shape, a frictional packing ratio of 20 to 200% and an average particle size of 5 to 500 .mu.m. The powders are useful for powder coatings, particularly roto-molding, roto-lining and electrostatic coating.

6. 发明授权

US4842940A Electrodeposition coating composition, electrodeposition process and electrodeposited article 失效
标题翻译：电沉积涂料组合物，电沉积工艺和电沉积制品
公开(公告)号：US4842940A
公开(公告)日：1989-06-27
申请号：US935418
申请日：1986-11-26
申请人： Tatsushiro Yoshimura , Nobuyuki Tomihashi , Tsutomu Terada
发明人： Tatsushiro Yoshimura , Nobuyuki Tomihashi , Tsutomu Terada
IPC分类号： C09D5/44 , C09D127/12 , C25D13/06
CPC分类号： C09D5/4407 , Y10S524/901 , Y10T428/31544
摘要： An electrodeposition coating composition comprising a fluorine-containing copolymer having an anionic functional group, a curing agent and water, said copolymer comprising:(a) 20 to 80% by mole of the structural unit of the formula (1):--CFX--CF.sub.2 -- (1)(b) 5 to 60% by mole of the structural unit of the formula (2): ##STR1## (c) 0 to 40% by mole of the structural unit of the formula (3): ##STR2## (d) 0 to 40% by mole of the structural unit of the formula (4): ##STR3## the total amount of the structural units (a), (b), (c) and (d) being 100% by mole. The composition of the invention can be baked to substrates at a low temperature in comparison with compositions containing conventional fluorine-containing copolymers, and the films obtained by electrodepositing the composition are excellent in gloss, weatherability, adhesion to the substrates, alkali resistance and smoothness.
摘要翻译：一种电沉积涂料组合物，其包含具有阴离子官能团的含氟共聚物，固化剂和水，所述共聚物包含：（a）20至80摩尔％的式（1）的结构单元：-CFX-CF 2 - （1）（b）式（2）的结构单元为5〜60摩尔％：（2）（c）式（3）的结构单元为0〜40摩尔％（3）（d）式（4）的结构单元为0〜40摩尔％：（4）结构单元（a），（b），（c）的总量，（d）为100摩尔％。与含有常规含氟共聚物的组合物相比，本发明的组合物可以在低温下烘烤至基材，并且通过电沉积该组合物获得的膜具有优异的光泽度，耐候性，对基材的粘附性，耐碱性和平滑性。

7. 发明授权

US4898779A Powders of tetrafluoroethylene copolymer and process for preparing the same 失效
标题翻译：四氟乙烯共聚物粉末及其制备方法
公开(公告)号：US4898779A
公开(公告)日：1990-02-06
申请号：US135217
申请日：1987-12-21
申请人： Tatsushiro Yoshimura , Nobuyuki Tomihashi , Shuhei Simasaki
发明人： Tatsushiro Yoshimura , Nobuyuki Tomihashi , Shuhei Simasaki
IPC分类号： B29B9/04 , B29B9/00 , C08F214/26 , C08J3/12
CPC分类号： C08J3/12 , B29B9/00 , C08J3/122 , C08J2327/18 , Y10T428/2982
摘要： Powders of tetrafluoroethylene copolymer having a non-spherical particle shape, a frictional packing ratio of 20 to 100% and an average particle size of 5 to 500 .mu.m. The powders are useful for powder coatings, particularly roto-moulding, roto-lining and electrostatic coating.

8. 发明申请

US20100028547A1 POLYBENZIMIDAZOLE COATING COMPOSITION 审中-公开
标题翻译：聚苯并咪唑涂料组合物
公开(公告)号：US20100028547A1
公开(公告)日：2010-02-04
申请号：US12448500
申请日：2007-12-25
申请人： Akihiko Shiga , Yoshitaka Yoshida , Nobuyuki Tomihashi , Yusei Katou
发明人： Akihiko Shiga , Yoshitaka Yoshida , Nobuyuki Tomihashi , Yusei Katou
IPC分类号： B05D3/02 , C09D139/04
CPC分类号： C09D179/04 , C08L79/04 , C09D7/65
摘要： The present invention provides a polybenzimidazole coating composition that can be easily applied to a base material and is capable of forming a coating film having a large thickness. In this composition, particulate polybenzimidazole is dispersed in a mixed solvent. The mixed solvent contains water and a polar solvent in which the polybenzimidazole dissolves at a high solubility.
摘要翻译：本发明提供一种能够容易地涂布在基材上并且能够形成厚度大的涂膜的聚苯并咪唑涂料组合物。在该组合物中，聚苯并咪唑颗粒分散在混合溶剂中。混合溶剂含有水和极性溶剂，其中聚苯并咪唑以高溶解度溶解。

9. 发明授权

US07550530B2 Water-based fluororubber composition for vulcanization and coated article 有权
标题翻译：用于硫化和涂层制品的水基氟橡胶组合物
公开(公告)号：US07550530B2
公开(公告)日：2009-06-23
申请号：US10558981
申请日：2004-06-01
申请人： Nobuyuki Tomihashi , Koichiro Ogita , Kiyotaro Terasaka
发明人： Nobuyuki Tomihashi , Koichiro Ogita , Kiyotaro Terasaka
IPC分类号： C08G75/02
CPC分类号： C09D127/16 , C08K5/0025 , C08L27/12 , C08L71/02 , Y10T428/2933 , C08L2666/02 , C08L2666/14
摘要： An aqueous fluoroelastomer curable composition including two liquids of a main material fluoroelastomer aqueous dispersion (I) and a fluoroelastomer-curing agent aqueous solution (II), wherein the above main material fluoroelastomer aqueous dispersion (I) is an aqueous dispersion having a pH of 6.5 to 8.5, comprising a fluoroelastomer (A), a dispersant (B), an acid acceptor (C) and a salt (D) composed of an acid with a pKa of 3 to 7 and a base with a pKa of 8 to 12, and the above fluoroelastomer-curing agent aqueous solution (II) is an aqueous solution including a fluoroelastomer-curing agent.
摘要翻译：一种包含主要含氟弹性体水分散体（I）和含氟弹性体固化剂水溶液（II）的两种液体的含氟弹性体固化性组合物，其中上述主要含氟弹性体水分散体（I）是pH为6.5的水分散体至8.5，包含含氟弹性体（A），分散剂（B），酸受体（C）和由pKa为3〜7的酸组成的盐（D）和pKa为8〜12的碱，上述含氟弹性体固化剂水溶液（II）是含氟弹性体固化剂的水溶液。

10. 发明授权

US07034076B2 Coating composition, fluorine-containing laminate and resin composition 有权
标题翻译：涂料组合物，含氟层压板和树脂组合物
公开(公告)号：US07034076B2
公开(公告)日：2006-04-25
申请号：US10740900
申请日：2003-12-22
申请人： Hiroshi Torii , Nobuyuki Tomihashi , Daisuke Mikame , Yoshihiro Soda , Koichiro Ogita
发明人： Hiroshi Torii , Nobuyuki Tomihashi , Daisuke Mikame , Yoshihiro Soda , Koichiro Ogita
IPC分类号： C08L79/08 , C08L81/04
CPC分类号： C09D179/08 , C08L77/00 , C08L79/08 , C08L81/02 , C09D5/002 , C09D5/036 , C09D181/02 , Y10T428/31551 , Y10T428/31681 , Y10T428/31692 , Y10T428/31699 , Y10T428/31721 , Y10T428/31725 , Y10T428/3175 , Y10T428/31757 , C08L81/00 , C08L2666/20
摘要： A coating composition including an amide group-containable macromolecule compound (A) having an amide group or to have an amide group and an anti-oxidizing material (B) capable of inhibiting oxidation of the amide group. The amide group-containable macromolecule compound (A) is an amide group-containing polymer (a1) having an amide group and an aromatic ring, and/or an amide group-containing-polymer precursor (a2) to convert into the amide group-containing polymer (a1) by baking at a time of coating with said coating composition. The anti-oxidizing material (B) accounts for 0.1 to 20 mass % of a total amount of said amnide group-containable macromolecule compound (A) and the anti-oxidizing material (B).
摘要翻译：一种包含具有酰胺基的酰胺基的高分子化合物（A）或能够抑制酰胺基氧化的酰胺基和抗氧化性物质（B）的涂料组合物。含酰胺基的高分子化合物（A）是具有酰胺基和芳香环的含酰胺基的聚合物（a1）和/或含酰胺基的聚合物前体（a2），以转化成酰胺基 - （a1）通过在涂布组合物涂布时进行烘烤。所述抗氧化性物质（B）占所述含有氨基封端基的高分子化合物（A）和抗氧化性物质（B）的总量的0.1〜20质量％。

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