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    • 8. 发明授权
    • Graphite particle, carbon-graphite composite particle and their production processes
    • 石墨颗粒,碳 - 石墨复合颗粒及其生产工艺
    • US08329136B2
    • 2012-12-11
    • US12086432
    • 2006-12-13
    • Tatsuo UmenoTakashi Iwao
    • Tatsuo UmenoTakashi Iwao
    • C01B31/04H01M4/133
    • H01M4/583C01B32/20C04B35/62839C04B35/62884C04B2235/425C04B2235/528C04B2235/5292C04B2235/5296C04B2235/5409C04B2235/5436H01M4/366H01M10/0525Y10T29/49108Y10T428/2982
    • The present invention relates to a graphite particle and a carbon-graphite composite particle both suitable for use in electrode for lithium ion secondary battery, as well as to processes for producing these particles. The graphite particle of the present invention has an average particle diameter of 5 to 50 μm, wherein one or more recesses having a depth of 0.1 to 10 μm are formed in the surface. The graphite particle is produced by a mixing step for mixing raw material graphite particles and recess-forming particles, a press molding step for press-molding the mixture composed of the raw material graphite particles and the recess-forming particles to obtain a molded article, a pulverization step for pulverizing the molded article, and a separation step for separating and removing the recess-forming particles from the pulverized molded article. The carbon-graphite composite particle of the present invention is produced by performing a thermal CVD step which comprises covering the surface of the above-mentioned graphite particle with a carbon layer.
    • 本发明涉及一种适用于锂离子二次电池用电极的石墨粒子和碳 - 石墨复合粒子,以及这些粒子的制造方法。 本发明的石墨粒子的平均粒径为5〜50μm,在表面形成有深度为0.1〜10μm的一个以上的凹部。 石墨颗粒通过混合原料石墨颗粒和凹陷形成颗粒的混合步骤制备,压制成型步骤,用于将由原料石墨颗粒和凹陷形成颗粒组成的混合物压制成型, 用于粉碎模制品的粉碎步骤和用于从粉碎的模制品分离和去除凹陷形成颗粒的分离步骤。 本发明的碳 - 石墨复合颗粒通过进行热CVD步骤来制造,所述热CVD步骤包括用碳层覆盖上述石墨颗粒的表面。