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1. 发明申请

US20120196784A1 DETERGENT FORMULATIONS FOR MACHINE DISHWASHING COMPRISING HYDROPHILICALLY MODIFIED POLYCARBOXYLATES 审中-公开
标题翻译：用于疏水改性聚碳酸酯的机械洗涤剂的洗涤剂配方
公开(公告)号：US20120196784A1
公开(公告)日：2012-08-02
申请号：US13444933
申请日：2012-04-12
申请人： Tanja Seebeck , Jürgen Tropsch , Lars Kissau
发明人： Tanja Seebeck , Jürgen Tropsch , Lars Kissau
IPC分类号： C11D3/37
CPC分类号： C11D3/3757 , C11D3/33
摘要： A phosphate-free detergent formulation for machine dishwashing is provided. The formulation contains as main components: copolymers of a monoethylenically unsaturated monocarboxylic acid and/or of a salt thereof, and an alkoxylated, monoethylenically unsaturated monomer, wherein the copolymer has a mean molecular weight Mw of from 30 000 to 500 000 g/mol and a K value of from 40 to 150, measured at pH 7 in 1% by weight aqueous solution at 25° C.; complexing agents; low-foaming nonionic surfactants; bleaches and, optionally, bleach activators; further builders; enzymes; and one or more further additives.
摘要翻译：提供了一种用于机洗餐具洗涤剂的无磷酸盐洗涤剂配方。该制剂含有：单烯属不饱和一元羧酸和/或其盐的共聚物和烷氧基化单烯属不饱和单体，其中共聚物的平均分子量Mw为30000至500000g / mol，在25℃在1重量％水溶液中在pH7测量的40至150的K值。络合剂; 低泡非离子表面活性剂; 漂白剂和任选的漂白活化剂; 进一步建设者酶; 和一种或多种其它添加剂。

2. 发明授权

US08440601B2 Detergent formulations for machine dishwashing comprising hydrophilically modified polycarboxylates 有权
标题翻译：用于机洗碗碟洗涤剂的洗涤剂配方包括亲水改性的聚羧酸盐
公开(公告)号：US08440601B2
公开(公告)日：2013-05-14
申请号：US13325446
申请日：2011-12-14
申请人： Tanja Seebeck , Juergen Tropsch , Lars Kissau
发明人： Tanja Seebeck , Juergen Tropsch , Lars Kissau
IPC分类号： C11D3/37
CPC分类号： C11D3/3757 , C11D3/33
摘要： A mixed powder or mixed granule for use in detergent formulations for machine dishwashing contains the following components: a) from 10 to 95% by weight of a copolymer of a1) from 50 to 93 mol % of acrylic acid and/or of a water-soluble salt of acrylic acid, a2) from 5 to 30 mol % of methacrylic acid and/or of a water-soluble salt of methacrylic acid, and a3) from 2 to 20 mol % of at least one nonionic monomer, wherein monomers a1) to a3) are copolymerized in a random or block manner, b) from 5 to 80% by weight of a complexing agent selected from the group consisting of a glycine-N,N-diacetic acid derivative and glutamic acid N,N-diacetic acid and salts thereof, c) from 0 to 20% by weight of a polyethylene glycol, of a nonionic surfactant or of a mixture thereof.
摘要翻译：用于机洗餐具洗涤剂的洗涤剂配方中使用的混合粉末或混合颗粒包含以下组分：a）10至95重量％的a1）50-93摩尔％丙烯酸和/或水 - 丙烯酸的可溶性盐，a2）5〜30摩尔％的甲基丙烯酸和/或甲基丙烯酸的水溶性盐，以及a3）2〜20摩尔％的至少一种非离子单体，其中单体a1）至a3）以无规或嵌段方式共聚，b）5-80重量％的选自甘氨酸-N，N-二乙酸衍生物和谷氨酸N，N-二乙酸的络合剂和其盐，c）0至20重量％的聚乙二醇，非离子表面活性剂或其混合物。

3. 发明申请

US20100187724A1 PROCESS FOR PRODUCING A FREE-FLOWING AND STORAGE-STABLE SOLID COMPRISING ESSENTIALLY ALPHA-ALANINE-N,N-DIACETIC ACID AND/OR ONE OR MORE DERIVATIVES OF ALPHA-ALANINE-N,N-DIACETIC ACID 审中-公开
标题翻译：用于生产含有ALPHA-ALANINE-N，N-二酸的碱性氨基酸，N-二乙酸和/或一种或多种衍生物的自由流动和储存稳定的固体的方法
公开(公告)号：US20100187724A1
公开(公告)日：2010-07-29
申请号：US12667051
申请日：2008-06-30
申请人： Robert Heinz , Karin Flore , Lars Kissau , Thomas Heidenfelder , Tanja Seebeck , Frank Mrzena
发明人： Robert Heinz , Karin Flore , Lars Kissau , Thomas Heidenfelder , Tanja Seebeck , Frank Mrzena
IPC分类号： B29C55/18
CPC分类号： C07C227/44 , B01J2/22 , B01J2/30 , C11D7/3245 , C11D17/0047 , C07C229/16
摘要： A process is proposed for producing a free-flowing and storage-stable solid comprising essentially α-alanine-N,N-diacetic acid and/or one or more derivatives of α-alanine-N,N-diacetic acid proceeding from a powder of α-alanine-N,N-diacetic acid and/or one or more derivatives of α-alanine-N,N-diacetic acid by a. compacting the powder of α-alanine-N,N-diacetic acid on a roller press to obtain slugs, b. crushing the slugs and c. screening the crushed slugs, which comprises performing the compaction on the roller press with addition of polyethylene glycol with a melting point greater than 35° C.
摘要翻译：提出了一种制备自由流动和储存稳定的固体的方法，其基本上包含α-丙氨酸-N，N-二乙酸和/或α-丙氨酸-N，N-二乙酸的一种或多种衍生物，其由 α-丙氨酸-N，N-二乙酸和/或α-丙氨酸-N，N-二乙酸的一种或多种衍生物。在辊压机上压制α-丙氨酸-N，N-二乙酸的粉末以获得s s，b。粉碎s子和c。筛选破碎的s lug，其中包括加入熔点大于35℃的聚乙二醇在辊压机上进行压实。

4. 发明授权

US08193139B2 Cleaning formulations for machine dishwashing comprising hydrophilically modified polycarboxylates 有权
标题翻译：用于机洗碗碟洗涤的清洁配方包括亲水改性的聚羧酸盐
公开(公告)号：US08193139B2
公开(公告)日：2012-06-05
申请号：US12063036
申请日：2006-08-28
申请人： Tanja Seebeck , Juergen Tropsch , Lars Kissau
发明人： Tanja Seebeck , Juergen Tropsch , Lars Kissau
IPC分类号： C11D3/37
CPC分类号： C11D3/3757 , C11D3/33
摘要： The invention relates to a phosphate-free cleaning formulation for machine dishwashing, comprising as components: a) 1 to 20% by weight of copolymers of a1) 50 to 93 mol % acrylic acid and/or of a water-soluble salt of acrylic acid, a2) 5 to 30 mol % of methacrylic acid and/or of a water-soluble salt of methacrylic acid and a3) 2 to 20 mol % of at least one nonionic monomer of the formula (I), b) 1 to 50% by weight of complexing agents chosen from the group consisting of glycine-N,N-diacetic acid derivatives and glutamic acid-N,N-diacetic acid and salts thereof, c) 1 to 15% by weight of low-foaming nonionic surfactants, d) 0 to 30% by weight of bleaches and optionally bleach activators, e) 0 to 60% by weight of further builders, f) 0 to 8% by weight of enzymes, g) 0 to 50% by weight of one or more further additives, such as anionic or zwitterionic surfactants, bleach catalysts, alkali carriers, corrosion inhibitors, antifoams, dyes, fragrances, fillers, organic solvents and water, where the sum of components a) to g) is 100% by weight.
摘要翻译：本发明涉及用于机器洗碗机的无磷酸盐清洁制剂，其包含如下组分：a）1至20重量％的a1）50至93摩尔％丙烯酸和/或丙烯酸的水溶性盐的共聚物，a2）5〜30摩尔％的甲基丙烯酸和/或甲基丙烯酸的水溶性盐和a）2〜20摩尔％的至少一种式（I）的非离子单体，b）1〜50摩尔％的选自甘氨酸-N，N-二乙酸衍生物和谷氨酸-N，N-二乙酸及其盐的络合剂，c）1至15重量％的低泡非离子表面活性剂，d ）0至30重量％的漂白剂和任选的漂白活化剂，e）0至60重量％的其它助洗剂，f）0至8重量％的酶，g）0至50重量％的一种或多种进一步的添加剂，如阴离子或两性离子表面活性剂，漂白催化剂，碱性载体，腐蚀抑制剂，消泡剂，染料，香料，填料，有机溶剂和水组分a）至g）的总和为100重量％。

5. 发明授权

US08093196B2 Cleaning formulations for machine dishwashing comprising hydrophilically modified polycarboxylates 有权
标题翻译：用于机洗碗碟洗涤的清洁配方包括亲水改性的聚羧酸盐
公开(公告)号：US08093196B2
公开(公告)日：2012-01-10
申请号：US12783726
申请日：2010-05-20
申请人： Tanja Seebeck , Juergen Tropsch , Lars Kissau
发明人： Tanja Seebeck , Juergen Tropsch , Lars Kissau
IPC分类号： C11D3/37 , C11D1/66 , C11D3/33
CPC分类号： C11D3/3757 , C11D3/33
摘要： A phosphate-free detergent formulation for machine dishwashing is provided. The formulation contains as main components: copolymers of a monoethylenically unsaturated monocarboxylic acid and/or of a salt thereof, and an alkoxylated, monoethylenically unsaturated monomer, wherein the copolymer has a mean molecular weight Mw of from 30 000 to 500 000 g/mol and a K value of from 40 to 150, measured at pH 7 in 1% by weight aqueous solution at 25° C.; complexing agents; low-foaming nonionic surfactants; bleaches and, optionally, bleach activators; further builders; enzymes; and one or more further additives.
摘要翻译：提供了一种用于机洗餐具洗涤剂的无磷酸盐洗涤剂配方。该制剂含有：单烯属不饱和一元羧酸和/或其盐的共聚物和烷氧基化单烯属不饱和单体，其中共聚物的平均分子量Mw为30000至500000g / mol，在25℃在1重量％水溶液中在pH7测量的40至150的K值。络合剂; 低泡非离子表面活性剂; 漂白剂和任选的漂白活化剂; 进一步建设者酶; 和一种或多种其它添加剂。

6. 发明授权

US07867966B2 Mixed powder or mixed granule based on glutamic acid-N, N-diacetic acid and salts thereof 有权
标题翻译：基于谷氨酸-N，N-二乙酸及其盐的混合粉末或混合颗粒
公开(公告)号：US07867966B2
公开(公告)日：2011-01-11
申请号：US12159095
申请日：2006-12-21
申请人： Tanja Seebeck , Lars Kissau
发明人： Tanja Seebeck , Lars Kissau
IPC分类号： C11D3/33 , C11D3/37 , C11D10/02 , D06L1/00 , B08B9/20
CPC分类号： C11D1/66 , C11D1/72 , C11D3/33 , C11D3/3707 , C11D3/3753 , C11D3/3776
摘要： A mixed powder or mixed granule comprising at least 80% by weight of a mixture of (a) from 5 to 95% by weight of at least one glutamic acid-N,N-diacetic acid derivative of the general formula (I) MOOC—(CH2)2C(COOM)-N(CH2COOM)2 (I) where M is hydrogen, ammonium, alkali metal, (b) from 5 to 95% by weight of at least one polyethylene glycol or of at least one nonionic surfactant or of a mixture thereof or of a polymer selected from the group consisting of polyvinyl alcohols, polyvinylpyrrolidones (PVP), polyalkylene glycols and derivatives thereof, processes for producing these mixed powders or mixed granules, the use of these mixed powders or mixed granules, and a solid laundry detergent and a solid dishwasher detergent comprising the inventive mixed powder or mixed granule are described.
摘要翻译：包含至少80重量％的（a）5至95重量％的至少一种通式（I）的谷氨酸-N，N-二乙酸衍生物的混合粉末或混合颗粒，MOOC- （CH2）2C（COOM）-N（CH2COOM）2（I）其中M是氢，铵，碱金属，（b）5至95重量％的至少一种聚乙二醇或至少一种非离子表面活性剂或的混合物或选自聚乙烯醇，聚乙烯吡咯烷酮（PVP），聚亚烷基二醇及其衍生物的聚合物的聚合物，制备这些混合粉末或混合颗粒的方法，使用这些混合粉末或混合颗粒，以及描述了固体洗衣洗涤剂和包含本发明混合粉末或混合颗粒的固体洗碗机洗涤剂。

7. 发明申请

US20100160203A1 CLEANING FORMULATIONS FOR MACHINE DISHWASHING COMPRISING HYDROPHILICALLY MODIFIED POLYCARBOXYLATES 有权
标题翻译：用于疏水改性聚碳酸酯的机器清洗清洁配方
公开(公告)号：US20100160203A1
公开(公告)日：2010-06-24
申请号：US12063036
申请日：2006-08-28
申请人： Tanja Seebeck , Juergen Tropsch , Lars Kissau
发明人： Tanja Seebeck , Juergen Tropsch , Lars Kissau
IPC分类号： C11D3/37
CPC分类号： C11D3/3757 , C11D3/33
摘要： The invention relates to a phosphate-free cleaning formulation for machine dishwashing, comprising as components: a) 1 to 20% by weight of copolymers of a1) 50 to 93 mol % acrylic acid and/or of a water-soluble salt of acrylic acid, a2) 5 to 30 mol % of methacrylic acid and/or of a water-soluble salt of methacrylic acid and a3) 2 to 20 mol % of at least one nonionic monomer of the formula (I), b) 1 to 50% by weight of complexing agents chosen from the group consisting of glycine-N,N-diacetic acid derivatives and glutamic acid-N,N-diacetic acid and salts thereof, c) 1 to 15% by weight of low-foaming nonionic surfactants, d) 0 to 30% by weight of bleaches and optionally bleach activators, e) 0 to 60% by weight of further builders, f) 0 to 8% by weight of enzymes, g) 0 to 50% by weight of one or more further additives, such as anionic or zwitterionic surfactants, bleach catalysts, alkali carriers, corrosion inhibitors, antifoams, dyes, fragrances, fillers, organic solvents and water, where the sum of components a) to g) is 100% by weight.
摘要翻译：本发明涉及用于机器洗碗机的无磷酸盐清洁制剂，其包含如下组分：a）1至20重量％的a1）50至93摩尔％丙烯酸和/或丙烯酸的水溶性盐的共聚物，a2）5〜30摩尔％的甲基丙烯酸和/或甲基丙烯酸的水溶性盐和a）2〜20摩尔％的至少一种式（I）的非离子单体，b）1〜50摩尔％的选自甘氨酸-N，N-二乙酸衍生物和谷氨酸-N，N-二乙酸及其盐的络合剂，c）1至15重量％的低泡非离子表面活性剂，d ）0至30重量％的漂白剂和任选的漂白活化剂，e）0至60重量％的其它助洗剂，f）0至8重量％的酶，g）0至50重量％的一种或多种进一步的添加剂，如阴离子或两性离子表面活性剂，漂白催化剂，碱性载体，腐蚀抑制剂，消泡剂，染料，香料，填料，有机溶剂和水组分a）至g）的总和为100重量％。

8. 发明申请

US20080300159A1 Mixed Powder or Mixed Granule Based on Glutamic Acid-N, N-Diacetic Acid and Salts Thereof 有权
标题翻译：基于谷氨酸-N，N-二乙酸及其盐的混合粉末或混合颗粒
公开(公告)号：US20080300159A1
公开(公告)日：2008-12-04
申请号：US12159095
申请日：2006-12-21
申请人： Tanja Seebeck , Lars Kissau
发明人： Tanja Seebeck , Lars Kissau
IPC分类号： C11D17/06
CPC分类号： C11D1/66 , C11D1/72 , C11D3/33 , C11D3/3707 , C11D3/3753 , C11D3/3776
摘要： A mixed powder or mixed granule comprising at least 80% by weight of a mixture of (a) from 5 to 95% by weight of at least one glutamic acid-N,N-diacetic acid derivative of the general formula (I) MOOC—(CH2)2C(COOM)-N(CH2COOM)2 (I) where M is hydrogen, ammonium, alkali metal, (b) from 5 to 95% by weight of at least one polyethylene glycol or of at least one nonionic surfactant or of a mixture thereof or of a polymer selected from the group consisting of polyvinyl alcohols, polyvinylpyrrolidones (PVP), polyalkylene glycols and derivatives thereof, processes for producing these mixed powders or mixed granules, the use of these mixed powders or mixed granules, and a solid laundry detergent and a solid dishwasher detergent comprising the inventive mixed powder or mixed granule are described.
摘要翻译：一种混合粉末或混合颗粒，其包含至少80重量％的（a）5至95重量％的至少一种通式（I）的谷氨酸-N，N-二乙酸衍生物的混合物。 in-line-formula description =“In-line Formulas”end =“lead”？> MOOC-（CH2）2C（COOM）-N（CH2COOM）2（I）其中M为氢，铵，碱金属，（b）5至95重量％的至少一种聚乙二醇或至少一种非离子表面活性剂或其混合物，或选自聚乙烯醇，聚乙烯吡咯烷酮（PVP），聚亚烷基二醇及其衍生物的聚合物的聚合物，制备这些混合粉末或混合颗粒的方法，使用这些混合粉末或混合颗粒，以及固体衣物洗涤剂和固体描述了包含本发明混合粉末或混合颗粒的洗碗机洗涤剂。

9. 发明申请

US20080188391A1 Cleaning Formulations for Machine Dishwashing Comprising Hyrdophilically Modified Polycarboxylates 审中-公开
标题翻译：含有嗜酸性改性聚羧酸盐的洗碗机清洗配方
公开(公告)号：US20080188391A1
公开(公告)日：2008-08-07
申请号：US12065011
申请日：2006-08-29
申请人： Tanja Seebeck , Jurgen Tropsch , Lars Kissau
发明人： Tanja Seebeck , Jurgen Tropsch , Lars Kissau
IPC分类号： C11D3/36 , C11D3/20
CPC分类号： C11D3/3757 , C11D3/33
摘要： The invention relates to a phosphate-free detergent formulation for machine dishwashing comprising, as components: a) from 1 to 20% by weight of copolymers of a1) from 50 to 99.5 mol % of a monoethylenically unsaturated monocarboxylic acid and/or of a salt thereof, a2) from 0.5 to 20 mol % of an alkoxylated, monoethylenically unsaturated monomer of the formula (I) a3) from 0 to 50 mol % of a monoethylenically unsaturated dicarboxylic acid, of an anhydride and/or of a salt thereof, a4) from 0 to 20 mol % of a further copolymerizable, monoethylenically unsaturated monomer, where the copolymer has a mean molecular weight Mw of from 30 000 to 500 000 g/mol and a K value of from 40 to 150, measured at pH 7 in 1% by weight aqueous solution at 25° C., b) from 1 to 50% by weight of complexing agents selected from the group consisting of nitrilotriacetic acid, ethylenediaminetetraacetic acid, diethylenetriaminepentaacetic acid, hydroxyethylethylenediaminetriacetic acid and glycine-N,N-diacetic acid and their derivatives, glutamic acid N,N-diacetic acid, iminodisuccinate, hydroxyiminodisuccinate, S,S-ethylene-diaminedisuccinate and aspartic acid diacetic acid and also the salts of the aforementioned substances, c) from 1 to 15% by weight of low-foaming nonionic surfactants, d) from 0.1 to 30% by weight of bleaches and, if appropriate, bleach activators, e) from 0 to 60% by weight of further builders, f) from 0 to 8% by weight of enzymes, g) from 0 to 50% by weight of one or more further additives, the sum of components a) to g) adding up to 100% by weight.
摘要翻译：本发明涉及一种用于机洗餐具洗涤剂的无磷酸盐洗涤剂配方，其包含以下成分：a）1至20重量％的a1）50-99.5mol％的单烯属不饱和单羧酸和/或盐其中，a2）0.5-20mol％的式（I）的烷氧基化单烯属不饱和单体a3）0-50mol％的单烯键式不饱和二羧酸酐和/或其盐，a4 ）0至20摩尔％的另外的可共聚的单烯属不饱和单体，其中共聚物的平均分子量M 3为30 000至500 000克/摩尔，K值为40 至150，在25℃下在1重量％水溶液中在pH7测量，b）1至50重量％的选自次氮基三乙酸，乙二胺四乙酸，二亚乙基三胺五乙酸，羟乙基乙二胺三乙酸和甘氨酸-N ，N-二乙酸及其衍生物，谷氨酸N，N-二乙酸，亚氨基二琥珀酸盐，羟基亚氨基二琥珀酸盐，S，S-乙烯二胺二琥珀酸盐和天冬氨酸二乙酸，以及上述物质的盐，c）1〜15％的低发泡非离子表面活性剂，d）0.1至30重量％的漂白剂，以及适当时漂白活化剂，e）0至60重量％的其它助洗剂，f）0至8重量％的酶，g）0至50重量％的一种或多种其它添加剂，组分a）至g）的总和相加至100重量％。

10. 发明申请

US20120122748A1 DETERGENT FORMULATIONS FOR MACHINE DISHWASHING COMPRISING HYDROPHILICALLY MODIFIED POLYCARBOXYLATES 有权
标题翻译：用于疏水改性聚碳酸酯的机械洗涤剂的洗涤剂配方
公开(公告)号：US20120122748A1
公开(公告)日：2012-05-17
申请号：US13325446
申请日：2011-12-14
申请人： Tanja Seebeck , Jürgen Tropsch , Lars Kissau
发明人： Tanja Seebeck , Jürgen Tropsch , Lars Kissau
IPC分类号： C11D7/60 , C11D3/60
CPC分类号： C11D3/3757 , C11D3/33
摘要： A mixed powder or mixed granule for use in detergent formulations for machine dishwashing contains the following components: a) from 10 to 95% by weight of a copolymer of al) from 50 to 93 mol % of acrylic acid and/or of a water-soluble salt of acrylic acid, a2) from 5 to 30 mol % of methacrylic acid and/or of a water-soluble salt of methacrylic acid, and a3) from 2 to 20 mol % of at least one nonionic monomer, wherein monomers a1) to a3) are copolymerized in a random or block manner, b) from 5 to 80% by weight of a complexing agent selected from the group consisting of a glycine-N,N-diacetic acid derivative and glutamic acid N,N-diacetic acid and salts thereof, c) from 0 to 20% by weight of a polyethylene glycol, of a nonionic surfactant or of a mixture thereof.
摘要翻译：用于机洗餐具洗涤剂的洗涤剂配方中使用的混合粉末或混合颗粒包含以下组分：a）10至95重量％的共聚物，Al）为50至93摩尔％的丙烯酸和/或水 - 丙烯酸的可溶性盐，a2）5〜30摩尔％的甲基丙烯酸和/或甲基丙烯酸的水溶性盐，以及a3）2〜20摩尔％的至少一种非离子单体，其中单体a1）至a3）以无规或嵌段方式共聚，b）5-80重量％的选自甘氨酸-N，N-二乙酸衍生物和谷氨酸N，N-二乙酸的络合剂和其盐，c）0至20重量％的聚乙二醇，非离子表面活性剂或其混合物。

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