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1. 发明申请

US20060111593A1 Coupling catalyst and process using the same 审中-公开
标题翻译：偶联催化剂和工艺使用相同
公开(公告)号：US20060111593A1
公开(公告)日：2006-05-25
申请号：US11327382
申请日：2006-01-09
申请人： Tamon Itahashi , Takashi Kamikawa
发明人： Tamon Itahashi , Takashi Kamikawa
IPC分类号： C07C43/20
CPC分类号： B01J31/181 , B01J23/755 , B01J31/1805 , B01J31/1815 , B01J31/1825 , B01J31/184 , B01J31/2295 , B01J2231/4211 , B01J2531/847 , C07B37/04 , C07D213/06 , C07D213/16
摘要： There are disclosed a process for producing a coupling compound of formula (1): (Y-)n-1)R1-R2-(R1)(n′-1) (1), wherein R1 and R2 independently represent a substituted or unsubstituted aryl group, which process is characterized by reacting an unsaturated organic compound of formula (2): n′(R1X1n) (2) wherein n, n′, and R1 are the same as defined above, and X1 is the same or different and independently represents a leaving group and bonded with a sp2 carbon atom of R1 group, with a boron compound of formula (3): m{R2(BX22)n′} (3) wherein R2 and n′ are the same as defined above, X2 represents a hydroxy group, an alkoxy group, in the presence of a catalyst containing (A) a nickel compound, and (B) a nitrogen-containing cyclic compound, and the catalyst.
摘要翻译：公开了制备式（1）的偶联化合物的方法：<？in-line-formula description =“In-line Formulas”end =“lead”→（Y-）n-1）（n'-1）（1）（1）（1）（1）其中R 1和R 2独立地表示取代或未取代的芳基，其中R 1和R 2独立地表示取代或未取代的芳基该方法的特征在于使式（2）的不饱和有机化合物：<？in-line-formula description =“In-line Formulas”end =“lead”→n'（R 1> （2）<？in-line-formula description =“In-line Formulas”end =“tail”？>其中n，n' 和R 1与上述定义相同，X 1相同或不同，并且独立地表示离去基团并且与R SUP的sp2碳原子键合具有式（3）的硼化合物：<？in-line-formula description =“In-line Formulas”end =“lead”？> m {R 2 SUP / >（BX 2 其中R＆lt; 2和n'与上述定义相同，X 2表示羟基，烷氧基，在含有（A）镍化合物的催化剂和（B ）含氮环状化合物和催化剂。

2. 发明授权

US07217677B2 Method for producing coupling compound 有权
标题翻译：偶联化合物的制备方法
公开(公告)号：US07217677B2
公开(公告)日：2007-05-15
申请号：US10757148
申请日：2004-01-14
申请人： Tamon Itahashi , Takashi Kamikawa
发明人： Tamon Itahashi , Takashi Kamikawa
IPC分类号： B01J31/00
CPC分类号： C07F15/04 , C07B37/04 , C07C1/321 , C07C17/263 , C07C29/32 , C07C29/34 , C07C41/30 , C07C45/68 , C07C67/293 , C07C253/30 , C07C2523/755 , C07C2531/22 , C07C2601/14 , C07D213/30 , C07D307/42 , C07D307/79 , C07F15/045 , C07C43/205 , C07C15/107 , C07C49/76 , C07C13/28 , C07C33/20 , C07C69/157 , C07C11/02 , C07C43/164 , C07C43/2055 , C07C13/47 , C07C43/23 , C07C33/28 , C07C33/46 , C07C43/225 , C07C22/08 , C07C255/33 , C07C255/34
摘要： A method is provided for producing a specific crosscoupling compound and a specific catalyst for producing the compound. The method includes reacting in the presence of a base and a nickel compound catalyst organic halide of the formula n′(R1X1n), wherein R1 is a hydrocarbon group and the α and β carbons to X′ are sp3 carbon atoms; X1 is a chlorine, bromine, or iodine atoms, and n and n1 and 1 or 2 but not both 2, with a compound having the formula m{R2(BX22)n′} where an R2 is an aryl, heteroaryl, or alkenyl group, and n′ is 1 or 2, X2 is independently a hydroxyl group, an alkoxy or arylalkoxy group or X22 together form an alkylenedioxy or arylenedioxy group, and m represents 1 or 2 but m≦n, and the boron atom is bonded to a sp2 carbon atom of R2 group or a boronic acid trimer anhydride.
摘要翻译：提供了一种用于制备特定的交叉耦合化合物和用于制备该化合物的特定催化剂的方法。该方法包括在碱和镍化合物催化剂存在下反应，式中n'（R 1，X 1，N 2）其中R 1是烃基，X'的α和β碳是sp 3 O 3个碳原子; X 1是一个氯，溴或碘原子，n和n和1和1或2而不是两者与具有式m的化合物{ 其中R 2是芳基，其中R 2是芳基，杂芳基或烯基，n'为1或2，X 2独立地为羟基，烷氧基或芳基烷氧基或X 2 2， / SUB一起形成亚烷基二氧基或亚芳基二氧基，m表示1或2，但m <= n，硼原子与R 2的S SUP>基团或硼酸三聚体酐。

3. 发明授权

US07238832B2 Production method of a coupling compound 有权
公开(公告)号：US07238832B2
公开(公告)日：2007-07-03
申请号：US10781198
申请日：2004-02-18
申请人： Tamon Itahashi , Takashi Kamikawa
发明人： Tamon Itahashi , Takashi Kamikawa
IPC分类号： C07C69/00 , C07C45/00 , C07C41/00 , C07C22/00 , C07C255/00
CPC分类号： B01J31/1815 , B01J31/183 , B01J2231/4211 , B01J2531/847 , C07B37/04 , C07C1/321 , C07C17/263 , C07C41/30 , C07C45/68 , C07C67/293 , C07C255/33 , C07C255/50 , C07C2601/14 , C07C15/107 , C07C13/28 , C07C22/08 , C07C49/233 , C07C69/017 , C07C69/007 , C07C69/16 , C07C69/157 , C07C43/2055 , C07C43/225
摘要： There is provided a method for producing a coupling compound of formula (1): (Y—)(n−1)R1—R2—(R1)(n′−1) (1) wherein R1, R2 n and n′ are as defined below, Y is R2 or X as defined below, which method comprises reacting an organic halogen compound of formula (2): n′(R1X1n) (2) wherein X1 represents a bromine or iodine, R1 represents a substituted or unsubstituted, linear, branched or cyclic hydrocarbon group of which α and β carbon atoms in relation to X1 are sp3 carbon atoms, n and n′ each independently represent an integer of 1 or 2, and provided that n and n′ do not simultaneously represent 2, with an organic boron compound of formula (3): m{R2(BX22)n′} (3) wherein R2 represents a substituted or unsubstituted aryl group or a substituted or unsubstituted alkenyl group and the boron atom is bonded with a sp2 carbon atom thereof, X2 represents a hydroxyl or alkoxy group, n′ is as defined above, m represents an integer of 1 or 2, and m is not more than n, in the presence of a catalyst comprising a) a nickel compound, and b) b-1) a compound of formula (i): or b-2) a compound of formula (ii):

4. 发明申请

US20060281925A1 METHOD FOR PRODUCING COUPLING COMPOUND 有权
标题翻译：生产联合化合物的方法
公开(公告)号：US20060281925A1
公开(公告)日：2006-12-14
申请号：US11465167
申请日：2006-08-17
申请人： Tamon Itahashi , Takashi Kamikawa
发明人： Tamon Itahashi , Takashi Kamikawa
IPC分类号： C07F15/00
CPC分类号： C07F15/04 , C07B37/04 , C07C1/321 , C07C17/263 , C07C29/32 , C07C29/34 , C07C41/30 , C07C45/68 , C07C67/293 , C07C253/30 , C07C2523/755 , C07C2531/22 , C07C2601/14 , C07D213/30 , C07D307/42 , C07D307/79 , C07F15/045 , C07C43/205 , C07C15/107 , C07C49/76 , C07C13/28 , C07C33/20 , C07C69/157 , C07C11/02 , C07C43/164 , C07C43/2055 , C07C13/47 , C07C43/23 , C07C33/28 , C07C33/46 , C07C43/225 , C07C22/08 , C07C255/33 , C07C255/34
摘要： A method is provided for producing a specific crosscoupling compound and a specific catalyst for producing the compound. The method includes reacting in the presence of a base and a nickel compound catalyst organic halide of the formula n′(R1X1n), wherein R1 is a hydrocarbon group and the α and β carbons to X′ are sp3 carbon atoms; X1 is a chlorine, bromine, or iodine atoms, and n and n1 are 1 or 2 but not both 2, with a compound having the formula m{R2(BX22)n′} where an R2 is an aryl, heteroaryl, or alkenyl group, and n′ is 1 or 2, X2 is independently a hydroxyl group, an alkoxy or arylalkoxy group or X22 together form an alkylenedioxy or arylenedioxy group, and m represents 1 or 2 but m≦n, and the boron atom is bonded to a sp2 carbon atom of R2 group or a boronic acid trimer anhydride.
摘要翻译：提供了一种用于制备特定的交叉耦合化合物和用于制备该化合物的特定催化剂的方法。该方法包括在碱和镍化合物催化剂存在下反应，式中n'（R 1，X 1，N 2）其中R 1是烃基，X'的α和β碳是sp 3 O 3个碳原子; X 1是一个氯，溴或碘原子，n和n 1是1或2但不是两个，具有式m的化合物{ 其中R 2是芳基，其中R 2是芳基，杂芳基或烯基，n'为1或2，X 2独立地为羟基，烷氧基或芳基烷氧基或X 2 2， / SUB一起形成亚烷基二氧基或亚芳基二氧基，m表示1或2，但m <= n，硼原子与R 2的S SUP>基团或硼酸三聚体酐。

5. 发明授权

US07041856B2 Coupling catalyst and process using the same 有权
标题翻译：偶联催化剂和工艺使用相同
公开(公告)号：US07041856B2
公开(公告)日：2006-05-09
申请号：US10277138
申请日：2002-10-22
申请人： Tamon Itahashi , Takashi Kamikawa
发明人： Tamon Itahashi , Takashi Kamikawa
IPC分类号： C07C41/30 , C07C213/06 , C07B37/04 , C07F15/04
CPC分类号： B01J31/181 , B01J23/755 , B01J31/1805 , B01J31/1815 , B01J31/1825 , B01J31/184 , B01J31/2295 , B01J2231/4211 , B01J2531/847 , C07B37/04 , C07D213/06 , C07D213/16
摘要： There are disclosed a process for producing a coupling compound of formula (1): (Y—)(n−1)R1—R2—(R1)(n′−1), (1) wherein R1 and R2 independently represent a substituted or unsubstituted aryl group, which process is characterized by reacting an unsaturated organic compound of formula (2): n′(R1X1n) (2) wherein n, n′, and R1 are the same as defined above, and X1 is the same or different and independently represents a leaving group and bonded with a sp2 carbon atom of R1 group, with a boron compound of formula (3): m{R2(BX22)n′} (3) wherein R2 and n′ are the same as defined above, X2 represents a hydroxy group, an alkoxy group, in the presence of a catalyst containing (A) a nickel compound, and (B) a nitrogen-containing cyclic compound, and the catalyst.
摘要翻译：公开了一种制备式（1）的偶联化合物的方法：<？in-line-formula description =“In-line Formulas”end =“lead”→（Y - ）（n'-1），（（1））（n'-1）其中R 1和R 2独立地表示取代或未取代的芳基，该方法的特征在于使式（2）的不饱和有机化合物：<？in-line-formula description =“In-line Formulas”end =“lead”？> n'（R＆（2）<？in-line-formula description =“In-line Formulas”end =“tail”？>其中n，n '和R 1'与上述定义相同，X 1相同或不同，并且独立地表示离去基团并与R a的sp 2碳原子键合，具有式（3）的硼化合物：<？in-line-formula description =“In-line Formulas”end =“lead”？> m {R SUP>（BX <2> （3）<？in-line-formula description =“In-line Formulas”end =“tail”？>其中R <2> 和n'与上述相同，X 2表示羟基，烷氧基，在含有（A）镍化合物的催化剂存在下，和（B）含氮环状化合物和催化剂。

6. 发明授权

US07553988B2 Method for producing coupling compound 有权
标题翻译：偶联化合物的制备方法
公开(公告)号：US07553988B2
公开(公告)日：2009-06-30
申请号：US11465167
申请日：2006-08-17
申请人： Tamon Itahashi , Takashi Kamikawa
发明人： Tamon Itahashi , Takashi Kamikawa
IPC分类号： C07C69/00
CPC分类号： C07F15/04 , C07B37/04 , C07C1/321 , C07C17/263 , C07C29/32 , C07C29/34 , C07C41/30 , C07C45/68 , C07C67/293 , C07C253/30 , C07C2523/755 , C07C2531/22 , C07C2601/14 , C07D213/30 , C07D307/42 , C07D307/79 , C07F15/045 , C07C43/205 , C07C15/107 , C07C49/76 , C07C13/28 , C07C33/20 , C07C69/157 , C07C11/02 , C07C43/164 , C07C43/2055 , C07C13/47 , C07C43/23 , C07C33/28 , C07C33/46 , C07C43/225 , C07C22/08 , C07C255/33 , C07C255/34
摘要： A method is provided for producing a specific crosscoupling compound and a specific catalyst for producing the compound. The method includes reacting in the presence of a base and a nickel compound catalyst organic halide of the formula n′(R1X1n), wherein R1 is a hydrocarbon group and the α and β carbons to X′ are sp3 carbon atoms; X1 is a chlorine, bromine, or iodine atoms, and n and n1 are 1 or 2 but not both 2, with a compound having the formula m{R2(BX22)n′} where an R2 is an aryl, heteroaryl, or alkenyl group, and n′ is 1 or 2, X2 is independently a hydroxyl group, an alkoxy or arylalkoxy group or X22 together form an alkylenedioxy or arylenedioxy group, and m represents 1 or 2 but m≦n, and the boron atom is bonded to a sp2 carbon atom of R2 group or a boronic acid trimer anhydride.
摘要翻译：提供了一种用于制备特定的交叉耦合化合物和用于制备该化合物的特定催化剂的方法。该方法包括在碱和镍化合物催化剂的存在下，使式n'（R1X1n）的有机卤化物反应，其中R 1是烃基，并且X 1的α和β碳是sp 3的碳原子; X1是氯，溴或碘原子，n和n1是1或2而不是两个，具有式m {R2（BX22）n'}的化合物，其中R2是芳基，杂芳基或烯基基团，n'为1或2，X2独立地为羟基，烷氧基或芳基烷氧基或X22一起形成亚烷基二氧基或亚芳基二氧基，m表示1或2，但m <= n，硼原子键合到R2基团的sp2碳原子或硼酸三聚酸酐。

7. 发明授权

US06965037B2 Method for producing aminocarbazoles 失效
标题翻译：生产氨基咔唑的方法
公开(公告)号：US06965037B2
公开(公告)日：2005-11-15
申请号：US10199028
申请日：2002-07-22
申请人： Takashi Kamikawa , Osamu Maruyama
发明人： Takashi Kamikawa , Osamu Maruyama
IPC分类号： B01J25/02 , C07B61/00 , C07D209/88 , C07D209/82
CPC分类号： C07D209/88
摘要： Disclosed is a method for producing an aminocarbazole by catalytically reducing a nitrocarbazole, wherein as a catalyst is used an active nickel-based catalyst prepared by contacting a nickel-based catalyst with an alkali and an iron compound under a hydrogen gas or inert gas atmosphere in an inert solvent, and according to the method of the present invention, decrease in reaction speed, decrease in yield of a product or the like depending upon the lot of the starting nitrocarbazoles can be prevented, and aminocarbazoles can be produced in a good yield constantly.
摘要翻译：公开了通过催化还原硝基咔唑制备氨基咔唑的方法，其中使用催化剂作为催化剂，其通过在氢气或惰性气体气氛下使镍基催化剂与碱和铁化合物接触而制备的活性镍基催化剂惰性溶剂，并且根据本发明的方法，可以防止反应速度的降低，产物的收率降低等，这取决于起始硝基咔唑的批次，氨基咔唑可以以良好的产率不断地产生。

8. 发明授权

US06548678B1 Method for producing 5-phenoxycarbonylbenzotriazole 失效
标题翻译： 5-苯氧基羰基苯并三唑的制备方法
公开(公告)号：US06548678B1
公开(公告)日：2003-04-15
申请号：US10252552
申请日：2002-09-24
申请人： Keiko Yamamoto , Takashi Kamikawa
发明人： Keiko Yamamoto , Takashi Kamikawa
IPC分类号： C07D24918
CPC分类号： C07D249/18
摘要： Disclosed is a method for producing 5-phenoxycarbonylbenzotriazole (I): by reacting 1H-benzotriazole-5-carboxylic acid (II): with diphenyl carbonate (III):
摘要翻译：公开了5-苯氧基羰基苯并三唑（I）的制备方法：使1H-苯并三唑-5-羧酸（II）与碳酸二苯酯（III）反应：

9. 发明授权

US08598349B2 Method for manufacturing conjugated aromatic compound 有权
标题翻译：共轭芳香族化合物的制造方法
公开(公告)号：US08598349B2
公开(公告)日：2013-12-03
申请号：US13144010
申请日：2010-01-18
申请人： Seiji Oda , Takashi Kamikawa , Akio Tanaka
发明人： Seiji Oda , Takashi Kamikawa , Akio Tanaka
IPC分类号： C07D401/04
CPC分类号： C07C45/72 , C07B37/04 , C07C17/269 , C07C41/30 , C07C67/343 , C07C253/30 , C07C303/30 , C08G61/12 , C08G2261/3442 , C08G2261/3444 , C07C25/18 , C07C49/76 , C07C49/84 , C07C69/76 , C07C43/2055 , C07C315/04
摘要： A method for manufacturing a conjugated aromatic compound comprising reacting an aromatic compound (A) substituted with a halogen as a leaving group with an aromatic compound (A) or an aromatic compound (B) substituted with a halogen as a leaving group and is structurally different from the aromatic compound (A), in the presence of (i) a nickel compound, (ii) a metal reducing agent, (iii) at least one ligand (L1) selected from the group consisting of a 2,2′-bipyridine compound having at least one electron-withdrawing group, and a 1,10-phenanthroline compound having at least one electron-withdrawing group, and (iv) at least one ligand (L2) selected from the group consisting of a 2,2′-bipyridine compound having at least one electron-releasing group, and a 1,10-phenanthroline compound having at least one electron-releasing group.
摘要翻译：一种共轭芳香族化合物的制造方法，其特征在于，包括使被取代为离去基团的卤素的芳香族化合物（A）与作为离去基团的卤素取代的芳香族化合物（A）或芳香族化合物（B）反应，结构不同在芳族化合物（A）中，在（i）镍化合物，（ii）金属还原剂，（iii）至少一种选自2,2'-联吡啶的配体（L1）的存在下，具有至少一个吸电子基团的化合物和具有至少一个吸电子基团的1,10-菲咯啉化合物，和（iv）至少一种选自2,2'- 具有至少一个电子释放基团的联吡啶化合物和具有至少一个电子释放基团的1,10-菲咯啉化合物。

10. 发明申请

US20110275859A1 METHOD FOR MANUFACTURING CONJUGATED AROMATIC COMPOUND 有权
公开(公告)号：US20110275859A1
公开(公告)日：2011-11-10
申请号：US13144010
申请日：2010-01-18
申请人： Seiji Oda , Takashi Kamikawa , Akio Tanaka
发明人： Seiji Oda , Takashi Kamikawa , Akio Tanaka
IPC分类号： C07C315/04
CPC分类号： C07C45/72 , C07B37/04 , C07C17/269 , C07C41/30 , C07C67/343 , C07C253/30 , C07C303/30 , C08G61/12 , C08G2261/3442 , C08G2261/3444 , C07C25/18 , C07C49/76 , C07C49/84 , C07C69/76 , C07C43/2055 , C07C315/04
摘要： A method for manufacturing a conjugated aromatic compound comprising reacting an aromatic compound (A) wherein one or two leaving groups selected from the group consisting of an iodine atom, a bromine atom and a chlorine atom are bonded to an aromatic ring and the aromatic compound (A) does not have (c1) a group represented by the following formula (10): wherein A1 represents a C1-C20 alkoxy group etc.; (g1) a C1-C20 alkyl group which may be substituted with a fluorine atom etc.; and (h1) a C2-C20 acyl group which may be substituted with a fluorine atom etc., at the neighboring carbon atom to the carbon atom to which the leaving group is bonded, with an aromatic compound (A) having the same structure as that of the above-mentioned aromatic compound (A) or an aromatic compound (B) wherein the aromatic compound (B) is structurally different from the above-mentioned aromatic compound (A), one or two leaving groups selected from the group consisting of an iodine atom, a bromine atom and a chlorine atom are bonded to an aromatic ring and the aromatic compound (B) does not have the above-mentioned (c1), (g1) and (h1) at the neighboring carbon atom to the carbon atom to which the leaving group is bonded, in the presence of (i) a nickel compound, (ii) a metal reducing agent, (iii) at least one ligand (L1) selected from the group consisting of a 2,2′-bipyridine compound having at least one electron-withdrawing group and having no substituent at 3-, 6-, 3′- and 6′-positions, and a 1,10-phenanthroline compound having at least one electron-withdrawing group and having no substituent at 2- and 9-positions, and (iv) at least one ligand (L2) selected from the group consisting of a 2,2′-bipyridine compound having at least one electron-releasing group and having no substituent at 3-, 6-, 3′- and 6′-positions, and a 1,10-phenanthroline compound having at least one electron-releasing group and having no substituent at 2- and 9-positions.

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