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1. 发明授权

US07435700B2 Chromium oxide compositions containing zinc, their preparation and their use as catalysts and catalyst precursors 有权
标题翻译：含有锌的氧化铬组合物，它们的制备及其作为催化剂和催化剂前体的用途
公开(公告)号：US07435700B2
公开(公告)日：2008-10-14
申请号：US10572628
申请日：2004-10-13
申请人： Tammy Georgette Amos , Velliyur Nott Mallikarjuna Rao , Allen Capron Sievert , Shekhar Subramoney
发明人： Tammy Georgette Amos , Velliyur Nott Mallikarjuna Rao , Allen Capron Sievert , Shekhar Subramoney
IPC分类号： B01J21/00 , C07C17/00
CPC分类号： B01J23/86 , B01J23/002 , B01J23/26 , B01J35/0006 , B01J35/002 , B01J37/03 , B01J2523/00 , C07C17/25 , C07C17/37 , C07C21/18 , B01J2523/27 , B01J2523/67
摘要： A chromium-containing catalyst is disclosed which includes both ZnCr2O4 and crystalline α-chromium oxide. The ZnCr2O4 contains between about 10 atom percent and 67 atom percent of the chromium in the composition and at least about 70 atom percent of the zinc in the composition, and at least about 90 atom percent of the chromium present as chromium oxide in the composition is present as ZnCr2O4 or crystalline α-chromium oxide. Also disclosed are a method for preparing this composition comprising ZnCr2O4 and crystalline α-chromium oxide; and a chromium-containing catalyst composition prepared by treatment of the composition comprising ZnCr2O4 and crystalline α-chromium oxide with a fluorinating agent. Also disclosed is a process for changing the fluorine distribution in a halogenated hydrocarbon, or incorporating fluorine in a saturated or unsaturated hydrocarbon, in the presence of at least one composition selected from the group consisting of (i) the ZnCr2O4 and crystalline α-chromium oxide compositions and (ii) the ZnCr2O4 and crystalline α-chromium oxide compositions which have been treated with a fluorinating agent.
摘要翻译：公开了一种含铬催化剂，其包括ZnCr 2 O 4 O 4和结晶α-氧化铬。 ZnCr 2 O 4 4含有组合物中铬的约10原子％至67原子％，组合物中的锌的至少约70原子％，以及作为组合物中作为氧化铬存在的至少约90原子％的铬以ZnCr 2 O 4 O 4或结晶α-氧化铬存在。还公开了一种制备该组合物的方法，该组合物包含ZnCr 2 O 4 O 4和结晶α-氧化铬; 以及通过用氟化剂处理包含ZnCr 2 O 4 O 4和结晶α-氧化铬的组合物制备的含铬催化剂组合物。还公开了一种改变卤代烃中的氟分布或在饱和或不饱和烃中引入氟的方法，所述方法是在至少一种选自（i）ZnCr 2 SO 2 O 3和结晶α-氧化铬组合物和（ii）ZnCr 2 O 4 O 4和结晶α-氧化铬组合物，它们具有用氟化剂处理。

2. 发明授权

US08017817B2 Process for the preparation of 1,1,3,3,3-pentafluoropropene and 1,2,3,3,3-pentafluoropropene 失效
标题翻译：制备1,1,3,3,3-五氟丙烯和1,2,3,3,3-五氟丙烯的方法
公开(公告)号：US08017817B2
公开(公告)日：2011-09-13
申请号：US11988257
申请日：2006-08-04
申请人： Velliyur Nott Mallikarjuna Rao , H. David Rosenfeld , Allen Capron Sievert , Shekhar Subramoney
发明人： Velliyur Nott Mallikarjuna Rao , H. David Rosenfeld , Allen Capron Sievert , Shekhar Subramoney
IPC分类号： C07C7/00
CPC分类号： B01J37/03 , B01J23/868 , B01J37/0009 , B01J37/26 , C07C17/21 , C07C17/23 , C07C17/25 , C07C21/18 , C07C19/10 , C07C19/08
摘要： A process for the manufacture of CF3CH═CF2 and CF3CF═CHF is disclosed. The process involves (a) reacting HF and chlorine and at least one halopropene of the formula CX3CCI═CCIX (where each X is independently F or Cl) to produce a product including both CF3CCI2CF3 and CF3CCIFCCIF2; (b) reacting CF3CCI2CF3 and CF3CCIFCCIF2 produced in (a) with hydrogen to produce a product including both CF3CH2CF3 and CF3CHFCHF2; (c) dehydrofluorinating CF3CH2CF3 and CF3CHFCHF2 produced in (b) to produce a product including both CF3CH═CF2 and CF3CF═CHF; and (d) recovering CF3CH═CF2 and CF3CF═CHF from the product produced in (c). In (a), both CF3CCI2CF3 and CF3CCIFCCIF2 are produced in the presence of a chlorofluorination catalyst consisting of (i) compositions comprising a crystalline alpha-chromium oxide where at least 0.05 atom % of the chromium atoms in the alpha-chromium oxide lattice are replaced by copper, and (H) compositions of (i) which have been treated with a fluorinating agent.
摘要翻译：公开了制备CF 3 CH 2 CF 2和CF 3 CF = CHF的方法。该方法包括（a）使HF和氯与至少一种式CX3CCI = CCIX的卤代丙烯（其中每个X独立地为F或Cl）反应，以产生包含CF 3 CCl 2 CF 3和CF 3 CClFCCIF 2的产物; （b）使（a）中制备的CF 3 CCl 2 CF 3和CF 3 CClFCCIF 2与氢反应以产生包含CF 3 CH 2 CF 3和CF 3 CHFCHF 2的产物; （c）在（b）中制备的CF 3 CH 2 CF 3和CF 3 CHFCHF 2脱氟化氟化产生包括CF 3 CH 2 CF 2和CF 3 CF = CHF的产物; 和（d）从（c）中制备的产物中回收CF 3CH≡CF2和CF 3 CF = CHF。在（a）中，CF 3 CCl 2 CF 3和CF 3 CClFCCIF 2均在氯氟化催化剂存在下制备，所述氯氟化催化剂由（i）包含α-氧化铬晶格中至少0.05原子％的铬原子的结晶α-氧化铬的组合物组成通过铜和（H）组合物（i）已用氟化剂处理。

3. 发明授权

US07659436B2 Process for the preparation of 1,1,1,3,3-penta-fluoropropane and/or 1,1,1,3,3,3-hexafluoropropane 失效
标题翻译：制备1,1,1,3,3-五氟丙烷和/或1,1,1,3,3,3-六氟丙烷的方法
公开(公告)号：US07659436B2
公开(公告)日：2010-02-09
申请号：US11988436
申请日：2006-08-04
申请人： Velliyur Nott Mallikarjuna Rao , H. David Rosenfeld , Allen Capron Sievert , Shekhar Subramoney
发明人： Velliyur Nott Mallikarjuna Rao , H. David Rosenfeld , Allen Capron Sievert , Shekhar Subramoney
IPC分类号： C07C17/00 , C07C17/10
CPC分类号： B01J23/868 , B01J37/0009 , B01J37/03 , C07C17/206 , C07C17/21 , C07C17/23 , C07C17/25 , C07C19/08 , C07C21/18 , C07C19/10
摘要： A process for the manufacture of CF3CH2CHF2 and/or CF3CH2CF3 is disclosed. The process involves (a) reacting HF and at least one halopropene of the formula CX3CCI═CCIX (where each X is independently F or Cl) to produce a product including both CF3CCI═CF2 and CF3CHCICF3; (b) reacting CF3CCI═CF2 and/or CF3CHCICF3 produced in (a) with hydrogen to produce a product including CF3CH2CHF2 and/or CF3CH2CF3; and (c) recovering CF3CH2CHF2 and/or CF3CH2CF3 from the product produced in (b). In (a), the CF3CCI═CF2 and CF3CHCICF3 are produced in the presence of a fluorination catalyst comprising at least one chromium-containing component selected from (i) a crystalline alpha-chromium oxide where at least 0.05 atom % of the chromium atoms in the alpha-chromium oxide lattice are replaced by divalent copper, and (ii) a chromium-containing composition of (i) which has been treated with a fluorinating agent.
摘要翻译：公开了制备CF 3 CH 2 CHF 2和/或CF 3 CH 2 CF 3的方法。该方法包括（a）使HF和式CX3CCI-CCIX（其中每个X独立地为F或Cl）至少一种卤代丙烯反应以产生包含CF 3 CCl-CF 2和CF 3 CHCICF 3的产物; （b）使（a）中制备的CF 3 CCl-CF 2和/或CF 3 CHCICF 3与氢反应以产生包含CF 3 CH 2 CHF 2和/或CF 3 CH 2 CF 3的产物; 和（c）从（b）中制备的产物中回收CF 3 CH 2 CHF 2和/或CF 3 CH 2 CF 3。在（a）中，CF 3 CCl-CF 2和CF 3 CHCICF 3在含有至少一种含铬组分的氟化催化剂的存在下制备，所述含铬组分选自（i）结晶α-氧化铬，其中至少0.05原子％所述α-氧化铬晶格被二价铜取代，和（ii）已经用氟化剂处理的（i）的含铬组合物。

4. 发明授权

US08053611B2 Process or the preparation of 1,1,1,3,3,3-hexafluoro-propane and at least one of 1,1,1,2,3,3-hexafluoropropane, hexafluoropropane and 1,1,1,2,3,3,3-heptafluoropropane 失效
标题翻译： 1,1,1,3,3,3-六氟丙烷和1,1,1,2,3,3-六氟丙烷，六氟丙烷和1,1,1,2,3中的至少一种的方法或制备，3,3-七氟丙烷
公开(公告)号：US08053611B2
公开(公告)日：2011-11-08
申请号：US11988258
申请日：2006-08-04
申请人： Velliyur Nott Mallikarjuna Rao , H. David Rosenfeld , Allen Capron Sievert , Shekhar Subramoney
发明人： Velliyur Nott Mallikarjuna Rao , H. David Rosenfeld , Allen Capron Sievert , Shekhar Subramoney
IPC分类号： C07C17/00
CPC分类号： B01J37/26 , B01J23/868 , C07C17/21 , C07C17/23 , C07C19/08 , C07C21/18 , C07C19/10
摘要： A process is disclosed for the manufacture of 1,1,1,3,3,3-hexafluoropropane and 1,1,1,2,3,3-hexafluoropropane, hexafluoropropene and/or 1,1,1,2,3,3,3-heptafluoropropane. The process involves (a) reacting HF, Cl2, and at least one halopropene of the formula CX3CCl═CClX (where each X is independently F or Cl) to produce a product comprising CF3CCl2CF3 and CF3CClFCClF2; (b) reacting CF3CCl2CF3 and CF3CClFCClF2 produced in (a) with hydrogen, optionally in the presence of HF, to produce a product comprising CF3CH2CF3 and at least one of CHF2CHFCF3, CF3CF═CF2 and CF3CFHCF3; and (c) recovering from the product produced in (b), CF3CH2CF3 and at least one of CHF2CHFCF3, CF3CF═CF2 and CF3CFHCF3. In (a), the CF3CCl2CF3 and CF3CClFCClF2 are produced in the presence of a chlorofluorination catalyst including (i) a crystalline alpha-chromium oxide where at least 0.05 atom % of the chromium atoms in the alpha-chromium oxide lattice are replaced by divalent copper, and/or (ii) a chromium-containing composition of (i) which has been treated with a fluorinating agent.
摘要翻译：公开了用于制造1,1,1,3,3,3-六氟丙烷和1,1,1,2,3,3-六氟丙烷，六氟丙烯和/或1,1,1,2,3， 3,3-七氟丙烷。该方法包括（a）使HF，Cl 2和至少一种式CX3CCl = CClX（其中每个X独立地为F或Cl）的卤代丙烯反应以产生包含CF 3 CCl 2 CF 3和CF 3 CClFCClF 2的产物; （b）使（a）中制备的CF 3 CCl 2 CF 3和CF 3 CClFCClF与任选在HF存在下的氢反应，生成包含CF 3 CH 2 CF 3和CHF 2 CHFCF 3，CF 3CF≡CF2和CF 3 CFHCF 3中的至少一种的产物; 和（c）从（b）中产生的产物，CF 3 CH 2 CF 3和CHF 2 CHFCF 3，CF 3CF≡CF2和CF 3 CFHCF 3中的至少一种中回收。在（a）中，CF 3 CCl 2 CF 3和CF 3 CClFCClF 2在氯氟化催化剂的存在下制备，包括（i）结晶α-氧化铬，其中至少0.05原子％的α-氧化铬晶格中的铬原子被二价铜，和/或（ⅱ）已经用氟化剂处理的（ⅰ）的含铬组合物。

5. 发明申请

US20110105808A1 Process for the Preparation of 1,1,3,3,3-Pentafluoropropene and 1,2,3,3,3-Pentafluoropropene 失效
标题翻译：制备1,1,3,3,3-五氟丙烯和1,2,3,3,3-五氟丙烯的方法
公开(公告)号：US20110105808A1
公开(公告)日：2011-05-05
申请号：US11988257
申请日：2006-08-04
申请人： Velliyur Nott Mallikarjuna Rao , H. David Rosenfeld , Allen Capron Sievert , Shekhar Subramoney
发明人： Velliyur Nott Mallikarjuna Rao , H. David Rosenfeld , Allen Capron Sievert , Shekhar Subramoney
IPC分类号： C07C17/08
CPC分类号： B01J37/03 , B01J23/868 , B01J37/0009 , B01J37/26 , C07C17/21 , C07C17/23 , C07C17/25 , C07C21/18 , C07C19/10 , C07C19/08
摘要： A process for the manufacture of CF3CH═CF2 and CF3CF═CHF is disclosed. The process involves (a) reacting HF and chlorine and at least one halopropene of the formula CX3CCl═CClX (where each X is independently F or Cl) to produce a product including both CF3CCl2CF3 and CF3CCIFCClF2; (b) reacting CF3CCl2CF3 and CF3CCIFCClF2 produced in (a) with hydrogen to produce a product including both CF3CH2CF3 and CF3CHFCHF2; (c) dehydrofluorinating CF3CH2CF3 and CF3CHFCHF2 produced in (b) to produce a product including both CF3CH═CF2 and CF3CF═CHF; and (d) recovering CF3CH═CF2 and CF3CF═CHF from the product produced in (c). In (a), both CF3CCl2CF3 and CF3CCIFCClF2 are produced in the presence of a chlorofluorination catalyst consisting of (i) compositions comprising a crystalline alpha-chromium oxide where at least 0.05 atom % of the chromium atoms in the alpha-chromium oxide lattice are replaced by copper, and (H) compositions of (i) which have been treated with a fluorinating agent.
摘要翻译：公开了制备CF 3 CH 2 CF 2和CF 3 CF = CHF的方法。该方法包括（a）使HF和氯与至少一种式CX3CCl = CClX（其中每个X独立地为F或Cl）的卤代丙烯反应以产生包含CF 3 CCl 2 CF 3和CF 3 CClFFCClF 2的产物; （b）使（a）中制备的CF 3 CCl 2 CF 3和CF 3 CClFFCClF与氢反应以产生包含CF 3 CH 2 CF 3和CF 3 CHFCHF 2的产物; （c）在（b）中制备的CF 3 CH 2 CF 3和CF 3 CHFCHF 2脱氟化氟化产生包括CF 3 CH 2 CF 2和CF 3 CF = CHF的产物; 和（d）从（c）中制备的产物中回收CF 3CH≡CF2和CF 3 CF = CHF。在（a）中，CF 3 CCl 2 CF 3和CF 3 CClFFCClF 2是在氯氟化催化剂存在下制备的，所述氯氟化催化剂由（i）包含α-氧化铬晶格中至少0.05原子％的铬原子的结晶α-氧化铬的组合物组成通过铜和（H）组合物（i）已用氟化剂处理。

6. 发明授权

US07663007B2 Process for the preparation of 1,3,3,3-tetrafluoropropene and/or 1,1,3,3,3-pentafluoropropene 失效
标题翻译：制备1,3,3,3-四氟丙烯和/或1,1,3,3,3-五氟丙烯的方法
公开(公告)号：US07663007B2
公开(公告)日：2010-02-16
申请号：US11988259
申请日：2006-08-04
申请人： Velliyur Nott Mallikarjuna Rao , H. David Rosenfeld , Allen Capron Sievert , Shekhar Subramoney
发明人： Velliyur Nott Mallikarjuna Rao , H. David Rosenfeld , Allen Capron Sievert , Shekhar Subramoney
IPC分类号： C07C17/00
CPC分类号： B01J23/868 , B01J37/0009 , B01J37/03 , B01J37/26 , C07C17/206 , C07C17/21 , C07C17/23 , C07C17/25 , C07C17/354 , C07C19/08 , C07C21/18 , C07C19/10
摘要： A process for the manufacture of CF3CH═CHF and/or CF3CH═CF2 is disclosed. The process involves (a) reacting HF and at least one halopropene of the formula CX3CCI═CCIX (where each X is independently F or CI) to produce a product including both CF3CCI═CF2 and CF3CHCICF3; (b) reacting CF3CCI═CF2 and/or CF3CHCICF3 produced in (a) with hydrogen to produce a product including CF3CH2CHF2 and/or CF3CH2CF3; (c) dehydrofluorinating CF3CH2CHF2 and/or CF3CH2CF3 produced in (b) to produce a product comprising CF3CH═CHF and/or CF3CH═CF2; and (d) recovering CF3CH═CHF and/or CF3CH═CF2 from the product produced in (c). In (a), the CF3CCI═CF2 and CF3CHCICF3 are produced in the presence of a fluorination catalyst comprising at least one chromium-containing component selected from (i) a crystalline alpha-chromium oxide where at least 0.05 atom % of the chromium atoms in the alpha-chromium oxide lattice are replaced by divalent copper, and (ii) a chromium-containing composition of (i) which has been treated with a fluorinating agent.
摘要翻译：公开了制备CF 3 CH-CHF和/或CF 3 CH-CF 2的方法。该方法包括（a）HF和至少一种式CX3CCI-CCIX的卤代丙烯（其中每个X独立地为F或Cl）反应以产生包含CF 3 CCl-CF 2和CF 3 CHCICF 3的产物; （b）使（a）中制备的CF 3 CCl-CF 2和/或CF 3 CHCICF 3与氢反应以产生包含CF 3 CH 2 CHF 2和/或CF 3 CH 2 CF 3的产物; （c）在（b）中制备的CF 3 CH 2 CHF 2和/或CF 3 CH 2 CF 3脱氟化氢以产生包含CF 3 CH-CHF和/或CF 3 CH-CF 2的产物; 和（d）从（c）中制备的产物中回收CF 3 CH-CHF和/或CF 3 CH-CF 2。在（a）中，CF 3 CCl-CF 2和CF 3 CHCICF 3在含有至少一种含铬组分的氟化催化剂的存在下制备，所述含铬组分选自（i）结晶α-氧化铬，其中至少0.05原子％所述α-氧化铬晶格被二价铜取代，和（ii）已经用氟化剂处理的（i）的含铬组合物。

7. 发明申请

US20090137853A1 Process for the Preparation of 1,1,1,3,3-Penta-Fluoropropane and/or 1,1,1,3,3,3-Hexafluoropropane 失效
标题翻译：制备1,1,1,3,3-五氟丙烷和/或1,1,1,3,3,3-六氟丙烷的方法
公开(公告)号：US20090137853A1
公开(公告)日：2009-05-28
申请号：US11988436
申请日：2006-08-04
申请人： Velliyur Nott Mallikarjuna Rao , David H. Rosenfeld , Allen Capron Sievert , Shekhar Subramoney
发明人： Velliyur Nott Mallikarjuna Rao , David H. Rosenfeld , Allen Capron Sievert , Shekhar Subramoney
IPC分类号： C07C17/087
CPC分类号： B01J23/868 , B01J37/0009 , B01J37/03 , C07C17/206 , C07C17/21 , C07C17/23 , C07C17/25 , C07C19/08 , C07C21/18 , C07C19/10
摘要： A process for the manufacture of CF3CH2CHF2 and/or CF3CH2CF3 is disclosed. The process involves (a) reacting HF and at least one halopropene of the formula CX3CCI═CCIX (where each X is independently F or Cl) to produce a product including both CF3CCI═CF2 and CF3CHCICF3; (b) reacting CF3CCI═CF2 and/or CF3CHCICF3 produced in (a) with hydrogen to produce a product including CF3CH2CHF2 and/or CF3CH2CF3; and (c) recovering CF3CH2CHF2 and/or CF3CH2CF3 from the product produced in (b). In (a), the CF3CCI═CF2 and CF3CHCICF3 are produced in the presence of a fluorination catalyst comprising at least one chromium-containing component selected from (i) a crystalline alpha-chromium oxide where at least 0.05 atom % of the chromium atoms in the alpha-chromium oxide lattice are replaced by divalent copper, and (ii) a chromium-containing composition of (i) which has been treated with a fluorinating agent.
摘要翻译：公开了制备CF 3 CH 2 CHF 2和/或CF 3 CH 2 CF 3的方法。该方法包括（a）使HF和式CX3CCI-CCIX（其中每个X独立地为F或Cl）至少一种卤代丙烯反应以产生包含CF 3 CCl-CF 2和CF 3 CHCICF 3的产物; （b）使（a）中制备的CF 3 CCl-CF 2和/或CF 3 CHCICF 3与氢反应以产生包含CF 3 CH 2 CHF 2和/或CF 3 CH 2 CF 3的产物; 和（c）从（b）中制备的产物中回收CF 3 CH 2 CHF 2和/或CF 3 CH 2 CF 3。在（a）中，CF 3 CCl-CF 2和CF 3 CHCICF 3在含有至少一种含铬组分的氟化催化剂的存在下制备，所述含铬组分选自（i）结晶α-氧化铬，其中至少0.05原子％所述α-氧化铬晶格被二价铜取代，和（ii）已经用氟化剂处理的（i）的含铬组合物。

8. 发明申请

US20080207964A1 Compositions containing chromium, oxygen and gold, their preparation, and their use as catalysts and catalyst precursors 审中-公开
标题翻译：含有铬，氧和金的组合物，它们的制备及其作为催化剂和催化剂前体的用途
公开(公告)号：US20080207964A1
公开(公告)日：2008-08-28
申请号：US12070827
申请日：2008-02-21
申请人： Velliyur Nott Mallikarjuna Rao , Allen Capron Sievert , H. David Rosenfeld , Shekhar Subramoney
发明人： Velliyur Nott Mallikarjuna Rao , Allen Capron Sievert , H. David Rosenfeld , Shekhar Subramoney
IPC分类号： C07C17/04 , C07C17/02 , B01J27/132 , B01J23/68
CPC分类号： C07C19/08 , B01J23/685 , B01J35/0013 , B01J35/006 , B01J37/0201 , B01J37/03 , B01J37/14 , B01J37/26 , C07C17/206 , C07C17/21 , C07C17/23 , C07C17/25 , C07C21/18 , C07C19/10
摘要： A catalyst composition is disclosed that includes chromium, oxygen, and gold as essential constituent elements. The amount of gold in the composition is from about 0.05 atom % to about 10 atom % based on the total amount of chromium and gold. Also disclosed is a process for changing the fluorine distribution (i.e., content and/or arrangement) in a hydrocarbon or halogenated hydrocarbon in the presence of the catalyst composition; and methods for preparing said catalyst composition. One preparation method involves; (a) co-precipitating a solid by adding ammonium hydroxide (aqueous ammonia) to an aqueous solution of a soluble gold salt and a soluble chromium salt that contains at least three moles of nitrate per mole of chromium in the solution and has a gold content of from about 0.05 atom % to about 10 atom % of the total content of gold and chromium in the solution to form an aqueous mixture containing co-precipitated solid; (b) drying the co-precipitated solid formed in (a); and (c) calcining the dried solid formed in (b) in an atmosphere containing at least 10% oxygen by volume. Another preparation method involves (a) impregnating solid chromium oxide with a solution of a soluble gold salt, (b) drying the impregnated chromium oxide prepared in (a); and optionally, (c) calcining the dried solid. A third preparation method involves (a) evaporating an aqueous solution of chromium(VI) oxide and a soluble gold salt to form a solid; (b) drying the solid formed in (a); and (c) calcining the dried solid formed in (b) in an atmosphere containing at least 10% oxygen by volume.
摘要翻译：公开了一种催化剂组合物，其包括铬，氧和金作为必要的组分元素。基于铬和金的总量，组合物中的金的量为约0.05原子％至约10原子％。还公开了在催化剂组合物存在下改变烃或卤代烃中的氟分布（即含量和/或排列）的方法; 以及制备所述催化剂组合物的方法。一种制备方法涉及到（a）通过向溶液中每摩尔铬含有至少三摩尔硝酸盐的可溶性金盐和可溶性铬盐的水溶液中加入氢氧化铵（氨水）共沉淀固体，并且具有金含量为溶液中金和铬的总含量的约0.05原子％至约10原子％，以形成含共沉淀固体的含水混合物; （b）干燥（a）中形成的共沉淀固体; 和（c）在（b）中形成的干燥固体在含有至少10体积％氧气的气氛中煅烧。另一种制备方法包括（a）用可溶性金盐溶液浸渍固体氧化铬，（b）干燥（a）中制备的浸渍的氧化铬; 和（c）煅烧干燥的固体。第三制备方法包括（a）蒸发氧化铬（VI）的水溶液和可溶性金盐以形成固体; （b）干燥（a）中形成的固体; 和（c）在（b）中形成的干燥固体在含有至少10体积％氧气的气氛中煅烧。

9. 发明申请

US20110118514A1 Process for the Preparation of 1,1,1,3,3,3-Hexafluoro-Propane and at Least One Of 1,1,1,2,3,3-Hexafluoropropane, Hexafluoropropane and 1,1,1,2,3,3,3-Heptafluoropropane 失效
标题翻译： 1,1,1,3,3,3-六氟丙烷的制备方法和1,1,1,2,3,3-六氟丙烷，六氟丙烷和1,1,1,2,3 ，3,3-七氟丙烷
公开(公告)号：US20110118514A1
公开(公告)日：2011-05-19
申请号：US11988258
申请日：2006-08-04
申请人： Velliyur Nott Mallikarjuna Rao , H. David Rosenfeld , Allen Capron Sievert , Shekhar Subramoney
发明人： Velliyur Nott Mallikarjuna Rao , H. David Rosenfeld , Allen Capron Sievert , Shekhar Subramoney
IPC分类号： C07C17/23 , C07C17/20
CPC分类号： B01J37/26 , B01J23/868 , C07C17/21 , C07C17/23 , C07C19/08 , C07C21/18 , C07C19/10
摘要： A process is disclosed for the manufacture of 1,1,1,3,3,3-hexafluoropropane and 1,1,1,2,3,3-hexafluoropropane, hexafluoropropene and/or 1,1,1,2,3,3,3-heptafluoropropane. The process involves (a) reacting HF, Cl2, and at least one halopropene of the formula CX3CCI═CCIX (where each X is independently F or CI) to produce a product comprising CF3CCI2CF3 and CF3CCIFCCIF2; (b) reacting CF3CCI2CF3 and CF3CCIFCCIF2 produced in (a) with hydrogen, optionally in the presence of HF, to produce a product comprising CF3CH2CF3 and at least one of CHF2CHFCF3, CF3CF═CF2 and CF3CFHCF3; and (c) recovering from the product produced in (b), CF3CH2CF3 and at least one of CHF2CHFCF3, CF3CF═CF2 and CF3CFHCF3. In (a), the CF3CCI2CF3 and CF3CCIFCCIF2 are produced in the presence of a chlorofluorination catalyst including (i) a crystalline alpha-chromium oxide where at least 0.05 atom % of the chromium atoms in the alpha-chromium oxide lattice are replaced by divalent copper, and/or (ii) a chromium-containing composition of (i) which has been treated with a fluorinating agent.
摘要翻译：公开了用于制造1,1,1,3,3,3-六氟丙烷和1,1,1,2,3,3-六氟丙烷，六氟丙烯和/或1,1,1,2,3， 3,3-七氟丙烷。该方法包括（a）使HF，Cl 2和至少一种式CX3CCI = CCIX（其中每个X独立地为F或Cl）的卤代丙烯反应，以产生包含CF 3 CCl 2 CF 3和CF 3 CClFCCIF 2的产物; （b）任选地在HF存在下使（a）中产生的CF 3 CCl 2 CF 3和CF 3 CClF CIFF 2与氢反应，以产生包含CF 3 CH 2 CF 3和CHF 2 CHFCF 3，CF 3CF≡CF2和CF 3 CFHCF 3中的至少一种的产物; 和（c）从（b）中产生的产物，CF 3 CH 2 CF 3和CHF 2 CHFCF 3，CF 3CF≡CF2和CF 3 CFHCF 3中的至少一种中回收。在（a）中，CF 3 CCl 2 CF 3和CF 3 CClFCCIF 2在氯氟化催化剂存在下制备，包括（i）α-氧化铬晶格中至少0.05原子％的铬原子被二价铜取代的结晶α-氧化铬，和/或（ⅱ）已经用氟化剂处理的（ⅰ）的含铬组合物。

10. 发明授权

US07678949B2 Process for the preparation of 1,3,3,3-tetrafluoropropene and/or 2,3,3,3-tetrafluoropropene 失效
标题翻译：制备1,3,3,3-四氟丙烯和/或2,3,3,3-四氟丙烯的方法
公开(公告)号：US07678949B2
公开(公告)日：2010-03-16
申请号：US11988983
申请日：2006-08-04
申请人： Velliyur Nott Mallikarjuna Rao , H. David Rosenfeld , Allen Capron Sievert , Shekhar Subramoney
发明人： Velliyur Nott Mallikarjuna Rao , H. David Rosenfeld , Allen Capron Sievert , Shekhar Subramoney
IPC分类号： C07C17/00
CPC分类号： C07C21/18 , B01J23/868 , B01J37/26 , C07C17/21 , C07C17/23 , C07C17/25 , C07C19/10
摘要： A process for the manufacture of CF3CH═CHF and/or CF3CF═CH2 is disclosed. The process involves (a) reacting HF and chlorine and at least one halopropene of the formula CX3CCI═CCIX (where each X is independently F or Cl) to produce a product including both CF3CCI2CCIF2 and CF3CCIFCCI2F; (b) reacting CF3CCI2CCIF2 and CF3CCIFCCI2F produced in (a) with hydrogen to produce a product including both CF3CH2CHF2 and CF3CHFCH2F; (c) dehydrofluorinating CF3CH2CHF2 and CF3CHFCH2F produced in (b) to produce a product including both CF3CH═CHF and CF3CF═CH2; and (d) recovering CF3CH═CHF and/or CF3CF═CH2 from the product produced in (c). In (a), both CF3CCI2CCIF2 and CF3CCIFCCI2F are produced in the presence of a chlorofluorination catalyst consisting of (i) compositions comprising a crystalline alpha-chromium oxide where at least 0.05 atom % of the chromium atoms in the alpha-chromium oxide lattice are replaced by copper, and (ii) compositions of (i) which have been treated with a fluorinating agent.
摘要翻译：公开了制造CF 3 CH = CHF和/或CF 3 CF = CH 2的方法。该方法包括（a）使HF和氯与至少一种式CX3CCI = CCIX的卤代丙烯（其中每个X独立地为F或Cl）反应以产生包含CF 3 CCl 2 CCIF 2和CF 3 CClFCCI 2 F的产物; （b）使（a）中制备的CF 3 CCl 2 CCIF 2和CF 3 CClFCCI 2 F与氢反应以产生包含CF 3 CH 2 CHF 2和CF 3 CHFCH 2 F的产物; （c）在（b）中制备的CF 3 CH 2 CHF 2和CF 3 CHFCH 2 F脱氟化氟化产生包括CF 3 CH = CHF和CF 3 CF = CH 2的产物; 和（d）从（c）中制备的产物中回收CF 3 CH = CHF和/或CF 3CF≡CH2。在（a）中，CF3CCI2CCIF2和CF3CCIFCCI2F都是在氯氟化催化剂存在下制备的，所述氯氟化催化剂由（i）包含结晶α-氧化铬的组合物组成，其中至少0.05原子％的α-氧化铬晶格中的铬原子被替换和（ii）已经用氟化剂处理的（i）的组合物。

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