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1. 发明授权

US06808846B2 Negative electrode for lithium secondary battery and manufacturing method thereof 有权
标题翻译：锂二次电池用负极及其制造方法
公开(公告)号：US06808846B2
公开(公告)日：2004-10-26
申请号：US10046697
申请日：2002-01-17
申请人： Takuya Hashimoto , Atsushi Fukui , Hiroshi Nakamura , Shin Fujitani
发明人： Takuya Hashimoto , Atsushi Fukui , Hiroshi Nakamura , Shin Fujitani
IPC分类号： H01M462
CPC分类号： H01M4/0471 , B22F2009/041 , B22F2998/00 , B22F2999/00 , C22C1/0416 , C22C21/00 , C22C45/08 , C22C2200/02 , H01M4/0483 , H01M4/13 , H01M4/38 , H01M4/386 , H01M4/40 , H01M4/624 , H01M4/626 , H01M4/661 , H01M10/052 , H01M2004/021 , B22F9/04 , B22F3/22 , B22F3/10 , B22F2201/11
摘要： A negative electrode for lithium secondary battery characterized in that the electrode is obtained by sintering a mixture of an active material alloy and a binder disposed on a current collector, or a mixture of an active material alloy, conductive metal powder and a binder disposed on a current collector, and the active material alloy after sintered is substantially amorphous.
摘要翻译：一种锂二次电池用负极，其特征在于，通过烧结活性物质合金和设置在集电体上的粘合剂的混合物，或者将活性物质合金，导电性金属粉末和粘合剂的混合物烧结而获得的电极集电体，烧结后的活性物质合金基本上是无定形的。

2. 发明授权

US5841043A Shaped body of hydrogen absorbing alloy and container packed with hydrogen absorbing alloy 失效
标题翻译：吸氢合金成型体和装有吸氢合金的容器
公开(公告)号：US5841043A
公开(公告)日：1998-11-24
申请号：US854846
申请日：1997-05-12
申请人： Koichi Nishimura , Takahiro Yonesaki , Shin Fujitani , Hiroshi Nakamura , Yumiko Nakamura , Ikuo Yonezu , Hiroshi Watanabe
发明人： Koichi Nishimura , Takahiro Yonesaki , Shin Fujitani , Hiroshi Nakamura , Yumiko Nakamura , Ikuo Yonezu , Hiroshi Watanabe
IPC分类号： B22F1/00 , B22F9/02 , C01B3/00 , C22C32/00 , F17C11/00 , H01M8/06 , C22C19/03
CPC分类号： H01M8/065 , B22F1/0014 , B22F1/0059 , B22F9/023 , C01B3/0005 , C01B3/0057 , C01B3/0078 , C01B3/0084 , C22C32/0094 , F17C11/005 , B22F2998/00 , Y02E60/321 , Y02E60/327 , Y02P20/129 , Y10S420/90
摘要： A shaped body of hydrogen absorbing alloy prepared by pressing a mixture of a hydrogen absorbing alloy powder A having a first particle-size distribution, a hydrogen absorbing alloy powder B having a second particle-size distribution and a binder C, the powder A being larger than the powder B in mean particle size, the mixture being at least 0.03 to not gerater than 0.50 in the mean particle size ratio r.sub.B /r.sub.A of the powder B to the powder A wherein r.sub.A and r.sub.B are the mean particle sizes of the respective powders A and B. The hydrogen absorbing alloy of the powder B is higher than the hydrogen absorbing alloy of the powder A in the rate of progress of pulverization resulting from absorption and desorption of hydrogen.
摘要翻译：通过压制具有第一粒度分布的吸氢合金粉末A，具有第二粒度分布的吸氢合金粉末B和粘合剂C的混合物制备的吸氢合金成形体，粉末A较大与平均粒径的粉末B相比，在粉末B与粉末A的平均粒径比rB / rA中，混合物的摩尔比为0.50以上，rA和rB为各粉末的平均粒径 A和B.粉末B的吸氢合金比由氢的吸收和解吸产生的粉碎进程的速度高于粉末A的吸氢合金。

3. 发明授权

US5688341A Hydrogen-absorbing alloy electrode and method for evaluating hydrogen-absorbing alloys for electrode 失效
标题翻译：吸氢合金电极及评估电极用吸氢合金的方法
公开(公告)号：US5688341A
公开(公告)日：1997-11-18
申请号：US676574
申请日：1996-07-01
申请人： Takahiro Isono , Hiroshi Watanabe , Shin Fujitani , Hiroshi Nakamura , Yumiko Nakamura , Ikuo Yonezu
发明人： Takahiro Isono , Hiroshi Watanabe , Shin Fujitani , Hiroshi Nakamura , Yumiko Nakamura , Ikuo Yonezu
IPC分类号： C01B3/00 , H01M4/38 , C21D11/00 , C21D1/54
CPC分类号： C01B3/0031 , C01B3/0057 , C01B3/0068 , H01M4/383 , Y02E60/327
摘要： A hydrogen-absorbing alloy electrode utilizes as an electrode material a hydrogen-absorbing alloy having selectively oriented crystals, which is expressed in terms of a specific maximum value obtained from analysis of powder X-ray diffractometry. This electrode, in which the hydrogen-absorbing alloy used is hardly pulverized upon repeated charge-discharge cycles and oxidation thereof is suppressed, gives metal hydride alkaline secondary batteries having excellent cycle characteristics. A method for evaluating hydogen-absorbing alloys for electrode comprises, utilizing the fact that there exists a clear relationship between specific parameters obtained by analyzing data based on the hydrogen-absorbing alloy to be evaluated and the characteristics of the electrode obtained therefrom, preparing and using analytical curves with the specific parameters. This method can evaluate rapidly and precisely various characteristics of hydrogen-absorbing alloys for electrode, without actually fabricating test cells therefrom.
摘要翻译：吸氢合金电极利用具有选择性取向晶体的吸氢合金作为电极材料，其以从粉末X射线衍射分析获得的特定最大值表示。在反复充放电循环中使用的吸氢合金几乎不被粉碎的电极及其氧化被抑制，得到具有优异的循环特性的金属氢化物碱性二次电池。用于评价电极用吸氢合金的方法包括利用通过基于待评价的吸氢合金分析数据获得的具体参数与由其获得的电极的特性之间存在明确的关系，准备和使用具有特定参数的分析曲线。该方法可以快速准确地评估用于电极的吸氢合金的各种特性，而不实际制造测试电池。

4. 发明授权

US5908487A Shaped body of hydrogen absorbing alloy and container packed with hydrogen absorbing alloy 失效
标题翻译：吸氢合金成型体和装有吸氢合金的容器
公开(公告)号：US5908487A
公开(公告)日：1999-06-01
申请号：US823013
申请日：1997-03-21
申请人： Koichi Nishimura , Takahiro Yonesaki , Shin Fujitani , Hiroshi Nakamura , Yumiko Nakamura , Ikuo Yonezu , Hiroshi Watanabe
发明人： Koichi Nishimura , Takahiro Yonesaki , Shin Fujitani , Hiroshi Nakamura , Yumiko Nakamura , Ikuo Yonezu , Hiroshi Watanabe
IPC分类号： B22F1/00 , B22F9/02 , C01B3/00 , C22C32/00 , F17C11/00 , H01M8/06 , B22F9/00
CPC分类号： H01M8/065 , B22F1/0014 , B22F1/0059 , B22F9/023 , C01B3/0005 , C01B3/0057 , C01B3/0078 , C01B3/0084 , C22C32/0094 , F17C11/005 , B22F2998/00 , Y02E60/321 , Y02E60/327 , Y02P20/129 , Y10S420/90
摘要： A hydrogen absorbing alloy-packed container packed with a mixture of powders classified respectively into at least two particle-size distribution groups, each of which is different in mean particle size, the powders comprising a hydrogen absorbing alloy singly or the combination of a hydrogen absorbing alloy and a substance not absorbing hydrogen, the mixture having a ratio r.sub.N+1 /r.sub.N, wherein r.sub.N is the mean particle size of the powder having a particle-size distribution of the Nth largest mean particle size, N being an integer of not smaller than 1, and r.sub.N+1 is the mean particle size of the powder having a particle-size distribution of the (N+1)th largest mean particle size, of at least 0.03 to not greater than 0.50. The alloy powders can be selected from the group consisting of lanthanum-nickel, mischmetal-nickel, iron titanium and titanium manganese.
摘要翻译：填充有分散在至少两个粒度分布基团中的粉末混合物的吸氢合金填充容器，每个粒度分布基团的平均粒度不同，单独地包含吸氢合金的粉末或吸氢合金的组合合金和不吸收氢的物质，混合物的比例为rN + 1 / rN，其中rN是具有第N个最大平均粒径的粒度分布的粉末的平均粒度，N不小于并且rN + 1是具有（N + 1）个最大平均粒径的粒度分布的粉末的平均粒度为至少0.03以上且0.50以下。合金粉末可选自镧 - 镍，混合稀土 - 镍，铁钛和钛锰。

5. 发明授权

US5851690A Hydrogen absorbing alloys 失效
标题翻译：吸氢合金
公开(公告)号：US5851690A
公开(公告)日：1998-12-22
申请号：US916446
申请日：1997-08-22
申请人： Yumiko Nakamura , Hiroshi Nakamura , Maki Kamikawa , Hiroshi Watanabe , Shin Fujitani , Ikuo Yonezu
发明人： Yumiko Nakamura , Hiroshi Nakamura , Maki Kamikawa , Hiroshi Watanabe , Shin Fujitani , Ikuo Yonezu
IPC分类号： C22C14/00 , C01B3/00 , C22C22/00 , H01M4/38
CPC分类号： C01B3/0052 , C01B3/0057 , H01M4/383 , Y02E60/327 , Y10S420/90
摘要： A hydrogen absorbing alloy for use in an environment where the alloy has the possibility of contacting oxygen is capable of inhibiting impairment of the hydrogen absorbing ability thereof when coming into contact with oxygen. The alloy has a composition represented in atomic ratio by Ti.sub.1-x Y.sub.x Mn.sub.y wherein x and y are in the range of 0
摘要翻译：在合金具有氧接触的可能性的环境中使用的吸氢合金能够抑制与氧接触时的吸氢能力的损害。该合金具有通过Ti1-xYxMny以原子比表示的组成，其中x和y分别在0

6. 发明授权

US5932513A Container packed with powder of hydrogen absorbing alloy 有权
标题翻译：容器中装有吸氢合金粉末
公开(公告)号：US5932513A
公开(公告)日：1999-08-03
申请号：US166140
申请日：1998-10-02
申请人： Hiroshi Nakamura , Shin Fujitani , Yumiko Nakamura , Hiroshi Watanabe , Ikuo Yonezu , Takahiro Yonesaki , Kouichi Nishimura
发明人： Hiroshi Nakamura , Shin Fujitani , Yumiko Nakamura , Hiroshi Watanabe , Ikuo Yonezu , Takahiro Yonesaki , Kouichi Nishimura
IPC分类号： B01J20/28 , B22F1/00 , B22F9/02 , C01B3/00 , C22C32/00 , F17C11/00 , H01M8/06 , B01J20/02 , B22F3/02
CPC分类号： F17C11/005 , B22F1/0014 , B22F1/0059 , B22F9/023 , C01B3/0005 , C01B3/0057 , C01B3/0078 , C01B3/0084 , C22C32/0094 , H01M8/065 , B22F2998/00 , Y02E60/321 , Y02E60/327 , Y10S420/90 , Y10T428/13
摘要： A container packed with a mixture of powders classified respectively into two or at least three particle-size distribution groups which are different in average particle size, the powders comprising a hydrogen absorbing alloy singly or the combination of such an alloy and a substance not absorbing hydrogen. The mixture is at least 0.03 to not greater than 0.50 in the ratio d.sub.2 /d.sub.1 wherein d.sub.1 is the average particle size of the powder having the particle-size distribution of the largest average particle size, and d.sub.2 is the average particle size of the powder having the particle-size distribution of the second largest average particle size. The weight ratio of the powder to the total weight of the powders is greater when that powder has a particle-size distribution of larger average particle size. The weight ratio of the powder having the particle-size distribution of the second largest average particle size to the powder having the particle-size distribution of the largest average particle size is at least 0.2 to not greater than 0.8.
摘要翻译：将分散有两种或至少三种平均粒度不同的粒度分布基团的粉末混合物填充的容器，该粉末包含单独的吸氢合金或这种合金与不吸收氢的物质的组合。混合物的比率d2 / d1为0.03以上，0.50以下，其中，d1为粒径分布最大的平均粒径的粉末的平均粒径，d2为粉末的平均粒径具有第二大平均粒径的粒度分布。当粉末具有较大平均粒度的粒度分布时，粉末与粉末的总重量的重量比较大。具有第二最大平均粒径的粒度分布的粉末与具有最大平均粒径的粒度分布的粉末的重量比至少为0.2以上且0.8以下。

7. 发明授权

US5900558A Container packed with powder of hydrogen absorbing alloy 失效
公开(公告)号：US5900558A
公开(公告)日：1999-05-04
申请号：US901193
申请日：1997-07-28
申请人： Hiroshi Nakamura , Shin Fujitani , Yumiko Nakamura , Hiroshi Watanabe , Ikuo Yonezu , Takahiro Yonesaki , Kouichi Nishimura
发明人： Hiroshi Nakamura , Shin Fujitani , Yumiko Nakamura , Hiroshi Watanabe , Ikuo Yonezu , Takahiro Yonesaki , Kouichi Nishimura
IPC分类号： B01J20/28 , B22F1/00 , B22F9/02 , C01B3/00 , C22C32/00 , F17C11/00 , H01M8/06 , C01B3/02 , C22C29/00
CPC分类号： F17C11/005 , B22F1/0014 , B22F1/0059 , B22F9/023 , C01B3/0005 , C01B3/0057 , C01B3/0078 , C01B3/0084 , C22C32/0094 , H01M8/065 , B22F2998/00 , Y02E60/321 , Y02E60/327 , Y10S420/90 , Y10T428/13
摘要： A container packed with a mixture of powders classified respectively into two or at least three particle-size distribution groups which are different in average particle size, the powders comprising a hydrogen absorbing alloy singly or the combination of such an alloy and a substance not absorbing hydrogen. The mixture is at least 0.03 to not greater than 0.50 in the ratio d.sub.2 /d.sub.1 wherein d.sub.1 is the average particle size of the powder having the particle-size distribution of the largest average particle size, and d.sub.2 is the average particle size of the powder having the particle-size distribution of the second largest average particle size. The weight ratio of the powder to the total weight of the powders is greater when that powder has a particle-size distribution of larger average particle size. The weight ratio of the powder having the particle-size distribution of the second largest average particle size to the powder having the particle-size distribution of the largest average particle size is at least 0.2 to not greater than 0.8.

8. 发明授权

US5496424A Hydrogen absorbing alloy and process for preparing same 失效
标题翻译：吸氢合金及其制备方法
公开(公告)号：US5496424A
公开(公告)日：1996-03-05
申请号：US131617
申请日：1993-10-05
申请人： Shin Fujitani , Hiroshi Nakamura , Hiroshi Watanabe , Ikuo Yonezu , Toshihiko Saito
发明人： Shin Fujitani , Hiroshi Nakamura , Hiroshi Watanabe , Ikuo Yonezu , Toshihiko Saito
IPC分类号： C01B3/00 , C22C19/03 , C22F1/10
CPC分类号： C22C19/03 , C01B3/0057 , Y02E60/327 , Y02P20/129 , Y10S420/90
摘要： A hydrogen absorbing alloy represented by the general formula R.sub.1-x A.sub.x (Ni.sub.5-y B.sub.y).sub.z wherein R is Mm (misch metal) or La, A is at least one element selected from the group consisting of Ce, Nd, Pr, Sm and Y, B is at least one element selected from the group consisting of Al, Sn, V, Cr, Mn, Fe, Co and Cu, 0.ltoreq.x.ltoreq.0.5, 0
摘要翻译：由通式R1-xAx（Ni5-yBy）z表示的吸氢合金，其中R是Mm（稀土金属）或La，A是选自Ce，Nd，Pr，Sm和Y中的至少一种元素，B是选自Al，Sn，V，Cr，Mn，Fe，Co和Cu中的至少一种元素，0

9. 发明授权

US5876869A Hydrogen absorbing alloy electrodes 失效
标题翻译：吸氢合金电极
公开(公告)号：US5876869A
公开(公告)日：1999-03-02
申请号：US759419
申请日：1996-12-05
申请人： Hiroshi Nakamura , Teruhiko Imoto , Toshikazu Yoshida , Shin Fujitani , Ikuo Yonezu
发明人： Hiroshi Nakamura , Teruhiko Imoto , Toshikazu Yoshida , Shin Fujitani , Ikuo Yonezu
IPC分类号： H01M4/38
CPC分类号： H01M4/383 , Y10S420/90
摘要： A hydrogen absorbing alloy electrode contains an alloy which comprises particles A of a first hydrogen absorbing alloy and particles B of a second hydrogen absorbing alloy of a composition different from the composition of the first alloy joined to the particles A, with a joint layer C formed at the resulting joint interfaces and having a new composition containing the component elements of the first and second alloys. In a specific embodiment, particles A of a first hydrogen absorbing alloy having a CaCu.sub.5 -type structure are joined to particles B of a second hydrogen absorbing alloy having a Zr--Ni Laves-phase structure. In another embodiment, particles A of a first hydrogen absorbing alloy having a CaCu.sub.5 -type structure are joined to particles B of a second hydrogen absorbing alloy having a CaCu.sub.5 -type structure and different form the first alloy in composition. In another embodiment, particles A of a first hydrogen absorbing alloy having a Zr--Ni Laves-phase structure are joined to particles B of a second hydrogen absorbing alloy having a Zr--Ni Laves-phase structure and different from the first alloy in composition.
摘要翻译：吸氢合金电极含有包含第一吸氢合金的粒子A和不同于与粒子A接合的第一合金的组成的第二吸氢合金的粒子B的合金，形成有接合层C 在所得的接合界面处并具有包含第一和第二合金的组分元素的新组合物。在具体实施方案中，具有CaCu5型结构的第一储氢合金的颗粒A与具有Zr-Ni Laves相结构的第二储氢合金的颗粒B接合。在另一个实施方案中，具有CaCu5型结构的第一储氢合金的颗粒A与CaCu5型结构的第二储氢合金的颗粒B接合，并且组成不同于第一合金。在另一个实施方案中，具有Zr-Ni Laves相结构的第一储氢合金的颗粒A与具有Zr-Ni Laves相结构且与组成不同的第一合金的第二储氢合金的颗粒B接合。

10. 发明授权

US5662729A Shaped body of hydrogen absorbing alloy and container packed with hydrogen absorbing alloy 失效
标题翻译：吸氢合金成型体和装有吸氢合金的容器
公开(公告)号：US5662729A
公开(公告)日：1997-09-02
申请号：US538371
申请日：1995-10-03
申请人： Koichi Nishimura , Takahiro Yonesaki , Shin Fujitani , Hiroshi Nakamura , Yumiko Nakamura , Ikuo Yonezu , Hiroshi Watanabe
发明人： Koichi Nishimura , Takahiro Yonesaki , Shin Fujitani , Hiroshi Nakamura , Yumiko Nakamura , Ikuo Yonezu , Hiroshi Watanabe
IPC分类号： B22F1/00 , B22F9/02 , C01B3/00 , C22C32/00 , F17C11/00 , H01M8/06 , C22C19/03
CPC分类号： H01M8/065 , B22F1/0014 , B22F1/0059 , B22F9/023 , C01B3/0005 , C01B3/0057 , C01B3/0078 , C01B3/0084 , C22C32/0094 , F17C11/005 , B22F2998/00 , Y02E60/321 , Y02E60/327 , Y02P20/129 , Y10S420/90
摘要： A shaped body of hydrogen absorbing alloy prepared by pressing a mixture of a hydrogen absorbing alloy powder A having a first particle-size distribution, a hydrogen absorbing alloy powder B having a second particle-size distribution and a binder C. The powder A is larger than the powder B in mean particle size. The mixture has a mean particle size ratio r.sub.B /r.sub.A of the powder B to the powder A, wherein r.sub.A and r.sub.B are the mean particle sizes of the respective powders A and B of at least 0.03 to not greater than 0.50. The hydrogen absorbing alloy of the powder B has a higher rate of progress of pulverization resulting from absorption and desorption of hydrogen than the hydrogen absorbing alloy of the powder A.
摘要翻译：通过压制具有第一粒度分布的吸氢合金粉末A，具有第二粒度分布的吸氢合金粉末B和粘合剂C的混合物制备的吸氢合金成形体。粉末A较大比平均粒径的粉末B。混合物的粉末B与粉末A的平均粒径比rB / rA，其中rA和rB是各粉末A和B的平均粒度为至少0.03至不大于0.50。粉末B的吸氢合金比粉末A的吸氢合金具有比吸收和解吸氢更高的粉碎进程。

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