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1. 发明授权

US5902516A Five-coordinate phosphorous compound, process for producing the same and its use 失效
标题翻译：五配位磷化合物，其制备方法及其用途
公开(公告)号：US5902516A
公开(公告)日：1999-05-11
申请号：US908202
申请日：1997-08-07
申请人： Naoki Inui , Taketoshi Kikuchi , Kanako Fukuda , Takashi Sanada
发明人： Naoki Inui , Taketoshi Kikuchi , Kanako Fukuda , Takashi Sanada
IPC分类号： C07F9/6571 , C07F9/6578 , C08K5/51 , C09K15/32 , C07D327/00 , C07F9/02
CPC分类号： C08K5/51 , C07F9/6571 , C07F9/6578 , C09K15/324
摘要： A five-coordinate phosphorous compound which is useful as an stabilizer for organic materials and represented by the formula (I): ##STR1## wherein R.sup.1, R.sup.2, R.sup.4 and R.sup.5 independently represent hydrogen atom, an alkyl group, a cycloalkyl group, an alkylcycloalkyl group, an aralkyl group or a phenyl group; R.sup.3 represents hydrogen atom or an alkyl group; X represents a direct bond, a sulfur atom or a group represented by --CHR.sup.6 -- wherein R.sup.6 represents hydrogen atom, an alkyl group or a cycloalkyl group, and a process for producing the compound (I) are provided.
摘要翻译：可用作有机材料稳定剂并由式（I）表示的五配位磷化合物：其中R1，R2，R4和R5独立地表示氢原子，烷基，环烷基，烷基环烷基，芳烷基或苯基; R3表示氢原子或烷基; X表示直接键，硫原子或-CHR 6 - 表示的基团，其中R 6表示氢原子，烷基或环烷基，以及制备化合物（I）的方法。

2. 发明授权

US5874494A Phosphites, process for producing them and their use 失效
标题翻译：亚磷酸酯，生产它们的过程及其用途
公开(公告)号：US5874494A
公开(公告)日：1999-02-23
申请号：US917486
申请日：1997-08-26
申请人： Naoki Inui , Taketoshi Kikuchi , Kanako Fukuda , Takashi Sanada
发明人： Naoki Inui , Taketoshi Kikuchi , Kanako Fukuda , Takashi Sanada
IPC分类号： C07F9/145 , C07F9/6574 , C07F9/6578 , C08K5/526
CPC分类号： C07F9/145 , C07F9/65744 , C07F9/6578 , C08K5/526
摘要： Phosphites which are useful as a deterioration inhibitor for organic material and are represented by the following formula: ##STR1## wherein R.sup.1, R.sup.2, R.sup.5 and R.sup.6 represent a hydrogen atom, an alkyl group, a cycloalkyl group, an alkylcycloalkyl group, an aralkyl group or a phenyl group;R.sup.3 represents hydrogen atom or an alkyl group;R.sup.4 represents a hydrogen atom, an alkyl group, a cycloalkyl group, an alkylcycloalkyl group, an aralkyl group or a phenyl group, or the two R.sup.4 together form a direct bond, a group represented by --S-- or an optionally substituted methylene group;A represents an alkylene group;W represents a group represented by --O-- or a group represented by --NR.sup.7wherein R.sup.7 represents a hydrogen atom, an alkyl group, etc.;B represents an alkylene group;and one of Y and Z represents a hydroxyl group, an alkoxy group or an aralkyloxy group, and the other one represents hydrogen atom or an alkyl group.
摘要翻译：可用作有机材料的劣化抑制剂的亚磷酸酯并由下式表示：其中R 1，R 2，R 5和R 6表示氢原子，烷基，环烷基，烷基环烷基，芳烷基或苯基; R3表示氢原子或烷基; R4表示氢原子，烷基，环烷基，烷基环烷基，芳烷基或苯基，或两者R4一起形成直接键，由-S-表示的基团或任选取代的亚甲基; A表示亚烷基; W表示由-O-表示的基团或由-NR 7表示的基团，其中R7表示氢原子，烷基等; B表示亚烷基; Y和Z中的一个表示羟基，烷氧基或芳烷氧基，另一个表示氢原子或烷基。

3. 发明授权

US6075159A Phosphite, a process for producing the same and a use thereof 失效
标题翻译：亚磷酸酯，其制备方法及其用途
公开(公告)号：US6075159A
公开(公告)日：2000-06-13
申请号：US961183
申请日：1997-10-30
申请人： Naoki Inui , Taketoshi Kikuchi , Kanako Fukuda , Takashi Sanada
发明人： Naoki Inui , Taketoshi Kikuchi , Kanako Fukuda , Takashi Sanada
IPC分类号： C09K15/32 , C07F9/145 , C07F9/6574 , C07F9/6578 , C08K5/526 , C08L23/00 , C08L101/00 , C07F9/06
CPC分类号： C08K5/526 , C07F9/145 , C07F9/65744 , C07F9/6578
摘要： A phosphite represented by the formula (I): ##STR1## wherein n repesents 1 or 2; A represents alkylene; B represents a direct bond or alkylene; one of Y and Z represents a hydroxyl group, alkoxy or aralkyloxy, and the other one represents a hydrogen atom or alkyl; X represents a group of formula (II): ##STR2## wherein R.sup.1 and R.sup.2 represent a hydrogen atom, an alkyl group, a cycloalkyl group, an alkylcycloalkyl group, an aralkyl group or a phenyl group; R.sup.3 represents a hydrogen atom or an alkyl group; and R.sup.4 represents a hydrogen atom, an alkyl group, a cycloalkyl group, an alkylcycloalkyl group, an aralkyl group or a phenyl group, or R.sup.4 may be combined to form a direct bond, a sulfur bond (--S--), or an unsubstituted or substituted methylene group; R.sup.5 and R.sup.6 independently represent a hydrogen atom, an alkyl group, a cycloalkyl group, an alkylcycloalkyl group, an aralkyl group or a phenyl group;R.sup.8 represents a hydrogen atom or an alkyl group; andR.sup.7 represents a hydrogen atom or an alkyl group or --CH(R8)--A--O--X; and the organic phosphorus compound is useful as a stabilizer for an organic material.
摘要翻译：由式（I）表示的亚磷酸酯：其中n个取代基1或2; A表示亚烷基; B表示直接键或亚烷基; Y和Z之一表示羟基，烷氧基或芳烷氧基，另一个表示氢原子或烷基; X表示式（II）的基团：其中R1和R2表示氢原子，烷基，环烷基，烷基环烷基，芳烷基或苯基; R3表示氢原子或烷基; 并且R 4表示氢原子，烷基，环烷基，烷基环烷基，芳烷基或苯基，或R 4可以结合形成直接键，硫键（-S-）或未取代的或取代的亚甲基; R5和R6独立地表示氢原子，烷基，环烷基，烷基环烷基，芳烷基或苯基; R8表示氢原子或烷基; 并且R 7表示氢原子或烷基或-CH（R 8）-A-O-X; 有机磷化合物可用作有机材料的稳定剂。

4. 发明授权

US5891939A Phosphites, process for producing them and their use 失效
标题翻译：亚磷酸酯，生产它们的过程及其用途
公开(公告)号：US5891939A
公开(公告)日：1999-04-06
申请号：US906972
申请日：1997-08-06
申请人： Taketoshi Kikuchi , Naoki Inui , Kanako Fukuda , Takashi Sanada
发明人： Taketoshi Kikuchi , Naoki Inui , Kanako Fukuda , Takashi Sanada
IPC分类号： C07F9/6574 , C07F9/6578 , C08K5/527 , C07F9/02
CPC分类号： C08K5/527 , C07F9/65744 , C07F9/6578
摘要： Phosphites inhibitors for organic material represented by the formula: ##STR1## wherein R.sup.1, R.sup.2, R.sup.4 and R.sup.5 independently represent hydrogen atom, an alkyl group, a cycloalkyl group, an alkylcycloalkyl group, an aralkyl group or a phenyl group; R.sup.3 is hydrogen atom or alkyl; X is a direct bond, sulfur atom, or methylene group which may optionally be substituted with alkyl or cycloalkyl; A represents a dihydric alcohol residue; B is a direct bond or alkylene; and one of Y and Z represents an alkoxy group or an aralkyloxy group, and the other one represents hydrogen atom or an alkyl group; and a process for producing the same are provided.
摘要翻译：由下式表示的有机材料用亚磷酸酯抑制剂：其中R1，R2，R4和R5独立地表示氢原子，烷基，环烷基，烷基环烷基，芳烷基或苯基; R3是氢原子或烷基; X是可以被烷基或环烷基任选取代的直接键，硫原子或亚甲基; A表示二元醇残基; B是直接键或亚烷基; Y和Z中的一个表示烷氧基或芳烷氧基，另一个表示氢原子或烷基; 并提供其制造方法。

5. 发明授权

US5889095A Phosphites, process for producing the same and their use 失效
标题翻译：亚磷酸酯，生产方法及其用途
公开(公告)号：US5889095A
公开(公告)日：1999-03-30
申请号：US905329
申请日：1997-08-04
申请人： Naoki Inui , Taketoshi Kikuchi , Kanako Fukuda , Takashi Sanada
发明人： Naoki Inui , Taketoshi Kikuchi , Kanako Fukuda , Takashi Sanada
IPC分类号： C07F9/6574 , C07F9/6578 , C08K5/527 , C09K15/32 , C08K5/49 , C07C69/76
CPC分类号： C07F9/65744 , C07F9/6578 , C08K5/527 , C09K15/322 , C09K15/324
摘要： A phosphite stabilizer for organic material is represented by the formula (1): ##STR1## wherein R.sup.1, R.sup.2, R.sup.4 and R.sup.5 is hydrogen, alkyl, cycloalkyl, alkyl, cycloalkyl, aralkyl or phenyl; R is hydrogen or alkyl; X is a direct bond, sulfur atom or a --CHR.sup.6 group in which R.sup.6 represents hydrogen, alkyl or cycloalkyl; A is an alkylene group having 2 to 8 carbon atoms or *--COR.sup.7 -- in which R.sup.7 is a direct bond or alkyl group, and * represents the bond to the oxygen atom of the phenoxy radical; and one of Y and Z represents a hydroxyl group, an alkoxy group or an aralkoxy group and the other one represents atom or an alkyl group.
摘要翻译：用于有机材料的亚磷酸酯稳定剂由式（1）表示：其中R 1，R 2，R 4和R 5是氢，烷基，环烷基，烷基，环烷基，芳烷基或苯基; R是氢或烷基; X是直接键，硫原子或-CHR6基团，其中R6表示氢，烷基或环烷基; A是具有2-8个碳原子的亚烷基或* -COR7-，其中R7是直接键或烷基，*表示与苯氧基的氧原子的键; Y和Z中的一个表示羟基，烷氧基或芳烷氧基，另一个表示原子或烷基。

6. 发明授权

US5830936A Phosphites, process for producing them and their use 失效
标题翻译：亚磷酸酯，生产它们的过程及其用途
公开(公告)号：US5830936A
公开(公告)日：1998-11-03
申请号：US916229
申请日：1997-08-22
申请人： Taketoshi Kikuchi , Naoki Inui , Kanako Fukuda , Takashi Sanada
发明人： Taketoshi Kikuchi , Naoki Inui , Kanako Fukuda , Takashi Sanada
IPC分类号： C07F9/6574 , C07F9/6578 , C08K5/527 , C07F9/02
CPC分类号： C08K5/527 , C07F9/65744 , C07F9/6578
摘要： Phosphites which are a deterioration inhibitors for organic material represented by the formula: ##STR1## wherein R.sup.1 and R.sup.2 independently represent a hydrogen atom, or certain hydrocarbyl radicals; X represents a direct bond, a sulfur atom or a methylene group which may optionally be substituted; Z is --A.sup.1 --CO--O--Y.sup.1 or --A.sup.2 --O--CO--Y.sup.2 wherein A.sup.1 is a direct bond or an alkylene group; Y.sup.1 is aralkyl or aryl; A.sup.2 is a residue of a dihydric alcohol; and Y.sup.2 is alkyl, aralkyl or a phenyl group, and a process for producing the same are provided.
摘要翻译：作为由下式表示的有机材料的劣化抑制剂的亚磷酸酯：其中R 1和R 2独立地表示氢原子或某些烃基; X表示直接键，硫原子或可任选被取代的亚甲基; Z是-A1-CO-O-Y1或-A2-O-CO-Y2，其中A1是直接键或亚烷基; Y1是芳烷基或芳基; A2是二元醇的残基; 并且Y2是烷基，芳烷基或苯基，并且提供其制备方法。

7. 发明授权

US06242514B1 Pentavalent phosphorus compound, production and use thereof 失效
标题翻译：五价磷化合物，其生产和使用
公开(公告)号：US06242514B1
公开(公告)日：2001-06-05
申请号：US08979106
申请日：1997-11-26
申请人： Taketoshi Kikuchi , Naoki Inui , Kanako Fukuda , Takashi Sanada
发明人： Taketoshi Kikuchi , Naoki Inui , Kanako Fukuda , Takashi Sanada
IPC分类号： C07F96574
CPC分类号： C07F9/65744 , C08K5/51 , C08K5/527
摘要： A pentavalent phosphorous compound represented by the formula (I): wherein RA forms a cyclic group together with E, O and P, E represents a direct bond or oxygen atom, F represents a connecting group, and RB represents a phenyl group which may be optionally substituted; and the pentavalent phosphorous compound is useful as a stabilizer for an organic material.
摘要翻译：由式（I）表示的五价磷化合物：其中RA与E，O和P一起形成环状基团，E表示直接键或氧原子，F表示连接基团，RB表示可以是任选取代; 并且五价磷化合物可用作有机材料的稳定剂。

8. 发明授权

US5914361A Cyclic phosphonites and their use as stabilizers for organic materials 失效
标题翻译：环状亚膦酸酯及其作为有机材料稳定剂的用途
公开(公告)号：US5914361A
公开(公告)日：1999-06-22
申请号：US917553
申请日：1997-08-26
申请人： Naoki Inui , Taketoshi Kikuchi , Kanako Fukuda
发明人： Naoki Inui , Taketoshi Kikuchi , Kanako Fukuda
IPC分类号： C07F9/6571 , C08K5/5393 , C08K5/5377 , C07F9/6574
CPC分类号： C07F9/65719 , C08K5/5393
摘要： Phosphonites which are useful as a deterioration inhibitor for organic material and are represented by the following formula: ##STR1## wherein X represents a connecting group, and R.sup.A represents a phenyl group which may be optionally substituted; and a process for producing the same are provided.
摘要翻译：可用作有机材料的劣化抑制剂的亚膦酸酯，由下式表示：其中X表示连接基团，RA表示可任意取代的苯基; 并提供其制造方法。

9. 发明授权

US5847187A Organic phosphorous compound, a process for producing the same and a use thereof 失效
标题翻译：有机磷化合物，其制备方法及其用途
公开(公告)号：US5847187A
公开(公告)日：1998-12-08
申请号：US942792
申请日：1997-10-02
申请人： Taketoshi Kikuchi , Naoki Inui , Kanaku Fukuda , Takashi Sanada
发明人： Taketoshi Kikuchi , Naoki Inui , Kanaku Fukuda , Takashi Sanada
IPC分类号： C07F9/24 , C07F9/6574 , C07F9/6578 , C07F9/6584 , C08K5/5399 , C07F9/06
CPC分类号： C08K5/5399 , C07F9/2458 , C07F9/65744 , C07F9/6578 , C07F9/6584
摘要： An organic phosphorous compound represented by the following formula (I): ##STR1## wherein R.sup.1, R.sup.2, R.sup.5 and R.sup.6 represent a hydrogen atom, an alkyl group, a cycloalkyl group, an alkylcycloalkyl group, an aralkyl group or a phenyl group; R.sup.3 represents a hydrogen atom or an alkyl group; R.sup.4 represents a hydrogen atom, an alkyl group, a cycloalkyl group, an alkylcycloalkyl group, an aralkyl group or a phenyl group, or the two R.sup.4 may be combined with each other to form a direct bond, a sulfur bond (--S--), or aN optionally substituted methylene group; R.sup.7 and R.sup.8 represent a hydrogen atom or an alkyl group, or R.sup.7 and R.sup.8 may be combined with each other to form an alkylene group; A represents an alkylene group; B represents a direct bond or an alkylene group; and one of Y and Z represents a hydroxyl group, an alkoxy group or an aralkyloxy group, and the other one represents a hydrogen atom or an alkyl group; and the organic phosphorous compound is useful as a stabilizer for an organic material.
摘要翻译：由下式（I）表示的有机磷化合物：其中R 1，R 2，R 5和R 6表示氢原子，烷基，环烷基，烷基环烷基，芳烷基或苯基组; R3表示氢原子或烷基; R4表示氢原子，烷基，环烷基，烷基环烷基，芳烷基或苯基，或者两个R 4可以相互结合形成直接键，硫键（-S-），或aN任选取代的亚甲基; R 7和R 8表示氢原子或烷基，或者R 7和R 8可以相互结合形成亚烷基; A表示亚烷基; B表示直接键或亚烷基; Y和Z中的一个表示羟基，烷氧基或芳烷氧基，另一个表示氢原子或烷基; 有机磷化合物可用作有机材料的稳定剂。

10. 发明授权

US5843339A Phosphites and their production and use 失效
标题翻译：亚磷酸盐及其生产和使用
公开(公告)号：US5843339A
公开(公告)日：1998-12-01
申请号：US723933
申请日：1996-10-01
申请人： Kanako Fukuda , Naoki Inui
发明人： Kanako Fukuda , Naoki Inui
IPC分类号： C09K15/32 , C07F9/6574 , C08K5/52 , C08K5/527 , C08L23/02 , C07F9/6571
CPC分类号： C07F9/65744 , C08K5/527
摘要： Phosphites represented by the general formula (I): ##STR1## wherein R.sup.1, R.sup.2, R.sup.4 and R.sup.5 independently represent a hydrogen atom, an alkyl group having 1 to 8 carbon atoms, a cycloalkyl group having 5 to 8 carbon atoms, an alkylcycloalkyl group having 6 to 12 carbon atoms, an aralkyl group having 7 to 12 carbon atoms or a phenyl group; R.sup.3 and R.sup.6 independently represent a hydrogen atom or an alkyl group having 1 to 8 carbon atoms; X.sub.1 is a dihydric alcohol residue, wherein HO--X.sub.1 --OH defines the corresponding dihydric alcohol from which residue X.sub.1, is obtained; and X.sub.2 is a direct bond or an alkylene group having 1 to 8 carbon atoms; and the phosphites are useful as stabilizers for organic materials.
摘要翻译：由通式（I）表示的亚磷酸酯：表示氢原子，碳原子数1〜8的烷基，碳原子数5〜8的环烷基，碳原子数6〜12的烷基环烷基，芳烷基， 7至12个碳原子或苯基; R3和R6独立地表示氢原子或碳原子数1〜8的烷基。 X1是二元醇残基，其中HO-X1-OH定义得到残留物X1的相应的二元醇; X2是直接键或碳原子数1〜8的亚烷基。亚磷酸酯可用作有机材料的稳定剂。

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