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1. 发明授权

US5767303A Process of producing carbonic diester 失效
标题翻译：生产碳酸二酯的工艺
公开(公告)号：US5767303A
公开(公告)日：1998-06-16
申请号：US876239
申请日：1997-06-16
申请人： Takeshi Minami , Noriyuki Yoneda , Yoshimi Shiroto , Haruto Kobayashi
发明人： Takeshi Minami , Noriyuki Yoneda , Yoshimi Shiroto , Haruto Kobayashi
IPC分类号： B01J31/02 , B01J31/18 , B01J31/40 , C07C68/00
CPC分类号： B01J31/30 , B01J31/0202 , B01J31/0204 , B01J31/0244 , B01J31/181 , B01J31/403 , C07C68/005 , B01J2531/16 , Y02P20/584
摘要： A process for the production of a carbonic diester, wherein an alcohol is reacted in a reaction zone with carbon monoxide and oxygen in the presence of (a) metallic copper or a copper compound, (b) a heterocyclic compound containing one or more nitrogen atoms in the cyclic skeleton and (c) a glycol ether represented by the following formula (I): R.sup.1 O--(CHR.sup.2 --CH.sub.2 O).sub.n --R.sup.3 (I) wherein R.sup.1 stands for an alkyl group having from 1 to 6 carbon atoms, R.sup.2 stands for a hydrogen atom or an alkyl group having 1 or 2 carbon atoms, R.sup.3 stands for a hydrogen atom or an alkyl group having from 1 to 6 carbon atoms and n is an integer of from 1 to 12.
摘要翻译：一种制备碳酸二酯的方法，其中在（a）金属铜或铜化合物存在下，醇在反应区与一氧化碳和氧反应，（b）含有一个或多个氮原子的杂环化合物在环状骨架中，（c）由下式（I）表示的二醇醚：R 1 O-（CHR 2 -CH 2 O）n -R 3（I）其中R 1表示具有1〜6个碳原子的烷基，R 2表示对于氢原子或具有1或2个碳原子的烷基，R 3表示氢原子或具有1至6个碳原子的烷基，n是1至12的整数。

2. 发明授权

US5445955A Immobilization of lipase on a polymer carrier containing epoxy and tertiary amino groups 失效
标题翻译：在含有环氧基和叔氨基的聚合物载体上固定脂肪酶
公开(公告)号：US5445955A
公开(公告)日：1995-08-29
申请号：US65496
申请日：1993-05-24
申请人： Yuzo Ikuta , Satoshi Tashiro , Yoshiyuki Hatano , Tadasu Fujita , Noboru Andoh , Sachio Asaoka , Haruto Kobayashi , Takeshi Minami
发明人： Yuzo Ikuta , Satoshi Tashiro , Yoshiyuki Hatano , Tadasu Fujita , Noboru Andoh , Sachio Asaoka , Haruto Kobayashi , Takeshi Minami
IPC分类号： C12N9/20 , C12N11/08 , C12P7/64 , C12N11/06
CPC分类号： C12P7/6454 , C12N11/08 , C12N9/20 , C12P7/6481
摘要： An immobilized lipase is prepared for transesterification of oils, fats or phospholipids in a reaction system containing a very small amount of water such as 50 to 2,000 ppm. The lipase may be a phospholipase such as phospholipase A.sub.2. In a first embodiment, lipase from a microorganism of the genus Rhizopus, Mucor, Alcaligenes or Candida is immobilized on the surface of a hydrophobic, insoluble organic polymer carrier having pores of an average diameter of 10 nm or larger. A solution of lipase is contacted with the polymer carrier for 10 minutes to 40 hours to covalently bond the lipase to the carrier. The immobilized lipase is dried under reduced pressure to a water content of 0.5 to 30 wt %. In a second embodiment, lipase is immobilized on the surface of a polymer carrier such as a hydrophobic, insoluble organic polymer carrier having a pore diameter of 5 to 1,000 nm and having a functional group capable of binding lipase in a aqueous solution and an anion-exchange group on the surface. Preferably, the functional group is an epoxy group and the anion-exchange group is a tertiary amino group. The lipase may be obtained from the same microorganism as in the first embodiment or from another lipase-producing microorganism. Immobilization can be carried out as in the first embodiment. It is preferred to contact a solution of lipase with the polymer carrier in the presence of a fatty acid or derivative thereof for 10 minutes to 10 hours to covalently bond the lipase to the polymer carrier.
摘要翻译：制备固定化的脂肪酶用于在含有非常少量的水如50-2000ppm的反应体系中对油，脂肪或磷脂进行酯交换反应。脂肪酶可以是磷脂酶如磷脂酶A2。在第一实施方案中，将来自根霉属，毛毛虫，产碱杆菌或假丝酵母属的微生物的脂肪酶固定在具有平均直径为10nm以上的孔的疏水性不溶性有机聚合物载体的表面。将脂肪酶溶液与聚合物载体接触10分钟至40小时，以将脂肪酶共价键合到载体上。将固定化的脂肪酶在减压下干燥至含水量为0.5〜30重量％。在第二实施方案中，将脂肪酶固定在聚合物载体的表面上，例如孔径为5至1000nm的疏水性不溶性有机聚合物载体，并且具有能够在水溶液中结合脂肪酶的官能团和阴离子交换树脂，交流组在表面上。优选地，官能团是环氧基团，阴离子交换基团是叔氨基。脂肪酶可以从与第一实施方案相同的微生物获得，或从另一种脂肪酶生产微生物获得。固定可以如第一实施例那样进行。优选在脂肪酸或其衍生物的存在下将脂肪酶与聚合物载体接触10分钟至10小时以将脂肪酶共价结合到聚合物载体上。

3. 发明授权

US5156877A Protein-rich products of brewer's spent grain origin 失效
标题翻译：啤酒酿造原料的蛋白质丰富产品
公开(公告)号：US5156877A
公开(公告)日：1992-10-20
申请号：US656593
申请日：1991-02-19
申请人： Sohtaroh Kishi , Takashi Kimura , Takeshi Minami , Haruto Kobayashi
发明人： Sohtaroh Kishi , Takashi Kimura , Takeshi Minami , Haruto Kobayashi
IPC分类号： A23K10/38 , A23J1/00 , A23J1/12 , A23J1/16 , A23J3/14 , C12F3/06
CPC分类号： A23J1/12 , A23J1/005
摘要： A protein-rich composition of brewer's spent grain origin is disclosed, which includes products separated from the husks of BSG and which contains 40 to 60% by weight of proteins, 12 to 18% by weight of lipids, 2 to 6% by weight of fibrous materials, and 1 to 4% by weight of ashes based on dry weight.

4. 发明申请

US20090259072A1 METHOD FOR REMOVING IODIDE COMPOUND FROM ORGANIC ACID 有权
标题翻译：从有机酸中除去碘化物的方法
公开(公告)号：US20090259072A1
公开(公告)日：2009-10-15
申请号：US12441476
申请日：2007-06-29
申请人： Yoichi Umehara , Takeshi Minami , Susumu Yamamoto , Haruto Kobayashi , Yasuo Hosono
发明人： Yoichi Umehara , Takeshi Minami , Susumu Yamamoto , Haruto Kobayashi , Yasuo Hosono
IPC分类号： C07C51/42
CPC分类号： C07C51/47 , C07C53/08
摘要： An iodide compound is adsorbed and removed from an organic acid containing the iodide compound as an impurity by passing the organic acid through a packed bed of a cation-exchange resin having silver ion carried thereon at 50° C. or lower. The cation-exchange resin is a macroporous-type resin with an average particle size of 0.3 to 0.6 mm and an average pore size of 15 to 28 nm, and silver ion substitutes for 40 to 60% of the active site.
摘要翻译：通过使有机酸通过其上承载有银离子的阳离子交换树脂的填充床在50℃以下，将含碘化合物的有机酸作为杂质吸附除去碘化物。阳离子交换树脂是平均粒径为0.3〜0.6mm，平均孔径为15〜28nm的大孔型树脂，银离子代替活性部位的40〜60％。

5. 发明授权

US07985878B2 Method for removing iodide compound from organic acid 有权
标题翻译：从有机酸中除去碘化合物的方法
公开(公告)号：US07985878B2
公开(公告)日：2011-07-26
申请号：US12441476
申请日：2007-06-29
申请人： Yoichi Umehara , Takeshi Minami , Susumu Yamamoto , Haruto Kobayashi , Yasuo Hosono
发明人： Yoichi Umehara , Takeshi Minami , Susumu Yamamoto , Haruto Kobayashi , Yasuo Hosono
IPC分类号： C07C51/42
CPC分类号： C07C51/47 , C07C53/08
摘要： An iodide compound is adsorbed and removed from an organic acid containing the iodide compound as an impurity by passing the organic acid through a packed bed of a cation-exchange resin having silver ion carried thereon at 50° C. or lower. The cation-exchange resin is a macroporous-type resin with an average particle size of 0.3 to 0.6 mm and an average pore size of 15 to 28 nm, and silver ion substitutes for 40 to 60% of the active site.
摘要翻译：通过使有机酸通过其上承载有银离子的阳离子交换树脂的填充床在50℃以下，将含碘化合物的有机酸作为杂质吸附除去碘化物。阳离子交换树脂是平均粒径为0.3〜0.6mm，平均孔径为15〜28nm的大孔型树脂，银离子代替活性部位的40〜60％。

6. 发明授权

US5569594A Transesterification with lipase immobilized on a polymer containing epoxy and tertiary amino groups 失效
标题翻译：固定在含有环氧基和叔氨基的聚合物上的脂肪酶进行酯交换
公开(公告)号：US5569594A
公开(公告)日：1996-10-29
申请号：US438921
申请日：1995-05-10
申请人： Yuzo Ikuta , Satoshi Tashiro , Yoshiyuki Hatano , Tadasu Fujita , Noboru Andoh , Sachio Asaoka , Haruto Kobayashi , Takeshi Minami
发明人： Yuzo Ikuta , Satoshi Tashiro , Yoshiyuki Hatano , Tadasu Fujita , Noboru Andoh , Sachio Asaoka , Haruto Kobayashi , Takeshi Minami
IPC分类号： C12N9/20 , C12N11/08 , C12P7/64 , C12N11/06 , C12P7/62
CPC分类号： C12P7/6454 , C12N11/08 , C12N9/20 , C12P7/6481
摘要： Transesterification involving a fat, or a fat and fatty acid, or a phospholipid is carried out with a lipase or phospholipase immobilized on a polymer carrier. The transesterification is preferably carried out in a system containing a very small amount of water such as 50 to 2,000 ppm. The phospholipase can be phospholipase A.sub.2. In a first embodiment, lipase from a microorganism of the genus Rhizopus, Mucor, Alcaligenes or Candida is immobilized on the surface of a hydrophobic, insoluble organic polymer carrier having pores of an average diameter of 10 nm or larger and having on the surface epoxy groups capable of covalently binding lipase. The immobilized lipase is dried under reduced pressure. In a second embodiment, lipase is immobilized on the surface of a polymer carrier such as a hydrophobic, insoluble organic polymer carrier having a pore diameter of 5 to 1,000 nm and having on the surface a functional group capable of binding lipase and an anion-exchange group. Preferably, the functional group is an epoxy group and the anion-exchange group is a tertiary amino group. The lipase may be obtained from the same microorganism as in the first embodiment or from another lipase-producing microorganism. Iramobilization can be carried out as in the first embodiment. It is preferred to contact a solution of lipase with the polymer carrier in the presence of a fatty acid or derivative thereof for 10 minutes to 10 hours to covalently bond the lipase to the polymer carrier.
摘要翻译：涉及脂肪或脂肪和脂肪酸或磷脂的酯交换是用固定在聚合物载体上的脂肪酶或磷脂酶进行的。酯交换优选在含有非常少量的水如50-2000ppm的体系中进行。磷脂酶可以是磷脂酶A2。在第一实施方案中，将来自根霉属，毛霉属，产碱杆菌属或假丝酵母属的微生物的脂肪酶固定在具有平均直径为10nm以上的孔的疏水性不溶性有机聚合物载体的表面，并且在表面具有环氧基能够共价结合脂肪酶。将固定的脂肪酶在减压下干燥。在第二实施方案中，将脂肪酶固定在聚合物载体的表面上，例如孔径为5至1000nm的疏水性不溶性有机聚合物载体，并且在表面上具有能够结合脂肪酶和阴离子交换的官能团组。优选地，官能团是环氧基团，阴离子交换基团是叔氨基。脂肪酶可以从与第一实施方案相同的微生物获得，或从另一种脂肪酶生产微生物获得。可以如第一实施方案那样进行消毒。优选在脂肪酸或其衍生物的存在下将脂肪酶与聚合物载体接触10分钟至10小时以将脂肪酶共价结合到聚合物载体上。

7. 发明授权

US5135765A Process for producing protein-rich product, fibrous product and/or vegetable oil from brewer's spent grain 失效
标题翻译：用于从啤酒花粉中生产富含蛋白质的产品，纤维制品和/或植物油的方法
公开(公告)号：US5135765A
公开(公告)日：1992-08-04
申请号：US437639
申请日：1989-11-16
申请人： Sohtaroh Kishi , Takashi Kimura , Takeshi Minami , Haruto Kobayashi
发明人： Sohtaroh Kishi , Takashi Kimura , Takeshi Minami , Haruto Kobayashi
IPC分类号： C12F3/06 , A23J1/00 , A23J1/12 , A23K1/06 , A23L1/308 , C11B1/04
CPC分类号： A23J1/12 , A23J1/005 , A23K10/38 , A23L33/21 , Y02P60/873
摘要： A process for producing a protein-rich product and/or a fibrous product is disclosed which includes the steps of pressing brewer's spent grain (BSG) in a wet state, and sieving the resulting pressed BSG in the presence of water to thereby separate it into a protein-containing fraction and a fibrous fraction.
摘要翻译：公开了一种生产富含蛋白质的产品和/或纤维制品的方法，该方法包括以下步骤：在潮湿状态下挤压冲泡机的废谷物（BSG），并在水的存在下筛分得到的压制的BSG，从而将其分离成含蛋白质的级分和纤维级分。

8. 发明授权

US4894950A Tree support-construction method 失效
标题翻译：树支撑施工方法
公开(公告)号：US4894950A
公开(公告)日：1990-01-23
申请号：US230889
申请日：1988-08-11
申请人： Kida Yukio , Haruto Kobayashi
发明人： Kida Yukio , Haruto Kobayashi
IPC分类号： A01G17/04 , A01G23/04
CPC分类号： A01G17/04
摘要： A method for positioning and supporting a tree having a tree stem and a rootball is disclosed wherein a hole is formed in a ground surface. Anchors are positioned within the hole. Block fragments are positioned around the tree stem. A securing member is disposed around the block fragments and the tree stem for securing the block fragments to the tree stem. The rootball is positioned within the hole. A tension member is connected to the securing member and the anchors. A tightening member is connected to the tension member for adjusting the tension of the tension member for retaining and tree within the hole. Thereafter, the rootball positioned within the hole is buried.
摘要翻译：公开了一种用于定位和支撑具有树茎和根茎的树的方法，其中在地面中形成有孔。锚定位于孔内。块碎片位于树干周围。在块碎片和树干周围设置固定构件，用于将块状碎片固定在树干上。根孔位于洞内。张紧构件连接到固定构件和锚固件。紧固构件连接到张紧构件，用于调节张紧构件的张力，用于保持和树在孔内。此后，埋置在孔内的根球。

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