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    • 4. 发明授权
    • Manufacturing method of film type battery
    • 薄膜式电池的制造方法
    • US5431701A
    • 1995-07-11
    • US122569
    • 1993-10-01
    • Hiroshi KagawaShiro KatoKazuo Murata
    • Hiroshi KagawaShiro KatoKazuo Murata
    • H01M6/12H01M10/04
    • H01M6/12H01M10/0436Y10T29/49108Y10T29/4911
    • A method for manufacturing a film type battery equipped with a generating element composed of a positive active material, an electrolyte and a negative active material placed one upon another in a layer structure. In order to enable easy mass-production of the film type battery having the above structure, the manufacturing method includes the steps of installing sealing agent layers on a surface of a positive current collector plate and placing the component materials of the generating element i.e. the positive active material, the electrolyte and the negative active material to through holes of the sealing agent layers.
    • PCT No.PCT / JP93 / 00159 Sec。 371日期:1993年10月1日 102(e)日期1993年10月1日PCT提交1993年2月8日PCT公布。 公开号WO93 / 16497 日期:1993年8月19日。一种制造薄膜型电池的方法,该薄膜型电池装备有以层状结构彼此叠置的正极活性材料,电解质和负极活性材料构成的发电元件。 为了能够容易地批量生产具有上述结构的薄膜型电池,该制造方法包括以下步骤:在正极集电板的表面上安装密封剂层,并将发电元件的组分材料置于正极 活性物质,电解质和负极活性物质到密封剂层的通孔。
    • 5. 发明授权
    • Composite polymer electrolyte composition
    • 复合聚合物电解质组成
    • US07732099B2
    • 2010-06-08
    • US10551330
    • 2004-03-15
    • Naoya OgataHiroshi KagawaMakiko Sada
    • Naoya OgataHiroshi KagawaMakiko Sada
    • H01M10/40
    • H01M10/0565H01B1/122H01G9/2009H01M8/0289H01M8/1023H01M8/1039H01M8/1044H01M8/1048H01M8/106H01M8/1072H01M10/0525H01M2300/0082H01M2300/0088Y02E10/542Y02E60/122Y02P70/56
    • A totally solid polymer electrolyte composition with high ionic conductivity and enhanced mechanical properties is provided. This electrolyte composition is produced by polymerizing a monomer composition comprising a molten quaternary ammonium salt having a polymerizable functional group introduced therein and a charge transfer ion source in the presence of a polymeric reinforcing material. The polymeric reinforcing material can be formed into a composite of polymer blend morphology by dissolving the monomer composition and the reinforcing material in an appropriate organic solvent and polymerizing the solution. Alternatively, the composite can be obtained by impregnating a porous sheet or film as the reinforcing material with the monomer composition and effecting polymerization. An electrolyte for lithium ion battery can be obtained by selecting a lithium salt as the charge transfer ion source; an electrolyte for fuel cell by selecting a proton donor; and an electrolyte for dye sensitized solar cell by selecting a redox ion pair. A polymer electrolyte composition not containing the charge transfer ion source is also useful as an electrolyte for electrolytic capacitor.
    • 提供了具有高离子电导率和增强的机械性能的完全固体聚合物电解质组合物。 该电解质组合物通过聚合含有引入其中具有可聚合官能团的熔融季铵盐的单体组合物和在聚合物增强材料存在下的电荷转移离子源来制备。 通过将单体组合物和增强材料溶解在合适的有机溶剂中并使溶液聚合,可以将聚合物增强材料形成为聚合物共混物形态的复合材料。 或者,可以通过用单体组合物浸渍多孔片材或膜作为增强材料并进行聚合来获得复合材料。 可以通过选择锂盐作为电荷转移离子源来获得用于锂离子电池的电解质; 用于选择质子供体的燃料电池用电解质; 以及通过选择氧化还原离子对的染料敏化太阳能电池的电解质。 不含电荷转移离子源的聚合物电解质组合物也可用作电解电容器的电解质。
    • 6. 发明申请
    • Composite polymer electrolyte composition
    • 复合聚合物电解质组成
    • US20060057465A1
    • 2006-03-16
    • US10551330
    • 2004-03-15
    • Naoya OgataHiroshi KagawaMakiko Sada
    • Naoya OgataHiroshi KagawaMakiko Sada
    • H01M10/40H01M6/18H01M8/10
    • H01M10/0565H01B1/122H01G9/2009H01M8/0289H01M8/1023H01M8/1039H01M8/1044H01M8/1048H01M8/106H01M8/1072H01M10/0525H01M2300/0082H01M2300/0088Y02E10/542Y02E60/122Y02P70/56
    • A totally solid polymer electrolyte composition with high ionic conductivity and enhanced mechanical properties is provided. This electrolyte composition is produced by polymerizing a monomer composition comprising a molten quaternary ammonium salt having a polymerizable functional group introduced therein and a charge transfer ion source in the presence of a polymeric reinforcing material. The polymeric reinforcing material can be formed into a composite of polymer blend morphology by dissolving the monomer composition and the reinforcing material in an appropriate organic solvent and polymerizing the solution. Alternatively, the composite can be obtained by impregnating, a porous sheet or film as the reinforcing material with the monomer composition and effecting polymerization. An electrolyte for lithium ion battery can be obtained by selecting a lithium salt as the charge transfer ion source; an electrolyte for fuel cell by selecting a proton donor; and an electrolyte for dye sensitized solar cell by selecting a redox ion pair. A polymer electrolyte composition not containing the charge transfer ion source is also useful as an electrolyte for electrolytic capacitor.
    • 提供了具有高离子电导率和增强的机械性能的完全固体聚合物电解质组合物。 该电解质组合物通过聚合含有引入其中具有可聚合官能团的熔融季铵盐的单体组合物和在聚合物增强材料存在下的电荷转移离子源来制备。 通过将单体组合物和增强材料溶解在合适的有机溶剂中并使溶液聚合,可以将聚合物增强材料形成为聚合物共混物形态的复合材料。 或者,可以通过用单体组合物浸渍多孔片材或膜作为增强材料并进行聚合来获得复合材料。 可以通过选择锂盐作为电荷转移离子源来获得用于锂离子电池的电解质; 用于选择质子供体的燃料电池用电解质; 以及通过选择氧化还原离子对的染料敏化太阳能电池的电解质。 不含电荷转移离子源的聚合物电解质组合物也可用作电解电容器的电解质。
    • 8. 发明授权
    • Film type battery and layer-built film type battery
    • 薄膜式电池和层压膜式电池
    • US5401595A
    • 1995-03-28
    • US87682
    • 1993-07-08
    • Hiroshi KagawaShiro KatoKazuo Murata
    • Hiroshi KagawaShiro KatoKazuo Murata
    • H01M2/02H01M2/22H01M2/34H01M6/12H01M6/18H01M6/46H01M6/50H01M2/26
    • H01M2/348H01M2/0212H01M2/22H01M2/34H01M6/12H01M6/46H01M6/5038H01M6/181
    • A film type battery including a positive current collector plate, a positive active material, electrolytes, a negative active material and a negative current collector plate laminated into a layer structure, wherein the positive active material, the negative active material and the electrolytes are peripherally sealed, the positive current collector plate and the negative current collector plate are integrated by sealing agents, a portion of the positive current collector plate and a portion of the negative current collector plate are not contacted by the active material, the electrolytes or the sealing agents, a positive terminal piece is fitted to the positive current collector plate at a side of the layer structure and a negative terminal piece is fitted to the negative current collector plate at the side of the layer structure.
    • PCT No.PCT / JP92 / 01577 Sec。 371日期:1993年7月8日 102(e)日期1993年7月8日PCT提交1992年12月2日PCT公布。 公开号WO93 / 11572 日期:1993年6月10日。一种薄膜型电池,其包括层叠成层状结构的正极集电板,正极活性物质,电解质,负极活性物质和负极集电板,其中所述正极活性物质,所述负极活性物质 材料和电解质外围密封,正极集电板和负极集电板通过密封剂一体化,正极集电板的一部分和负极集电板的一部分不与活性材料接触, 电解质或密封剂,正极端子装配在层状结构侧的正极集电板上,负极端子嵌入在层状结构侧的负极集电板上。
    • 9. 发明授权
    • Sodium-sulfur storage battery and a manufacturing method of the same
    • 钠硫蓄电池及其制造方法
    • US4627996A
    • 1986-12-09
    • US792742
    • 1985-10-30
    • Hiroshi Kagawa
    • Hiroshi Kagawa
    • H01M2/04H01M2/08H01M10/39H01M10/00B32B3/06
    • H01M2/08H01M10/3909H01M2/0447Y10T428/2405
    • A manufacturing method of a sodium-sulfur storage battery wherein a negative cover is thermocompressively jointed to an upper surface of an alpha alumina ring which are jointed with solder glass to a solid electrolyte tube, and a positive cover is thermocompressively jointed to a lower surface of said alpha alumina ring, is characterized in that diffusion layers of chrome are provided on the surfaces of the negative and positive covers, coating layers of aluminum are provided at least on the surfaces, which are thermocompressively jointed, of the negative and positive covers, and thermocompressively jointing surfaces are thermocompressively jointed in the air with aluminum rings thereon, respectively. Said negative and positive covers may be made from stainless steel, iron or alloy of iron and nickel. Said chrome diffusion layers may be about 20.mu.-120.mu. in thickness, respectively, and said aluminum layers may be about 5.mu.-90.mu. in thickness, respectively.
    • 一种钠 - 硫蓄电池的制造方法,其中将负极盖热压连接到与焊料玻璃接合到固体电解质管的α氧化铝环的上表面上,并将正极盖热压接合到 所述α氧化铝环的特征在于,在负极和正极盖的表面上设置有铬的扩散层,至少在负极和正极盖的热压接合表面上提供铝的涂层,以及 热空气接合表面分别与空气中的铝环热压接合。 所述负极和正极盖可以由不锈钢,铁或铁和镍的合金制成。 所述铬扩散层的厚度可以分别为约20μm〜120μm,所述铝层的厚度分别为约5〜90μm。
    • 10. 发明授权
    • Sodium-sulfur storage battery
    • 钠硫蓄电池
    • US4615957A
    • 1986-10-07
    • US724989
    • 1985-04-19
    • Hiroshi Kagawa
    • Hiroshi Kagawa
    • H01M4/66H01M10/39
    • H01M4/661H01M10/3909H01M4/66H01M4/663
    • The present disclosure describes a sodium-sulfur storage battery comprising a sodium-ion conductive solid electrolyte tube; a positive electroconductive material consisting of graphite felt or carbon felt, and a metal sulfide layer disposed between the solid electrolyte tube and the positive electro-conductive material. Said metal sulfide layer may be sulfurated metal such as aluminum, nickel, copper, iron, tin, zinc, lead, magnesium and chrome. A metal member may be disposed between the solid electrolyte tube and the positive electroconductive material to form said metal sulfide layer by a sulfurated part formed at least at the surface of said metal member.
    • 本公开内容描述了包含钠离子导电固体电解质管的钠硫蓄电池; 由石墨毡或碳毡组成的正导电材料和设置在固体电解质管和正导电材料之间的金属硫化物层。 所述金属硫化物层可以是诸如铝,镍,铜,铁,锡,锌,铅,镁和铬的硫化金属。 金属构件可以设置在固体电解质管和正导电材料之间,以通过至少在所述金属构件的表面形成的硫化部分形成所述金属硫化物层。